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Tracking the Light-Induced Excited-State Dynamics and Structural Configurations of an Extraordinarily Long-Lived Metastable State at Room Temperature

Time-resolved X-ray (Tr-XAS) and optical transient absorption (OTA) spectroscopy in the pico-microsecond time scale coupled with Density Functional theory calculations are applied to study the light-induced spin crossover processes of a Fe-based macrocyclic complex in solution. Tr-XAS analysis after light illumination shows the formation of a seven-coordinated high spin quintet metastable state which relaxes to a six-coordinated high spin configuration before decaying to ground state. Kinetic analysis of the macrocyclic complex reveals an unprecedented long-lived decay lifetime of ~42.6 µs. Comparative studies with a non-macrocyclic counterpart illustrate a significantly shortened ~568-old decay lifetime of ~75 ns, and highlight the importance of the ligand arrangement in stabilizing the reactivity of the excited state. Lastly, OTA analysis shows the seven-coordinated high spin state to be formed within ~6.2 ps. Finally, these findings provide a complete understanding of the spin crossover reaction and relaxation pathways of the macrocyclic complex, and reveal the importance of a flexible coordination environment for their rational design.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Effect of Thermodenuding on the Structure of Nascent Flame Soot Aggregates

The optical properties (absorption and scattering) of soot particles depend on soot size and index of refraction, but also on the soot complex morphology and the internal mixing with materials that can condense on a freshly emitted (nascent) soot particle and coat it. This coating can affect the soot optical properties by refracting light, or by changing the soot aggregate structure. A common approach to studying the effect of coating on soot optical properties is to measure the absorption and scattering coefficients in ambient air, and then measure them again after removing the coating using a thermodenuder. In this approach, it is assumed that: (1) most of the coating material is removed; (2) charred organic coating does not add to the refractory carbon; (3) oxidation of soot is negligible; and, (4) the structure of the pre-existing soot core is left unaltered, despite the potential oxidation of the core at elevated temperatures. In this study, we investigated the validity of the last assumption, by studying the effect of thermodenuding on the morphology of nascent soot. To this end, we analyzed the morphological properties of laboratory generated nascent soot, before and after thermodenuding. Our investigation shows that there is only minor restructuring of nascent soot by thermodenuding

54 ENVIRONMENTAL SCIENCES↗

Retrieving Aerosol Characteristics From the PACE Mission, Part 1: Ocean Color Instrument

NASA’s Plankton, Aerosol, Clouds, ocean Ecosystem (PACE) satellite mission is scheduled to launch in 2022, with the Ocean Color Instrument (OCI) on board. For the first time reflected sunlight from the Earth across a broad spectrum from the ultraviolet (UV: 350 nm) to the short wave infrared (SWIR: 2260 nm) will be measured from a single instrument at 1 km spatial resolution. While seven discrete bands will represent the SWIR, the spectrum from 350 to 890 nm will be continuously covered with a spectral resolution of 5 nm. OCI will thus combine in a single instrument (and at an enhanced spatial resolution for the UV) the heritage capabilities of the Moderate resolution Imaging Spectroradiometer (MODIS) and the Ozone Monitoring Instrument (OMI), while covering the oxygen A-band (O2A). Designed for ocean color and ocean biology retrievals, OCI also enables continuation of heritage satellite aerosol products and the development of new aerosol characterization from space. In particular the combination of MODIS and OMI characteristics allows deriving aerosol height, absorption and optical depth along with a measure of particle size distribution. This is achieved by using the traditional MODIS visible-to-SWIR wavelengths to constrain spectral aerosol optical depth and particle size. Extrapolating this information to the UV channels allows retrieval of aerosol absorption and layer height. A more direct method to derive aerosol layer height makes use of O2A absorption methods, despite the relative coarseness of the nominal 5 nm spectral resolution of OCI. Altogether the PACE mission with OCI will be an unprecedented opportunity for aerosol characterization that will continue climate data records from the past decades and propel aerosol science forward toward new opportunities.

PACE↗

Asymptotic Solutions for Optical Properties of Large Particles with Strong Absorption

The transverse wave condition is not applicable to the refracted electromagnetic wave within the context of geometrical optics when absorption is involved. Either the transverse magnetic (TM) or the transverse electric (TE) wave condition can be assumed for the wave to locally satisfy the electromagnetic boundary condition in a ray-tracing calculation. The assumed wave mode affects both the reflection and the refraction coefficients. As a result, nonunique solutions for these coefficients are inevitable. In this study the appropriate solutions for the Fresnel reflection-refraction coefficients are identified in light-scattering calculations based on the ray-tracing technique. In particular, a 3x2 refraction or transmission matrix is derived to account for the inhomogeneity of the refracted wave in an absorbing medium. An asymptotic solution that completely includes the effect of medium absorption on Fresnel coefficients is obtained for the scattering properties of a general polyhedral particle. Numerical results are presented for hexagonal plates and columns with both preferred and random orientations.

Yang, Ping↗

Major improvements on the longwave radiative interactions between surface and clouds in the Polar Regions in atmospheric global circulation model (GCM). Final Project Report

1. Summary of Work and Accomplishments in Year 1 (01/15/2015-01/14/2016). We developed new ice cloud parameterizations based on state-of-the-art MODIS Collection 6 (MC6) ice particle model. Features of the model include the consideration of surface roughness of ice crystals and spectral consistency in cloud property retrievals. Using more than 14,000 particle size distributions (PSDs) from in-situ measurements and the latest ice particle single-scattering property library, our parameterizations provide band-averaged bulk-scattering properties. According to statistics of fittings, the parameterization schemes represent the band-averaged bulk-scattering properties very well. Compared to the ice particle model developed by Fu (1998), flux simulations with the MC6 particle model result in larger upward flux at the top of the atmosphere (TOA) and smaller at the surface for typical cirrus clouds. In the assessment of the effect of longwave light scattering, our results also support the conclusions of previous studies. The error in flux calculations reaches about 10 W/m 2 when a cirrus cloud is thin and its particle size is small. 2. Summary of Work and Accomplishments in Year 2 (01/15/2016-01/14/2017) Clouds are a major modulator of the global radiation budgets. However, representations of clouds in general circulation models (GCMs) neglect many important processes, particularly those related to ice clouds. One major uncertainty source is the radiative transfer scheme in GCMs. To reduce the computational burden in most GCMs, absorption is the only radiative transfer process considered in longwave spectral bands. Recently, a state-of-the-art MC6 ice model has been available, which provides spectral consistency in ice cloud retrievals. With an advanced light scattering library for ice particles, we performed sensitivity studies of the potential impacts on the climate including light scattering for MC6 model and other 11 ice cloud models. Specifically, we modified RRTMG_LW (the GCM version of Longwave Rapid Radiative Transfer Model), a radiative transfer module widely used in GCMs and numerical prediction models, to identify flux simulation differences with and without considering light scattering processes. The simulations with light scattering come from a rigorous radiative solver, DISORT (Discrete Ordinates Radiative Transfer Program for a Multi-Layered Plane-Parallel Medium), are used as benchmarks. The results show that the weighted annual mean biases of RRTMG_LW for the upward flux at the top of the atmosphere, the downward flux at the surface, and the net flux into the atmosphere are about 0.8 ± 0.3, -0.1 ± 0.05, and -0.7 ± 0.3 W m-2, respectively. According to the different the ice crystal shapes, the weighted annual mean bias for heating rate is about -0.006 ± 0.02 to 0.04 K/day. 3. Summary of Work and Accomplishments in Year 3 (01/15/2017-01/14/2018) Since absorption dominates optical properties of clouds in the longwave (LW) spectrum, most of general circulation models (GCMs) only take absorption properties of clouds into account in the radiative transfer modules in order to reduce computational costs. To quantify the biases of excluding LW scattering when clouds exist, we simulated fluxes and heating rates by using satellite data from Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO), CloudSat, Clouds and the Earth’s Radiant Energy System (CERES) and Moderate Resolution Imaging Spectrometer (MODIS) merged products (CCCM) in 2010. In annual global average, neglecting LW scattering causes overestimation by 2.6 W/m 2 for the top-of-atmosphere (TOA) upward fluxes and underestimation by 1.2 W/m 2 for surface downward fluxes. In particular, regional extreme biases are approximately 12 W/m 2 for TOA upward fluxes and are approximately -3.6 W/m 2 for surface downward fluxes, or are approximately 5% of the global averaged outgoing longwave radiation (OLR) and 1% of the global averaged surface downward fluxes, respectively. In terms of heating rates, on average, LW scattering heats the whole atmosphere column by 0.0045 K/day, heats the cloud layers by 0.0420 K/day, heats the surface by 0.028 K/day, and cools the tropopause by 0.018 K/day.

58 GEOSCIENCES↗

Electronic band structure and optical properties of antimony selenide under pressure

In this work we present the optical properties of Antimony Selenide (Sb{sub 2}Se{sub 3}) under ambient conditions and under pressure of 9.2 GPa obtained using first principles calculations. We investigated the electronic band structure using the FP-LAPW method within the sphere of the density functional theory. Optical properties like refractive index, absorption coefficient and optical conductivity are calculated using the WIEN2k code.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

QUASARS PROBING QUASARS. IV. JOINT CONSTRAINTS ON THE CIRCUMGALACTIC MEDIUM FROM ABSORPTION AND EMISSION

We have constructed a sample of 29 close projected quasar pairs where the background quasar spectrum reveals absorption from optically thick H I gas associated with the foreground quasar. These unique sightlines allow us to study the quasar circumgalactic medium (CGM) in absorption and emission simultaneously, because the background quasar pinpoints large concentrations of gas where Ly{alpha} emission, resulting from quasar-powered fluorescence, resonant Ly{alpha} scattering, and/or cooling radiation, is expected. A sensitive search (1{sigma} surface-brightness limits of SB{sub Ly{alpha}}{approx_equal}3 Multiplication-Sign 10{sup -18} erg s{sup -1} cm{sup -2} arcsec{sup -2}) for diffuse Ly{alpha} emission in the environments of the foreground (predominantly radio-quiet) quasars is conducted using Gemini/GMOS and Keck/LRIS slit spectroscopy. We fail to detect large-scale {approx}100 kpc Ly{alpha} emission, either at the location of the optically thick absorbers or in the foreground quasar halos, in all cases except a single system. We interpret these non-detections as evidence that the gas detected in absorption is shadowed from the quasar UV radiation due to obscuration effects, which are frequently invoked in unified models of active galactic nuclei. Small-scale R {approx}< 50 kpc extended Ly{alpha} nebulosities are detected in 34% of our sample, which are likely the high-redshift analogs of the extended emission-line regions (EELRs) commonly observed around low-redshift (z < 0.5) quasars. This may be fluorescent recombination radiation from a population of very dense clouds with a low covering fraction illuminated by the quasar. We also detect a compact high rest-frame equivalent width (W{sub Ly{alpha}} > 50 A) Ly{alpha}-emitter with luminosity L{sub Ly{alpha}} = 2.1 {+-} 0.32 Multiplication-Sign 10{sup 41} erg s{sup -1} at small impact parameter R = 134 kpc from one foreground quasar, and argue that it is more likely to result from quasar-powered fluorescence, than simply be a star-forming galaxy clustered around the quasar. Our observations imply that much deeper integrations with upcoming integral-field spectrometers such as MUSE and KCWI will be able to routinely detect a diffuse Ly{alpha} glow around bright quasars on scales R {approx} 100 kpc and thus directly image the CGM.

79 ASTRONOMY AND ASTROPHYSICS↗

QUASARS PROBING QUASARS. VI. EXCESS H I ABSORPTION WITHIN ONE PROPER Mpc OF z ∼ 2 QUASARS

With close pairs of quasars at different redshifts, a background quasar sightline can be used to study a foreground quasar's environment in absorption. We use a sample of 650 projected quasar pairs to study the H I Lyα absorption transverse to luminous, z ∼ 2 quasars at proper separations of 30 kpc < R < 1 Mpc. In contrast to measurements along the line-of-sight, regions transverse to quasars exhibit enhanced H I Lyα absorption and a larger variance than the ambient intergalactic medium, with increasing absorption and variance toward smaller scales. Analysis of composite spectra reveals excess absorption characterized by a Lyα equivalent width profile W = 2.3 Å (R /100 kpc){sup –0.46}. We also observe a high (≅ 60%) covering factor of strong, optically thick H I absorbers (H I column N{sub H{sub I}}>10{sup 17.3} cm{sup -2}) at separations R < 200 kpc, which decreases to ∼20% at R ≅ 1 Mpc, but still represents a significant excess over the cosmic average. This excess of optically thick absorption can be described by a quasar-absorber cross-correlation function ξ{sub QA}(r) = (r/r{sub 0}){sup γ} with a large correlation length r{sub 0} = 12.5{sup +2.7}{sub -1.4} h{sup -1} Mpc (comoving) and γ=1.68{sup +0.14}{sub -0.30}. The H I absorption measured around quasars exceeds that of any previously studied population, consistent with quasars being hosted by massive dark matter halos M{sub halo} ≈ 10{sup 12.5} M{sub ☉} at z ∼ 2.5. The environments of these massive halos are highly biased toward producing optically thick gas, and may even dominate the cosmic abundance of Lyman limit systems and hence the intergalactic opacity to ionizing photons at z ∼ 2.5. The anisotropic absorption around quasars implies the transverse direction is much less likely to be illuminated by ionizing radiation than the line-of-sight.

79 ASTRONOMY AND ASTROPHYSICS↗

Crystalline Silicon Solar Cells

Most solar cells are fabricated from crystalline or semicrystalline silicon since they are relatively inexpensive starting materials and the resulting solar cells are very efficient. As a result, the optical properties of silicon are extremely important in many aspects of solar cell manufacture, and have been determined by many groups using several techniques. The most reliable values of the optical functions of silicon have been determined using spectroscopic ellipsometry, augmented by optical transmission measurements of the absorption coefficient for wavelengths greater than 700 nm. Obviously, these optical functions depend on the wavelength of light, but they also depend significantly on temperature and morphology. Several thin films are very important to solar cell manufacture, including silicon nitride, silicon dioxide, and aluminum oxide. While the optical properties of these thin films are strong functions of deposition conditions, spectroscopic ellipsometry is ideal for characterizing them. This work will present recent spectroscopic ellipsometry data and optical transmission data from which the optical functions of silicon are obtained. The optical transmission data have been fit from 700 to 1200 nm to a modification of Macfarlane’s et al. formula [Phys. Rev. 111, (1958) 759], resulting in a reduced χ2 of 0.84. This formulation is particularly valuable in that it gives the optical absorption coefficient from 700 to 1200 nm as a function of both wavelength and temperature.

Jellison Jr, Gerald Earle↗

Synthesis and optical properties of phosphorus doped ZnO: X-ray absorption, X-ray emission, and X-ray excited optical luminescence studies

Abstract Over the past decades, zinc oxide semiconductor and its derivatives have been extensively developed because of its optoelectronic properties. Since ZnO is an intrinsic n-type semiconductor, how to synthesize high-quality p-type ZnO semiconductors and investigate their optoelectronic properties and local chemical structures are important and necessary. In this article, two studies of synthesizing both undoped and phosphorus-doped ZnO nanostructures by hydrothermal method and chemical vapor deposition (CVD) technique are presented. Scanning electron microscopy (SEM) and laboratory X-ray diffraction (XRD) are used to track the surface morphology and the crystalline structure of both undoped and phosphorus doped ZnO nanostructures, respectively. X-ray absorption near edge structures (XANES), X-ray emission spectroscopy (XES) and X-ray excited optical luminescence (XEOL) are also used to determine the local chemical information of both undoped and phosphorus-doped ZnO nano/microstructures such as local symmetry and optical properties. It is found that the phosphorus is successfully doped into the surface of ZnO and substituted the Zn. The phosphorus-doped ZnO products have better crystallinity and less oxygen vacancies on the surface. These two are correlated as one leads to the other. The XEOL results suggest that the average bandgap for undoped and phosphorus doped ZnO is the same, 3.24 eV. The second derivative of the absorption-emission spectra yields the fundamental bandgap for undoped ZnO and phosphorus-doped ZnO is 3.25 eV. The implication of this observation is discussed.

Chemistry↗

Photothermoelastic contrast in nanoscale infrared spectroscopy

The contrast formation mechanism in nanoscale Infrared (IR) Spectroscopy is analyzed. The temperature distribution and elastic displacement across the illuminated T-shape boundary between two materials with different IR-radiation absorption coefficients and thermo-physical and elastic properties located on a rigid substrate are calculated self-consistently for different frequencies f ~ (1 kHz–1 MHz) of IR-radiation modulation (fully coupled problem). Analytical expressions for the temperature and displacement profiles across the “thermo-elastic step” are derived in the decoupling approximation for f = 0 (“static limit”), and conditions for approximation validity at low frequencies of IR-modulation are established. The step height was found to be thickness-independent for thick layers and proportional to the square of the thickness for very thin films. The theoretical results will be of potential interest for applications in the scanning thermo-ionic and thermal infrared microscopies for relatively long sample thermalization times and possibly for photothermal induced resonance microscopy using optomechanical probes.

36 MATERIALS SCIENCE↗

Electrical and optical properties of fluid iron from compressed to expanded regime

Using quantum molecular dynamics simulations, we show that the electrical and optical properties of fluid iron change dramatically from compressed to expanded regime. Along isochores, the main trend of the electrical resistivity, which is in good agreement with experimental data, is found to be well reproduced by our calculations. Near low densities, where the constant volume derivative of the electrical resistivity on internal energy becomes negative, the transition of iron from the metallic to the non-metallic state takes place. The study of the optical conductivity, absorption coefficient, and Rosseland mean opacity shows that, quantum molecular dynamics combined with the Kubo-Greenwood formula provide powerful tools to explore the electrical and optical properties of fluid iron.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Optical-property coefficient estimation of bulky medium in experiments with a succinctly analytical calculation

Diffuse optical imaging enables to reconstruct distribution of optical properties, absorption and scattering coefficients, in tissue for breast cancer detection based on diffusion equation with the help of the initial guess obtained from measured data. To estimate the initial guess of the optical-property coefficients, an analytical solution of diffusion equation can be used and compared with the measured data. The analytical solution for a homogeneous infinite medium can be obtained in the frequency domain, expressing that the photon intensity and the phase lag relative to the distance between source and detector in a linear relationship. In this study, a succinct calculation using the trigonometric relation is proposed to estimate the optical-property coefficients. A tank-type and a cylinder Lipovenoes phantoms with two concentrations of 1.25% and 2.5% are employed and measured for verification. It is found that the method proposed here shows better results and results in estimation errors of 0–14.81% for μ{sub a} and 20–42% for μ{sub s}′.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of TiO 2 content on the crystallization and the color of (ZrO 2 ,TiO 2 )-doped Li 2 O-Al 2 O 3 -SiO 2 glasses

Glass–ceramics formed by controlled crystallization of Li 2 O–Al 2 O 3 –SiO 2 (LAS) parent glasses are well-known for their low thermal expansion and transparency. In order to promote bulk crystallization, it is necessary to add nucleating agents like TiO 2 and ZrO 2 to the glass composition leading to ZrTiO 4 nuclei during heating, followed by the crystallization of a β-quartz phase that transforms into β-spodumene at higher temperature. Generally, these glass–ceramics present a yellowish-brown coloration whose intensity increases with the crystallization rate and that is partly due to coloring elements like titanium. In this study, we investigated the origin of the evolution of the color of LAS glasses and glass–ceramics by varying the TiO 2 concentration. To do this, several TiO 2 -bearing LAS glasses (with TiO 2 ranging from 0 to 4 mol% and 1 mol% ZrO 2 ) were prepared and heat treated at a given temperature (925 °C) to study the impact of the TiO 2 concentration on their crystallization behavior and their color. The crystallization and microstructure of LAS glasses and glass–ceramics were studied by DTA, XRD and TEM whereas their structure was investigated by EPR, optical and X-ray absorption spectroscopies. From all the results obtained, the evolution of the optical absorption and coloration of LAS glasses and glass–ceramics was mainly explained by Ti 4+ –O 2- charge transfer (glasses) and by gap absorption and Rayleigh scattering of nanocrystals (glass–ceramics).

Chavoutier, M.↗

Understanding the optical properties of ZnO{sub 1−x}S{sub x} and ZnO{sub 1−x}Se{sub x} alloys

ZnO{sub 1−x}Y{sub x} with chalcogen element Y exhibits intriguing optoelectronic properties as the alloying strongly impacts the band-gap energy E{sub g}(x). In this work, we analyze and compare the electronic structures and the dielectric responses of Zn(O,S) and Zn(O,Se) alloys by means of the density functional theory and the partially self-consistent GW approach. We model the crystalline stability from the total energies, and the results indicate that Zn(O,S) is more stable as alloy than Zn(O,Se). We demonstrate also that ion relaxation strongly affects total energies, and that the band-gap bowing depends primarily on local relaxation of the bonds. Moreover, we show that the composition dependent band-gap needs to be analyzed by the band anti-crossing model for small alloying concentration, while the alloying band-bowing model is accurate for strong alloying. We find that the Se-based alloys have a stronger change in the band-gap energy (for instance, ΔE{sub g}(0.50) = E{sub g}(ZnO) – E{sub g}(x = 0.50) ≈ 2.2 eV) compared with that of the S-based alloy (ΔE{sub g}(0.50) = 1.2 eV), mainly due to a stronger relaxation of the Zn–anion bonds that affects the electronic structure near the band edges. The optical properties of the alloys are discussed in terms of the complex dielectric function ε(ω) = ε{sub 1}(ω) + iε{sub 2}(ω) and the absorption coefficient α(ω). While the large band-gap bowing directly impacts the low-energy absorption spectra, the high-frequency dielectric constant ε{sub ∞} is correlated to the intensity of the dielectric response at energies above 4 eV. Therefore, the dielectric constant is only weakly affected by the non-linear band-gap variation. Despite strong structural relaxation, the high absorption coefficients of the alloys demonstrate that the alloys have well-behaved optoelectronic properties.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Influence of a fat layer on the near infrared spectra of human muscle: quantitative analysis based on two-layered Monte Carlo simulations and phantom experiments

The influence of fat thickness on the diffuse reflectance spectra of muscle in the near infrared (NIR) region is studied by Monte Carlo simulations of a two-layer structure and with phantom experiments. A polynomial relationship was established between the fat thickness and the detected diffuse reflectance. The influence of a range of optical coefficients (absorption and reduced scattering) for fat and muscle over the known range of human physiological values was also investigated. Subject-to-subject variation in the fat optical coefficients and thickness can be ignored if the fat thickness is less than 5 mm. A method was proposed to correct the fat thickness influence. c2005 Optical Society of America.

NASA Discipline Life Sciences Technologies↗

Ultraviolet ISM diagnostics for star-forming galaxies. I. Tracers of metallicity and extinction

We have observed a sample of 14 nearby (z∼0.03) star-forming blue compact galaxies (BCGs) in the rest-frame far-UV (∼1150–2200 Å) using the Cosmic Origins Spectrograph on the Hubble Space Telescope. We have also generated a grid of stellar population synthesis models using the Starburst99 evolutionary synthesis code, allowing us to compare observations and theoretical predictions for the Si iv-1400 and C iv-1550 UV indices; both are comprised of a blend of stellar wind and interstellar lines and have been proposed as metallicity diagnostics in the UV. Our models and observations both demonstrate that there is a positive linear correlation with metallicity for both indices, and we find generally good agreement between our observations and the predictions of the Starburst99 models (with the models slightly under-estimating the value of the indices due to contributions from interstellar lines not simulated by a stellar population synthesis code). By combining the rest-frame UV observations with pre-existing rest-frame optical spectrophotometry of our BCG sample, we also directly compare the predictions of metallicity and extinction diagnostics across both wavelength regimes. This comparison reveals a correlation between the UV absorption and optical strong-line diagnostics, offering the first means of directly comparing interstellar medium (ISM) properties determined across different rest-frame regimes. Finally, using our Starburst99 model grid, we determine theoretical values for the short-wavelength UV continuum slope, β{sub 18}, which can be used for determining extinction in rest-frame UV spectra of star-forming galaxies. We consider the implications of these results and discuss future work aimed at parameterizing these and other environmental diagnostics in the UV (a suite of diagnostics that could offer particular utility in the study of star-forming galaxies at high redshift) as well as the development of robust comparisons between ISM diagnostics across a broad wavelength baseline.

79 ASTRONOMY AND ASTROPHYSICS↗

The absorption line spectrum of 1331 + 170.

The absorption-rich optical and near-infrared spectrum of the quasi-stellar object 1331 + 170 is analyzed. The emission-line redshift is about 2.08, and at least three absorption systems are shown to be present; the absorption redshifts are 1.7755, 1.7851, and 1.9637. We conclude that the absorbing material giving rise to the three systems is intrinsic to the QSO despite the high velocity difference between emission and absorption systems and the low velocity dispersion within each absorption system.

Strittmatter, P. A.↗