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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,513 records · Page 84
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Geometry of quantum Hall states: Gravitational anomaly and transport coefficients

We show that universal transport coefficients of the fractional quantum Hall effect (FQHE) can be understood as a response to variations of spatial geometry. Some transport properties are essentially governed by the gravitational anomaly. We develop a general method to compute correlation functions of FQH states in a curved space, where local transformation properties of these states are examined through local geometric variations. We introduce the notion of a generating functional and relate it to geometric invariant functionals recently studied in geometry. We develop two complementary methods to study the geometry of the FQHE. One method is based on iterating a Ward identity, while the other is based on a field theoretical formulation of the FQHE through a path integral formalism.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Plasmon-Enhanced Photocatalytic CO 2 Conversion within Metal–Organic Frameworks under Visible Light

Materials development for artificial photosynthesis, in particular, CO 2 reduction, has been under extensive efforts, ranging from inorganic semiconductors to molecular complexes. In this report, we demonstrate a metal-organic framework (MOF)-coated nanoparticle photocatalyst with enhanced CO 2 reduction activity and stability, which stems from having two different functional units for activity enhancement and catalytic stability combined together as a single construct. Covalently attaching a CO 2 -to-CO conversion photocatalyst Re I (CO) 3 (BPYDC)Cl, BPYDC = 2,2'-bipyridine-5,5'-dicarboxylate, to a zirconium MOF, UiO-67 (Re n -MOF), prevents dimerization leading to deactivation. By systematically controlling its density in the framework (n = 0, 1, 2, 3, 5, 11, 16, and 24 complexes per unit cell), the highest photocatalytic activity was found for Re 3 -MOF. Structural analysis of Re n -MOFs suggests that a fine balance of proximity between photoactive centers is needed for cooperatively enhanced photocatalytic activity, where an optimum number of Re complexes per unit cell should reach the highest activity. Here, based on the structure-activity correlation of Re n -MOFs, Re 3 -MOF was coated onto Ag nanocubes (Ag$\subset$Re 3 -MOF), which spatially confined photoactive Re centers to the intensified near-surface electric fields at the surface of Ag nanocubes, resulting in a 7-fold enhancement of CO 2 -to-CO conversion under visible light with long-term stability maintained up to 48 h.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Stress and Strain Heterogeneity and Persistence in Uniaxially‐ and Triaxially‐Loaded Sandstone

Two critical questions in brittle rock mechanics are how rocks developed localized strains and to what extent internal stress heterogeneity controls this localization and subsequent macroscopic failure. Definitive answers have not yet been found, but would provide insight into rock fracture mechanics as relevant to hydrocarbon extraction and sequestration. Here, we use synchrotron X‐ray tomography (XRT) and 3D X‐ray diffraction (3DXRD) during uniaxial and triaxial tests on Nugget and Bentheimer sandstones to examine strain and stress localization prior to mechanical failure. 3DXRD was used to measure intra‐granular lattice strains which were used to compute elastic stress tensors of each grain. Digital volume correlation (DVC) was applied to XRT images to determine the strain field in the sample. Both samples featured marked spatial heterogeneity, localization, and temporal persistence of elevated stresses and strains during their mechanical deformation toward failure. Both samples featured a majority of grains with at least one principal stress component that was tensile, a signature of the influence of heterogeneity on stress transmission. Measurements further revealed that compressive stress orientations and statistics evolved in a similar manner to those of inter‐particle forces in loose granular materials, with triaxially‐compressed rock exhibiting enhanced grain stress heterogeneity compared to uniaxially‐compressed rock. Our results complement recent work by others who employed XRT and scanning 3DXRD to study triaxially‐compressed sandstone, but extend those results to uniaxial compression, sandstones of varied porosity, and grain stress measurements throughout the 3D full extent of the samples rather than in a single layer examined with scanning 3DXRD.

58 GEOSCIENCES↗
DOE OSTI2011

Quantifying pulsed laser induced damage to graphene

As an emerging optical material, graphene's ultrafast dynamics are often probed using pulsed lasers yet the region in which optical damage takes place is largely uncharted. Here, femtosecond laser pulses induced localized damage in single-layer graphene on sapphire. Raman spatial mapping, SEM, and AFM microscopy quantified the damage. The resulting size of the damaged area has a linear correlation with the optical fluence. These results demonstrate local modification of sp{sup 2}-carbon bonding structures with optical pulse fluences as low as 14 mJ/cm{sup 2}, an order-of-magnitude lower than measured and theoretical ablation thresholds.

36 MATERIALS SCIENCE↗
DOE OSTI2014

Expansion dynamics of ultrafast laser produced plasmas in the presence of ambient argon

In this paper, we report the emission features of fs laser ablated brass plasma plumes at various Ar background pressure levels ranging from vacuum to atmospheric conditions. Spectrally integrated 2D-imaging of plasma self-emission showed several interesting features at various pressure levels which consists of plume morphological changes, increase in persistence, confinement, and internal structures. Spatially resolved wavelength dispersed images of the plume were recorded for characterizing the spectral features at various pressure levels and also used for obtaining spatial distribution of Cu I and Zn I species in the plume, signal to noise ratios and fundamental parameters of the plasma; viz. temperature and density. The spatial evolution of excitation temperature and density showed significant changes at various ambient pressure levels and these results were correlated to morphological changes seen in the plume images. Optimum signal to background ratios for emission lines were observed in the moderate pressure range (~ 1-10 Torr). Optical time-of-flight profiles were used to study time evolution of various species in the plume and noticed oscillations at intermediate pressure levels. Possible mechanisms for observed changes in plume shape, optical emission intensity, and dual peak structures in time-of-flight profiles were discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Characterization of total ionizing dose damage in COTS pinned photodiode CMOS image sensors

The characterization of total ionizing dose (TID) damage in COTS pinned photodiode (PPD) CMOS image sensors (CISs) is investigated. The radiation experiments are carried out at a {sup 60}Co γ-ray source. The CISs are produced by 0.18-μm CMOS technology and the pixel architecture is 8T global shutter pixel with correlated double sampling (CDS) based on a 4T PPD front end. The parameters of CISs such as temporal domain, spatial domain, and spectral domain are measured at the CIS test system as the EMVA 1288 standard before and after irradiation. The dark current, random noise, dark signal non-uniformity (DSNU), photo response non-uniformity (PRNU), overall system gain, saturation output, dynamic range (DR), signal to noise ratio (SNR), quantum efficiency (QE), and responsivity versus the TID are reported. The behaviors of the tested CISs show remarkable degradations after radiation. The degradation mechanisms of CISs induced by TID damage are also analyzed.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Understanding and predicting damage and failure at grain boundaries in BCC Ta

Understanding the effect of grain boundaries (GBs) on the deformation and spall behavior is critical to designing materials with tailored failure responses under dynamic loading. This understanding is hampered by the lack of in situ imaging capability with the optimum spatial and temporal resolution during dynamic experiments, as well as by the scarcity of a systematic data set that correlates boundary structure to failure, especially in BCC metals. To fill in this gap in the current understanding, molecular dynamics simulations are performed on a set of 74 bi-crystals in Ta with a [110] symmetric tilt axis. Our results show a correlation between GB misorientation angle and spall strength and also highlight the importance of GB structure itself in determining the spall strength. Specifically, we find a direct correlation between the ability of the GB to plasticity deform through slip/twinning and its spall strength. Additionally, a change in the deformation mechanism from dislocation-meditated to twinning-dominated plasticity is observed as a function of misorientation angles, which results in lowered spall strengths for high-angle GBs.

Chen, J. (ORCID:000000018633229X)↗
DOE OSTI2015

SOLAR SOURCES OF {sup 3}He-RICH SOLAR ENERGETIC PARTICLE EVENTS IN SOLAR CYCLE 24

Using high-cadence EUV images obtained by the Atmospheric Imaging Assembly (AIA) on board the Solar Dynamics Observatory, we investigate the solar sources of 26 {sup 3}He-rich solar energetic particle events at ≲1 MeV nucleon{sup −1} that were well-observed by the Advanced Composition Explorer during solar cycle 24. Identification of the solar sources is based on the association of {sup 3}He-rich events with type III radio bursts and electron events as observed by Wind. The source locations are further verified in EUV images from the Solar and Terrestrial Relations Observatory, which provides information on solar activities in the regions not visible from the Earth. Based on AIA observations, {sup 3}He-rich events are not only associated with coronal jets as emphasized in solar cycle 23 studies, but also with more spatially extended eruptions. The properties of the {sup 3}He-rich events do not appear to be strongly correlated with those of the source regions. As in the previous studies, the magnetic connection between the source region and the observer is not always reproduced adequately by the simple potential field source surface model combined with the Parker spiral. Instead, we find a broad longitudinal distribution of the source regions extending well beyond the west limb, with the longitude deviating significantly from that expected from the observed solar wind speed.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Quantum spin liquid with seven elementary particles

We present an exactly solvable model of a quantum spin liquid with Abelian anyons in d = 2 spatial dimensions. With spins 1/2 on a triangular lattice and six-body interactions, our model has zero spin correlation length and localized elementary excitations like the toric codes of Kitaev and Wen. In contrast to those earlier models, it has more elementary particles—four bosons and three fermions—and higher topological degeneracy of 64 on a torus. Elementary excitations are boson-fermion pairs that come in 12 distinct flavors. We use string operators to expose the topological nature of the model.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

SU-E-I-51: Quantitative Assessment of X-Ray Imaging Detector Performance in a Clinical Setting - a Simple Approach Using a Commercial Instrument

Purpose: To measure and compare the performance of X-ray imaging detectors in a clinical setting using a dedicated instrument for the quantitative determination of detector performance. Methods: The DQEPro (DQE Instruments Inc., London, Ontario Canada) was used to determine the MTF, NPS and DQE using an IEC compliant methodology for three different imaging modalities: conventional radiography (CsI-based detector), general-purpose radioscopy (CsI-based detector), and mammography (a-Se based detector). The radiation qualities (IEC) RQA-5 and RQA-M-2 were used for the CsI-based and a-Se-based detectors, respectively. The DQEPro alleviates some of the difficulties associated with DQE measurements by automatically positioning test devices over the detector, guiding the user through the image acquisition process and providing software for calculations. Results: A comparison of the NPS showed that the image noise of the a-Se detector was less correlated than the CsI detectors. A consistently higher performance was observed for the a-Se detector at all spatial frequencies (MTF: 0.97@0.25 cy/mm, DQE: 0.72@0.25 cy/mm) and the DQE drops off slower than for the CsI detectors. The CsI detector used for conventional radiography displayed a higher performance at low spatial frequencies compared to the CsI detector used for radioscopy (DQE: 0.65 vs 0.60@0.25 cy/mm). However, at spatial frequencies above 1.3 cy/mm, the radioscopy detector displayed better performance than the conventional radiography detector (DQE: 0.35 vs 0.24@2.00 cy/mm). Conclusion: The difference in the MTF, NPS and DQE that was observed for the two different CsI detectors and the a-Se detector reflect the imaging tasks that the different detector types are intended for. The DQEPro has made the determination and calculation of quantitative metrics of X-ray imaging detector performance substantially more convenient and accessible to undertake in a clinical setting.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2014

Assimilation of Time-Averaged Pseudoproxies for Climate Reconstruction

The efficacy of a novel ensemble data assimilation (DA) technique is examined in the climate field reconstruction (CFR) of surface temperature. A minimalistic, computationally inexpensive DA technique is employed that requires only a static ensemble of climatologically plausible states. Pseudoproxy experiments are performed with both general circulation model (GCM) and Twentieth Century Reanalysis (20CR) data by reconstructing surface temperature fields from a sparse network of noisy pseudoproxies. The DA approach is compared to a conventional CFR approach based on principal component analysis (PCA) for experiments on global domains. DA outperforms PCA in reconstructing global-mean temperature in all experiments and is more consistent across experiments, with a range of time series correlations of 0.69–0.94 compared to 0.19–0.87 for the PCA method. DA improvements are even more evident in spatial reconstruction skill, especially in sparsely sampled pseudoproxy regions and for 20CR experiments. It is hypothesized that DA improves spatial reconstructions because it relies on coherent, spatially local temperature patterns, which remain robust even when glacial states are used to reconstruct nonglacial states and vice versa. These local relationships, as utilized by DA, appear to be more robust than the orthogonal patterns of variability utilized by PCA. Comparing results for GCM and 20CR data indicates that pseudoproxy experiments that rely solely on GCM data may give a false impression of reconstruction skill.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Crustal Strain Rates in the Western United States and Their Relationship with Earthquake Rates

Abstract We present a suite of strain rate models for the western United States based on geologic and geodetic data. The geologic data consist of Quaternary fault-slip rates and the geodetic data consists of a new compilation of Global Positioning System (GPS) velocities derived from continuous, semicontinuous, and campaign measurements. We remove postseismic deformation from the GPS time series in order for our geodetic strain rate model to best capture the interseismic strain accumulation rate. We present models based on either geologic or geodetic data, but also create a hybrid model. Although there are some differences between the models, the large-scale features are the same, with the noticeable exception for the Pacific Northwest where interseismic strain is naturally more distributed than the long-term strain release. We also present a map of earthquake rate densities based on mainshocks, and the result has similar spatial features similar to the strain rate models (at least in the southwestern United States). We perform a general correlation analysis between strain rate and seismicity rate (south of Cascadia) and find a change in linearity between seismicity and strain rates from slow to faster deforming areas with seismicity rates relatively lower for the latter. The extent of that change depends a bit on assumptions made on the declustering and completeness of the catalog, but the finding of a change in slope is robust across the different strain rate models. Linearity for all areas is only expected when Gutenberg–Richter parameters and parameters involved in the conversion from strain to moment rate are uniform across the study area. We discuss these qualifications, but find no single satisfactory explanation for our observation. Moreover, when considering a rather short time and space, theoretical considerations of sampling from a power-law distribution actually predict there to be a power law instead of a linear relationship, generally consistent with our observation.

Geochemistry & Geophysics↗
DOE OSTI2014

Measurement of the photon electroproduction cross section at JLAB with the goal of performing a Rosenbluth separation of the DVCS contribution

The study of the inner structure of hadrons allows us to understand the nature of the interactions between partons, quarks and gluons, described by Quantum Chromodynamics. The elastic scattering reactions, which have been studied in order to measure the nucleon form factors, are included in this frame. The inelastic scattering reactions are also included in this frame, they allow us to obtain information about the nucleon structure thanks to the development of the parton distribution functions (PDFs). While through elastic scattering we can obtain information about the charge distribution of the nucleon, and hence, about the spatial distribution of the partons, through inelastic scattering we obtain information about the momentum distributions of partons, by employing the PDFs. However, we can study the exclusive inelastic scattering reactions, such as the Deeply Virtual Compton Scattering (DVCS), wich allow us to access to the spatial and momentum distributions simultaneously. This is possible thanks to the generalized parton distributions (GPDs), which allow us to correlate both types of distributions. The process known as DVCS is the easiest way to access the GPDs. This process can be expressed as the scattering of an electron by a proton by means of a virtual photon with the result of the scattered initial particles plus a real photon. We find a process competing with DVCS known as Bethe-Heitler (BH), in which the real photon is radiated by the lepton rather than the quark. Due to the small cross section of DVCS, of the order of nb, in order to conduct these kind of experiments it is necessary to make use of facilities capable of providing high beam intensities. One of these facilities is the Thomas Jefferson National Accelerator Facility , where the experiment JLab E07-007, "Complete Separation of Virtual Photon and π⁰ Electroproduction Observables of Unpolarized Protons", took place during the months of October to December of 2010. The main goal of this experiment is the isolation of the contribution from the term coming form the DVCS from the interference term, resulting from the BH contribution. This isolation is known as "Rosenbluth Separation". The work presented in this thesis focuses on the analysis of the data stored by the electromagnetic calorimeter, employed for the detection of real photons. There is also a a theoretical introduction to the study of the nucleon structure, reviewing the concepts of form factors and parton distributions through elastic and inelastic processes. The computation of the photon leptoproduction cross section is described in detail, as well as the goals of experiment E07-007. This thesis also describes the analysis of the data stored by the electromagnetic calorimeter, with the purpose of obtaining the kinematic variables of the real photons resulting from DVCS reactions. Finally, it describes the selection of events from stored data, the applied cuts to kinematical variables and the background subtraction. Also, the process of extraction of the necessary observables for computing the photon leptoproduction cross section is described, along with the main steps followed to perform the Monte Carlo simulation used in this computation. The resulting cross sections are shown at the end of this thesis.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Electronic Structure, Spectroscopy and Correlation Effects in Novel Materials

This project was targeted on electronic structure, spectroscopic studies, and correlation effects in a variety of novel materials of great current interest. Spectroscopies resolved highly in momentum, energy or spatial dimensions are playing a key role in unraveling the nature of the ground state and excitation properties in wide classes of novel materials. The seminal insights thus obtained are of critical importance not only for answering some of the fundamental questions facing condensed matter physics and materials science today, but also for understanding and thus helping to design and develop new materials with desirable properties, which will continue to be the key to the survival of mankind and its energy needs as a technological society long into the future. However, spectroscopies do not provide a direct map of electronic states, but act as a very complex ‘filter’ or ‘mapping’ of the underlying spectrum. This connection between the electronic states and measured spectra—called the ‘matrix element effect’—is in general an extremely complex function of the phase space of the experiment (e.g. energy/polarization of photons in photoemission), presenting both a challenge and an opportunity. So motivated, this project pursued techniques for realistic treatment of electronic spectra of a wide variety of materials, which served as a prelude to formulating and implementing methodologies for making direct connection with various spectroscopies such as ARPES, STS/STM, and inelastic light scattering. Specific systems are topological materials, including 2D ultrathin films beyond graphene, novel superconductors, and nanocrystals, among others. Our goal was to exploit the strengths of various spectroscopies to piece together the most complete picture of electronic states in systems of current interest, enabling direct and sharpened confrontations with theoretical models, and also to help advance the reach of various spectroscopies.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Heating and Acceleration of Solar Wind by Parametric Decay Instability Mediated Turbulence

One of the main goals of this project to understand the origin of density fluctuations in the solar winds, as revealed by the NASA’s Flagship satellite Parker Solar Probe (PSP) measurements, which motivates us to simulate and analyze magnetohydrodynamic (MHD) turbulence in the compressible regime. To achieve this goal, we have developed a set of sophisticated turbulence driving methods to study how MHD turbulence will develop under different time-correlated fluctuations at large-scales. Another key advance is that we have developed a new 3+1 (three spatial plus time domain) 4D FFT analysis of simulation data-cubes so that we can perform the spatio-temporal spectrum and mode decomposition studies on MHD turbulence.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Ultrasonic Model-Based Iterative Reconstruction with Spatially Variant Regularization for One-Sided Non-Destructive Evaluation

One-sided ultrasonic non-destructive evaluation (UNDE) uses ultrasound signals to investigate and inspect structures that are only accessible from one side. A widely used reconstruction technique in UNDE is the synthetic aperture focusing technique (SAFT). SAFT produces fast reconstruction and reasonable images for simple structures. However, for large complex structures, SAFT reconstructions suffer from noise and artifacts. To resolve some of the drawbacks of SAFT, an ultrasonic model-based iterative reconstruction (MBIR) algorithm, a method based on Bayesian estimation, was proposed that showed significant enhancement over SAFT in reducing noise and artifacts. In this paper, we build on previous investigations of the use of MBIR reconstruction on ultrasound data by proposing a spatially varying prior-model to account for artifacts from deeper regions and a 3D regularizer to account for correlations between scans from adjacent regions. We demonstrate that the use of the new prior model in MBIR can significantly improve reconstructions compared to SAFT and the previously proposed MBIR technique.

Almansouri, Hani↗
DOE OSTI2021

Are Methanol-Derived Foliar Methyl Acetate Emissions a Tracer of Acetate-Mediated Drought Survival in Plants?

Upregulation of acetate fermentation in plants has recently been described as an evolutionarily conserved drought survival strategy, with the amount of acetate produced directly correlating to survival. However, destructive measurements are required to evaluate acetate-linked drought responses, limiting the temporal and spatial scales that can be studied. Here, 13C-labeling studies with poplar (Populus trichocarpa) branches confirmed that methyl acetate is produced in plants from the acetate-linked acetylation of methanol. Methyl acetate emissions from detached leaves were strongly stimulated during desiccation, with total emissions decreasing with the leaf developmental stage. In addition, diurnal methyl acetate emissions from whole physiologically active poplar branches increased as a function of temperature, and light-dark transitions resulted in significant emission bursts lasting several hours. During experimental drought treatments of potted poplar saplings, light-dark methyl acetate emission bursts were eliminated while strong enhancements in methyl acetate emissions lasting > 6 days were observed with their initiation coinciding with the suppression of transpiration and photosynthesis. The results suggest that methyl acetate emissions represent a novel non-invasive tracer of acetate-mediated temperature and drought survival response in plants. The findings may have important implications for the future understanding of acetate-mediated drought responses to transcription, cellular metabolism, and hormone signaling, as well as its associated changes in carbon cycling and water use from individual plants to whole ecosystems.

59 BASIC BIOLOGICAL SCIENCES↗