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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,513 records · Page 84
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Transient and thermo-economic analysis of MED-MVC desalination system

An exergo-economic model is used to assess the performance of a multi-effect desalination plant integrated to a mechanical vapor compressor unit (MED-MVC) with a water production capacity of 1500 $m^3$/day. The results show that the second law efficiency ($\eta_{II}$) 2.8%. The MVC and evaporator units are responsible for about 39 and 52% of the total exergy destruction, respectively. The total water price (TWP) is 1.70 $\$/m^3$ when calculated using a simple conventional economic model and 1.63 $\$/m^3$ when calculated using an exergy-based cost model. Increasing the number of effects from 1 to 6 results in a 39% reduction in the specific power consumption (SPC), a 70% increase in $\eta_{II}$ and a 24% decrease in TWP. A dynamic model is developed to investigate the effect of fluctuations of compressor work ($\dot{W}_c$) and inlet seawater temperature ($T_{sw}$) on the plant behavior and performance. The dynamic model results show that the disturbance in $\dot{W}$ has a significant effect on the plant transient behavior and may cause the plant to cease operation while a disturbance in $T_{sw}$ has only a moderate impact. Increasing $T_{sw}$ above a certain value of the steady-state condition without proper control on the plant response could lead to evaporator dry out. In term of performance, a reduction in $\dot{W}_c$ causes a decrease in the plant production capacity and SPC, while it increases the plant performance ratio (PR). On the other hand, a reduction in the inlet $T_{sw}$ causes a reduction in the plant production capacity and PR and an increase in SPC for the same compressor work. Furthermore, a comparison between a MED-MVC system and a MED integrated to a thermal vapor compressor system (MED-TVC) reveals that the latter system is rather sensitive to the reduction in $T_{sw}$ due to the presence of the condenser unit in the MED-TVC. The response of the MED-MVC system is slower than the MED-TVC which is due to the high thermal capacity of the preheaters for the feed in the MED-MVC.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2025

Electrochemical Removal of Se(IV) from Wastewater Using RuO2‑Based Catalysts

The removal of selenite (SeO32-) from water is challenging due to the risk of secondary pollutants. To address this, we developed RuO2-based nanocatalysts on the titanium plate (RuO2/TP) for direct electrochemical reduction of Se(IV) to elemental selenium [Se(0)]. Optimizing Sn doping in RuO2 nanoparticles to induce charge redistribution enabled the Ru0.9Sn0.1Ox/TP catalyst to achieve ∼90% Se(IV) removal across concentrations of 0.1, 1, and 10 mM at -2 mA cm-2 over 8 h, outperforming undoped RuO2/TP. Furthermore, Ru0.9Sn0.1Ox/TP also maintained ∼90% removal efficiency in 1 mM of Se(IV) solutions containing competitive anions (0.5 M Cl-, 0.1 M SO42-, 0.01 M NO3-, and their mixtures), demonstrating suitability for complex wastewater treatment. Importantly, the catalysts were recyclable, with no observable contamination introduced into the solution. Density functional theory (DFT) calculations suggest that Sn doping effectively reduces the energy barrier for the reduction of Se(IV) to Se(0).

Hao, Shaoyun↗
DOE OSTI2024

Noise reduction of stochastic density functional theory for metals

Density Functional Theory (DFT) has become a cornerstone in the modeling of metals. However, accurately simulating metals, particularly under extreme conditions, presents two significant challenges. First, simulating complex metallic systems at low electron temperatures is difficult due to their highly delocalized density matrix. Second, modeling metallic warm-dense materials at very high electron temperatures is challenging because it requires the computation of a large number of partially occupied orbitals. This study demonstrates that both challenges can be effectively addressed using the latest advances in linear-scaling stochastic DFT methodologies. Despite the inherent introduction of noise into all computed properties by stochastic DFT, this research evaluates the efficacy of various noise reduction techniques under different thermal conditions. Our observations indicate that the effectiveness of noise reduction strategies varies significantly with the electron temperature. Furthermore, we provide evidence that the computational cost of stochastic DFT methods scales linearly with system size for metal systems, regardless of the electron temperature regime.

Chemistry↗
NASA NTRS1986

Viscous flow drag reduction by acoustic excitation

An experimental program in which the effectiveness of a single large eddy break up (LEBU) blade is enhanced by proper acoustic excitation is described. Acoustic waves are generated in response to the incident large scale eddies and directed at the blade trailing edge through the test surface floor below the manipulator blade. The acoustic input is phase locked to the incident flow. Control of the acoustic input apparently allows enhancement of the large eddy cancellation process leading to a decrease of skin friction coefficient. Control of this process with acoustic excitation indicates that vortex unwinding is the mechanism for large eddy destruction in the boundary layer. A deeper understanding of this phenomena could lead to better drag reduction technology and further understanding of the physics of the turbulent boundary layer.

Nagel, Robert T.↗
DOE OSTI2018

Effects of rolling processes on ridging generation of ferritic stainless steel

Highlights: • The effects of microstructural refinement and texture on ridging are analysed. • Optimal reduction during cold rolling benefits the enhancement of ridging resistance. • A Steckel-mill rolling method is proposed to improve ridging resistance of FSS 430. • 30% of ridging height reduction can be achieved with proposed rolling method. - Abstract: In order to reduce the ridging generation of ferritic stainless steel (FSS) during forming process, the crystallographic texture of the FSS was modified by optimisation of both rolling and annealing processes. A systematic study was carried out to improve the ridging resistance of the FSS by investigating the sequential changes in microstructure and texture during different rolling and annealing processes. The results show that the surface roughness of the final sheet strained by 20% along the rolling direction is decreased by 20% to 30% using Steckel-mill rolling compared to traditional tandem rolling. A direct correlation is found between the ridging resistance of the FSS and the rolling routines. It has been observed that an optimal reduction value during cold rolling process is critical to the microstructural refinement and surface quality improvement of the FSS. Reduction of the fraction of {001} <110> component by optimisation of the rolling processes is found to be effective in reducing the ridging height of the FSS during the formation process.

36 MATERIALS SCIENCE↗
NASA NTRS2012

Integrated Path Differential Absorption Lidar Optimizations Based on Pre-Analyzed Atmospheric Data for ASCENDS Mission Applications

In this paper a modeling method based on data reductions is investigated which includes pre analyzed MERRA atmospheric fields for quantitative estimates of uncertainties introduced in the integrated path differential absorption methods for the sensing of various molecules including CO2. This approach represents the extension of our existing lidar modeling framework previously developed and allows effective on- and offline wavelength optimizations and weighting function analysis to minimize the interference effects such as those due to temperature sensitivity and water vapor absorption. The new simulation methodology is different from the previous implementation in that it allows analysis of atmospheric effects over annual spans and the entire Earth coverage which was achieved due to the data reduction methods employed. The effectiveness of the proposed simulation approach is demonstrated with application to the mixing ratio retrievals for the future ASCENDS mission. Independent analysis of multiple accuracy limiting factors including the temperature, water vapor interferences, and selected system parameters is further used to identify favorable spectral regions as well as wavelength combinations facilitating the reduction in total errors in the retrieved XCO2 values.

Pliutau, Denis↗
DOE OSTI2022

Visible-Light-Driven, Iridium-Catalyzed Hydrogen Atom Transfer: Mechanistic Studies, Identification of Intermediates, and Catalyst Improvements

The harvesting of visible light is a powerful strategy for the synthesis of weak chemical bonds involving hydrogen that are below the thermodynamic threshold for spontaneous H 2 evolution. Piano-stool iridium hydride complexes are effective for the bluelight- driven hydrogenation of organic substrates and contrathermodynamic dearomative isomerization. In this work, a combination of spectroscopic measurements, isotopic labeling, structure–reactivity relationships, and computational studies has been used to explore the mechanism of these stoichiometric and catalytic reactions. Photophysical measurements on the iridium hydride catalysts demonstrated the generation of long-lived excited states with principally metal-to-ligand charge transfer (MLCT) character. Transient absorption spectroscopic studies with a representative substrate, anthracene revealed a diffusion-controlled dynamic quenching of the MLCT state. The triplet state of anthracene was detected immediately after the quenching events, suggesting that triplet–triplet energy transfer initiated the photocatalytic process. The key role of triplet anthracene on the post-energy transfer step was further demonstrated by employing photocatalytic hydrogenation with a triplet photosensitizer and a HAT agent, hydroquinone. DFT calculations support a concerted hydrogen atom transfer mechanism in lieu of stepwise electron/proton or proton/electron transfer pathways. Kinetic monitoring of the deactivation channel established an inverse kinetic isotope effect, supporting reversible C(sp 2 )–H reductive coupling followed by rate-limiting ligand dissociation. Mechanistic insights enabled design of a piano-stool iridium hydride catalyst with a rationally modified supporting ligand that exhibited improved photostability under blue light irradiation. The complex also provided improved catalytic performance toward photoinduced hydrogenation with H 2 and contra-thermodynamic isomerization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1996

The effect of aperture averaging upon tropospheric delay fluctuations seen with a DSN antenna

The spectrum of tropospheric delay fluctuations expected for a DSN antenna at time scales less than 100 s has been calculated. A new feature included in these calculations is the effect of aperture averaging, which causes a reduction in delay fluctuations on time scales less than the antenna wind speed crossing time, approximately equal to 5-10 s. On time scales less than a few seconds, the Allan deviation sigma(sub y)(Delta(t)) varies as (Delta(t))(sup +1), rather than sigma(sub y)(Delta(t)) varies as (Delta(t))(exp -1/6) without aperture averaging. Due to thermal radiometer noise, calibration of tropospheric delay fluctuations with water vapor radiometers will not be possible on time scales less than approximately 10 s. However, the tropospheric fluctuation level will be small enough that radio science measurements with a spacecraft on time scales less than a few seconds will be limited by the stability of frequency standards and/or other nontropospheric effects.

Linfield, R.↗
NASA NTRS1996

The Effect of Aperture Averaging Upon Tropospheric Delay Fluctuations Seen with a DSN Antenna

The spectrum of tropospheric delay fluctuations expected for a DSN antenna at time scales less than 100 s has been calculated. A new feature included in these calculations is the effect of aperture averaging, which causes a reduction in delay fluctuations on time scales less than the antenna wind speed crossing time, approx. equal to 5-10 s. On time scales less than a few seconds, the Allan deviation sigma(y)(Delta(t)) is proportional to (Delta(t))(exp +1), rather than sigma(y)(Delta(t)) proportional to (Delta(t))(exp -1/6) without aperture averaging. Due to thermal radiometer noise, calibration of tropospheric delay fluctuations with water vapor radiometers will not be possible on time scales less than approx. equal to 10 s. However, the tropospheric fluctuation level will be small enough that radio science measurements with a spacecraft on time scales less than a few seconds will be limited by the stability of frequency standards and/or other nontropospheric effects.

Linfield, R.↗
NASA NTRS2017

Parametric Investigation on the Use of Lateral and Logitudinal Rotor Trim Flapping for Tiltrotor Noise Reduction

This paper presents an acoustics parametric study of the effect of varying lateral and longitudinal rotor trim flapping angles (tip-path-plane tilt) on noise radiated by an isolated 26-ft diameter proprotor, similar to that of the AW609 tiltrotor, in edgewise flight. Three tip-path-plane angle of attack operating conditions of -9, 0 and 6 deg, at 80 knots, were investigated. Results showed that: 1) minimum noise was attained for the tip-path-plane angle of attack value of -9 deg, and 2) changing the cyclic trim state (i.e., controls) altered the airloads and produced noticeable changes to the low-frequency (LF) and blade-vortex interaction (BVI) radiated-noise magnitude and directionality. In particular, by trimming the rotor to a positive (inboard) lateral flapping angle of 4 deg, further reductions up to 3 dB in the low-frequency noise sound pressure level were attained without significantly impacting the BVI noise for longitudinal tip-path-plane angles of -9 and 6 deg.

Noise Reduction↗
DOE OSTI2022

Synthesis and Characterization of Pt‐Ag Icosahedral Nanocages with Enhanced Catalytic Activity toward Oxygen Reduction

Abstract There is an urgent need to develop cost‐effective electrocatalysts based on Pt for a broad spectrum of applications, including those vital to the operation of fuel cells. Hollowing out the interior of Pt nanocrystals offers a simple and viable strategy for maximizing the utilization efficiency of this precious metal while enhancing the electrocatalytic performance. Herein, we report the synthesis and electrocatalytic evaluation of Pt−Ag icosahedral nanocages with an average wall thickness of 1.6 nm. The Pt atoms are coated on the surface of Ag icosahedral seeds, leading to the formation of Ag@Pt nL core‐shell icosahedral nanocrystals with tunable shell thicknesses. The core‐shell nanocrystals are then converted to icosahedral nanocages by selectively etching away the Ag in the core. The as‐obtained nanocages with a composition of Pt 4.5 Ag exhibit an almost 3‐fold enhancement in specific activity toward oxygen reduction relative to the commercial Pt/C in acid media.

Wang, Wenxia↗
NASA NTRS2012

Exhaust Plume Effects on Sonic Boom for a Delta Wing and a Swept Wing-Body Model

Supersonic travel is not allowed over populated areas due to the disturbance caused by the sonic boom. Research has been performed on sonic boom reduction and has included the contribution of the exhaust nozzle plume. Plume effect on sonic boom has progressed from the study of isolated nozzles to a study with four exhaust plumes integrated with a wing-body vehicle. This report provides a baseline analysis of the generic wing-body vehicle to demonstrate the effect of the nozzle exhaust on the near-field pressure profile. Reductions occurred in the peak-to-peak magnitude of the pressure profile for a swept wing-body vehicle. The exhaust plumes also had a favorable effect as the nozzles were moved outward along the wing-span.

Castner, Raymond↗
NASA NTRS2011

Two-Arm Flexible Thermal Strap

Airborne and space infrared cameras require highly flexible direct cooling of mechanically-sensitive focal planes. A thermal electric cooler is often used together with a thermal strap as a means to transport the thermal energy removed from the infrared detector. While effective, traditional thermal straps are only truly flexible in one direction. In this scenario, a cooling solution must be highly conductive, lightweight, able to operate within a vacuum, and highly flexible in all axes to accommodate adjustment of the focal plane while transmitting minimal force. A two-armed thermal strap using three end pieces and a twisted section offers enhanced elastic movement, significantly beyond the motion permitted by existing thermal straps. This design innovation allows for large elastic displacements in two planes and moderate elasticity in the third plane. By contrast, a more conventional strap of the same conductance offers less flexibility and asymmetrical elasticity. The two-arm configuration reduces the bending moment of inertia for a given conductance by creating the same cross-sectional area for thermal conduction, but with only half the thickness. This reduction in the thickness has a significant effect on the flexibility since there is a cubic relationship between the thickness and the rigidity or bending moment of inertia. The novelty of the technology lies in the mechanical design and manufacturing of the thermal strap. The enhanced flexibility will facilitate cooling of mechanically sensitive components (example: optical focal planes). This development is a significant contribution to the thermal cooling of optics. It is known to be especially important in the thermal control of optical focal planes due to their highly sensitive alignment requirements and mechanical sensitivity; however, many other applications exist including the cooling of gimbal-mounted components.

Urquiza, Eugenio↗
DOE OSTI2017

Sensitivity of natural gas deployment in the US power sector to future carbon policy expectations

One option for reducing carbon emissions in the power sector is replacement of coal-fired generation with less carbon-intensive natural gas combined cycle (NGCC) generation. In the United States, where there is abundant, low-cost natural gas supply, increased NGCC deployment could be a cost-effective emissions abatement opportunity at relatively modest carbon prices. However, under scenarios in which carbon prices rise and deeper emissions reductions are achieved, other technologies may be more cost-effective than NGCC in the future. In this analysis, using a US energy system model with foresight (a version of the National Energy Modeling System or “NEMS” model), we find that varying expectations about carbon prices after 2030 does not materially affect NGCC deployment prior to 2030, all else equal. An important implication of this result is that, under the set of natural gas and carbon price trajectories explored here, myopic behavior or other imperfect expectations about potential future carbon policy do not change the natural gas deployment path or lead to stranded natural gas generation infrastructure. Lastly, we explain these results in terms of the underlying economic competition between available generation technologies and discuss the broader relevance to US climate change mitigation policy.

03 NATURAL GAS↗
NASA NTRS2001

Magnetic Damping of g-Jitter Induced Double-Diffusive Convection

This paper describes a numerical study of the g-jitter driven double diffusive convective flows, thermal and concentration distributions in binary alloy melt systems subject to an external magnetic field. The study is based on the finite element solution of transient magnetohydrodynamic equations governing the momentum, thermal and solutal transport in the melt pool. Numerical simulations are conducted using the synthesized single- and multi- frequency g-jitter as well as the real g-jitter data taken during space flights with or without an applied magnetic field. It is found that for the conditions studied, the main melt flow follows approximately a lineal- superposition of velocity components induced by individual g-jitter components, regardless of whether a magnetic field exists or not. The flow field is characterized by a recirculating double diffusive convection loop oscillating in time with a defined frequency equal to that of the driving g-jitter force. An applied magnetic field has little effect on the oscillating recirculating pattern, except around the moment in time when the flow reverses its direction. The field has no effect on the oscillation period, but it changes the phase angle. It is very effective in suppressing the flow intensity and produces a notable reduction of the solutal striation and time fluctuations in the melt. For a given magnetic field strength, the magnetic damping effect is more pronounced on the velocity associated with the largest g-jitter component present and/or the g-jitter spiking peaks. A stronger magnetic field is more effective in suppressing the melt convection and also is more helpful in bringing the convection in phase with the g-jitter driving force. The applied field is particularly useful in suppressing the effect of real g-jitter spikes on both flow and solutal distributions. With appropriately selected magnetic fields, the convective flows caused by g-jitter can be reduced sufficiently and diffusion dominant. solutal transport in the melt is possible.

Shu, Y.↗
DOE OSTI2018

Characterization of Microstructure, Mechanical Properties and Formability of Cryorolled AA5083 Alloy Sheets

In this work, microstructure, mechanical properties and formability of cryorolled and annealed AA5083 alloy sheets have been characterized and a comparison has been made with cold rolled and annealed sheets. Five-millimeter-thick sheets of this alloy were cryorolled in multiple passes to a final thickness of 1 mm (80% reduction with a true strain of 1.6). Effect of annealing time and temperature on hardness has been studied, and it has been found that a short annealing at 275 °C for 15 min after cryorolling would yield a good combination of strength and ductility. Microstructural investigations showed that the cryorolled and short annealed samples possess bimodal grain structure which is responsible for better mechanical properties than cold rolled sheets. From the experimentally determined forming limit diagrams, the limit strains of cryorolled sheets have been found to be almost equal to conventional cold rolled and annealed sheets in all modes of deformation. No major differences have been found in strain distribution also. This work clearly demonstrates that cryorolling of AA5083 alloy sheets followed by a short annealing with bimodal grain structure can be used for sheet metal forming applications with higher strength and toughness than conventional sheets without any reduction in formability.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Energy consumption and CO{sub 2} emissions in Iran, 2025

Climate change and global warming as the key human societies' threats are essentially associated with energy consumption and CO{sub 2} emissions. A system dynamic model was developed in this study to model the energy consumption and CO{sub 2} emission trends for Iran over 2000–2025. Energy policy factors are considered in analyzing the impact of different energy consumption factors on environmental quality. The simulation results show that the total energy consumption is predicted to reach 2150 by 2025, while that value in 2010 is 1910, which increased by 4.3% yearly. Accordingly, the total CO{sub 2} emissions in 2025 will reach 985 million tonnes, which shows about 5% increase yearly. Furthermore, we constructed policy scenarios based on energy intensity reduction. The analysis show that CO{sub 2} emissions will decrease by 12.14% in 2025 compared to 2010 in the scenario of 5% energy intensity reduction, and 17.8% in the 10% energy intensity reduction scenario. The results obtained in this study provide substantial awareness regarding Irans future energy and CO{sub 2} emission outlines. - Highlights: • Creation of an energy consumption model using system dynamics. • The effect of different policies on energy consumption and emission reductions. • An ascending trend for the environmental costs caused by CO{sub 2} emissions is observed. • An urgent need for energy saving and emission reductions in Iran.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Rheological Characterization of Biomass Feedstock for Alternative Energy Applications

With the increased necessity of alternative energy resources, bulk feedstock biomass materials were characterized with the purpose of replacing depleting energy supplies such as fossil fuels and other nonrenewable energy sources. Residual organic waste material (biomass) left over from agricultural processing and handling systems was recycled, and further investigated for renewable energy use. Understanding the scope of flowability for biomass material yielded more efficient, and economical crop harvesting, transporting, and storing method design for the agricultural industry. The effects of moisture on bulk solid flowability was investigated using a variety of parametric testing methods that measure basic flowability energy, and other properties such as compressibility and material resistance. In an industry where organic material is a wasteful byproduct, converting this biomass material into a new energy source and streamlining efficiently for innovative agricultural development supports a clean, renewable energy approach to everyday nonrenewable energy uses, such as oil, propane, and coal. As observed from the repeatable results from the investigated rheological material properties, biomass is an incredibly diverse material that requires modern engineering solutions to revolutionize biomass into a renewable energy source. Biomass will decarbonize petroleum (nonrenewable) derived fuels and chemicals, yielding recyclable carbon. This push to replace fossil fuels with recycled carbon is ideal because of the abundant, renewable, and otherwise agricultural waste of corn stover material. Decarburization, and reduction of C0 2 emissions reduces the effects of global warming.

09 BIOMASS FUELS↗