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At least 1,513 records · Page 84

Iodine Modulates the MACl‐Assisted Growth of FAPbI 3 for High Efficiency Perovskite Solar Cells

The preferential growth of α-phase formamidinium perovskite (α-FAPbI 3 ) at low temperatures can be achieved with the incorporation of chloride-based additives, with methylammonium chloride (MACl) being the most common example. However, compared to other less-volatile chloride additives, MACl only remains in the growing perovskite film for a short time before evaporating during annealing, primarily influencing the early stages of film formation. In addition, evaporation of MACl as methylamine (MA 0 ) and HCl can introduce a side reaction between MA 0 and formamidinium (FA), undermining the compositional purity and phase stability of α-FAPbI 3 . In this study, it is demonstrated that addition of iodine (I 2 ) into the FAPbI 3 precursor solution containing MACl suppresses the MA-FA side reaction during annealing. Additionally, MACl evaporation is delayed owing to strong interaction with triiodide. The added I 2 facilitates spontaneous growth of α-FAPbI 3 prior to annealing, with an improved bottom morphology due to the formation of fewer byproducts. Perovskite solar cells derived from an I 2 -incorporated solution deliver a champion power conversion efficiency of 25.2% that is attributed to suppressed non-radiative recombination.

14 SOLAR ENERGY↗

Proceedings of the 2019 PV Reliability Workshop, 26-28 February 2019, Lakewood, Colorado

NREL hosts an annual Photovoltaic Reliability Workshop (PVRW) so solar technology experts can share information leading to the improvement of PV module reliability. Such improvement reduces the cost of solar electricity and promotes investor confidence in the technology - both critical goals for moving PV technologies deeper into the electricity marketplace. This document collects the presentations and posters from the 2019 PV Reliability Workshop, which was hosted by NREL from Tuesday, February 26, to Thursday, February 28, 2019.

14 SOLAR ENERGY↗

Proceedings of the 2018 PV Reliability Workshop, 27 February - 1 March 2018, Lakewood, Colorado

NREL hosts an annual Photovoltaic Reliability Workshop (PVRW) so solar technology experts can share information leading to the improvement of PV module reliability. Such improvement reduces the cost of solar electricity and promotes investor confidence in the technology - both critical goals for moving PV technologies deeper into the electricity marketplace. This document collects the presentations and posters from the 2018 PV Reliability Workshop, which was hosted by NREL from Tuesday, February 27, to Thursday, March 1, 2018.

14 SOLAR ENERGY↗

Observations of PV Systems Post-Hurricane

NREL's observations of post-hurricane photovoltaic (PV) systems were shared with PV reliability researchers during the Photovoltaic Reliability Workshop held in Lakewood, Colorado the week of February 26, 2018. NREL hosts an annual Photovoltaic Reliability Workshop (PVRW) so that solar technology experts can share information leading to the improvement of PV module reliability. Such improvement reduces the cost of solar electricity and promotes investor confidence in the technology - both critical goals for moving PV technologies deeper into the electricity marketplace. This presentation is intended to share real world examples of PV survivability during and after Hurricanes Irma and Maria in 2017.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Power Generator with Thermo-Differential Modules

A thermoelectric power generator consists of an oven box and a solar cooker/solar reflector unit. The solar reflector concentrates sunlight into heat and transfers the heat into the oven box via a heat pipe. The oven box unit is surrounded by five thermoelectric modules and is located at the bottom end of the solar reflector. When the heat is pumped into one side of the thermoelectric module and ejected from the opposite side at ambient temperatures, an electrical current is produced. Typical temperature accumulation in the solar reflector is approximately 200 C (392 F). The heat pipe then transfers heat into the oven box with a loss of about 40 percent. At the ambient temperature of about 20 C (68 F), the temperature differential is about 100 C (180 F) apart. Each thermoelectric module, generates about 6 watts of power. One oven box with five thermoelectric modules produces about 30 watts. The system provides power for unattended instruments in remote areas, such as space colonies and space vehicles, and in polar and other remote regions on Earth.

Saiz, John R.↗

Future-proofing photovoltaics module reliability through a unifying predictive modeling framework

Solar energy, especially photovoltaics (PV), plays a significant role in the global energy transition required for decarbonization. Technological advancements in increasing efficiencies coupled with cost reductions through economies of scale made PV a cost-competitive energy source set to exceed the milestone of 1 TW globally deployed capacity in 2022. However, ongoing downward price pressure coupled with increasing service life expectations creates tremendous challenges for reliability engineers in ensuring the safe and reliable operation of PV modules and systems over the anticipated service life. Today's reliability research efforts aim for module lifetimes of up to 50 years. Still, our current tools fall short in accurately assessing degradation mechanisms and failure modes over such extended periods. We argue that the well-established PV reliability learning cycle needs to be accelerated to keep up with the rapid technological advancements and high expectations that are put on PV and its role in the global energy transition. In this article, we explore the evolution of the PV reliability learning cycle and highlight the significance that predictive modeling capabilities will have on future PV module reliability. We propose creating a unifying modeling framework - which once established will enable the holistic assessment of PV module reliability, accelerate the PV reliability learning cycle, and bring us closer to quantitative service life predictions of PV modules.

14 SOLAR ENERGY↗

Summary of process research analysis efforts

A summary of solar-cell process research analysis efforts was presented. Process design and cell design are interactive efforts where technology from integrated circuit processes and other processes are blended. The primary factors that control cell efficiency are: (1) the bulk parameters of the available sheet material, (2) the retention and enhancement of these bulk parameters, and (3) the cell design and the cost to produce versus the finished cells performance. The process sequences need to be tailored to be compatible with the sheet form, the cell shape form, and the processing equipment. New process options that require further evaluation and utilization are lasers, robotics, thermal pulse techniques, and new materials. There are numerous process control techniques that can be adapted and used that will improve product uniformity and reduced costs. Two factors that can lead to longer life modules are the use of solar cell diffusion barriers and improved encapsulation.

Burger, D. R.↗

Battery Reinitialization of the Photovoltaic Module of the International Space Station

The photovoltaic (PV) module on the International Space Station (ISS) has been operating since November 2000 and supporting electric power demands of the ISS and its crew of three. The PV module contains photovoltaic arrays that convert solar energy to electrical power and an integrated equipment assembly (IEA) that houses electrical hardware and batteries for electric power regulation and storage. Each PV module contains two independent power channels for fault tolerance. Each power channel contains three batteries in parallel to meet its performance requirements and for fault tolerance. Each battery consists of 76 Ni-Hydrogen (Ni-H2) cells in series. These 76 cells are contained in two orbital replaceable units (ORU) that are connected in series. On-orbit data are monitored and trended to ensure that all hardware is operating normally. Review of on-orbit data showed that while five batteries are operating very well, one is showing signs of mismatched ORUs. The cell pressure in the two ORUs differs by an amount that exceeds the recommended range. The reason for this abnormal behavior may be that the two ORUs have different use history. An assessment was performed and it was determined that capacity of this battery would be limited by the lower pressure ORU. Steps are being taken to reduce this pressure differential before battery capacity drops to the point of affecting its ability to meet performance requirements. As a first step, a battery reinitialization procedure was developed to reduce this pressure differential. The procedure was successfully carried out on-orbit and the pressure differential was reduced to the recommended range. This paper describes the battery performance and the consequences of mismatched ORUs that make a battery. The paper also describes the reinitialization procedure, how it was performed on orbit, and battery performance after the reinitialization. On-orbit data monitoring and trending is an ongoing activity and it will continue as ISS assembly progresses.

Hajela, Gyan↗

Modulation of Galactic Cosmic Rays in the Inner Heliosphere, Comparing with PAMELA Measurements

We develop a numerical model to study the time-dependent modulation of galactic cosmic rays in the inner heliosphere. In the model, a time-delayed modified Parker heliospheric magnetic field (HMF) and a new diffusion coefficient model, NLGCE-F, from Qin and Zhang, are adopted. In addition, the latitudinal dependence of magnetic turbulence magnitude is assumed to be ∼(1+sin{sup 2}θ)/2 from the observations of Ulysses, and the radial dependence is assumed to be ∼r{sup S}, where we choose an expression of S as a function of the heliospheric current sheet tilt angle. We show that the analytical expression used to describe the spatial variation of HMF turbulence magnitude agrees well with the Ulysses, Voyager 1, and Voyager 2 observations. By numerically calculating the modulation code, we get the proton energy spectra as a function of time during the recent solar minimum, it is shown that the modulation results are consistent with the Payload for Antimatter-Matter Exploration and Light-nuclei Astrophysics measurements.

79 ASTRONOMY AND ASTROPHYSICS↗

The causes of goemagnetic activity

The causes of geomagnetic activity are studied both theoretically in terms of the reconnection model and empirically using the am-index and interplanetary solar wind parameters. It is found that two separate mechanisms supply energy to the magnetosphere. One mechanism depends critically on the magnitude and direction of the interplanetary magnetic field. Both depend strongly on solar wind speed. The energy input is modulated by the tilt of the dipole axis being maximum for 90 deg tilt against the solar wind flow direction. The energy input due to reconnection has no significant seasonal variations for equal amount of both sector polarities.

Svalgaard, L.↗

Interplanetary flow systems associated with cosmic ray modulation in 1977-1980

The hydromagnetic flow configurations associated with the cosmic ray modulation in 1977-1980 were determined using solar wind plasma and magnetic field data from Voyager 1 and 2 and Helios 1. The modulation was related to two types of large-scale systems of flows: one containing a number of transients such as shocks and postshock flows, the other consisting primarily of a series of quasi-stationary flows following interaction regions containing a stream interface and often bounded by a forward-reverse shock pair. Each of three major episodes of cosmic ray modulation was associated with the passage of a system of transient flows. Plateaus in the cosmic ray intensity-time profile were associated with the passage of systems of corotating streams.

Burlaga, L. F.↗

2016 NREL Photovoltaic Module Reliability Workshop

NREL's Photovoltaic (PV) Module Reliability Workshop (PVMRW) brings together PV reliability experts to share information, leading to the improvement of PV module reliability. Such improvement reduces the cost of solar electricity and promotes investor confidence in the technology - both critical goals for moving PV technologies deeper into the electricity marketplace.

14 SOLAR ENERGY↗

2015 NREL Photovoltaic Module Reliability Workshops

NREL's Photovoltaic (PV) Module Reliability Workshop (PVMRW) brings together PV reliability experts to share information, leading to the improvement of PV module reliability. Such improvement reduces the cost of solar electricity and promotes investor confidence in the technology--both critical goals for moving PV technologies deeper into the electricity marketplace.

14 SOLAR ENERGY↗

Development of a thermal storage module using modified anhydrous sodium hydroxide

The laboratory scale testing of a modified anhydrous NaOH latent heat storage concept for small solar thermal power systems such as total energy systems utilizing organic Rankine systems is discussed. A diagnostic test on the thermal energy storage module and an investigation of alternative heat transfer fluids and heat exchange concepts are specifically addressed. A previously developed computer simulation model is modified to predict the performance of the module in a solar total energy system environment. In addition, the computer model is expanded to investigate parametrically the incorporation of a second heat exchange inside the module which will vaporize and superheat the Rankine cycle power fluid.

Rice, R. E.↗

A 100 kW-Class Technology Demonstrator for Space Solar Power

A first step in the development of solar power from space is the flight demonstration of critical technologies. These fundamental technologies include efficient solar power collection and generation, power management and distribution, and thermal management. In addition, the integration and utilization of these technologies into a viable satellite bus could provide an energy-rich platform for a portfolio of payload experiments such as wireless power transmission (WPT). This paper presents the preliminary design of a concept for a 100 kW-class free-flying platform suitable for flight demonstration of technology experiments. Recent space solar power (SSP) studies by NASA have taken a stepping stones approach that lead to the gigawatt systems necessary to cost-effectively deliver power from space. These steps start with a 100 kW-class satellite, leading to a 500 kW and then a 1 MW-class platform. Later steps develop a 100 MW bus that could eventually lead to a 1-2 GW pilot plant for SSP. Our studies have shown that a modular approach is cost effective. Modular designs include individual laser-power-beaming satellites that fly in constellations or that are autonomously assembled into larger structures at geosynchronous orbit (GEO). Microwave power-beamed approaches are also modularized into large numbers of identical units of solar arrays, power converters, or supporting structures for arrays and microwave transmitting antennas. A cost-effective approach to launching these modular units is to use existing Earth-to-orbit (ETO) launch systems, in which the modules are dropped into low Earth orbit (LEO) and then the modules perform their own orbit transfer to GEO using expendable solar arrays to power solar electric thrusters. At GEO, the modules either rendezvous and are assembled robotically into larger platforms, or are deployed into constellations of identical laser power-beaming satellites. Since solar electric propulsion by the modules is cost-effective for both self-transport of the modules from LEO to GEO, and for on-orbit stationkeeping and repositioning capability during the satellite’s lifetime, this technology is also critical in technology development for SSP. The 100 kW-class technology demonstrator will utilize advanced solar power collection and generation technologies, power management and distribution, advanced thermal management, and solar electric propulsion. State-of-the-art solar concentrators, highly efficient multi-junction solar cells, integrated thermal management on the arrays, and innovative deployable structure design and packaging make the 100 kW satellite feasible for launch on one existing launch vehicle. Early SSP studies showed that a major percentage of the on-orbit mass for power-beaming satellites was from massive power converters at the solar arrays, at the bus, at the power transmitter, or at combinations of these locations. Higher voltage mays and power management and distribution (PMAD) systems reduce or eliminate the need for many of these massive power converters, and could enable direct-drive of high-voltage solar electric thrusters. Lightweight, highly efficient thermal management systems are a critical technology that must be developed and flown for SSP feasibility. Large amounts of power on satellites imply that large amounts of waste heat will need to be managed. In addition, several of the more innovative lightweight configurations proposed for SSP satellites take advantage of solar concentrators that are intractable without advanced thermal management technologies for the solar arrays. These thermal management systems include efficient interfaces with the WPT systems or other high-power technology experiments, lightweight deployable radiators that can be easily integrated into satellite buses, and efficient reliable thermal distribution systems that can pipe heat from the technology experiments to the radiators. In addition to demonstrating the integration and use of these mission-critical technologies, the 100 kw-class satellite will provide a large experiment deck for a portfolio of technology experiments. Current plans for this technology demonstrator allow 2000 kg of payload capability and up to 100 kW of power. The technology experiments could include one or more wireless power transmission demonstrations, either to the Earth’s surface or to a suitable space-based receiver. Technology experiments to quantify the on-orbit performance of critical technologies for SSP or space exploration are welcomed. In addition, the technology experiments provide an opportunity for international cooperation, to advance technology readiness levels of SSP technologies that require flight demonstration. This paper will present the preliminary design for a 100 kW solar-powered satellite and a variety of technology experiments that may be suitable for flight demonstration. In addition, a space-to-Earth-surface WPT experiment will be discussed.

Connie Carrington↗

Analysis of Al diffusion processes in TiN barrier layers for the application in silicon solar cell metallization

An evaporated Al layer is known as an excellent rear metallization for highly efficient solar cells, but suffers from incompatibility with a common solder process. To enable solar cell-interconnection and module integration, in this work the Al layer is complemented with a solder stack of TiN/Ti/Ag or TiN/NiV/Ag, in which the TiN layer acts as an Al diffusion barrier. X-ray photoelectron spectroscopy measurements prove that diffusion of Al through the stack and the formation of an Al{sub 2}O{sub 3} layer on the stack's surface are responsible for a loss of solderability after a strong post-metallization anneal, which is often mandatory to improve contact resistance and passivation quality. An optimization of the reactive TiN sputter process results in a densification of the TiN layer, which improves its barrier quality against Al diffusion. However, measurements with X-ray diffraction and scanning electron microscopy show that small grains with vertical grain boundaries persist, which still offer fast diffusion paths. Therefore, the concept of stuffing is introduced. By incorporating oxygen into the grain boundaries of the sputtered TiN layer, Al diffusion is strongly reduced as confirmed by secondary ion mass spectroscopy profiles. A quantitative analysis reveals a one order of magnitude lower Al diffusion coefficient for stuffed TiN layers. This metallization system maintains its solderability even after strong post-metallization annealing at 425 °C for 15 min. This paper thus presents an industrially feasible, conventionally solderable, and long-term stable metallization scheme for highly efficient silicon solar cells.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Preliminary design package for maxi-therm heat exchanger module

Heat exchangers were developed for use in a solar heating and cooling system installed in a single family dwelling. Each of the three exchangers consisted of a heating and cooling module and a submersed electric water heating element. Information necessary to evaluate the preliminary design of the heat exchanger is presented in terms of the development and verification plans, performance specifications, installation and maintenance, and hazard analysis.

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