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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,495 records · Page 83

Superheater Corrosion Produced By Biomass Fuels

About 90% of the world's bioenergy is produced by burning renewable biomass fuels. Low-cost biomass fuels such as agricultural wastes typically contain more alkali metals and chlorine than conventional fuels. Although the efficiency of a boiler's steam cycle can be increased by raising its maximum steam temperature, alkali metals and chlorine released in biofuel boilers cause accelerated corrosion and fouling at high superheater steam temperatures. Most alloys that resist high temperature corrosion protect themselves with a surface layer of Cr{sub 2}O{sub 3}. However, this Cr{sub 2}O{sub 3} can be fluxed away by reactions that form alkali chromates or volatilized as chromic acid. This paper reviews recent research on superheater corrosion mechanisms and superheater alloy performance in biomass boilers firing black liquor, biomass fuels, blends of biomass with fossil fuels and municipal waste.

09 BIOMASS FUELS↗

Expanding the potential for saline formations : modeling carbon dioxide storage, water extraction and treatment for power plant cooling.

The National Water, Energy and Carbon Sequestration simulation model (WECSsim) is being developed to address the question, 'Where in the current and future U.S. fossil fuel based electricity generation fleet are there opportunities to couple CO{sub 2} storage and extracted water use, and what are the economic and water demand-related impacts of these systems compared to traditional power systems?' The WECSsim collaborative team initially applied this framework to a test case region in the San Juan Basin, New Mexico. Recently, the model has been expanded to incorporate the lower 48 states of the U.S. Significant effort has been spent characterizing locations throughout the U.S. where CO{sub 2} might be stored in saline formations including substantial data collection and analysis efforts to supplement the incomplete brine data offered in the NatCarb database. WECSsim calculates costs associated with CO{sub 2} capture and storage (CCS) for the power plant to saline formation combinations including parasitic energy costs of CO{sub 2} capture, CO{sub 2} pipelines, water treatment options, and the net benefit of water treatment for power plant cooling. Currently, the model can identify the least-cost deep saline formation CO{sub 2} storage option for any current or proposed coal or natural gas-fired power plant in the lower 48 states. Initial results suggest that additional, cumulative water withdrawals resulting from national scale CCS may range from 676 million gallons per day (MGD) to 30,155 MGD depending on the makeup power and cooling technologies being utilized. These demands represent 0.20% to 8.7% of the U.S. total fresh water withdrawals in the year 2000, respectively. These regional and ultimately nation-wide, bottom-up scenarios coupling power plants and saline formations throughout the U.S. can be used to support state or national energy development plans and strategies.

01 COAL, LIGNITE, AND PEAT↗

Energy Systems Laboratory Groundbreaking

INL recently broke ground for a research facility that will house research programs for bioenergy, advanced battery systems, and new hybrid energy systems that integrate renewable, fossil and nuclear energy sources. Here's video from the groundbreaking ceremony for INL's new Energy Systems Laboratory. You can learn more about CAES research at http://www.facebook.com/idahonationallaboratory.

99 GENERAL AND MISCELLANEOUS↗

NETL - Fuel Reforming Facilities

Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

30 DIRECT ENERGY CONVERSION↗

Carbon Sequestration

Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

01 COAL, LIGNITE, AND PEAT↗

Nuclear Hybrid Energy Systems: Challenges and Opportunities

With growing demand of energy and costs of the fossil fuels, coupled with the environmental concerns have resulted in an increased interest in alternative energy sources. Nuclear hybrid energy systems (NHES) are being considered which incorporates renewable energy sources such as solar and wind energy combined with nuclear reactor and energy storage to meet the peak hours demand imposed on the grid, along with providing process heat for other potential industrial applications. This concept could potentially satisfy various energy demands and improve reliability, robustness and resilience for the entire system as a whole, along with economic and net efficiency gains. This paper provides a brief understanding of potential NHES system and architecture along with the challenges

42 ENGINEERING↗

Simulation of integrated pollutant removal (IPR) water-treatment system using ASPEN Plus

Capturing CO2 from fossil fuel combustion provides an opportunity for tapping a significant water source which can be used as service water for a capture-ready power plant and its peripherals. Researchers at the National Energy Technology Laboratory (NETL) have patented a process—Integrated Pollutant Removal (IPR®)—that uses off-the-shelf technology to produce a sequestration ready CO2 stream from an oxy-combustion power plant. Water condensed from oxy-combustion flue gas via the IPR system has been analyzed for composition and an approach for its treatment—for in-process reuse and for release—has been outlined. A computer simulation model in ASPEN Plus has been developed to simulate water treatment of flue gas derived wastewater from IPR systems. At the field installation, water condensed in the IPR process contains fly ash particles, sodium (largely from spray-tower buffering) and sulfur species as well as heavy metals, cations, and anions. An IPR wastewater treatment system was modeled using unit operations such as equalization, coagulation and flocculation, reverse osmosis, lime softening, crystallization, and pH correction. According to the model results, 70% (by mass) of the inlet stream can be treated as pure water, the other 20% yields as saleable products such as gypsum (CaSO4) and salt (NaCl) and the remaining portion is the waste. More than 99% of fly ash particles are removed in the coagulation and flocculation unit and these solids can be used as filler materials in various applications with further treatment. Results discussed relate to a slipstream IPR installation and are verified experimentally in the coagulation/flocculation step.

20 FOSSIL-FUELED POWER PLANTS↗

SUBTASK 3.12 – GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL

The goal of this project was to evaluate the performance of Illinois No. 6 coal blended with biomass in a small-scale entrained-flow gasifier and demonstrate the production of liquid fuels under three scenarios. The first scenario used traditional techniques for cleaning the syngas prior to Fischer–Tropsch (FT) synthesis, including gas sweetening with a physical solvent. In the second scenario, the CO2 was not removed from the gas stream prior to FT synthesis. In the third scenario, only warm-gas cleanup techniques were used, such that the feed gas to the FT unit contained both moisture and CO2. The results of the testing showed that the liquid fuels production from the FT catalyst was significantly hindered by the presence of moisture and CO2 in the syngas. Further testing would be needed to determine if this thermally efficient process is feasible with other FT catalysts. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the Illinois Clean Coal Institute.

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NETL - Thermogravimetric Analysis Laboratory

Researchers in NETL's Thermal Analysis Laboratory are investigating chemical looping combustion. As a clean and efficient fossil fuel technology, chemical looping combustion controls CO 2 emissions and offers a promising alternative to traditional combustion.

20 FOSSIL-FUELED POWER PLANTS↗

Subtask 2.18 - Advancing CO 2 Capture Technology: Partnership for CO 2 Capture (PCO 2 C) Phase III

Industries and utilities continue to investigate ways to decrease their carbon footprint. Carbon capture and storage (CCS) can enable existing power generation facilities to meet the current national CO 2 reduction goals. The Partnership for CO2 Capture Phase III focused on several important research areas in an effort to find ways to decrease the cost of capture across both precombustion and postcombustion platforms. Two flue gas pretreatment technologies for postcombustion capture, an SO 2 reduction scrubbing technology from Cansolv Technologies Inc. and the Tri-Mer filtration technology that combines particulate, NOx, and SO 2 control, were evaluated on the Energy & Environmental Research Center’s (EERC’s) pilot-scale test system. Pretreating the flue gas should enable more efficient, and therefore less expensive, CO 2 capture. Both technologies were found to be effective in pretreating flue gas prior to CO 2 capture. Two new postcombustion capture solvents were tested, one from the Korea Carbon Capture and Sequestration R&D Center (KCRC) and one from CO 2 Solutions Incorporated. Both of these solvents showed the ability to capture CO 2 while requiring less regeneration energy, which would reduce the cost of capture. Hydrogen separation membranes from Commonwealth Scientific and Industrial Research Organisation were evaluated through precombustion testing. They are composed of vanadium alloy, which is less expensive than the palladium alloys that are typically used. Their performance was comparable to that of other membranes that have been tested at the EERC. Aspen Plus® software was used to model the KCRC and CO 2 Solutions solvents and found that they would result in significantly improved overall plant performance. The modeling effort also showed that the parasitic steam load at partial capture of 45% is less than half that of 90% overall capture, indicating savings that could be accrued if 90% capture is not required. Modeling of three regional power plants using the Carnegie Mellon Integrated Environmental Control Model showed that, among other things, the use of a bypass during partial capture may minimize the size of the capture tower(s) and result in a slight reduction in the revenue required to operate the capture facility. The results reinforced that a one-size-fits-all approach cannot be taken to adding capture to a power plant. Laboratory testing indicated that Fourier transform infrared spectroscopy could be used to continuously sample stack emissions at CO 2 capture facilities to detect and quantify any residual amine or its degradation products, particularly nitrosamines. The information gathered during Phase III is important for utility stakeholders as they determine how to reduce their CO 2 emissions in a carbon-constrained world. This subtask was funded through the EERC–U.S. Department of Energy (DOE) Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the North Dakota Industrial Commission, PPL Montana, Nebraska Public Power District, Tri-Mer Corporation, Montana–Dakota Utilities Co., Basin Electric Power Cooperative, KCRC/Korean Institute of Energy Research, Cansolv Technologies, and CO 2 Solutions, Inc.

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Robust Ceramic Coaxial Cable Down-Hole Sensors for Long-Term In Situ Monitoring of Geologic CO 2 Injection and Storage

Energy generation by use of fossil fuels produces large volumes of CO 2 and other greenhouse gases, whose accumulation in the atmosphere is widely seen as undesirable. CO 2 Capture followed by sequestration has been identified as the solution. Subsurface geologic formations offer a potential location for long-term storage of CO 2 because of their requisite size. Unfortunately, the inaccessibility and complexity of the subsurface, the wide range of scales of variability, and the coupled nonlinear processes, impose tremendous challenges to determine the transport and predict the fate of the stored CO 2 . Among the various monitoring approaches, in situ down-hole monitoring of the various state parameters provides critical and direct data points that can be used to validate the models, optimize the injection, detect leakage and track the CO 2 plume. However, down-hole sensors that can withstand the harsh conditions and operate over decades of the project lifecycle remain unavailable. Given that the widespread of carbon capture and storage will be the necessity and reality in the future, fundamental and applied research is required to address the significant challenges and technological gaps in lack of long-term reliable down-hole sensors This project focused on the development and demonstration of a novel, low-cost, distributed, robust ceramic coaxial cable sensor platform for in situ down-hole monitoring of geologic CO 2 injection and storage with high spatial and temporal resolutions. The coaxial cable Fabry-Perot interferometer (CCFPI) has been studied as a general sensor platform for in situ, long-term, measurement of temperature, pressure and strain, which are critical to CO 2 injection and storage. A novel signal processing scheme has been developed and demonstrated for dense multiplexing of the sensors for low-cost distributed sensing with high spatial resolution. The developed temperature, pressure and strain sensors have been extensively tested under laboratory conditions that are similar to the downhole CO 2 storage environment, showing excellent capability for in situ monitoring the various parameters that are important to model, optimize the injection, detect leakage and track the CO 2 plume. In addition, the interactions between the sensor datum and the geological models have been investigated in details for the purposes of model validation, guiding sensor installation/placement, enhancement of model prediction capability and optimization of the injection processes. This project has resulted in the successful development of new ceramic coaxial cable based sensor systems that can monitor directly the changes in pressure, temperature, and strain caused by increased reservoir pressure and reduced reservoir temperature due to the supercritical CO 2 injection. Integrated with geological models, the sensors and measurement data can improve the possibility to identify plume movement and leakage in the cap rock and wells with higher precision and more accuracy. The low cost, ease of deployment, small size and dense multiplexing features of the new sensing technology will allow a large number of sensors to be deployed to address the objective to demonstrate that 99% of the CO 2 remains in the injection zone.

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Mickey Leland Energy Fellowship 2016

The Mickey Leland Fellowship program provide students with the opportunity to study energy at the U.S. Department of Energy, Office of Fossil Energy.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

H2@Scale Resource and Market Analysis

This presentation overviews progress to date on the H2@Scale resource and market analysis work. The work finds, for example, that hydrogen demand of 60 MMT/yr is possible when transportation and industry are considered; resources are available to meet that demand; using renewable resources would reduce emissions and fossil use by over 15%; further impacts are possible when considering synergistic benefits; additional analysis is underway to improve understanding of potential markets and synergistic impacts; and further analysis will be necessary to estimate impacts due to spatial characteristics, feedback effects in the economy, and inertia characteristics.

30 DIRECT ENERGY CONVERSION↗

chapter 40 - Gasification Technologies, "Handbook of Climate Change Mitigation and Adaptation"

Gasification is an enabling technology for the clean-up of fossil and biomass fuels for energy production. A history of gasifier development is told from the perspective of a technology evolving to meet the ever changing market needs. The chemistry and physics of coal conversion includes pyrolysis, combustion, gasification, mineral transformations as well as a discussion of the materials developed to meet the most challenging gasifier applications. Integrated gasification and combined cycle processes are discussed with respect to electrical power production. The distinguishing features for different types of gasifiers are described including fixed bed, fluidized bed, entrained flow, transport gasifiers. The twelve major gasifiers being marketed today are described. The hydrodynamics and kinetics of each are reviewed along with salient differences in performance, such as gas composition, when using a variety of fuels under different conditions. Critical operational features that are discussed include oxidizing media, air or oxygen blown; the system pressure; fuel feed stock; and downstream clean-up. Thermal integration is discussed with respect to its impact on the gasifier performance. Gas clean-up is also considered with respect to the removal of potential pollutants and the shifting to environmentally benign transportation and process fuels.

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Looking Inside a Tyrannosaur’s Skull

Researchers using Los Alamos’ unique neutron-imaging and high-energy X-ray capabilities have exposed the inner structures of the fossil skull of a 74-million-year-old tyrannosauroid dinosaur nicknamed the Bisti Beast in the highest-resolution scan of tyrannosaur skull ever done.

47 OTHER INSTRUMENTATION↗

Treatment of Produced Water from Carbon Sequestration Sites for Water Reuse and Mineral Recovery

Southern Research along with Advanced Resources International, Inc. (ARI), Heartland Technology Partners, LLC (Heartland), New Logic Research, Inc. (New Logic), and Mr. Michael N. DiFilippo, Consultant developed a concept for an on-site strategy and design for management of produced water from CO 2 sequestration sites for maximum water reuse. When CO 2 is injected into deep saline aquifers, it may be necessary to produce water from the reservoir to reduce reservoir pressure. The New Logic Research, vibratory shear enhanced process (VSEP) membrane technology, and Heartland Technology Partners, low momentum-high turbulence (LM-HT) evaporation technology was selected for evaluation for treating this produced water from a 530 MW natural gas combined cycle (NGCC) power plant by utilizing waste heat from the plant to drive the evaporation process. The technology was also evaluated for application to a coal-fired power plant in lieu of the NGCC power plant. The results from the project show that the application of the proposed technology to the 530 MW NGCC power plant scenario could be feasible. The results indicate that formation water TDS has a very large impact on the technical and economic feasibility of the process. One advantage of formations with low TDS water is that the VSEP membrane can be utilized to pre-concentrate the produced water upstream of the LM-HT. The results indicate that a significant portion of the exhaust gas from the NGCC power plant will have to be utilized to provide waste heat for the LM-HT evaporator; however, less will be required with low-TDS formation water. The CAPEX costs for LM-HT for all three formations (97.8USD to 122.7USD MM/year) and VSEP plus LM-HT (106.6USD MM/year) for the Keg River formation is high in cost but lower than all technology compared including crystallization, VSEP plus crystallization, FO plus LM-HT, VCE plus LM-HT, and VCE plus crystallization. The OPEX for the LM-HT for all three formations (6.33USD to 7.97USD MM/year) and VSEP plus LM-HT (13.29USD MM/year) for the Keg River formation is lower than crystallization, VSEP plus crystallization, FO plus LM-HT, and FO plus crystallization. Only VCE plus LM-HT and VCE plus crystallization have a comparable OPEX costs to LM-HT for all three formation and VSEP plus LM-HT for the Keg River formation. The coal-fired power plant comparison showed that it is not feasible to apply the technology to that type of fossil fuel plant.

04 OIL SHALES AND TAR SANDS↗

An assessment of potential CO2 Sources throughout the Illinois Basin Subtask 5.1 – CO2 Source Assessment Topical Report

Large-scale anthropogenic CO2 sources (>100,000 tonnes/year) were catalogued and assessed for the Illinois East Sub-Basin project area. The portfolio of sources is quite diverse, and contains not only fossil-based power generation facilities but also ethanol, chemical, and refinery facilities. Over 60% of the facilities are relatively new (i.e. post year 2000 construction) hence increasing the likelihood that retrofitting the facility with a carbon capture plant is feasible. Two of the facilities have indicated interest in being “early adopters” should the CarbonSAFE project eventually transition to a build and operate phase: the Prairie State Generating Company’s electricity generation facility near Marissa, Illinois, and Quasar Syngas, LLC’s Wabash ammonia/direct-reduced iron plant, currently in development north of Terre Haute, Indiana.

01 COAL, LIGNITE, AND PEAT↗