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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,477 records · Page 82
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Dispersal, habitat filtering, and eco-evolutionary dynamics as drivers of local and global wetland viral biogeography

Abstract Wetlands store 20–30% of the world’s soil carbon, and identifying the microbial controls on these carbon reserves is essential to predicting feedbacks to climate change. Although viral infections likely play important roles in wetland ecosystem dynamics, we lack a basic understanding of wetland viral ecology. Here 63 viral size-fraction metagenomes (viromes) and paired total metagenomes were generated from three time points in 2021 at seven fresh- and saltwater wetlands in the California Bodega Marine Reserve. We recovered 12,826 viral population genomic sequences (vOTUs), only 4.4% of which were detected at the same field site two years prior, indicating a small degree of population stability or recurrence. Viral communities differed most significantly among the seven wetland sites and were also structured by habitat (plant community composition and salinity). Read mapping to a new version of our reference database, PIGEONv2.0 (515,763 vOTUs), revealed 196 vOTUs present over large geographic distances, often reflecting shared habitat characteristics. Wetland vOTU microdiversity was significantly lower locally than globally and lower within than between time points, indicating greater divergence with increasing spatiotemporal distance. Viruses tended to have broad predicted host ranges via CRISPR spacer linkages to metagenome-assembled genomes, and increased SNP frequencies in CRISPR-targeted major tail protein genes suggest potential viral eco-evolutionary dynamics in response to both immune targeting and changes in host cell receptors involved in viral attachment. Together, these results highlight the importance of dispersal, environmental selection, and eco-evolutionary dynamics as drivers of local and global wetland viral biogeography.

Environmental Sciences & Ecology↗
DOE OSTI2017

Chlorophyll a with a farnesyl tail in thermophilic cyanobacteria

Photosystem II (PSII) of oxygenic photosynthetic organisms normally contains exclusively chlorophyll a (Chl a ) as its major light-harvesting pigment. Chl a canonically consists of the chlorin headgroup with a 20-carbon, 4-isoprene unit, phytyl tail. We have examined the 1.9 Å crystal structure of PSII from thermophilic cyanobacteria reported by Shen and coworkers in 2012 (PDB accession of 3ARC/3WU2). A newly refined electron density map from this structure, presented here, reveals that some assignments of the cofactors may be different from those modeled in the 3ARC/3WU2 structure, including a specific Chl a that appears to have a truncated tail by one isoprene unit. Here, we provide experimental evidence using high-performance liquid chromatography and mass spectrometry for a small population of Chl a esterified to a 15-carbon farnesyl tail in PSII of thermophilic cyanobacteria.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Correlation of SWIR imaging with LPBF 304L stainless steel part properties

In the Laser Powder Bed Fusion (LPBF) process, the local thermal history can vary significantly over a part as the heat transfer characteristics and the laser scan path are geometry dependent. The variations introduce the potential for defects that lead to part failure, some of which are difficult to identify non-destructively with common ex-situ evaluation techniques. These defects include significant microstructural and mechanical property differences in the part interiors. In this paper, thermal features are extracted from in-situ Short-Wave Infrared (SWIR) imaging measurements to compile voxel based part representations and understand how the complexities in the thermal history affect part performance. The deviations in thermal features due to different laser processing parameters and complex scan pathing are explored. Empirical correlations are developed to map thermal features with the engineering properties (bulk yield strength, area percentage porosity, and local state) of 304L stainless steel parts manufactured by LPBF. Processing modes (insufficient melting and keyholing) are determined by mapping part property measurements with multiple thermal features. Generating the relationships between thermographic measurements and resulting SLM part properties lays the foundation for in-situ part qualification.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Is more always better? Tribofilm evolution and tribological behavior impacted by the concentration of ZDDP, ionic liquid, and ZDDP-Ionic liquid combination

Anti-wear additives (AWs), like zinc dialkyldithiophosphates (ZDDPs), have been used in lubricants for more than a half-century, and more effective candidate AWs, like oil-soluble ionic liquids (ILs), are emerging. However, there is a lack of fundamental understanding of how the AW concentration impacts the tribochemical activities at the contact interface. This study systematically investigated the friction and wear behavior in correlation to the tribofilm morphology and composition as a function of the concentration of a ZDDP, a phosphonium-alkylphosphate IL, and an IL+ZDDP combination. The ZDDP concentration rising from 0.4 to 6.4 wt% caused a proportionally increased friction coefficient, which was well correlated to a thicker, rougher, and more brittle tribofilm. This was further understood by the decreasing phosphates but increasing sulfur compounds in the ZDDP tribofilm. In contrast, the IL and IL+ZDDP maintained a low and stable friction coefficient at 0.5 wt% or above. There was no sulfur in the IL tribofilm, and the sulfur compounds were maintained at a low level in the tribofilm for IL+ZDDP even at high concentrations. Results suggested minimizing the sulfur content in the tribofilm would be an effective way to control the friction. An interesting V-shape relationship between the AW concentration and the wear loss was observed for both the IL-containing AWs, with an optimum at 2 wt% for the IL alone and 0.46–0.92 wt% for the IL+ZDDP, respectively. A unique heat map was created using the phosphorus binding energy distribution to reveal the phosphate polymerization at different depths of the tribofilms, which provided additional insight for the tribofilm evolution.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Recombination activity of grain boundaries in high-performance multicrystalline Si during solar cell processing

Here in this work, we applied internal quantum efficiency mapping to study the recombination activity of grain boundaries in High Performance Multicrystalline Silicon under different processing conditions. Wafers were divided into groups and underwent different thermal processing, consisting of phosphorus diffusion gettering and surface passivation with hydrogen rich layers. After these thermal treatments, wafers were processed into heterojunction with intrinsic thin layer solar cells. Light Beam Induced Current and Electron Backscatter Diffraction were applied to analyse the influence of thermal treatment during standard solar cell processing on different types of grain boundaries. The results show that after cell processing, most random-angle grain boundaries in the material are well passivated, but small-angle grain boundaries are not well passivated. Special cases of coincidence site lattice grain boundaries with high recombination activity are also found. Based on micro-X-ray fluorescence measurements, a change in the contamination level is suggested as the reason behind their increased activity. Published by AIP Publishing.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Correlational selection and genetic architecture shape the evolution of the leaf economics spectrum in a perennial grass

The generality of the worldwide leaf economics spectrum (LES) has made it a pillar of trait-based ecological research. Yet, few studies have examined the processes shaping the evolution of the LES within species, in part, because most species occupy only a small portion of the LES. Here, to address this gap, we took advantage of the distinct leaf economics strategies present in different ecotypes of the phenotypically diverse perennial grass Panicum virgatum (switchgrass) to generate a genetic mapping population, which we planted in common gardens at three sites spanning 12 degrees of latitude in the central United States. With this genetic mapping population, we evaluated two potentially interacting causes of LES evolution: 1) genetic architecture, where multiple traits are influenced by either the same gene (pleiotropy) or by genes in close physical proximity (genetic linkage), and 2) correlational selection, where selection acts on traits in combination rather than in isolation. We found that shared genetic architecture influenced covariation between photosynthetic rate (A MASS ) and leaf nitrogen (N MASS ) and between A MASS and leaf mass per area (LMA). We also found that correlational selection favored the trait combinations predicted by the LES (e.g., high LMA with low N MASS or low LMA with high N MASS ) and disfavored other, mismatched trait combinations at two of the three sites. Together, these results demonstrate how the evolution of an integrated LES within species can arise from multiple evolutionary causes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

Shear banding, intermittency, jamming, and dynamic phases for skyrmions in inhomogeneous pinning arrays

In this work, we examine driven skyrmion dynamics in systems with inhomogeneous pinning where a strip of strong pinning coexists with a region containing no pinning. For driving parallel to the strip, we find that the initial skyrmion motion is confined to the unpinned region and the skyrmion Hall angle is zero. At larger drives, a transition occurs to a phase in which motion also appears within the pinned region, creating a shear band in the skyrmion velocity, while the skyrmion Hall angle is still zero. As the drive increases further, the flow becomes disordered and the skyrmion Hall angle increases with drive until saturating at the highest drives when the system transitions into a moving crystal phase. The different dynamic phases are associated with velocity and density gradients across the pinning boundaries. We map out the dynamic phases as a function of pinning strength, skyrmion density, and Magnus force strength, and correlate the phase boundaries with features in the velocity-force curves and changes in the local and global ordering of the skyrmion structure. For large Magnus forces, the shear banding instability is replaced by large-scale intermittent flow in the pinned region accompanied by simultaneous motion perpendicular to the direction of the drive, which appears as oscillations in the transport curves. We also examine the case of a drive applied perpendicular to the strip, where we find a jamming effect in which the skyrmion flow is blocked by skyrmion-skyrmion interactions until the drive is large enough to induce plastic flow.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Multichannel charge Kondo effect and non-Fermi-liquid fixed points in conventional and topological superconductor islands

We study multiterminal Majorana and conventional superconducting islands in the vicinity of the charge degeneracy point using bosonization and the numerical renormalization group. Both models map to the multichannel charge Kondo problem, but for noninteracting normal leads they flow to different non-Fermi-liquid fixed points at low temperatures. We compare and contrast both cases by numerically obtaining the full crossover to the low-temperature regime, and we predict distinctive transport signatures. Here, the differences between the two types of islands result from a crucial distinction between charge-2e and charge-e transfer in the conventional and topological case, respectively. In the conventional case, our results establish s-wave islands as a platform to study the intermediate multichannel Kondo fixed point. In the topological setup, the crossover temperature to non-Fermi-liquid behavior is relatively high as it is proportional to the level broadening, and the transport results are not sensitive to channel coupling anisotropy, moving away from the charge degeneracy point or including a small Majorana hybridization, which makes our proposal experimentally feasible.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Creation and Investigation of Organic Light-Emitting Structures Containing Arrays of Colloidal Quantum Dots

We have created organic electroluminescent structures—ITO/TPD/Alq3/Al and ITO/PEDOT:PSS/TPD/Alq3/Al—which are organic light-emitting diodes (OLEDs). Experiments on the incorporation of CdSe/ZnS colloidal quantum dots into the active layer of the structure have been performed. The parameters of the created structures have been determined using optical-spectroscopy methods. The appropriateness of using the method of high-speed vacuum thermal deposition as a main method for the deposition of structural layers has been demonstrated, and the possibility of accelerated formation of layers of the material without disturbing its chemical structure has been shown. By measuring the photoluminescence spectra at different points in samples, we have determined the quality of the obtained structures and plotted maps of the radiation power distribution of the material and of its thickness. Recommendations for the creation of upper contacts and other regions of light-emitting structures have been formulated. We have created organic structures with ITO/PEDOT:PSS/TPD/TPD + CQD’s CdSe/Alq3/Al colloidal quantum dots, in which electroluminescence of CdSe/ZnS quantum dots has been obtained for a wide range of applied voltages. It has been shown that the introduction of colloidal quantum dots into the structure leads to a significant modification of its electroluminescence spectrum.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2023

Improved quality metrics for association and reproducibility in chromatin accessibility data using mutual information

Correlation metrics are widely utilized in genomics analysis and often implemented with little regard to assumptions of normality, homoscedasticity, and independence of values. This is especially true when comparing values between replicated sequencing experiments that probe chromatin accessibility, such as assays for transposase-accessible chromatin via sequencing (ATAC-seq). Such data can possess several regions across the human genome with little to no sequencing depth and are thus non-normal with a large portion of zero values. Despite distributed use in the epigenomics field, few studies have evaluated and benchmarked how correlation and association statistics behave across ATAC-seq experiments with known differences or the effects of removing specific outliers from the data. Here, we developed a computational simulation of ATAC-seq data to elucidate the behavior of correlation statistics and to compare their accuracy under set conditions of reproducibility. Using these simulations, we monitored the behavior of several correlation statistics, including the Pearson’s R and Spearman’s ρ coefficients as well as Kendall’s τ and Top–Down correlation. We also test the behavior of association measures, including the coefficient of determination R 2 , Kendall’s W, and normalized mutual information. Our experiments reveal an insensitivity of most statistics, including Spear man’s ρ, Kendall’s τ, and Kendall’s W, to increasing differences between simulated ATAC-seq replicates. The removal of co-zeros (regions lacking mapped sequenced reads) between simulated experiments greatly improves the estimates of correlation and association. After removing co-zeros, the R 2 coefficient and normalized mutual information display the best performance, having a closer one-to-one relationship with the known portion of shared, enhanced loci between simulated replicates. When comparing values between experimental ATAC-seq data using a random forest model, mutual information best predicts ATAC-seq replicate relationships. Collectively, this study demonstrates how measures of correlation and association can behave in epigenomics experiments. We provide improved strategies for quantifying relationships in these increasingly prevalent and important chromatin accessibility assays.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Evaluation of In-Situ AM Process Monitoring Techniques and Potential for Detecting Process Anomalies and Undesirable Microstructures

The US Department of Energy’s Advanced Materials and Manufacturing Technologies (AMMT) program is pursuing rapid qualification of new materials for fabrication of nuclear relevant components using advanced manufacturing techniques. Particular interest is placed on code-qualifying stainless steel (SS) 316H processed by laser powder bed fusion (LPBF) additive manufacturing. A paradigm that incorporates data from in-situ sensing during the printing, ex-situ characterization, and advanced artificial intelligence–based models was established under the Transformation Challenge Reactor (TCR) program to develop a pedigree for each fabricated component that could be tracked from the feedstock to the component’s release for application. Under the TCR program, the Peregrine software was developed as a tool for incorporating the vast amounts of in-situ and ex-situ characterization data collected; all data stored on a rapidly growing digital platform. The digital platform allows for users to link site-specific process anomalies to the macro- and microstructure. The platform will eventually be able to predict component performance, which will be crucial to qualifying materials and components in risk-averse industries such as those supporting and building nuclear reactors. Current in-situ process monitoring techniques that are already integrated with software like Peregrine are advantageous for identifying process anomalies including powder spatter, component edge swelling, recoating-build interactions, and so on. However, additional data are required to fully predict the resulting microstructures needed for identifying relationships to component performance. The rapid cooling rates observed in LPBF are some of the highest of any bulk manufacturing process, resulting in heterogenous microstructures and typically causing anisotropy in mechanical properties. Moreover, evolved residual thermal stresses are high, which can cause severe defects such as delamination or cracking. Therefore, other in-situ monitoring methods are warranted for exploration to measure and map the thermal history, and potentially the stress state, of each build. This report summarizes different in-situ monitoring strategies proposed for LPBF with a focus on the more developed sensor systems. Novel capabilities for measuring melt pool temperatures are also addressed to better inform modeling efforts.

36 MATERIALS SCIENCE↗
NASA NTRS1972

Size frequency distribution of Martian craters and relative age of light and dark terrains.

Light and dark terrains in and around Meridiani Sinus, mapped on the imagery from Mariner 6 and Mariner 7, were found to have significantly different cumulative size frequency distributions of craters. The light terrain on a mosaic of frames 6N11, 6N13, and 6N19 has a greater proportion of large craters and a lesser proportion of smaller craters than the dark terrain on the same frames. The light terrain is interpreted to be generally older than the dark terrain. The filling or partial filling of the smaller craters on the light terrain by surface detritus is suggested. Several wide-angle frames have remarkably similar cumulative crater size frequency distributions that may be representative of a large portion of the Martian surface.

Woronow, A.↗
NASA NTRS1973

Task 1: Water Depth Management, 1388

The author has identified the following significant results. ERTS-1 MSS data taken on October 10, 1972, of the Little Bahama Bank are being used to demonstrate the use of ERTS-1 data for mapping of shallow water features for the purpose of upgrading world navigation charts. Marked reflectance differences occur for the shallow water areas in bands 4, 5, and 6. Digital processing of two adjacent data tapes within the ERTS-1 frame covering an area of about 40 by 40 miles has been completed. Correlation of depth measurements to 5 meters has been successful. A mathematical model for depth measurements using ratio of voltages in band 4 and 5 has been successfully developed and is being tested for accuracy. Additional studies for areas near Puerto Rico and in northern Lake Michigan will be undertaken. Satellite data will also provide geographical evidence for verifying existence or nonexistence of doubtful shoal waters now appearing on world charts and considered to be hazardous to shipping.

Polcyn, F. C.↗
NASA NTRS1973

Calculations of water depth from ERTS-MSS data

ERTS-1 MSS data taken on October 10, 1972 of the Little Bahama Bank are being used to demonstrate the use of ERTS-1 data for mapping of shallow water features for the purpose of upgrading world navigation charts. Marked reflectance differences occur for the shallow water areas in Bands 4, 5, and 6. Digital processing of two adjacent data tapes within the ERTS frame covering an area of about 40 by 40 miles has been completed. Correlation of depth measurements to 5 meters has been successful. A mathematical model for depth measurements using ratio of voltages in Band 4 and 5 has been successfully developed and is being tested for accuracy. Additional studies for areas near Puerto Rico and in Northern Lake Michigan will be undertaken. Satellite data will also provide geographical evidence for verifying existence or nonexistence of doubtful shoal waters now appearing on world charts and considered to be hazardous to shipping.

Polcyn, F. C.↗
NASA NTRS1975

A multidisciplinary study of earth resources imagery of Australia, Antarctica and Papua, New Guinea

The author has identified the following significant results. A thirteen category recognition map was prepared, showing forest, water, grassland, and exposed rock types. Preliminary assessment of classification accuracies showed that water, forest, meadow, and Niobrara shale were the most accurately mapped classes. Unsatisfactory results, were obtained in an attempt to discrimate sparse forest cover over different substrates. As base elevation varied from 7,000 to 13,000 ft, with an atmospheric visibility of 48 km, no changes in water and forest recognition were observed. Granodiorite recognition accuracy decreased monotonically as base elevation increased, even though the training set location was at 10,000 ft elevation. For snow varying in base elevation from 9400 to 8420 ft, recognition decreases from 99% at the 9400 ft training set elevation to 88% at 8420 ft. Calculations of expected radiance at the ERTS sensor from snow reflectance measured at the site and from Turner model calculations of irradiance, transmission and path radiance, reveal that snow signals should not be clipped, assuming that calculations and ERTS calibration constants were correct.

Fisher, N. H.↗
NASA NTRS1977

Significance of operator variation and the angle of illumination in lineament analysis on synoptic images

The significance of operator variation and the angle of illumination in acquired imagery is analyzed for lineament analysis. Five operators analyzed a LANDSAT image and four photographs of a plastic relief map illuminated at a low angle from varying directions of the Prescott, Arizona region. Significant differences were found in both number and length of the lineaments recognized by the different investigators for the images. The actual coincidence of lineaments recognized by the investigators for the same image is exceptionally low. Even the directional data on lineament orientation is significantly different from operator to operator and from image to image. Cluster analysis of the orientation data displays a clustering by operators rather than by images. It is recommended that extreme caution be taken before attempting to compare different investigators' results in lineament analysis.

Siegal, B. S.↗
NASA NTRS1977

A mini/microcomputer-based land use information system

The paper describes the Multipurpose Interactive NASA Information System (MINIS), a data management system for land-use applications. MINIS is written nearly entirely in FORTRAN IV, and has a full range of conditional, Boolean and arithmetic commands, as well as extensive format control and the capability of interactive file creation and updating. It requires a mini or microcomputer with at least 64 K of core or semiconductor memory. MINIS has its own equation-oriented query language for retrieval from different kinds of data bases. It features a graphics output which permits output of overlay maps. Some experience of the U.S. Department of Agriculture and the Tennessee State Planning Office with MINIS is discussed.

Seitz, R. N.↗
NASA NTRS1977

Use of thermal-infrared imagery in ground-water investigations in Montana

Thermal infrared imagery was used to locate ground-water inflow along three streams and one lake in Montana. The thermal scanner used in May 1972, March 1973, and November 1975 was mounted in a twin-engined aircraft. On the 1973 and 1975 flights, the data were recorded in an analog format on magnetic tape in flight, later were converted to digital format, and were computer processed using an assignment of patterns to indicate differences in water temperature. Output from the image processing program was converted to a temperature map having an isotherm spacing of 0.5 C. Computerization was found to be the most efficient method to manipulate data from lakes, large rivers, and narrow sinuous streams.

Boettcher, A. J.↗