Pressure Loading with In-Situ Permeability Measurement of SiC Ceramic Matrix Composite Tube
Silicon carbide fiber in a silicon carbide matrix composite (SiC-SiC) has been actively researched as a potential structural material to be used in advanced high temperature gas reactors (HTGR) and as an accident tolerant cladding material for light water reactors (LWR). This ceramic composite material demonstrates desirable properties for use in nuclear reactor core that include retention of strength from ambient to LWR and HTGR operating and accident temperatures and stability under neutron radiation. However, the ceramic composite material must be designed to meet all the necessary, application driven requirements before it could be implemented in a reactor design. As one of the requirements for a fuel cladding material, the composite has to maintain high level of impermeability as to retain fission gases throughout the fuel cycle. General Atomics (GA) had previously reported results on permeability levels obtained by CVI produced SiC-SiC composites. It has been determined that for LWR size cladding tube that is 51 mm long the permeability allocation equivalent to currently used claddings is 7.3 E-10 atm*cc/sec. With high level of attention to possible sources of leaks in a test setup, it has been demonstrated that a CVI SiC-SiC composites produced by GA can achieve a leak rate of 1 E-12 atm*cc/sec, and therefore it meets the permeability allocation for a fuel cladding. Further study showed that a particular SiC-SiC composite tube can remain impermeable after being pressure loaded well above LWR normal operating conditions. In the study done by Deck et al., hoop stress was applied to a composite tube using pressure load on the inside surface in a load-unload stepwise sequence with increasing maximum applied stress at each step and measuring permeability between steps. The tested composite comprised of 70% thickness of SiC-SiC composite which provides fracture toughness and bears a majority of the applied stress and a 30% thickness of monolithic SiC layer on the outside surface to provide an impermeable barrier. The composite remained impermeable up to internal pressure of 56 MPa which is more than 2.5 times greater than a typical pressure at the end of life in a fuel rod.