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At least 1,477 records · Page 82

Numerical experiments with model monophyletic and paraphyletic taxa

The problem of how accurately paraphyletic taxa versus monophyletic (i.e., holophyletic) groups (clades) capture underlying species patterns of diversity and extinction is explored with Monte Carlo simulations. Phylogenies are modeled as stochastic trees. Paraphyletic taxa are defined in an arbitrary manner by randomly choosing progenitors and clustering all descendants not belonging to other taxa. These taxa are then examined to determine which are clades, and the remaining paraphyletic groups are dissected to discover monophyletic subgroups. Comparisons of diversity patterns and extinction rates between modeled taxa and lineages indicate that paraphyletic groups can adequately capture lineage information under a variety of conditions of diversification and mass extinction. This suggests that these groups constitute more than mere "taxonomic noise" in this context. But, strictly monophyletic groups perform somewhat better, especially with regard to mass extinctions. However, when low levels of paleontologic sampling are simulated, the veracity of clades deteriorates, especially with respect to diversity, and modeled paraphyletic taxa often capture more information about underlying lineages. Thus, for studies of diversity and taxic evolution in the fossil record, traditional paleontologic genera and families need not be rejected in favor of cladistically-defined taxa.

Non-NASA Center↗

Evolutionary dynamics of plants and animals: a comparative approach

Patterns of longevity and rate of appearance of taxa in the fossil record indicate a different evolutionary dynamic between land plants and marine invertebrates. Among marine invertebrates, rates of taxonomic turnover declined through the Phanerozoic, with increasingly extinction-resistant, long-lived, clades coming to dominate. Among terrestrial vascular plants, rates of turnover increased through the Phanerozoic, with short-lived, extinction-prone clades coming to dominate from the Devonian to the present. Terrestrial vertebrates appear to approximate the marine invertebrate pattern more closely than the plant record. We identify two features which individually or jointly may have influenced this distinction. First, land plants continuously invaded stressful environments during their evolution, while marine invertebrates and terrestrial vertebrates did not. Second, the relative structural simplicity and indeterminate mode of plant growth vs. the relative structural complexity and determinate mode of animal growth may have influenced the timing of major clade origin in the two groups.

Review↗

Precambrian animal diversity: putative phosphatized embryos from the Doushantuo Formation of China

Putative fossil embryos and larvae from the Precambrian phosphorite rocks of the Doushantuo Formation in Southwest China have been examined in thin section by bright field and polarized light microscopy. Although we cannot completely exclude a nonbiological or nonmetazoan origin, we identified what appear to be modern cnidarian developmental stages, including both anthozoan planula larvae and hydrozoan embryos. Most importantly, the sections contain a variety of small (</=200 microm) structures that greatly resemble gastrula stage embryos of modern bilaterian forms.

Non-NASA Center↗

Early animal evolution: emerging views from comparative biology and geology

The Cambrian appearance of fossils representing diverse phyla has long inspired hypotheses about possible genetic or environmental catalysts of early animal evolution. Only recently, however, have data begun to emerge that can resolve the sequence of genetic and morphological innovations, environmental events, and ecological interactions that collectively shaped Cambrian evolution. Assembly of the modern genetic tool kit for development and the initial divergence of major animal clades occurred during the Proterozoic Eon. Crown group morphologies diversified in the Cambrian through changes in the genetic regulatory networks that organize animal ontogeny. Cambrian radiation may have been triggered by environmental perturbation near the Proterozoic-Cambrian boundary and subsequently amplified by ecological interactions within reorganized ecosystems.

Non-NASA Center↗

Decoupled temporal patterns of evolution and ecology in two post-Paleozoic clades

Counts of taxonomic diversity are the prevailing standards for documenting large-scale patterns of evolution in the fossil record. However, the secular pattern of relative ecological importance between the bryozoan clades Cyclostomata and Cheilostomata is not reflected fully in compilations of generic diversity or within-fauna species richness, and the delayed ecological recovery of the Cheilostomata after the mass extinction at the Cretaceous-Tertiary boundary is missed entirely. These observations demonstrate that evolutionary success and ecological dominance can be decoupled and profoundly different, even over tens of millions of years.

Non-NASA Center↗

Search for past life on Mars: possible relic biogenic activity in martian meteorite ALH84001

Fresh fracture surfaces of the martian meteorite ALH84001 contain abundant polycyclic aromatic hydrocarbons (PAHs). These fresh fracture surfaces also display carbonate globules. Contamination studies suggest that the PAHs are indigenous to the meteorite. High-resolution scanning and transmission electron microscopy study of surface textures and internal structures of selected carbonate globules show that the globules contain fine-grained, secondary phases of single-domain magnetite and Fe-sulfides. The carbonate globules are similar in texture and size to some terrestrial bacterially induced carbonate precipitates. Although inorganic formation is possible, formation of the globules by biogenic processes could explain many of the observed features, including the PAHs. The PAHs, the carbonate globules, and their associated secondary mineral phases and textures could thus be fossil remains of a past martian biota.

NASA Discipline Number 52-10↗

Response to Comment on 'Prevented Mortality and Greenhouse Gas Emissions from Historical and Projected Nuclear Power'

Sovacool et al.'s analysis of our paper contains numerous errors, misinterpretations, and dubious assumptions. For instance, we make no presumption in our paper that nuclear power is the only major option to replace fossil fuels nor have we in the past, as evidenced by our other peer-reviewed publications. Furthermore, all of our results are based on complete fuel cycle analysis and are presented as mean values along with their ranges. Thus it is incorrect to claim that we single out the worst estimates for coal mortality. Contrary to Sovacool et al.'s assertions, our only bias is our belief that humanity's best chance of success for mitigating the daunting challenge of climate change is to utilize all available and proven means.

coal↗

Global Methane Assessment: Benefits and Costs of Mitigating Methane Emissions

The assessment highlights the critical role that cutting methane emissions, including from the fossil fuel industry, plays in slowing the rate of global warming. Cutting human-caused methane by 45% this decade would keep warming beneath a threshold agreed by world leaders. There are multiple benefits to acting including: the rapid reduction of warming, which can help prevent dangerous climate tipping points; improved air quality that can save hundreds of thousands of lives; improve food security by preventing crop losses; and create jobs through mitigation efforts while increasing productivity through reduced heat stress.

Methane↗

Clean Air Policies Are Key for Successfully Mitigating Arctic Warming

A tighter integration of modeling frameworks for climate and air quality is urgently needed to assess the impacts of clean air policies on future Arctic and global climate. We combined a new model emulator and comprehensive emissions scenarios for air pollutants and greenhouse gases to assess climate and human health co-benefits of emissions reductions. Fossil fuel use is projected to rapidly decline in an increasingly sustainable world, resulting in far-reaching air quality benefits. Despite human health benefits, reductions in sulfur emissions in a more sustainable world could enhance Arctic warming by 0.8 °C in 2050 relative to the 1995–2014, thereby offsetting climate benefits of greenhouse gas reductions. Targeted and technically feasible emissions reduction opportunities exist for achieving simultaneous climate and human health co-benefits. It would be particularly beneficial to unlock a newly identified mitigation potential for carbon particulate matter, yielding Arctic climate benefits equivalent to those from carbon dioxide reductions by 2050.

Atmospheric chemistry↗

Towards Long-Term Corrosion Resistance in FE Service Environments

The push for carbon capture and sequestration for fossil fuel energy production has materials performance challenges in terms of high temperature oxidation and corrosion resistance. Such challenges will be illustrated with examples from several current technologies that are close to being realized. These include cases where existing technologies are being modified—for example fireside corrosion resulting from increased corrosivity of flue gas in coal boilers refit for oxy-fuel combustion, or steam corrosion resulting from increased temperatures in advanced ultra supercritical steam boilers. New technology concepts also push the high temperature corrosion and oxidation limits—for example the effects of multiple oxidants during the use of high CO2 and water flue gas used as turbine working fluids.

01 COAL, LIGNITE, AND PEAT↗

INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING

This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

42 ENGINEERING↗

Use of a hybrid technology in a critical security system.

Assigning an acceptable level of power reliability in a security system environment requires a methodical approach to design when considering the alternatives tied to the reliability and life of the system. The downtime for a piece of equipment, be it for failure, routine maintenance, replacement, or refurbishment or connection of new equipment is a major factor in determining the reliability of the overall system. In addition to these factors is the condition where the system is static or dynamic in its growth. Most highly reliable security power source systems are supplied by utility power with uninterruptable power source (UPS) and generator backup. The combination of UPS and generator backup with a reliable utility typically provides full compliance to security requirements. In the energy market and from government agencies, there is growing pressure to utilize alternative sources of energy other than fossil fuel to increase the number of local generating systems to reduce dependence on remote generating stations and cut down on carbon effects to the environment. There are also conditions where a security system may be limited on functionality due to lack of utility power in remote locations. One alternative energy source is a renewable energy hybrid system including a photovoltaic or solar system with battery bank and backup generator set. This is a viable source of energy in the residential and commercial markets where energy management schemes can be incorporated and systems are monitored and maintained regularly. But, the reliability of this source could be considered diminished when considering the security system environment where stringent uptime requirements are required.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Gas Turbine/Solar Parabolic Trough Hybrid Design Using Molten Salt Heat Transfer Fluid: Preprint

Parabolic trough power plants can provide reliable power by incorporating either thermal energy storage (TES) or backup heat from fossil fuels. This paper describes a gas turbine / parabolic trough hybrid design that combines a solar contribution greater than 50% with gas heat rates that rival those of natural gas combined-cycle plants. Previous work illustrated benefits of integrating gasturbines with conventional oil heat-transfer-fluid (HTF) troughs running at 390?C. This work extends that analysis to examine the integration of gas turbines with salt-HTF troughs running at 450 degrees C and including TES. Using gas turbine waste heat to supplement the TES system provides greater operating flexibility while enhancing the efficiency of gas utilization. The analysis indicatesthat the hybrid plant design produces solar-derived electricity and gas-derived electricity at lower cost than either system operating alone.

14 SOLAR ENERGY↗

Use of a hybrid technology in a critical security system.

Assigning an acceptable level of power reliability in a security system environment requires a methodical approach to design when considering the alternatives tied to the reliability and life of the system. The downtime for a piece of equipment, be it for failure, routine maintenance, replacement, or refurbishment or connection of new equipment is a major factor in determining the reliability of the overall system. In addition to these factors is the condition where the system is static or dynamic in its growth. Most highly reliable security power source systems are supplied by utility power with uninterruptable power source (UPS) and generator backup. The combination of UPS and generator backup with a reliable utility typically provides full compliance to security requirements. In the energy market and from government agencies, there is growing pressure to utilize alternative sources of energy other than fossil fuel to increase the number of local generating systems to reduce dependence on remote generating stations and cut down on carbon effects to the environment. There are also conditions where a security system may be limited on functionality due to lack of utility power in remote locations. One alternative energy source is a renewable energy hybrid system including a photovoltaic or solar system with battery bank and backup generator set. This is a viable source of energy in the residential and commercial markets where energy management schemes can be incorporated and systems are monitored and maintained regularly. But, the reliability of this source could be considered diminished when considering the security system environment where stringent uptime requirements are required.

14 SOLAR ENERGY↗

2011 Laser Diagnostics in Combustion Gordon Research Conference, (August 14-19, 2011, Waterville Valley Resort, Waterville Valley, NH)

The vast majority of the world's energy needs are met by combustion of fossil fuels. Optimum utilization of limited resources and control of emissions of pollutants and greenhouse gases demand sustained improvement of combustion technology. This task can be satisfied only by detailed knowledge of the underlying physical and chemical processes. Non-intrusive laser diagnostics continuously contribute to our growing understanding of these complex and coupled multi-scale processes. The GRC on Laser Diagnostics in Combustion focuses on the most recent scientific advances and brings together scientists and engineers working at the leading edge of combustion research. Major tasks of the community are developing and applying methods for precise and accurate measurements of fluid motion and temperatures; chemical compositions; multi-phase phenomena appearing near walls, in spray and sooting combustion; improving sensitivities, precision, spatial resolution and tracking transients in their spatio-temporal development. The properties and behaviour of novel laser sources, detectors, optical systems that lead to new diagnostic capabilities are also part of the conference program.

42 ENGINEERING↗

Accelerating the Computation of Detailed Chemical Reaction Kinetics for Simulating Combustion of Complex Fuels

Combustion of hydrocarbon fuels has been a very challenging scientific and engineering problem due to the complexity of turbulent flows and hydrocarbon reaction kinetics. There is an urgent need to develop an efficient modeling capability to accurately predict the combustion of complex fuels. Detailed chemical kinetic models for the surrogates of fuels such as gasoline, diesel and JP-8 consist of thousands of chemical species and Arrhenius reaction steps. Oxygenated fuels such as bio-fuels and heavier hydrocarbons, such as from newer fossil fuel sources, are expected to have a much more complex chemistry requiring increasingly larger chemical kinetic models. Such models are beyond current computational capability, except for homogeneous or partially stirred reactor type calculations. The advent of highly parallel multi-core processors and graphical processing units (GPUs) promises a steep increase in computational performance in the coming years. This paper will present a software framework that translates the detailed chemical kinetic models to high- performance code targeted for GPU accelerators.

02 PETROLEUM↗

Electrodeposition of Metals in Catalyst Synthesis: The Case of Platinum Monolayer Electrocatalysts

The concern about energy sources, their availability, and related environmental effects, is at an all time high. Proton Exchange Membrane Fuel Cells (PEMFCs) - with an efficiency higher than that of internal combustion engines, light weight, low operating temperature, and fast-start-up capability - are strong candidates for automotive applications. Transportation applications could be especially important in shaping up the new energy economy since they may entail a substantial decrease in the adverse environmental effects linked to the use of fossil fuels and prolong their availability. The largest portion of the cost of PEMFCs reflects the large amount of Pt needed in the cathode's catalytic layer due to the low catalytic activity of Pt for the oxygen reduction reaction (ORR). Recently, considerable advances have been made in fuel cell electrocatalysis yielding improved electrocatalysts, and increasing our understanding of the kinetics of the ORR in combination with significant advances in theoretical treatments. Some of these studies involved: (1) alloying Pt to synthesize bi-metallic catalysts, (2) core-shell nanoparticles catalysts, (3) the role of size, structure, and shape of nanoparticles, and (4) de-alloying of bimetallic alloys. However, a complete understanding of the ORR kinetics on Pt, the best single element catalyst, and of its low efficiency, is yet to be achieved. These problems, compounded with the high Pt content in current cathode catalysts, and with their gradual loss of performance under operating conditions, still hamper commercialization of fuel cells. In order to minimize the amount of noble metal electrocatalysts and maximize their utilization, while achieving high catalytic activity, numerous synthetic approaches have been attempted. The electrocatalysts were prepared using vacuum deposition methods, wet chemistry methods, or electrodeposition techniques. Electrodeposition in particular has several attractive features with respect to the application in catalyst synthesis such as simplicity of operation and ease of control of the deposition conditions. In this article we describe the application of metal electrodeposition in the synthesis of a new type of electrocatalysts comprising a Pt monolayer (Pt{sub ML}) on metal or alloy nanoparticles. The concept of Pt{sub ML} electrocatalysts offers a possible solution to the impasse caused by a slow ORR kinetics and the consequent large Pt content of conventional electrocatalysts. A Pt{sub ML} shell on a nanoparticle substrate core ensures that every Pt atom is available for catalytic activity; in other words, a Pt{sub ML} achieves the ultimate reduction in Pt loading and complete Pt utilization. Also, through geometric and electronic interaction with the substrate a Pt{sub ML} can change its electronic properties and be more active and durable than pure-Pt electrocatalysts.

30 DIRECT ENERGY CONVERSION↗