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NASA NTRS1993

Lunar soils grain size catalog

This catalog compiles every available grain size distribution for Apollo surface soils, trench samples, cores, and Luna 24 soils. Original laboratory data are tabled, and cumulative weight distribution curves and histograms are plotted. Standard statistical parameters are calculated using the method of moments. Photos and location comments describe the sample environment and geological setting. This catalog can help researchers describe the geotechnical conditions and site variability of the lunar surface essential to the design of a lunar base.

Graf, John C.↗
NASA NTRS2007

Piloted Ignition to Flaming in Smoldering Fire-Retarded Polyurethane Foam

Experimental results are presented on the piloted transition from smoldering to flaming in the fire-retarded polyurethane foam Pyrell . The samples are small rectangular blocks with a square cross section, vertically placed in the wall of a vertical wind tunnel. Three of the vertical sample sides are insulated and the fourth side is exposed to an upward oxidizer flow of variable oxygen concentration and to a variable radiant heat flux. The gases emitted from the smoldering reaction pass upwards through a pilot, which consists of a coiled resistance heating wire. In order to compensate for the solid-phase and gas-phase effects of the fire retardants on the piloted transition from smoldering to flaming in Pyrell, it was necessary to assist the process by increasing the power supplied to the smolder igniter and the pilot (compared to that used for non-fire retarded foam). The experiments indicate that the piloted transition from smoldering to flaming occurs when the gaseous mixture at the pilot passes the lean flammability limit. It was found that increasing the oxygen concentration or the external heat flux increases the likelihood of a piloted transition from smoldering to flaming, and generally decreases the time delay to transition. The piloted transition to flaming is observed in oxygen concentrations of 23% and above in both low-density and high-density Pyrell. Comparisons with previous experiments show that the piloted transition from smoldering to flaming is possible under a wider range of external conditions (i.e. lower oxygen concentration) than the spontaneous transition from smoldering to flaming. The results show that the fire retardants in Pyrell are very effective in preventing the piloted transition to flaming in normal air, but Pyrell is susceptible to smoldering and the piloted transition to flaming in oxygen-enriched environments. Therefore, precautions should be taken in the design of applications of Pyrell in oxygen-enriched environments to reduce to the risk of a piloted transition to flaming.

Putzeys, O.↗
NASA NTRS2012

SWOT: The Surface Water and Ocean Topography Mission. Wide- Swath Altimetric Elevation on Earth

The elevation of the surface of the ocean and freshwater bodies on land holds key information on many important processes of the Earth System. The elevation of the ocean surface, called ocean surface topography, has been measured by conventional nadirlooking radar altimeter for the past two decades. The data collected have been used for the study of large-scale circulation and sea level change. However, the spatial resolution of the observations has limited the study to scales larger than about 200 km, leaving the smaller scales containing substantial kinetic energy of ocean circulation that is responsible for the flux of heat, dissolved gas and nutrients between the upper and the deep ocean. This flux is important to the understanding of the ocean's role in regulatingfuture climate change.The elevation of the water bodies on land is a key parameter required for the computation of storage and discharge of freshwater in rivers, lakes, and wetlands. Globally, the spatial and temporal variability of water storage and discharge is poorly known due to the lack of well-sampled observations. In situ networks measuring river flows are declining worldwide due to economic and political reasons. Conventional altimeter observations suffers from the complexity of multiple peaks caused by the reflections from water, vegetation canopy and rough topography, resulting in much less valid data over land than over the ocean. Another major limitation is the large inter track distance preventing good coverage of rivers and other water bodies.This document provides descriptions of a new measurement technique using radar interferometry to obtain wide-swath measurement of water elevation at high resolution over both the ocean and land. Making this type of measurement, which addresses the shortcomings of conventional altimetry in both oceanographic and hydrologic applications, is the objective of a mission concept called Surface Water and Ocean Topography (SWOT), which was recommended by the National Research Council's first decadal survey of NASA's Earth science program. This document provides wide-ranging examples of research opportunities in oceanography and land hydrology that would be enabled by the new type of measurement. Additional applications in many other branches of Earth System science ranging from ocean bathymetry to sea ice dynamics are also discussed. Many of the technical issues in making the measurement are discussed as well. Also presented is a preliminary design of the SWOT Mission concept, which is being jointly developed by NASA and CNES, with contributions from the Canadian Space Agency.

altimetry↗
NASA NTRS2014

Noble Gases in Two Fragments of Different Lithologies from the Almahata Sitta Meteorite

The Almahata Sitta meteorite, whose preat-mospheric body was the asteroid 2008 TC3, fell on October 7, 2008 in the Nubian Desert in northern Sudan [e.g., 1, 2]. Numer-ous fragments have been recovered during several expeditions organized from December 2008 [2]. The meteorite was classified as an anomalous polymict ureilite with several different kinds of chondritic fragments [e.g., 3-5]. Noble gas studies performed on several fragments from the meteorite showed cosmic-ray expo-sure ages of about 20 My [e.g., 6-8], although slightly shorter ages were also reported in [9, 10]. Concentrations of trapped heavy noble gases are variable among the fragments of different lithologies [9, 10]. We report noble gas data on two samples from the #1 and #47 fragments [2], which were the same as those re-ported by Ott et al. [9]. Experimental Procedure: Weights of bulk samples #1 and #47 used in this work were 16.1 mg and 17.6 mg, respectively. Noble gases were extracted by stepwise heating at the tempera-tures of 800, 1200 and 1800˚C for #1 and 600, 800, 1000, 1200, 1400, 1600 and 1800˚C for #47. Concentrations and isotopic ra-tios of noble gases were measured with a modified-VG5400/MS-III at the Geochemical Research Center, University of Tokyo. Results and Discussion: Cosmogenic He and Ne are domi-nant in both #1 and #47, but trapped Ar, Kr and Xe concentra-tions are much higher in #47 than in #1, showing that noble gas compositions in #47 are similar to those of ureilites. 3He/21Ne and 22Ne/21Ne of cosmogenic He and Ne are 4.8 and 1.12 for #1 and 3.6 and 1.06 for #47, respectively, both of which plot on a Bern line [11]. This indicates negligible loss of cosmogenic 3He from #1 in our sample, unlike the low 3He/21Ne of 3.1 for #1 by Ott et al. [9]. Concentrations of cosmogenic 3He and 21Ne (10-8 cc/g) are 30 and 6.3 for #1 and 32 and 9.0 for #47, respectively, which are higher than those in [9] and give cosmic-ray exposure ages of ca. 20 My depending on assumed production rates. Rela-tive abundances of trapped 36Ar, 84Kr and 132Xe for #1 resemble those of Q-component, which is a dominant trapped noble gas component in chondrites. In contrast to #1, #47 plots below a trend for ureilites [12] as well as Q, which implies a partial loss of trapped 36Ar from the lithology of #47.

Nagao, K.↗
NASA NTRS2015

A Framework for Orbital Performance Evaluation in Distributed Space Missions for Earth Observation

Distributed Space Missions (DSMs) are gaining momentum in their application to earth science missions owing to their unique ability to increase observation sampling in spatial, spectral and temporal dimensions simultaneously. DSM architectures have a large number of design variables and since they are expected to increase mission flexibility, scalability, evolvability and robustness, their design is a complex problem with many variables and objectives affecting performance. There are very few open-access tools available to explore the tradespace of variables which allow performance assessment and are easy to plug into science goals, and therefore select the most optimal design. This paper presents a software tool developed on the MATLAB engine interfacing with STK, for DSM orbit design and selection. It is capable of generating thousands of homogeneous constellation or formation flight architectures based on pre-defined design variable ranges and sizing those architectures in terms of predefined performance metrics. The metrics can be input into observing system simulation experiments, as available from the science teams, allowing dynamic coupling of science and engineering designs. Design variables include but are not restricted to constellation type, formation flight type, FOV of instrument, altitude and inclination of chief orbits, differential orbital elements, leader satellites, latitudes or regions of interest, planes and satellite numbers. Intermediate performance metrics include angular coverage, number of accesses, revisit coverage, access deterioration over time at every point of the Earth's grid. The orbit design process can be streamlined and variables more bounded along the way, owing to the availability of low fidelity and low complexity models such as corrected HCW equations up to high precision STK models with J2 and drag. The tool can thus help any scientist or program manager select pre-Phase A, Pareto optimal DSM designs for a variety of science goals without having to delve into the details of the engineering design process.

Earth Science↗
NASA NTRS2018

Representativeness of CO and O3 Along ATom Transects Derived from GEOS-5 and GMI-CTM Simulations

One major goal for the NASA Atmospheric Tomography Mission (ATom) is producing an observation-based chemical climatology to represent the atmospheric heterogeneity. In this study, we use CO and O3 observations and global atmospheric model simulations to examine the spatial representativeness of the ATom-1 and -2 transects within a 4D framework provided by the NASA GEOS-5 and GMI-CTM models. Based on the probability density functions, we find that the variability of CO and O3 along the flight tracks is well hindcast by the model when sampled per ATom flights. The CO variations along the ATom-transect are likely representative of the typical CO variations over the whole Pacific basin during both the ATom-1 and -2 periods, the northern Atlantic during the ATom-1 period, and the tropical Atlantic in the ATom-2 period. Over southern Atlantic, CO along the ATom-1 transects is likely less well mixed than that of the broader region, but is still representative of the median CO concentration. CO along the ATom-2 transect is likely higher than the median CO concentration over this region. For O3, the agreements between PDFs of O3 sampled along the ATom transects and over the broader regions are fair to good over all six regions (Scores > 0.65) with notable discrepancies over some regions. For example, in ATom-1 over the northern Pacific and Atlantic, the transect samples air masses with higher O3 levels. During ATom-2, the transect over-represents the occurrence of O3 plumes over tropical Pacific. Over the southern Pacific and Atlantic for both ATom-1 and -2, the transects have a less uniform distribution compared to the surrounding basins, but still represent the median O3 abundance. Overall, we conclude in most cases that ATom measurements represent the statistical variations of these two species over the ocean basins at the time of measurement. Higher-order statistics, including covariance of species, has not been tested in this study.

ozone↗
NASA NTRS2019

The New NASA Ames Infrared Optical Constant Facility. Determinations for Titan Aerosol-, and Exoplanet and Brown Dwarf Cloud Particle Analogs

Here we present a new optical constant facility developed at NASA Ames that will allow the determination of optical constants in the infrared of various materials, analogs of hazes and cloud particles in (exo)planet atmospheres and brown dwarfs. Our facility is composed of a Fourier Transform Infrared (FTIR) spectrometer continuously covering the Near-IR, mid-IR and Far-IR range (from 0.74 to 200 µm), coupled to variable angle transmittance and reflectance accessories that allow the characterization of the scattering properties of nonhomogeneous samples (laboratory planetary aerosol analogs, films, slabs of material, crystals, powders...) over a wide incidence and emittance angle range (0-90 degrees). This permits the angular light distribution in both transmission and reflection measurements to be characterized, enabling the determination of the complex indices of refraction, n and k, over the full NIR-FIR range via modeling of the laboratory observations. The resulting refractive indices are critical input parameters in radiative transfer models, exoplanet and brown dwarf cloud models, protoplanetary disk simulations and other models used for the interpretation of observational data from past, current and future (exo)planetary NASA missions. We will present preliminary data obtained on Titan aerosol analogs produced in the Titan Haze Simulation (THS) experiment on COSmIC, a unique experimental platform developed at NASA Ames that allows the simulation of Titan's complex atmospheric chemistry at Titan-like temperature (200 K). We will also introduce a new study of the optical properties of ammonium-bearing phosphates, potential cloud particles forming in temperate exoplanets and brown dwarfs.

Planetary Science↗
NASA NTRS2019

Numerical Investigation and Optimization of a Flushwall Injector for Scramjet Applications at Hypervelocity Flow Conditions

An investigation utilizing Reynolds-averaged simulations (RAS) was performed in order to find optimal designs for an interdigitated flushwall injector suitable for scramjet applications at hypervelocity conditions. The flight Mach number, duct height, spanwise width, and injection angle were the design variables selected to maximize two objective functions: the thrust potential and combustion efficiency. A Latin hypercube sampling design-of-experiments method was used to select design points for RAS. A methodology was developed that automated building geometries and generating grids for each design. The ensuing RAS analysis generated the performance database from which the two objective functions of interest were computed using a one-dimensional performance utility. The data were fitted using four surrogate models: an artificial neural network (ANN) model, a cubic polynomial, a quadratic polynomial, and a Kriging model. Variance-based decomposition showed that both objective functions were primarily driven by changes in the duct height. Multiobjective design optimization was performed for all four surrogate models via a genetic algorithm method. Optimal solutions were obtained at the upper and lower bounds of the flight Mach number range. The Kriging model obtained an optimal solution set that predicted high values for both objective functions. Additionally, three challenge points were selected to assess the designs on the Pareto fronts. Further sampling among the designs of the Pareto fronts are required in order to lower the errors and perform more accurate surrogate-based optimization. sed optimization.

Shenoy, Rajiv R.↗
DOE OSTI2019

Power-Law Scaling in the Internal Variability of Cumulus Cloud Size Distributions due to Subsampling and Spatial Organization

In this study, the spatial structure of cumulus cloud populations is investigated using three-dimensional snapshots from large-domain LES experiments. The aim is to understand and quantify the internal variability in cloud size distributions due to subsampling effects and spatial organization. A set of idealized shallow cumulus cases is selected with varying degrees of spatial organization, including a slowly organizing marine precipitating case and five more quickly organizing diurnal cases over land. A subdomain analysis is applied, yielding cloud number distributions at sample sizes ranging from severely undersampled to nearly complete. A strong power-law scaling is found in the relation between cloud number variability and subdomain size, reflecting an inverse linear relation. Scaling subdomain size by cloud size yields a data collapse across time points and cases, highlighting the role played by cloud spacing in controlling the stochastic variability. Spatial organization acts on top of this baseline model by increasing the maximum cloud size and by enhancing the variability in the number of smallest clouds. This reflects that the smaller clouds start to live on top of larger-scale thermodynamic structures, such as cold pools, which favor or inhibit their formation. Compositing all continental cumulus cases suggests the existence of a prototype diurnal time dependence in the spatial organization. A simple stochastic expression for cloud number variability is proposed that is formulated in terms of two dimensionless groups, which allows objective estimation of the degree of spatial organization in simulated and observed cumulus cloud populations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Process Development of the Vaporizing Foil Actuator Welding Technique

The industrial focus on continuous improvement for products is leading design engineers to consider multi-material design concepts more frequently. The design concepts use the advantages of each material while simultaneously minimizing the drawbacks. It also allows for the overall weight of the products to be reduced. Some traditional joining methods, though, struggle to join dissimilar material combinations. A technique known as vaporizing foil actuator welding, which was developed around ten years ago, is a solid-state joining method that has the potential to overcome the barriers to dissimilar material joining. The biggest drawbacks of vaporizing foil actuator welding are that it is still exclusively used in laboratory settings and early in the technology development process. As such, there is not enough confidence in the process for it to be transitioned to manufacturing environments yet. This work begins by analyzing the current state of the technology and identifying a roadmap to achieve a transition to manufacturing. The analysis found that increased confidence in the technology requires sample to sample repeatability to be improved. Beyond that, the process also needs to be fully automated before it can be considered as a viable technique for mass production. In order to further develop the technique, a fully automated work cell was constructed. By removing the human element from the process, this cell helped identify iii the aspects which contribute to process variability. The positioning of the vaporizing foil actuator was identified as the most important factor in process stability. A small set of samples were made in the automated cell with the addition of one component epoxy adhesive around the perimeter of the weld. These samples showed improved process repeatability compared with the samples made without adhesive. This indicates that small amounts of adhesive may be critical in using the process in industrial settings. Additionally, work was performed with manual positioning and adhesive dispensing. This work found that a hybrid joint behaves like traditional weld bonding, where the addition of adhesive makes the joint stronger than if either of the two joining methods were used on their own. To realize this performance with vaporizing foil actuator welding, though, the adhesive needs to be protected from burning during the rapid compression of air during the impact process.

36 MATERIALS SCIENCE↗
NASA NTRS1971

A variable-step-size robust delta modulator.

Description of an analytically obtained optimum adaptive delta modulator-demodulator configuration. The device utilizes two past samples to obtain a step size which minimizes the mean square error for a Markov-Gaussian source. The optimum system is compared, using computer simulations, with a linear delta modulator and an enhanced Abate delta modulator. In addition, the performance is compared to the rate distortion bound for a Markov source. It is shown that the optimum delta modulator is neither quantization nor slope-overload limited. The highly nonlinear equations obtained for the optimum transmitter and receiver are approximated by piecewise-linear equations in order to obtain system equations which can be transformed into hardware. The derivation of the experimental system is presented.

Song, C. L.↗
DOE OSTI2017

Impact of microstructure on the thermoelectric properties of the ternary compound Ce{sub 3}Cu{sub 3}Sb{sub 4}

We present detailed structural and thermoelectric studies of the ternary compound Ce{sub 3}Cu{sub 3}Sb{sub 4}. This material is of interest due to previously reported considerable thermopower above room temperature (∼ 100 μV/K) and low thermal conductivity (2 W/(m K)). Here, we present detailed studies concerning microstructural and thermoelectric data, their variation across the samples and possible explanations for the observed behaviour. We have used X-ray diffraction, scanning electron microscopy (SEM), and time-of-flight secondary ion mass spectrometry (TOF-SIMS) for microstructural analysis. The thermoelectric properties were examined using a physical property measurement system (PPMS). We analyse the impact of the sample quality on the thermoelectric properties. The most unstable parameter is the material resistivity which varies between 1.5 and 15 mΩ cm at room temperature. The properties variability is mainly due to structural defects caused by stresses during material preparation and also due to formation of foreign phases CeCuSb{sub 2} and CeSb. The figure of merit ZT is also strongly dependent on the quality of the sample. The largest value ZT ≈ 0.15 at 400 K is determined for the almost stoichiometric sample with small amounts of a impurity phases. - Highlights: •The Ce{sub 3}Cu{sub 3}Sb{sub 4} has considerable thermoelectric properties and potential for further chemical and/or structural modification. •The control over foreign phases formation is challenging. •The defects arising during arc melting process highly deteriorate ZT of material.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Propagating Mixed Uncertainties in Cyber Attacker Payoffs: Exploration of Two-Phase Monte Carlo Sampling and Probability Bounds Analysis

Securing cyber-systems on a continual basis against a multitude of adverse events is a challenging undertaking. Game-theoretic approaches, that model actions of strategic decision-makers, are increasingly being applied to address cybersecurity resource allocation challenges. Such game-based models account for multiple player actions and represent cyber attacker payoffs mostly as point utility estimates. Since a cyber-attacker’s payoff generation mechanism is largely unknown, appropriate representation and propagation of uncertainty is a critical task. In this paper we expand on prior work and focus on operationalizing the probabilistic uncertainty quantification framework, for a notional cyber system, through: 1) representation of uncertain attacker and system-related modeling variables as probability distributions and mathematical intervals, and 2) exploration of uncertainty propagation techniques including two-phase Monte Carlo sampling and probability bounds analysis.

cyber security↗
DOE OSTI2016

Oak ridge national laboratory automated clean chemistry for bulk analysis of environmental swipe samples

To shorten the lengthy and costly manual chemical purification procedures, sample preparation methods for mass spectrometry are being automated using commercial-off-the-shelf (COTS) equipment. This addresses a serious need in the nuclear safeguards community to debottleneck the separation of U and Pu in environmental samples—currently performed by overburdened chemists—with a method that allows unattended, overnight operation. In collaboration with Elemental Scientific Inc., the prepFAST-MC2 was designed based on current COTS equipment that was modified for U/Pu separations utilizing Eichrom™ TEVA and UTEVA resins. Initial verification of individual columns yielded small elution volumes with consistent elution profiles and good recovery. Combined column calibration demonstrated ample separation without crosscontamination of the eluent. Automated packing and unpacking of the built-in columns initially showed >15% deviation in resin loading by weight, which can lead to inconsistent separations. Optimization of the packing and unpacking methods led to a reduction in the variability of the packed resin to less than 5% daily. The reproducibility of the automated system was tested with samples containing 30 ng U and 15 pg Pu, which were separated in a series with alternating reagent blanks. These experiments showed very good washout of both the resin and the sample from the columns as evidenced by low blank values. Analysis of the major and minor isotope ratios for U and Pu provided values well within data quality limits for the International Atomic Energy Agency. Additionally, system process blanks spiked with 233U and 244Pu tracers were separated using the automated system after it was moved outside of a clean room and yielded levels equivalent to clean room blanks, confirming that the system can produce high quality results without the need for expensive clean room infrastructure. Comparison of the amount of personnel time necessary for successful manual vs. automated chemical separations showed a significant decrease in hands-on time from 9.8 hours to 35 minutes for seven samples, respectively. This documented time savings and reduced labor translates to a significant cost savings per sample. Overall, the system will enable faster sample reporting times at reduced costs by limiting personnel hours dedicated to the chemical separation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2013

X-ray View of Four High-Luminosity Swift-BAT AGN: Unveiling Obscuration and Reflection with Suzaku

Aims. A complete census of obscured Active Galactic Nuclei (AGN) is necessary to reveal the history of the super massive black hole (SMBH) growth and galaxy evolution in the Universe given the complex feedback processes and the fact that much of this growth occurs in an obscured phase. In this context, hard X-ray surveys and dedicated follow-up observations represent a unique tool for selecting highly absorbed AGN and for characterizing the obscuring matter surrounding the SMBH. Here we focus on the absorption and reflection occurring in highly luminous, quasar-like AGN, to study the relation between the geometry of the absorbing matter and the AGN nature (e.g. X-ray, optical, and radio properties), and to help to determine the column density dependency on the AGN luminosity. Methods. The Swift/BAT nine-month survey observed 153 AGN, all with ultra-hard X-ray BAT fluxes in excess of 10(exp −11) erg per square centimeter and an average redshift of 0.03. Among them, four of the most luminous BAT AGN (44.73 less than LogLBAT less than 45.31) were selected as targets of Suzaku follow-up observations: J2246.0+3941 (3C 452), J0407.4+0339 (3C 105), J0318.7+6828, and J0918.5+0425. The column density, scattered/reflected emission, the properties of the Fe K line, and a possible variability are fully analyzed. For the latter, the spectral properties from Chandra, XMM-Newton and Swift/XRT public observations were compared with the present Suzaku analysis, adding an original spectral analysis when non was available from the literature. Results. Of our sample, 3C 452 is the only certain Compton-thick AGN candidate because of i) the high absorption (N(sub H) approximately 4 × 10(exp 23) per square centimeter) and strong Compton reflection; ii) the lack of variability; iii) the "buried" nature, i.e. the low scattering fraction (less than 0.5%) and the extremely low relative [OIII] luminosity. In contrast 3C 105 is not reflection-dominated, despite the comparable column density, X-ray luminosity and radio morphology, but shows a strong long-term variability in flux and scattering fraction, consistent with the soft emission being scattered from a distant region (e.g., the narrow emission line region). The sample presents high (greater than 100) X-to- [OIII] luminosity ratios, with an extreme value of R(sup X)(sub [OIII]) approximately 800 for 3C 452, confirming the [OIII] luminosity to be affected by residual extinction in presence of mild absorption, especially for "buried" AGN such as 3C 452. Three of our targets are powerful FRII radio galaxies, which is shown by their high luminosity and absorption; this makes them the most luminous and absorbed AGN of the BAT Seyfert survey despite the inversely proportional N(sub H) - L(sub X) relation.

SwiftBAG AGN↗
NASA NTRS2019

The Ability of GeoCarb to Constrain the Interannual Variability of Carbon Gases over the Amazon

We perform a number of idealized assimilation experiments with the GEOS constituent data assimilation system to test the ability of GeoCarb retrievals of CO, CO2, and CH4 to constrain the interannual variability of these gases over the Amazon. Retrievals for instruments on other satellites which observe in similar channels (e.g. MOPITT, GOSAT, and OCO-2) are limited due to persistent cloud coverage. Given its ability to sample the same location multiple times in one day, the expectation is that GeoCarb retrievals will return more soundings than those from previous missions. The goal of the assimilation experiments is to understand which scanning strategies lead to the best sounding densities and thus have the best chance of constraining interannual variability in the carbon species. The experiments each begin by picking a given year at random from a nature run (i.e., a model simulation meant to represent the truth). The model fields are sampled according to a given strategy and then screened to account for cloud coverage. Next, we pick another year at random and assimilate the synthetic GeoCarb samples into the GEOS model for that year. The output of the assimilation, 6-hourly, 3D fields of each constituent, is then directly comparable to the nature run. This comparison allows us to evaluate the ability of GeoCarb measurements to constrain the interannual variability of each gas.

Weir, B.↗
NASA NTRS1995

Reflectance spectroscopy of ferric sulfate-bearing montmorillonites as Mars soil analog materials

Spectroscopic analyses have shown that smectites enhanced in the laboratory with additional ferric species exhibit important similarities to those of the soils on Mars. Ferrihydrite in these chemically treated smectites has features in the visible to near-infrared region that resemble the energies and band strengths of features in reflectance spectra observed for several bright regions on Mars. New samples have been prepared with sulfate as well, because S was found by Viking to be a major component in the surface material on Mars. A suite of ferrihydrite-bearing and ferric sulfate-bearing montmorillonites, prepared with variable Fe3+ and S concentrations and variable pH conditions, has been analyzed using reflectance spectroscopy in the visible and infrared regions, Mossbauer spectroscopy at room temperature and 4 K, differential thermal analysis, and X-ray diffraction. These analyses support the formation of ferrihydrite of variable crystallinity in the ferrihydrite-bearing montmorillonites and a combination of schwertmannite and ferrihydrite in the ferric sulfate-bearing montmorillonites. Small quantities of poorly crystalline or nanophase forms of other ferric materials may also be present in these samples. The chemical formation conditions of the ferrihydrite-bearing and ferric sulfate-bearing montmorillonites influence the character of the low temperature Mossbauer sextets and the visible reflectance spectra. An absorption minimum is observed at 0.88-0.89 micrometers in spectra of the ferric sulfate-bearing samples, and at 0.89-0.92 micrometers in spectra of the ferrihydrate-bearing montmorillonites. Mossbauer spectra of the ferric sulfate-bearing montmorillonites indicate variable concentrations of ferrihydrite and schwertmannite in the interlaminar spaces and along grain surfaces. Dehydration under reduced atmospheric pressure conditions induces a greater effect on the adsorbed and interlayer water in ferrihydrite-bearing montmorillonite than on the water in ferric sulfate-bearing montmorillonite. Reflectance spectra of ferric sulfate-bearing montmorillonite include a strong 3-micrometers band that is more resistant to dry atmospheric conditions than the 3-micrometers band in spectra of similarly prepared ferrihydrite-bearing montmorillonites.

NASA Discipline Exobiology↗
DOE OSTI2019

Duality between ( 2 + 1 ) d quantum critical points

We describe the simulated data sample for the “Photometric LSST Astronomical Time Series Classi-fication Challenge” (PLAsTiCC), a publicly available challenge to classify transient and variable eventsthat will be observed by the Large Synoptic Survey Telescope (LSST), a new facility expected tostart in the early 2020s. The challenge was hosted by Kaggle, ran from 2018 September 28 to 2018December 17, and included 1,094 teams competing for prizes. Here we provide details of the 18 tran-sient and variable source models, which were not revealed until after the challenge, and release themodel libraries athttps://doi.org/10.5281/zenodo.2612896. We describe the LSST OperationsSimulator used to predict realistic observing conditions, and we describe the publicly availableSNANAsimulation code used to transform the models into observed fluxes and uncertainties in the LSSTpassbands (ugrizy). AlthoughPLAsTiCChas finished, the publicly available models and simulationtools are being used within the astronomy community to further improve classification, and to studycontamination in photometrically identified samples of type Ia supernova used to measure propertiesof dark energy. Our simulation framework will continue serving as a platform to improve thePLAsTiCCmodels, and to develop new models.

Senthil, T.↗