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DOE OSTI2021

CRADA Number NFE1706843 with SkyNano LLC (CRADA Final Report)

Cooperative Research and Development Agreement (CRADA) NFE-17-06843 between Oak Ridge National Laboratory (ORNL) and SkyNano LLC focused on studying and developing a better fundamental understanding of SkyNano’s technology to capture and convert CO 2 into solid carbon nanostructures, including carbon nanotubes (CNTs), using electrochemistry at elevated temperatures in molten salts. The project focused on developing a fundamental scientific understanding of how electrochemistry influences the dynamic catalytic processes that drive the formation of CNTs on electrodes, while developing synthesis and processing technology relevant to implementation of the technology – including chemical engineering to aid in recapturing the lithium carbonate electrolyte essential to the process, and the modeling and testing of systems with the required thermal management at practical scales.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1990

Discrete-vortex model for the symmetric-vortex flow on cones

A relatively simple but accurate potential flow model was developed for studying the symmetric vortex flow on cones. The model is a modified version of the model first developed by Bryson, in which discrete vortices and straight-line feeding sheets were used to represent the flow field. It differs, however, in the zero-force condition used to position the vortices and determine their circulation strengths. The Bryson model imposed the condition that the net force on the feeding sheets and discrete vortices must be zero. The proposed model satisfies this zero-force condition by having the vortices move as free vortices, at a velocity equal to at the local crossflow velocity at their centers. When the free-vortex assumption is made, a solution is obtained in the form of two nonlinear algebraic equations that relate the vortex center coordinates and vortex strengths to the cone angle and angle of attack. The vortex center locations calculated using the model are in good agreement with experimental values. The cone normal forces as well as center locations are in good agreement with the vortex cloud method of calculating symmetric flow fields.

Gainer, Thomas G.↗

DOE OSTI2016

Rating Correlations Between Customs Codes and Export Control Lists: Assessing the Needs and Challenges

Correlation tables are the linchpins between the customs codes used to classify commodities in international trade and the control lists used for strategic trade control (STC) purposes. While understanding the customs classification system can help the STC community better understand strategic trade flows, better identify which trade operations require permits, and more effectively detect illegal exports, the two systems are different in scope, philosophy, content, and objectives. Many indications point to the limitations of these correlation tables, and it is important to understand the nature of the limitations and the complex underlying reasons to conceive possible improvements. As part of its Strategic Trade and Supply Chain Analytics Initiative, Argonne National Laboratory supported a study of a subset of the European Union’s TARIC correlation table. The study included development of a methodology and an approach to rating the quality and relevance of individual correlations. The study was intended as a first step to engage the STC community in deflections and initiatives to improve the conception and use of correlations, and its conclusions illustrate the scope and complex nature of the challenges to overcome. This paper presents the two classification systems, analyzes the needs for correlation tables and the complex challenges associated with them, summarizes key findings, and proposes possible ways forward.

commodity classification↗

NASA NTRS1984

Finite-difference fluid dynamics computer mathematical models for the design and interpretation of experiments for space flight

Numerical methods are used to design a spherical baroclinic flow model experiment of the large scale atmosphere flow for Spacelab. The dielectric simulation of radial gravity is only dominant in a low gravity environment. Computer codes are developed to study the processes at work in crystal growing systems which are also candidates for space flight. Crystalline materials rarely achieve their potential properties because of imperfections and component concentration variations. Thermosolutal convection in the liquid melt can be the cause of these imperfections. Such convection is suppressed in a low gravity environment. Two and three dimensional finite difference codes are being used for this work. Nonuniform meshes and implicit iterative methods are used. The iterative method for steady solutions is based on time stepping but has the options of different time steps for velocity and temperature and of a time step varying smoothly with position according to specified powers of the mesh spacings. This allows for more rapid convergence. The code being developed for the crystal growth studies allows for growth of the crystal as the solid-liquid interface. The moving interface is followed using finite differences; shape variations are permitted. For convenience in applying finite differences in the solid and liquid, a time dependent coordinate transformation is used to make this interface a coordinate surface.

Roberts, G. O.↗

NASA NTRS2019

Summary of Space Environment Magnetometer and Particle Replacement Experiment (SEMPRE) Study

As part of the GOES-R series follow on architecture study following the NOAA Satellite Observing System Architecture (NSOSA) study, a study team evaluated the feasibility of accommodating the GOES in-situ instruments (Magnetometer and Particle Detectors) on a dedicated spacecraft with no impact to the overall baseline mission cost assuming two large observatories. The accommodations cost on a primary operational type observatory are non-negligible requiring: a large non-magnetic boom to reduce the impact of the spacecraft interference on the magnetometer; and strict contamination control and magnetic cleanliness to prevent magnetic contamination near the magnetometers. These, along with the additional interface complexities greatly increase the cost of larger spacecraft by extending integration time with a large marching army. By contrast, a dedicated mission provides flexibility in location and refresh rate not afforded when these sensors are launched as secondary payloads. This study performed an informal industry survey of small form-factor instruments currently flying or in process of being developed. The study identified three potential particle detector suites and multiple magnetometers that will satisfy the requirements while having low enough volume and mass to allow accommodation on a rideshare class spacecraft. Using the largest of the identified particle detector suites, the Goddard Space Flight Center Mission Design Lab developed a design for a rideshare spacecraft that will accommodate the particle detector suite and magnetometer. The cost of the spacecraft, based on multiple cost models, is comparable to the cost of accommodating the magnetometer and particle detector suite on two (East and West) larger main observatories.

Todirita, Monica↗

DOE OSTI2012

Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

The research advanced fundamental science and applied engineering for increasing the efficiency of internal combustion engines and meeting emissions regulations with biofuels. The project developed a laboratory with new experiments and allowed investigation of new fuels and their combustion and emissions. This project supports a sustainable domestic biofuels and automotive industry creating economic opportunities across the nation, reducing the dependence on foreign oil, and enhancing U.S. energy security. The one year period of research developed fundamental knowledge and applied technology in advanced combustion, emissions and biofuels formulation to increase vehicle's efficiency. Biofuels combustion was investigated in a Compression Ignition Direct Injection (DI) to develop idling strategies with biofuels and an Indirect Diesel Injection (IDI) intended for auxiliary power unit.

33 ADVANCED PROPULSION SYSTEMS↗

DOE OSTI2012

Renewable Energy Laboratory Development for Biofuels Advanced Combustion Studies

09 BIOMASS FUELS↗

NASA NTRS2002

Modeling and control for closed environment plant production systems

A computer program was developed to study multiple crop production and control in controlled environment plant production systems. The program simulates crop growth and development under nominal and off-nominal environments. Time-series crop models for wheat (Triticum aestivum), soybean (Glycine max), and white potato (Solanum tuberosum) are integrated with a model-based predictive controller. The controller evaluates and compensates for effects of environmental disturbances on crop production scheduling. The crop models consist of a set of nonlinear polynomial equations, six for each crop, developed using multivariate polynomial regression (MPR). Simulated data from DSSAT crop models, previously modified for crop production in controlled environments with hydroponics under elevated atmospheric carbon dioxide concentration, were used for the MPR fitting. The model-based predictive controller adjusts light intensity, air temperature, and carbon dioxide concentration set points in response to environmental perturbations. Control signals are determined from minimization of a cost function, which is based on the weighted control effort and squared-error between the system response and desired reference signal.

NASA Discipline Life Support Systems↗

DOE OSTI2015

SU-E-J-190: Development of Abdominal Compression & Respiratory Guiding System Using Gas Pressure Sensor

Purpose: Abdominal compression is known to be effective but, often makes external-marker-based monitoring of breathing motion not feasible. In this study, we developed and evaluated a system that enables both abdominal compression and monitoring of residual abdominal motion simultaneously. The system can also provide visual-biofeedback capability. Methods: The system developed consists of a compression belt, an abdominal motion monitoring sensor (gas pressure sensor) and a visual biofeedback device. The compression belt was designed to be able to compress the frontal side of the abdomen. The pressure level of the belt is controlled by air volume and monitored in real time using the gas pressure sensor. The system displays not only the real-time monitoring curve but also a guiding respiration model (e.g., a breath hold or shallow breathing curve) simultaneously on the head mounted display to help patients keep their breathing pattern as consistent as possible. Three healthy volunteers were enrolled in this pilot study and respiratory signals (pressure variations) were obtained both with and without effective abdominal compression to investigate the feasibility of the developed system. Two guidance patterns, breath hold and shallow breathing, were tested. Results: All volunteers showed smaller abdominal motion with compression (about 40% amplitude reduction compared to without compression). However, the system was able to monitor residual abdominal motion for all volunteers. Even under abdominal compression, in addition, it was possible to make the subjects successfully follow the guide patterns using the visual biofeedback system. Conclusion: The developed abdominal compression & respiratory guiding system was feasible for residual abdominal motion management. It is considered that the system can be used for a respiratory motion involved radiation therapy while maintaining the merit of abdominal compression. This work was supported by the Radiation Technology R&D program (No. 2013M2A2A7043498) and the Mid-career Researcher Program (2014R1A2A1A10050270) through the National Research Foundation of Korea funded by the Ministry of Science, ICT&Future Planning.

60 APPLIED LIFE SCIENCES↗

NASA NTRS1997

Optical Design of the Developmental Cryogenic Active Telescope Testbed (DCATT)

In the summer of 1996, three Study teams developed conceptual designs and mission architectures for the Next Generation Space Telescope (NGST). Each group highlighted areas of technology development that need to be further advanced to meet the goals of the NGST mission. The most important areas for future study included: deployable structures, lightweight optics, cryogenic optics and mechanisms, passive cooling, and on-orbit closed loop wavefront sensing and control. NASA and industry are currently planning to develop a series of ground testbeds and validation flights to demonstrate many of these technologies. The Deployed Cryogenic Active Telescope Testbed (DCATT) is a system level testbed to be developed at Goddard Space Flight Center in three phases over an extended period of time. This testbed will combine an actively controlled telescope with the hardware and software elements of a closed loop wavefront sensing and control system to achieve diffraction limited imaging at 2 microns. We will present an overview of the system level requirements, a discussion of the optical design, and results of performance analyses for the Phase 1 ambient concept for DCATT,

Davila, Pam↗

DOE OSTI2017

Demonstration of reduced-order urban scale building energy models

The aim of this study is to demonstrate a developed framework to rapidly create urban scale reduced-order building energy models using a systematic summary of the simplifications required for the representation of building exterior and thermal zones. These urban scale reduced-order models rely on the contribution of influential variables to the internal, external, and system thermal loads. OpenStudio Application Programming Interface (API) serves as a tool to automate the process of model creation and demonstrate the developed framework. The results of this study show that the accuracy of the developed reduced-order building energy models varies only up to 10% with the selection of different thermal zones. In addition, to assess complexity of the developed reduced-order building energy models, this study develops a novel framework to quantify complexity of the building energy models. Consequently, this study empowers the building energy modelers to quantify their building energy model systematically in order to report the model complexity alongside the building energy model accuracy. An exhaustive analysis on four university campuses suggests that the urban neighborhood buildings lend themselves to simplified typical shapes. Specifically, building energy modelers can utilize the developed typical shapes to represent more than 80% of the U.S. buildings documented in the CBECS database. One main benefits of this developed framework is the opportunity for different models including airflow and solar radiation models to share the same exterior representation, allowing a unifying exchange data. Altogether, the results of this study have implications for a large-scale modeling of buildings in support of urban energy consumption analyses or assessment of a large number of alternative solutions in support of retrofit decision-making in the building industry.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2021

Towards Resolving the Risk of Turbine Collision on Fish: FY21-22 Seedling Report Phase I

The most important concern for permitting tidal and river turbines is the collision risk of marine animals with the turbine blades. Our understanding of the risk to individual fish from colliding with turbine blades is poor; if these collisions were to occur, it is unknown whether fish will sustain recoverable injuries or be killed. Equally unknown is the impact these collisions might have on populations, particularly for threatened, endangered, or commercially managed fish species. In addition to observations of interactions of fish with turbines, numerical models need to be developed or expanded to predict impacts on fish populations. These models could replace expensive and technically challenging monitoring programs in high energy, often murky, tidal or river waters. In this project, a multi-pronged approach was taken to understand the state of knowledge for collision risk of fish with turbines and build a pathway forward. This approach included a workshop with experts, a literature review of modeling and empirical studies, the development of a research framework, and the identification of case studies to address through future work. This project is a first step towards the future development of effective and robust numerical models for assessing the collision risk of fish around turbines. This will achieve a balanced and improved estimate of the severity of collision risk to fish at the population scale.

Garavelli, Lysel↗

DOE OSTI2024

Development and Outcomes of Returning Polycyclic Aromatic Hydrocarbon Exposure Results in the Washington Heights, NYC Community

Report-back of research results (RBRR) is becoming standard practice for environmental health research studies. RBRR is thought to increase environmental health literacy (EHL), although standardized measurements are limited. For this study, we developed a report back document on exposure to air pollutants, Polycyclic Aromatic Hydrocarbons, during pregnancy through community engaged research and evaluated whether the report increased EHL. We used focus groups and surveys to gather feedback on the report document from an initial group of study participants (Group 1, n = 22) and then sent the revised report to a larger number of participants (Group 2, n = 168). We conducted focus groups among participants in Group 1 and discussed their suggested changes to the report and how those changes could be implemented. Participants in focus groups demonstrated multiple levels of EHL. While participant engagement critically informed report development, a survey comparing feedback from Group 1 (initial report) and Group 2 (revised report) did not show a significant difference in the ease of reading the report or knowledge gained about air pollutants. We acknowledge that our approach was limited by a lack of EHL tools that assess knowledge and behavior change, and a reliance on quantitative methodologies. Future approaches that merge qualitative and quantitative methodologies to evaluate RBRR and methodologies for assessing RBRR materials and subsequent changes in knowledge, attitudes, and behavior, may be necessary.

Children’s Environmental Health↗

NASA NTRS1985

An experimental study of plane mixing layer development

Mean flow and turbulence was measured in the near field of two plane mixing layers in air with a maximum velocity of 21 m/sec. The experimental rig enabled mixing layers of velocity ratios 0 and 0.46 to be generated simultaneously. Gases with both tripped and untripped initial boundary layers were studied. It was found that the two stream layer developed to the self preserving state in a distance much shorter than did the single stream layer which followed accepted criteria for the development distance. The asymptotic levels of the turbulence quantities in the two stream layer and the development of the single stream layer showed agreement with existing data. It is suggested that the two stream mixing layer should provide a better test case for the development of turbulence models and calculation methods than the single stream mixing layer.

Mehta, R. D.↗

DOE OSTI2014

Energy transfer models in nitrogen plasmas: Analysis of N{sub 2}(X{sup 1}Σ{sup +}{sub g})–N({sup 4}S{sub u})–e{sup −} interaction

The relaxation of N{sub 2}(X{sup 1}Σ{sup +}{sub g}) molecules in a background gas composed of N({sup 4}S{sub u}) atoms and free electrons is studied by using an ideal isochoric and isothermic chemical reactor. A rovibrational state-to-state model is developed to study energy transfer process induced by free electron and atomic collisions. The required cross sections and the corresponding rate coefficients are taken from two well-known kinetic databases: NASA Ames kinetic mechanism for the description of the N{sub 2}(X{sup 1}Σ{sup +}{sub g})–N({sup 4}S{sub u}) processes and the Phys4Entry database for the electron driven processes, N{sub 2}(X{sup 1}Σ{sup +}{sub g})–e{sup −}. The evolution of the population densities of each individual rovibrational level is explicitly determined via the numerical solution of the master equation for temperatures ranging from 10000 to 30 000 K. It was found that the distribution of the rovibrational energy levels of N{sub 2}(X{sup 1}Σ{sup +}{sub g}) is strongly influenced by the electron driven collisional processes, which promote the excitation of the low lying vibrational levels. The macroscopic vibrational energy relaxation is governed by the molecule-atom collisions, when free electrons, initially cold are relaxing to the final heat-bath temperature. Thus, the main role of the free electrons is to ensure the equilibration of vibrational and free electron excitation, thus validating the existence of the local equilibrium T{sup V}–T{sup e}. However, if electrons and heavy particles are assumed to be in equilibrium at the heat bath temperature, electron driven processes dominate the vibrational relaxation. Finally, we have assessed the validity of the Landau-Teller model for the description of the inelastic energy transfer between molecules and free electrons. In the case of free-electron temperatures lower than 10 000 K, Landau-Teller relaxation model gives an accurate description of the vibrational relaxation, while at higher temperatures the error in the predictions can be significant and the model should not be used.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2012

Development of High Resolution Land Surface Parameters for the Community Land Model

There is a growing need for high-resolution land surface parameters as land surface models are being applied at increasingly higher spatial resolution offline as well as in regional and global models. The default land surface parameters for the most recent version of the Community Land Model (i.e. CLM 4.0) are at 0.5° or coarser resolutions, released with the Community Earth System Model (CESM). Plant Functional Types (PFTs), vegetation properties such as Leaf Area Index (LAI), Stem Area Index (SAI), and non-vegetated land covers were developed using remotely sensed datasets retrieved in late 1990’s and the beginning of this century. In this study, we developed new land surface parameters for CLM 4.0, specifically PFTs, LAI, SAI and non-vegetated land cover composition, at 0.05° resolution globally based on the most recent MODIS land cover and improved MODIS LAI products. Compared to the current CLM 4.0 parameters, the new parameters produced a decreased coverage by bare soil and trees, but an increased coverage by shrub, grass, and cropland. The new parameters result in a decrease in global seasonal LAI, with the biggest decrease in boreal forests; however, the new parameters also show a large increase in LAI in tropical forest. Differences between the new and the current parameters are mainly caused by changes in the sources of remotely sensed data and the representation of land cover in the source data. Advantages and disadvantages of each dataset were discussed in order to provide guidance on the use of the data. The new high-resolution land surface parameters have been used in a coupled land-atmosphere model (WRF-CLM) applied to the western U.S. to demonstrate their use in high-resolution modeling. A remapping method from the latitude/longitude grid of the CLM data to the WRF grids with map projection was also demonstrated. Future work will include global offline CLM simulations to examine the impacts of source data resolution and subsequent land parameter changes on simulated land surface processes.

Environmental Molecular Sciences Laboratory↗

NASA NTRS1978

Hydraulic model of the Chesapeake Bay

Preliminary planning for the formulation of the first year of hydraulic studies on the Chesapeake Bay model was recently completed. The primary purpose of this initial effort was to develop a study program that is both responsive to problems of immediate importance and at the same time ensure that from the very beginning of operation maximum economical use is made of the model. The formulation of this preliminary study plan involved an extensive analysis of the environmental, economic, and social aspects of a series of current problems in order to establish a priority listing of their importance. The study program that evolved is oriented towards the analysis of the effects of some of the works of man on the Chesapeake Bay estuarine environment.

Robinson, A. E., Jr.↗

NASA NTRS1985

Subsonic pressure distributions near a wing-fin juncture on a supersonic arrow-wing configuration with wing-mounted vertical fins

A generic supersonic arrow-wing configuration has been extensively studied to develop a consistent experimental data base to aid in verifying analytical prediction methods. One of the wing configurations studied was a twisted and cambered wing with wing-mounted vertical fins and trailing-edge flaps. The pressure data obtained on that configuration was limited in the wing-fin juncture region, and no pressures were obtained on the fin itself. However, detailed data in the juncture region and on the fin are essential to check out the analytical prediction methods. Therefore, the model was modified to provide details of the juncture pressure field as well as pressures on the fin. The results of this experimental investigation showed that the addition of a fin helped improve the wing pressure distribution outboard of the fin. Deflection of the trailing-edge flap did not adversely affect this trend. The pressure distributions on the vertical fin were generally affected more by change in angle of attack than by flap deflection. The spanwise pressure distribution on the fin itself indicated a load reversal with angle of attack.

Huffman, J. K.↗