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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,495 records · Page 83

A review of the fabrication methods and mechanical behavior of continuous thermoplastic polymer fiber–thermoplastic polymer matrix composites

Abstract Thermoplastic polymer fiber–thermoplastic polymer matrix composites (PPCs or PRFPs), often recognized as self‐reinforced or single polymer composites, are potential candidates for future advanced polymer composites because of various advantages ( e.g., recyclability, formability, low‐cost, ultra‐lightweight, environmental friendliness, etc.). The manufacturability and mechanical behavior of these composites compared to conventional carbon‐/glass‐/aramid‐fiber‐reinforced polymers is of great interest to the composites community, but there are a limited number of studies in this area. To this end, this paper reviewed fabrication methods with different processing parameters and mechanical behavior of uni‐/multi‐directional thermoplastic PPCs featuring continuous thermoplastic polymer fibers from limited data in the literature. It was shown that most specific behaviors (normalized by density) of these materials in various loading conditions (e.g., quasi‐static tension/shear/flexure, tension‐tension fatigue, and out‐of‐plane impacting, etc.) are comparable to or better than glass‐/aramid‐fiber‐reinforced polymers. Particularly, the specific ductility in the foregoing conditions outperforms all the carbon‐/glass‐/aramid‐fiber‐reinforced polymers. Thermoplastic PPCs with remarkable performance can be achieved through several uncomplicated methods (e.g., film stacking, hot compaction, powder and solution impregnations, matrix infusion and injection molding, additive manufacturing, etc.), which have some similarities to the methods used for carbon‐/glass‐/aramid‐fiber‐reinforced polymers. Moreover, several opportunities and challenging problems of thermoplastic PPCs were summarized at the end of this review paper. Efficient solutions may require countless efforts in the composites community to further strengthen the performance and understanding of thermoplastic PPCs for wide applications in various engineering fields in the future.

36 MATERIALS SCIENCE↗

Unraveling the impact of the degree of dry mixing on dry-processed lithium-ion battery electrodes

Dry processing of lithium-ion battery electrodes facilely realizes the powder-to-film manner, which is thus regarded as a highly promising strategy for lithium-ion battery manufacturing. However, a fundamental understanding of the impact of the involved dry mixing is still rarely reported. In this work, the degree of dry mixing is monitored by the dry mixing time, and a set of dry-processed electrodes with different degree of dry mixing is accordingly prepared and comprehensively studied. This work novelly reveals that the degree of dry mixing exhibits pronounced impact on the morphology, the homogeneity of electrode components and the degree of PTFE fiberization, which leads to difference in the mechanical strength and electrochemical performance of dry-processed electrodes. Accordingly, it is suggested that a moderate degree of dry mixing is preferred for high-performance dry-processed lithium-ion battery electrodes.

25 ENERGY STORAGE↗

Effects of Protective Shell Enclosures on Uranium Adsorbing Polymers

Here, this study aims to evaluate the impact of shell enclosures on the uranium uptake of amidoxime-based polymeric adsorbents they contain. Researchers have observed that the tensile strength of the adsorbent’s polyethylene backbone is degraded after γ-irradiation to induce grafting of the amidoxime ligand. A two-part system was developed to decouple the mechanical and chemical requirements of the adsorbent by encapsulating them in a hard, permeable shell. The water flow in six shell designs and an unenclosed adsorbent for control in a recirculating flume was analyzed via a novel method developed using the measurement of radium extracted onto MnO 2 impregnated acrylic fibers. Although the water flow was found to vary with enclosure design, orien- tation to the flow, and placement within the flume, little to no difference was observed in the uranium adsorption rate between all enclosures. The results of this study will be used to design a large-scale ocean deployment of a uranium harvesting system.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Optimized CRISPR Interference System for Investigating Pseudomonas alloputida Genes Involved in Rhizosphere Microbiome Assembly

Pseudomonas alloputida KT2440 (formerly P. putida) has become both a well-known chassis organism for synthetic biology and a model organism for rhizosphere colonization. Here, we describe a CRISPR interference (CRISPRi) system in KT2440 for exploring microbe–microbe interactions in the rhizosphere and for use in industrial systems. Our CRISPRi system features three different promoter systems (XylS/P m , LacI/P lac , and AraC/P BAD ) and a dCas9 codon-optimized for Pseudomonads, all located on a mini-Tn7-based transposon that inserts into a neutral site in the genome. It also includes a suite of pSEVA-derived sgRNA expression vectors, where the expression is driven by synthetic promoters varying in strength. We compare the three promoter systems in terms of how well they can precisely modulate gene expression, and we discuss the impact of environmental factors, such as media choice, on the success of CRISPRi. We demonstrate that CRISPRi is functional in bacteria colonizing the rhizosphere, with repression of essential genes leading to a 10–100-fold reduction in P. alloputida cells per root. Finally, we show that CRISPRi can be used to modulate microbe–microbe interactions. When the gene pvdH is repressed and P. alloputida is unable to produce pyoverdine, it loses its ability to inhibit other microbes in vitro. Furthermore, our design is amendable for future CRISPRi-seq studies and in multispecies microbial communities, with the different promoter systems providing a means to control the level of gene expression in many different environments.

Bacteria↗

Extended anharmonic collapse of phonon dispersions in SnS and SnSe

The lattice dynamics and high-temperature structural transition in SnS and SnSe are investigated via inelastic neutron scattering, high-resolution Raman spectroscopy and anharmonic first-principles simulations. We uncover a spectacular, extreme softening and reconstruction of an entire manifold of low-energy acoustic and optic branches across a structural transition, reflecting strong directionality in bonding strength and anharmonicity. Further, our results solve a prior controversy by revealing the soft-mode mechanism of the phase transition that impacts thermal transport and thermoelectric efficiency. Our simulations of anharmonic phonon renormalization go beyond low-order perturbation theory and capture these striking effects, showing that the large phonon shifts directly affect the thermal conductivity by altering both the phonon scattering phase space and the group velocities. These results provide a detailed microscopic understanding of phase stability and thermal transport in technologically important materials, providing further insights on ways to control phonon propagation in thermoelectrics, photovoltaics, and other materials requiring thermal management.

36 MATERIALS SCIENCE↗

NEET-AMM Final Technical Report on Laser Direct Manufacturing (LDM) for Nuclear Power Components

Final technical report summarizes the program progress and technical accomplishments of the Laser Direct Manufacturing (LDM) for Nuclear Power Components project. A series of experiments varying build process parameters (scan speed and laser power) were conducted at the outset to establish the optimal build conditions for each of the alloys. Fabrication was completed in collaboration with Quad City Manufacturing Laboratory (QCML). The density of all sample specimens was measured and compared to literature values. Optimal build process conditions giving fabricated part densities close to literature values were chosen for making mechanical test coupons. Test coupons whose principal axis is on the x-y plane (perpendicular to build direction) and on the z plane (parallel to build direction) were built and tested as part of the experimental build matrix to understand the impact of the anisotropic nature of the process.. Investigations are described 316L SS, Inconel 600, 718 and 800 and oxide dispersion strengthed 316L SS (Yttria) alloys.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Vigilance: A Review of the Literature and Applications to Sentry Duty

Vigilance, or sustained attention, involves the ability to maintain focus and remain alert for prolonged periods of time. Problems associated with the ability to sustain attention were first identified in real-world combat situations during World War II, and they continue to abound and evolve as new and different types of situations requiring vigilance arise. This paper provides a review of the vigilance literature that describes the primary psychophysical, task, environmental, pharmacological, and individual factors that impact vigilance performance. The paper also describes how seminal findings from vigilance research apply specifically to the task of sentry duty. The strengths and weaknesses of a human sentry and options to integrate human and automated functions for vigilance tasks are discussed. Finally, techniques that may improve vigilance performance for sentry duty tasks are identified.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Flow characteristics in the exhaust of a pulsed megawatt gas fed arc

The transient flow generated by a pulsed, megawatt-level, gas-fed arc with an applied magnetic nozzle has been examined with a new design piezoelectric pressure transducer. Sensor thermal conduction and accelerations have been examined and eliminated in the 500 microsec period of plasma flow. Existence of a large magnitude cold gas pressure front of 20 microsec duration has been reconfirmed and its relationship to the following plasma flow of about 200 microsec duration has been examined for the first time. At a point 30 cm from the arc source, initially near vacuum conditions (typically with an arc current of 11.2 kA and 1 tesla applied magnetic field), a pressure pulse of unionized gas with a magnitude of 10,000 N/sq m is followed by plasma flows with nearly constant impact pressure of 1000 N/sq m. Pressure and number density in this plasma region are seen to decrease with applied magnetic field strength.

Michels, C. J.↗

Tethers for Mars space operations

A tether-mediated transport system is proposed in which mass may be transferred between the Martian surface, Mars orbit, and open space, using the orbital momentum of Phobos and Deimos. The performance and materials strength requirements of a prototype tether system are studied with attention given to: tether dynamics effects during different stages of operation; micrometeoroid impact effects; replacement of tether segments; and contingency methods in case of tether failure. A schematic diagram of the proposed tether transportation system is provided.

Penzo, P. A.↗

A timely rationale for space exploration

Space exploration is shown to be useful for enhancing a country's education, technology, and economic competitiveness. Technologies required for the Space Exploration Initiative are compared to emerging technologies identified by the U.S. Department of Commerce. The impact of previous space ventures on specific technologies are illustrated with examples such as miniaturized electronics, computers and software, and high-strength materials. The case for educational advancement as a by-product of space exploration is made by discussing the high-level requirements of the programs and describing the inspirational effect of space exploration on young students. Invigorating space exploration is argued to generate near- and long-term economic opportunities for key sectors of the national economy by means of technology transfer, space-resource utilization, and the commercialization of space.

Peterson, Douglas D.↗

Indentability of conventional and negative Poisson's ratio foams

The indentation resistance of foams, both of conventional structure and of re-entrant structure giving rise to negative Poisson's ratio, is studied using holographic interferometry. In holographic indentation tests, re-entrant foams had higher yield strengths sigma(sub y) and lower stiffness E than conventional foams of the same original relative density. Calculated energy absorption for dynamic impact is considerably higher for re-entrant foam than conventional foam.

Lakes, R. S.↗

Design Concept for a Reusable/Propellantless MXER Tether Space Transportation System

The Momentum Exchange/Electrodynamic Reboost (MXER) tether facility is a transformational concept that significantly reduces the fuel requirements (and associated costs) in transferring payloads above low earth orbit (LEO). Facility reboost is accomplished without propellant by driving current against a voltage created by a conducting tether's interaction with the Earth's magnetic field (electrodynamic reboost). This system can be used for transferring a variety of payloads (scientific, cargo, and human space vehicles) to multiple destinations including geosynchronous transfer orbit, the Moon or Mars. MXER technology advancement requires development in two key areas: survivable, high tensile strength non-conducting tethers and reliable, lightweight payload catch/release mechanisms. Fundamental requirements associated with the MXER non-conducting strength tether and catch mechanism designs will be presented. Key requirements for the tether design include high specific-strength (tensile strength/material density), material survivability to the space environment (atomic oxygen and ultraviolet radiation), and structural survivability to micrometeoroid/orbital debris (MM/OD) impacts. The driving mechanism key,gequirements include low mass-to-capture-volume ratio, positional and velocity error tolerance, and operational reliability. Preliminary tether and catch mechanism design criteria are presented, which have been used as guidelines to "screen" and down-select initial concepts. Candidate tether materials and protective coatings are summarized along with their performance in simulated space environments (e.g., oxygen plasma, thermal cycling). A candidate catch mechanism design concept is presented along with examples of demonstration hardware.

McCandless, B., II↗

Response of Damaged and Undamaged Tailored Extension-Shear-Coupled Composite Panels

The results of an analytical and experimental investigation of the response of composite I-stiffener panels with extension-shear coupling are presented. This tailored concept, when used in the panel cover skins of a tiltrotor aircraft wing has the potential for increasing the aeroelastic stability margins and improving the aircraft productivity. The extension-shear coupling is achieved by using unbalanced plus or minus 45 deg. plies in the skin. Experimental and STAGS analysis results are compared for eight I-stiffener panel specimens. The results indicate that the tailored concept would be feasible to use in the wing skin of a tiltrotor aircraft. Evaluation of specimens impacted at an energy level of 500 in.-lbs indicate a minimal loss in stiffness and less than 30 percent loss in strength. Evaluation of specimens with severed center stiffener and adjacent skin indicated a strength loss in excess of 60 percent.

Baker, Donald J.↗

Diagnosing the Nature of Land-Atmosphere Coupling: A Case Study of Dry/Wet Extremes in the U. S. Southern Great Plains

Land-atmosphere (L-A) interactions play a critical role in determining the diurnal evolution of land surface and planetary boundary layer (PBL) temperature and moisture states and fluxes. In turn, these interactions regulate the strength of the connection between surface moisture and precipitation in a coupled system. To address model deficiencies, recent studies have focused on development of diagnostics to quantify the strength and accuracy of the land- PBL coupling at the process-level. In this paper, a diagnosis of the nature and impacts of local land-atmosphere coupling (LoCo) during dry and wet extreme conditions is presented using a combination of models and observations during the summers of 2006 and 2007 in the U.S. Southern Great Plains. A range of diagnostics exploring the links and feedbacks between soil moisture and precipitation are applied to the dry/wet regimes exhibited in this region, and in the process a thorough evaluation of nine different land-PBL scheme couplings is conducted under the umbrella of a high-resolution regional modeling testbed. Results show that the sign and magnitude of errors in land surface energy balance components are sensitive to the choice of land surface model, regime type, and running mode. In addition, LoCo diagnostics show that the sensitivity of L-A coupling is stronger towards the land during dry conditions, while the PBL scheme coupling becomes more important during the wet regime. Results also demonstrate how LoCo diagnostics can be applied to any modeling system (e.g. reanalysis products) in the context of their integrated impacts on the process-chain connecting the land surface to the PBL and in support of hydrological anomalies.

Santanello, Joseph A. Jr.↗

Dynamic Acquisition and Retrieval Tool (DART) for Comet Sample Return : Session: 2.06.Robotic Mobility and Sample Acquisition Systems

The 2011 Decadal Survey for planetary science released by the National Research Council of the National Academies identified Comet Surface Sample Return (CSSR) as one of five high priority potential New Frontiers-class missions in the next decade. The main objectives of the research described in this publication are: develop a concept for an end-to-end system for collecting and storing a comet sample to be returned to Earth; design, fabricate and test a prototype Dynamic Acquisition and Retrieval Tool (DART) capable of collecting 500 cc sample in a canister and eject the canister with a predetermined speed; identify a set of simulants with physical properties at room temperature that suitably match the physical properties of the comet surface as it would be sampled. We propose the use of a dart that would be launched from the spacecraft to impact and penetrate the comet surface. After collecting the sample, the sample canister would be ejected at a speed greater than the comet's escape velocity and captured by the spacecraft, packaged into a return capsule and returned to Earth. The dart would be composed of an inner tube or sample canister, an outer tube, a decelerator, a means of capturing and retaining the sample, and a mechanism to eject the canister with the sample for later rendezvous with the spacecraft. One of the significant unknowns is the physical properties of the comet surface. Based on new findings from the recent Deep Impact comet encounter mission, we have limited our search of solutions for sampling materials to materials with 10 to 100 kPa shear strength in loose or consolidated form. As the possible range of values for the comet surface temperature is also significantly different than room temperature and testing at conditions other than the room temperature can become resource intensive, we sought sample simulants with physical properties at room temperature similar to the expected physical properties of the comet surface material. The chosen DART configuration, the efforts to identify a test simulant and the properties of these simulants, and the results of the preliminary testing will be described in this paper.

Dynamic Acquisition and Retrieval Tool (DART)↗

Diagnosing the Nature of Land-Atmosphere Coupling: A Case Study of Dry/Wet Extremes in the U.S. Southern Great Plains

Land-atmosphere (L-A) interactions play a critical role in determining the diurnal evolution of land surface and planetary boundary layer (PBL) temperature and moisture states and fluxes. In turn, these interactions regulate the strength of the connection between surface moisture and precipitation in a coupled system. To address model deficiencies, recent studies have focused on development of diagnostics to quantify the strength and accuracy of the land-PBL coupling at the process level. In this paper, a diagnosis of the nature and impacts of local land-atmosphere coupling (LoCo) during dry and wet extreme conditions is presented using a combination of models and observations during the summers of 2006 and 2007 in the U.S. southern Great Plains. A range of diagnostics exploring the links and feedbacks between soil moisture and precipitation is applied to the dry/wet regimes exhibited in this region, and in the process, a thorough evaluation of nine different land-PBL scheme couplings is conducted under the umbrella of a high-resolution regional modeling test bed. Results show that the sign and magnitude of errors in land surface energy balance components are sensitive to the choice of land surface model, regime type, and running mode. In addition, LoCo diagnostics show that the sensitivity of L-A coupling is stronger toward the land during dry conditions, while the PBL scheme coupling becomes more important during the wet regime. Results also demonstrate how LoCo diagnostics can be applied to any modeling system (e.g., reanalysis products) in the context of their integrated impacts on the process chain connecting the land surface to the PBL and in support of hydrological anomalies.

southern plains↗

Combustor-Turbine Interactions By Using the Open National Combustion Code (OpenNCC) and the Glenn-HT Code

We develop the methodology of coupling two different computational fluid dynamic (CFD) codes, OpenNCC and Glenn-HT, in order to investigate the unsteady flow fields inside the combustor and around the first-stage stator of a high-pressure turbine (HPT) from the energy efficient engine (E 3 ) program. In our coupling strategy, OpenNCC, a time accurate unstructured mesh multi-phase combustion CFD code, is applied to the combustor region and Glenn-HT, a structured mesh CFD code designed for turbine applications, is utilized inside the HPT region. As a proof of concept, we first simulate the three-dimensional airflow over the backward facing step and compared the predicted pressure coefficient against experimental data. We then considered a Jet-A/Air combustor with the NASA single learn direct injector (LDI) as a reacting flow test case. Here, Glenn-HT is used in the downstream of the combustor and assumes that the working fluid is a single gas (i.e., air) where the properties of the gas are taken from time- and area-averaged values at the combustor exit. A fully coupled combustor-turbine simulation using both OpenNCC and Glenn-HT was conducted on the E 3 combustor and a detailed analysis done pertaining to how a realistic combustor outflow affects migration of hot-streaks and its impact on the aerodynamic behavior inside the HPT. It is found that the combustion dynamics (i.e., the switching main and pilot flame strength) significantly alters the aerodynamic behavior inside the HPT including hot-streak migration. Variations of the temperature and the velocity magnitude in the passage could be up to ±75 and ±15. These large variations are an important part of the combustor-turbine interactions, which are overlooked by a single component simulation of the HPT while imposing the steady inflow boundary condition at the HPT inlet. Finally, it is observed the strong density gradient associated with the hot-streaks and the pressure gradient at the passage significantly enhances the baroclinic torque, affecting the vorticity field.

CFD hot-streaks↗

Scalar Atomic Defect-Based Solid-State Self-calibrating Magnetometer (3SM) for Space Plasma Analysis

The Earth’s magnetosphere is a system of multiple, co-located particle populations interacting via plasma waves. Things to understand are driving processes, radiation belt and ring current issues, auroral physics, internal plasma processes, and magnetosphere-ionosphere mapping issues. These plasma-physics processes enable the Earth’s magnetosphere to evolve in response to temporal changes in the solar wind and they underlie the phenomena of space weather, which impacts spacecraft systems, astronauts, radio communications, and ground based electric-power grids. The objective of 3SM is to measure magnetic field strength and to calibrate the Vector Magnetometer (VM) device to maintain absolute accuracy during a mission. The 3SM features make the instrument preferably suited not only for the traditional role of scalar magnetometers as absolute references for the calibration of the on-board vector instruments, but also for extended operational capacities, such as higher frequency scalar measurements (of potential interest for magnetosphere studies for the low frequency part of the spectrum) or autonomous scalar / vector operations. Diamond has been the solid-state platform of choice for quantum device technologies for some time, however, it suffers from difficulties such as scalability, integration, and cost. While the diamond platform is very useful for quantum technologies, further development is needed to make it viable. The material platform of choice for NASA Glenn’s Quantum Sensing And Spin Physics (Q-SASP) is silicon carbide (SiC). This is due to the much higher industry development of the SiC material platform for high-power and high-temperature electronics. It leverages both the decades-long SiC development expertise and infrastructure at NASA Glenn and its growing capabilities in quantum metrology. To make SiC devices usable for quantum technologies such as quantum sources, a much deeper understanding of defects is needed. Q-SASP is developing quantum metrology capabilities to evaluate the energy structure, defect formation energy, band structure augmentation, generation/recombination rates, and limits of dipole-dipole coupling in non-metal implanted SiC devices. This can be achieved by analysis of zero-field splitting, low-field resonance, and singlet-triplet mixing through various forms of Electrically Detectable Magnetic Resonance (EDMR) and Near-Zero Field Magnetic Resonance (NZFMR) spectroscopy. This work will discuss recent system developments, device developments, computational modeling, and spectroscopy results and analysis of defects created by non-metal implantations in SiC devices. The defect formation energies of V Si ,V C , V C V Si , N C V Si , N Si , N C in 4H-SiC are previously reported values in other research [2]-[3]. The defect formation energies of PSi and PC were calculated in GPAW [fig 1A]. The basic underlying mechanism of the zero-field phenomenon is the mixing of singlet and triplet states [4]-[5]. In most spin-dependent transport, two electron spins are involved, and thus one must consider each of their interactions with the field. We investigated the electronic and magnetic properties of 4H-SiC and 6H-SiC. The defect formation energy helps us determine what types of defects we are observing in the SiC EDMR experiment. They have very low formation energy (it is negative). The phosphorus substitution in 4H-SiC is a very stable defect. The band diagrams provide us with vital information about how the electronic properties of SiC (such as band gap) change as we add non-metal defects. The zero-field splitting parameters allow us to study the inflection point in the NZFMR [fig 1B]. We clearly observed zero-field splitting. We also noted that the zero-field splitting remained constant with changing bias. We aspect it zero-field splitting to remain constant while the hyperfine and exchange interaction perturbations shift under the influence of an external magnetic field. This is the essence of quantum magnetometry and self-calibration.

space plasma↗