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At least 1,477 records · Page 82

Instability of Bose-Einstein condensation into the one-particle ground state on quantum graphs under repulsive perturbations

In this paper we investigate Bose-Einstein condensation into the one-particle ground state in interacting quantum many-particle systems on graphs. We extend previous results obtained for particles on an interval and show that even arbitrarily small repulsive two-particle interactions destroy the condensate in the one-particle ground state present in the non-interacting Bose gas. Our results also cover singular two-particle interactions, such as the well-known Lieb-Liniger model, in the thermodynamic limit.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Gravitational wave from dark sector with dark pion

In this work, we investigate the spectra of gravitational waves produced by chiral symmetry breaking in dark quantum chromodynamics (dQCD) sector. The dark pion (π) can be a dark matter candidate as weakly interacting massive particle (WIMP) or strongly interacting massive particle (SIMP). For a WIMP scenario, we introduce the dQCD sector coupled to the standard model (SM) sector with classical scale invariance and investigate the annihilation process of the dark pion via the 2π → 2 SM process. For a SIMP scenario, we investigate the 3π → 2π annihilation process of the dark pion as a SIMP using chiral perturbation theory. We find that in the WIMP scenario the gravitational wave background spectra can be observed by future space gravitational wave antennas. On the other hand, when the dark pion is the SIMP dark matter with the constraints for the chiral perturbative limit and pion-pion scattering cross section, the chiral phase transition becomes crossover and then the gravitational waves are not produced.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DARWIN: towards the ultimate dark matter detector

DARk matter WImp search with liquid xenoN (DARWIN) will be an experiment for the direct detection of dark matter using a multi-ton liquid xenon time projection chamber at its core. Its primary goal will be to explore the experimentally accessible parameter space for Weakly Interacting Massive Particles (WIMPs) in a wide mass-range, until neutrino interactions with the target become an irreducible background. The prompt scintillation light and the charge signals induced by particle interactions in the xenon will be observed by VUV sensitive, ultra-low background photosensors. Besides its excellent sensitivity to WIMPs above a mass of 5 GeV/ c {sup 2}, such a detector with its large mass, low-energy threshold and ultra-low background level will also be sensitive to other rare interactions. It will search for solar axions, galactic axion-like particles and the neutrinoless double-beta decay of {sup 136}Xe, as well as measure the low-energy solar neutrino flux with < 1% precision, observe coherent neutrino-nucleus interactions, and detect galactic supernovae. We present the concept of the DARWIN detector and discuss its physics reach, the main sources of backgrounds and the ongoing detector design and R and D efforts.

79 ASTRONOMY AND ASTROPHYSICS↗

The role of plasma–atom and molecule interactions on power & particle balance during detachment on the MAST Upgrade Super-X divertor

This paper shows first quantitative analysis of the detachment processes in the MAST Upgrade Super-X divertor (SXD). We identify an unprecedented impact of plasma-molecular interactions involving molecular ions (likely $D^+_2$), resulting in strong ion sinks (Molecular Activated Recombination—MAR), leading to a reduction of ion target flux. The MAR ion sinks exceed the divertor ion sources before electron-ion recombination (EIR) starts to occur, suggesting that significant ionisation occurs outside of the divertor chamber. In the EIR region, $T_e \ll 0.2$ eV is observed and MAR remains significant in these deep detached phases. The total ion sink strength demonstrates the capability for particle (ion) exhaust in the Super-X Configuration. Molecular Activated Dissociation is the dominant volumetric neutral atom creation process can lead to an electron cooling of 20% of $P_\mathrm{SOL}$. The measured total radiative power losses in the divertor chamber are consistent with inferred hydrogenic radiative power losses. This suggests that intrinsic divertor impurity radiation, despite the carbon walls, is minor in the divertor chamber. This contrasts previous TCV results, which may be associated with enhanced plasma-neutral interactions and reduced chemical erosion in the detached, tightly baffled SXD. The above observations have also been observed in higher heat flux (narrower SOL width) type I ELMy H-mode discharges. This provides evidence that the characterisation in this paper may be general.

plasma-molecular interactions↗

UHV studies of the interaction of CO with small supported metal particles, Pd/mica

The interaction of carbon monoxide with small palladium particles supported on UHV-cleaved and heat-treated single-crystal mica was studied. The Pd particles were characterized and tested using the techniques of flash thermal desorption, Auger electron spectroscopy, core electron energy loss spectroscopy, and transmission electron microscopy. Evidence is presented for CO decomposition on Pd particles during CO adsorption-desorption experiments. The rate of CO decomposition increased rapidly with diminishing particle size. Residual carbon from CO decomposition blocked CO adsorption and had a strong poisoning effect on the CO oxidation reaction.

Doering, D. L.↗

Toward particle-resolved accuracy in Euler–Lagrange simulations of multiphase flow using machine learning and pairwise interaction extended point-particle (PIEP) approximation

This study presents two different machine learning approaches for the modeling of hydrodynamic force on particles in a particle-laden multiphase flow. Results from particle-resolved direct numerical simulations (PR-DNS) of flow over a random array of stationary particles for eight combinations of particle Reynolds number (Re) and volume fraction (φ) are used in the development of the models. The first approach follows a two-step process. In the first flow prediction step, the perturbation flow due to a particle is obtained as an axisymmetric superposable wake using linear regression. In the second force prediction step, the force on a particle is evaluated in terms of the perturbation flow induced by all its neighbors using the generalized Faxén form of the force expression. In the second approach, the force data on all the particles from the PR-DNS simulations are used to develop an artificial neural network (ANN) model for direct prediction of force on a particle. Due to the unavoidable limitation on the number of fully resolved particles in the PR-DNS simulations, direct force prediction with the ANN model tends to over-fit the data and performs poorly in the prediction of test data. In contrast, due to the millions of grid points used in the PR-DNS simulations, accurate flow prediction is possible, which then allows accurate prediction of particle force. This hybridization of multiphase physics and machine learning is particularly important, since it blends the strength of each, and the resulting pairwise interaction extended point-particle model cannot be developed by either physics or machine learning alone.

42 ENGINEERING↗

UHV studies of the interaction of CO with small supported metal particles, Ni/mica

The interaction of carbon monoxide with small nickel (Ni) particles supported on UHV-cleaved mica was studied using flash thermal desorption, Auger electron spectroscopy, and transmission electron microscopy. Molecular desorption was accompanied by decomposition of CO at a rate strongly dependent on particle size. Recombination of surface-precipitated carbon with adsorbed oxygen was observed, and gas-induced morphological particle changes because of exposure to CO and O2 are analyzed in some detail.

Doering, D. L.↗

Gas-Grain Simulation Facility: Fundamental studies of particle formation and interactions. Volume 1: Executive summary and overview

An overview of the Gas-Grain Simulation Facility (GGSF) project and its current status is provided. The proceedings of the Gas-Grain Simulation Facility Experiments Workshop are recorded. The goal of the workshop was to define experiments for the GGSF--a small particle microgravity research facility. The workshop addressed the opportunity for performing, in Earth orbit, a wide variety of experiments that involve single small particles (grains) or clouds of particles. The first volume includes the executive summary, overview, scientific justification, history, and planned development of the Facility.

Fogleman, Guy↗

Gas-Grain Simulation Facility: Fundamental studies of particle formation and interactions. Volume 2: Abstracts, candidate experiments and feasibility study

An overview of the Gas-Grain Simulation Facility (GGSF) project and its current status is provided. The proceedings of the Gas-Grain Simulation Facility Experiments Workshop are recorded. The goal of the workshop was to define experiments for the GGSF--a small particle microgravity research facility. The workshop addressed the opportunity for performing, in Earth orbit, a wide variety of experiments that involve single small particles (grains) or clouds of particles. Twenty experiments from the fields of exobiology, planetary science, astrophysics, atmospheric science, biology, physics, and chemistry were described at the workshop and are outlined in Volume 2. Each experiment description included specific scientific objectives, an outline of the experimental procedure, and the anticipated GGSF performance requirements. Since these experiments represent the types of studies that will ultimately be proposed for the facility, they will be used to define the general science requirements of the GGSF. Also included in the second volume is a physics feasibility study and abstracts of example Gas-Grain Simulation Facility experiments and related experiments in progress.

Fogleman, Guy↗

Dispersive approaches for three-particle final state interaction

In this work, we presented different representations of Khuri-Treiman equation, the advantage and disadvantage of each representations are discussed. With a scattering amplitude toy model, we also studied the sensitivity of solution of KT equation to left-hand cut of toy model and to the different approximate methods. At last, we give a brief discussion of Watson's theorem when three particles in final states are involved.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Probing surface-adsorbate interactions through active particle dynamics

Adsorbate molecules present in a reaction mixture may bind to and block catalytic sites. Measurement of the surface coverage of these molecules via adsorption isotherms is critical for modeling and design of catalytic reactions on surfaces. However, it is challenging to measure isotherms in solution in a way that is directly relevant to catalytic activity under reaction conditions, particularly since adsorbates may bind with an enormous range of surface affinity parameters. Here we used the motion of self-propelled catalytic Janus particles, which employ the decomposition of hydrogen peroxide fuel as a propulsion mechanism, to determine the effective surface coverage of thioglycerol, furfural, and ethanol on a platinum surface as a function of concentration in aqueous solution by measuring the decrease in active motion due to the blocking of active sites. For strongly adsorbing thioglycerol, this effective coverage was compared and contrasted to the total adsorbed amount measured using inductively-coupled plasma analysis. Demonstrating the broad applicability of this approach, the surface affinity of the three adsorbates spanned more than four orders of magnitude. For each species, the adsorbate-mediated attenuation of active motion occurred over a wide concentration range and was well-described by a Langmuir isotherm. The strongly interacting thioglycerol had the highest affinity towards the surface (K a = 15.5 ± 4.3 mM –1 ) and fully deactivated the active particle motion at surface saturation. Furfural had an intermediate affinity (K a = 0.42 ± 0.07 mM –1 ) but did not fully block H 2 O 2 access to the surface at apparent saturation, consistent with a maximum fractional surface coverage of θ max = 0.67. Ethanol exhibited even lower affinity (K a = 0.0025 ± 2x10 -4 mM –1 ) and its coverage saturated at only θ max = 0.38. Analysis of isotherms at elevated temperatures enabled direct extraction of the enthalpies of adsorption. The degree of surface coverage at adsorbate saturation appeared to correlate with the relative energies of adsorption for the different adsorbate species and was consistent with adsorbate saturation of one of multiple active site populations towards H 2 O 2 decomposition. Furthermore, computational investigations into solvent effects on furfural adsorption showed good quantitative agreement with the experimental results. This work leverages unique properties of active particles to explore fundamental catalysis questions and demonstrates a novel paradigm for significant and experimentally accessible multidisciplinary research.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

SuperCDMS Prototype Detector Design and Testing

A substantial amount of astrophysical evidence indicates that approximately a quarter of all energy in the universe is composed of a nonluminous, and nonbaryonic \dark" matter. Of the potential dark matter particle candidates, Weakly Interacting Massive Particles, or WIMPs, is particularly well motivated. As a means to directly detect WIMP interactions with baryonic matter, the Cryogenic Dark Matter Search (CDMS) project was established, operating at the Soudan Underground Laboratory from 2003 - 2015, under the CDMS II and SuperCDMS Soudan experiments. CDMS detectors simultaneously measure the ionization and phonon energies of recoil events in Si and Ge crystals kept at cryogenic temperatures in a low-background environment. The ratio of ionization energy to recoil energy serves as a discrimination parameter to separate nuclear recoil events from the electron-recoil background. The next installation, SuperCDMS SNOLAB, is preparing for future operation, with an initial payload of eighteen Ge and six Si, 100 mm diameter, 33 mm thick detectors. Of this initial payload, eight Ge and four Si detectors will operate in a high-voltage ( 100 V) mode, which have an increased sensitivity to low-mass WIMPs due to decreased energy thresholds. The SuperCDMS test facility at University of Minnesota aids in the detector R&D and characterization of prototype detectors, as part of the scale-up eort for Super- CDMS SNOLAB. This thesis presents the rst full ionization and phonon characterization study of a 100 mm diameter, 33 mm thick prototype Ge detector with interleaved phonon and ionization channels. Measurements include ionization collection eciency, surface event rejection capabilities, and successful demonstration of nuclear recoil event discrimination. Results indicate that 100 mm diameter, interleaved Ge detectors show potential for use in SuperCDMS SNOLAB. As part of detector R&D, the Minnesota test facility also looks beyond the next stage of SuperCDMS, investigating larger individual detectors as a means to easily scale up the sensitive mass of future searches. This thesis presents the design and initial testing results of a prototype 150 mm diameter, 33 mm thick silicon ionization detector, which is 5.2 times larger than those used in SuperCDMS at Soudan and 2.25 times larger than those planned for use at SuperCDMS SNOLAB. In addition, the detector was operated with contact-free ionization electrodes to minimize bias leakage currents, which can limit operation at high bias voltages. The results show promise for the operation of both large volume silicon detectors and contact-free ionization electrodes for scaling up detector mass and bias.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Filled Elastomers: Mechanistic and Physics-Driven Modeling and Applications as Smart Materials

Elastomers are made of chain-like molecules to form networks that can sustain large deformation. Rubbers are thermosetting elastomers that are obtained from irreversible curing reactions. Curing reactions create permanent bonds between the molecular chains. On the other hand, thermoplastic elastomers do not need curing reactions. Incorporation of appropriated filler particles, as has been practiced for decades, can significantly enhance mechanical properties of elastomers. However, there are fundamental questions about polymer matrix composites (PMCs) that still elude complete understanding. This is because the macroscopic properties of PMCs depend not only on the overall volume fraction (ϕ) of the filler particles, but also on their spatial distribution (i.e., primary, secondary, and tertiary structure). This work aims at reviewing how the mechanical properties of PMCs are related to the microstructure of filler particles and to the interaction between filler particles and polymer matrices. Overall, soft rubbery matrices dictate the elasticity/hyperelasticity of the PMCs while the reinforcement involves polymer–particle interactions that can significantly influence the mechanical properties of the polymer matrix interface. For ϕ values higher than a threshold, percolation of the filler particles can lead to significant reinforcement. While viscoelastic behavior may be attributed to the soft rubbery component, inelastic behaviors like the Mullins and Payne effects are highly correlated to the microstructures of the polymer matrix and the filler particles, as well as that of the polymer–particle interface. Additionally, the incorporation of specific filler particles within intelligently designed polymer systems has been shown to yield a variety of functional and responsive materials, commonly termed smart materials. We review three types of smart PMCs, i.e., magnetoelastic (M-), shape-memory (SM-), and self-healing (SH-) PMCs, and discuss the constitutive models for these smart materials.

36 MATERIALS SCIENCE↗

Modeling crud attachment on fuel surfaces - Role of interaction forces

Crud deposition is one of the major cause of fuel failures in PWRs operating in U.S. and around the world. Various experimental and computational studies have tried to relate thickness or amount of crud deposits to evaporative flux maps. Macroscopic models relating evaporation rate to deposition rate and the total amount of deposit, do not take into account shape of deposition patterns, interaction mechanisms between the crud particles and interactions between crud particles and substrate (in this case fuel surface). However, experimentally it is observed that there is spatiotemporal variation in the porosity and structure of crud layer deposits. It is also important to note that the deposition kinetics and the amount of deposits is highly dependent upon local or global chemistry which impact the interactions between particles and surfaces, and eventually effect attachment probability. The focus of this summary will be to present a model to describe the crud attachment kinetics on a fuel surface. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The Interaction Between an Insoluble Particle and an Advancing Solid/Liquid Interface: Micro-Gravity Experiments and Theoretical Developments

The interaction of an insoluble particle with an advancing solid/liquid interface (SLI) has been a subject of investigation for the past four decades. While the original interest stemmed from geology applications (e.g., frost heaving in soil), researchers soon realized that the complex science associated with such an interaction is relevant to many other scientific fields encompassing metal matrix composites (MMCs), high temperature superconductors, inclusion management in steel, growth of monotectics, and preservation of biological cells. During solidification of a liquid containing an insoluble particle, three distinct interaction phenomena have been experimentally observed: instantaneous engulfment of the particle, continuous pushing, and particle pushing followed by engulfment. It was also observed that for given experimental conditions and particle size there is a critical solidification velocity, V(sub cr), above which a particle is engulfed. During solidification of MMCs pushing leads to particle agglomeration at the grain boundaries and this has detrimental effects on mechanical properties of the casting. Consequently, the process must be designed for instantaneous engulfment to occur. This implies the development of accurate theoretical models to predict V(sub cr), and perform benchmark experiments to test the validity of such models. Although considerable progress has been made in understanding the pushing/engulfment phenomenon (PEP), its quantification in terms of the material and processing parameters remains a focus of research. Since natural convection currents occurring during terrestrial solidification experiments complicate the study of PEP, execution of experiments on the International Space Station (ISS) has been approved and funded by NASA. Extensive terrestrial (1g) experiments and preliminary micro-gravity (mu g) experiments on two space shuttle missions have been conducted in preparation for future experiments on the ISS. The investigated systems included metal-ceramic particles (pure aluminum - zirconia particles) and transparent organic - non-reactive particles (succinonitrile - polystyrene and biphenyl - glass). This paper will discuss the experimental results obtained in both lg and pg conditions and the influence of the natural convection on V(sub cr). A summary of past mathematical models and our recent theoretical developments will also be presented to explain the experimentally observed particle/SLI interaction.

Catalina, Adrian V.↗