Search NASA⌕ Search

SEARCH · Search NASA

Results for “UTILITY PROGRAM DESIGN”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,513 records · Page 84

Commercial Buildings Partnerships - Overview of Higher education projects

The Commercial Building Partnership (CBP), a public/private, cost-shared program sponsored by the U.S. Department of Energy (DOE), paired selected commercial building owners and operators with representatives of DOE, its national laboratories, and private-sector technical experts. These teams explored energy-saving measures across building systems – including some considered too costly or technologically challenging – and used advanced energy modeling to achieve peak whole-building performance. Modeling results were then included in new construction or retrofit designs to achieve significant energy reductions. CBP design goals aimed to achieve 50 percent energy savings compared to ANSI/ASHRAE/IES Standard 90.1-2004 for new construction, while retrofits are designed to consume at least 30 percent less energy than either Standard 90.1-2004 or current consumption. After construction and commissioning of the project, laboratory staff continued to work with partners to collect and analyze data for verification of the actual energy reduction. CBP projects represent diverse building types in commercial real estate, including lodging, grocery, retail, higher education, office, and warehouse/storage facilities. Partners also commit to replicating low-energy technologies and strategies from their CBP projects throughout their building portfolios. As a result of CBP projects, five sector overviews (Lodging, Food Sales, General Merchandise, Higher Education, Offices) were created to capture successful strategies and recommended energy efficiency measures that could broadly be applied across these sectors. These overviews are supplemented with individual case studies providing specific details on the decision criteria, modeling results, and lessons learned on specific projects. Sector overviews and CBP case studies will also be updated to reflect verified data and replication strategies as they become available.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Hazard and risk analysis framework for nuclear power plant–based integrated energy systems

Employing integrated energy systems (IESs) with nuclear power plants (NPPs) can improve NPP utilization by leveraging dedicated thermal and electric power delivery, but it may also increase operational safety risks. This paper presents a framework to identify and quantify hazards and risks for such IESs. The framework combines accidentology to review past industrial accidents with failure modes and effects analysis (FMEA) to identify potential future incidents. Hydrogen explosion and toxic chemical release hazards are of particular concern. Explosion consequences are quantified using the Bauwens-Dorofeev (Bauwens) and trinitrotoluene equivalent mass (TNT-EM) methods, while chemical release consequences are computed using the Gaussian atmospheric dispersion method. Operational disturbances from direct electrical and thermal integration that may affect NPP safety are modeled using probabilistic risk analysis (PRA). Hazards and risks are then evaluated for regulatory compliance. The framework is applied to IESs comprising pressurized or boiling water reactors supplying three levels of thermal and electrical power to industrial customers. Case studies include high-temperature steam electrolysis hydrogen plants of varying capacities and a synthetic fuel production plant. Sensitivity analysis examines piping component failures in the PRA model as a precursor to cost estimation for thermal extraction line design. Additionally, Fussel-Vessely (FV) and risk increase importance (RII) measures identify risk-informed design improvements for the thermal extraction system. FMEA highlights hazards such as loss of offsite power, prompt loss of electrical load, loss of thermal output, and immediate steam diversion, in addition to hydrogen explosions and toxic chemical releases. Both Bauwens and TNT-EM methods suggest maintaining several hundred meters of separation between the NPP and hydrogen facility to mitigate explosion risks. PRA results show a maximum initiating event frequency increase of 1.15% and an overall risk increase of 0.28%. Importance measure analysis identifies upstream pipe leak isolation components as critical. Evaluating the results against safety regulations, it is concluded that hazards and risks can be managed to comply with regulations through risk-informed thermal and electrical connection designs, component selection, maintenance programs, and safe separation distances between NPPs and integrated industrial facilities.

08 - HYDROGEN↗

A decomposition approach based on meta-heuristics and exact methods for solving a two-stage stochastic biofuel hub-and-spoke network problem

An alternative to the production of fossil transportation fuels is the production of biofuels, particularly, bioethanol. One of the main opportunity areas is the reduction in the overall cost of biofuel. An approach to reduce this cost is to design and implement a supply chain (SC) that considers the quality-related properties of the biomass as well as the economies of scale to minimize the logistics and quality-related costs. This problem is formulated as a hub location problem, which has been classified as an NP-hard problem, thus, meta-heuristics are a suitable approach to solve this problem. We propose a hybrid meta-heuristic solution procedure to solve large-scale instances of a two-stage stochastic biomass-to-biorefinery hub-and-spoke network problem. This solution procedure is proposed to support the large-scale production and distribution of bioethanol by considering the variability in its moisture and ash contents. The hybrid method utilizes a simulated annealing-simplex method to find an initial solution and a tabu search-simplex method to improve the solution. Numerical experimentation was performed on a realistic case study in Texas. The findings demonstrate that the hybrid procedure outperforms the standard L-shaped (LS) method. The meta-heuristic combining simulated annealing and tabu search with the simplex method (SATS-SM) achieved 2.48% lower costs and required 96.57% less time, on average, when compared to the results from using the LS.

09 BIOMASS FUELS↗

Automatic generation and simulation of urban building energy models based on city datasets for city-scale building retrofit analysis

Buildings in cities consume 30–70% of total primary energy, and improving building energy efficiency is one of the key strategies towards sustainable urbanization. Urban building energy models (UBEM) can support city managers to evaluate and prioritize energy conservation measures (ECMs) for investment and the design of incentive and rebate programs. This paper presents the retrofit analysis feature of City Building Energy Saver (CityBES) to automatically generate and simulate UBEM using EnergyPlus based on cities’ building datasets and user-selected ECMs. CityBES is a new open web-based tool to support city-scale building energy efficiency strategic plans and programs. The technical details of using CityBES for UBEM generation and simulation are introduced, including the workflow, key assumptions, and major databases. Also presented is a case study that analyzes the potential retrofit energy use and energy cost savings of five individual ECMs and two measure packages for 940 office and retail buildings in six city districts in northeast San Francisco, United States. The results show that: (1) all five measures together can save 23–38% of site energy per building; (2) replacing lighting with light-emitting diode lamps and adding air economizers to existing heating, ventilation and air-conditioning (HVAC) systems are most cost-effective with an average payback of 2.0 and 4.3 years, respectively; and (3) it is not economical to upgrade HVAC systems or replace windows in San Francisco due to the city's mild climate and minimal cooling and heating loads. Furthermore, the CityBES retrofit analysis feature does not require users to have deep knowledge of building systems or technologies for the generation and simulation of building energy models, which helps overcome major technical barriers for city managers and their consultants to adopt UBEM.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

GHEP WIBT (Guidelines for Home Energy Professionals Weatherization Installer Badges Toolkit) [SWR-20-69]

The National Renewable Energy Laboratory (NREL) and the U.S. Department of Energy's (DOE) Weatherization Assistance Program (WAP) are collaborating with the home energy retrofit industry to support the development of skilled workers. The Installer Badges Toolkit provides a flexible, customizable, and voluntary approach to training and skills recognition for WAP implementers, utility programs, private-sector workers, and contractors. In Fiscal Year 2018, DOE, along with the Crew Leader scheme committee, determined the Retrofit Installer Technician (RIT) Job Task Analysis (JTA) could be eliminated and its tasks inserted in the Crew Leader JTA. The RIT tasks became the basis of the Installer Badges. The Badges Toolkit was updated in 2020 to add licensing and copyright agreements. Users must cite the copyright information when using or distributing copies of the Badges Toolkit in any way. The technical content has remained unchanged from previous versions of the Badges Toolkit. The Toolkit for home retrofits consists of 25 Badges, each representing different energy efficiency tasks that an installer could perform on a home. Each Badge defines the desired outcome, criteria to verify, applicable material requirements, and references to Standard Work Specifications (SWS) or other relevant standards. The Badges provide a consistent approach to training by ensuring that installers in different regions are learning the same skills nationwide. Organizations can also customize the Toolkit by choosing only those Badges that are relevant to their program. The Badges Toolkit includes five pieces: "How to Use the Badges Toolkit" provides a brief overview of how a Grantee, Subgrantee, or training provider may approach using the toolkit. The "Badges Toolkit: Worksheet" includes what to consider when determining whether and how to best incorporate the Badges into a weatherization assistance program. The "Crew Leader Job Task Analysis Spreadsheet" indicates how the Badges align with specific areas of the JTA. The "Installer Badges Passport" features separate pages for each Badge, which include places for the installer and the supervisor/trainer to record the number of times a task has been successfully completed. The "Installer Badges Verification Criteria" includes sample inspection checklists for each Badge. These can be modified as needed based on approved variance requests or more stringent requirements. They also provide a basis for consistent inspections and awarding of Badges. Note: All elements of the Badges Toolkit are designed for use by potential program implementers. They are not off-the-shelf products intended for immediate deployment. Program implementers must review and modify as needed, revise verification criteria to match local requirements, complete worksheets, and otherwise define the parameters of their own badging program.

Desai, Jal↗

Integral Experiment Final Design for Thermal/Epithermal eXperiments (TEX) Plutonium Additional Mixed Spectrum Configurations

This report presents the final design (CED-2) for three additional mixed-spectra configurations for plutonium Thermal/Epithermal eXperiments (TEX) to target the intermediate energy region (IER-553). The baseline cases of IER-184 (PU-MET-MIXED-002 [2]) spanned the entire fission energy spectrum. Case 3, which had a median fission energy (MFE) of approximately 6E-5 MeV and had a fission fraction of about 42% in the intermediate energy range, resulted in a $k_{eff}$ overestimation of 1.1%. Compared to 749 previous ICSBEP plutonium benchmarks, the baseline cases accurately predicted the experiments in the thermal and fast regions where the majority of benchmarks inhabit. The benchmarks in the intermediate energy region to date are sparse and overestimate $k_{eff}$ with an average C/E between 1.02 and 1.03. The additional proposed configurations span the whole of the intermediate energy region. The experimental design utilizes the plutonium/aluminum metal alloy Zero Power Physics Reactor (ZPPR) Plutonium-Aluminum No-Nickel (PANN) plates with varying polyethylene moderator thicknesses to span the intermediate fission energy region. Each of the cases have varying fractions of thermal, intermediate, and fast fissions. The designs were chosen to maximize the intermediate energy fraction. The experiment will take place on the universal critical assembly machine, Planet. The layers will be split as equally as possible between the lower platen and the upper stationary platform of Planet. The upper half of the experimental configuration will also have an upper reflector of polyethylene of specified thicknesses to achieve criticality when the lower platen is raised fully. The previous IER-184 configurations, specifically Case 3, were used to determine the configurations for the additional experiments and neutronics calculations were used to fine-tune the configurations to ensure criticality. The quadrature sum uncertainty in Δ$k_{eff}$ for Case 3 in PU-MET-MIXED-002 was found to be 0.00219. Section 3.8 gives a detailed description of the uncertainties calculated. The additional configurations, which are based directly on Case 3, are expected to have similar uncertainties. However, it is possible to reduce the overall uncertainty of Δ$k_{eff}$ for the additional configurations using the knowledge obtained from the calculations in the benchmark.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Single-Crystal Sapphire Optical Fiber Sensor Instrumentation

This report summarizes technical progress on the program “Single-Crystal Sapphire Optical Fiber Sensor Instrumentation,” funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering at Virginia Tech. This project was completed in three phases, each with a separate focus. Phase I of the program, from October 1999 to April 2002, was devoted to development of sensing schema for use in high temperature, harsh environments. Different sensing designs were proposed and tested in the laboratory. Phase II of the program, from April 2002 to April 2009, focused on bringing the sensor technologies, which had already been successfully demonstrated in the laboratory, to a level where the sensors could be deployed in harsh industrial environments and eventually become commercially viable through a series of field tests. Also, a new sensing scheme was developed and tested with numerous advantages over all previous ones in Phase II. Phase III of the program, September 2009 to December 2013, focused on development of the new sensing scheme for field testing in conjunction with materials engineering of the improved sensor packaging lifetimes. In Phase I, three different sensing principles were studied: sapphire air-gap extrinsic Fabry-Perot sensors; intensity-based polarimetric sensors; and broadband polarimetric sensors. Black body radiation tests and corrosion tests were also performed in this phase. The outcome of the first phase of this program was the selection of broadband polarimetric differential interferometry (BPDI) for further prototype instrumentation development. This approach is based on the measurement of the optical path difference (OPD) between two orthogonally polarized light beams in a single-crystal sapphire disk. At the beginning of Phase II, in June 2004, the BPDI sensor was tested at the Wabash River coal gasifier facility in Terre Haute, Indiana. Due to business conditions at industrial partner and several logistical problems, this field test was not successful. An alternative high-temperature sensing system using sapphire wafer-based extrinsic Fabry-Perot interferometry was then developed as a significant improvement over the BPDI solution. From June 2006 to June 2008, three consecutive field tests were performed with the new sapphire wafer sensors at the TECO coal gasifier in Tampa, Florida. One of the sensors survived in the industrial coal gasifier for 7 months, over which time the existing thermocouples were replaced twice. The outcome of these TECO field tests suggests that the sapphire wafer sensor has very good potential to be commercialized. However packaging and sensor protection issues need additional development. During Phase III, several major improvements in the design and fabrication process of the sensor have been achieved through experiments and theoretical analysis. Studies on the property of the key components in the sensor head, including the sapphire fiber and sapphire wafer, were also conducted, for a better understanding of the sensor behavior. A final design based on all knowledge and experience has been developed, free of any issues encountered during the entire research. Sensors with this design performed well as expected in lab long-term tests, and were deployed in the sensing probe of the final coal-gasifier field test. Sensor packaging and protection was improved through materials engineering through testing of packaging designs in two blank probe packaging tests at Eastman Chemical in Kingsport, TN. Performance analysis of the blank probe packaging resulted in improve package designs culminating in a 3rd generation probe packaging utilized for the full field test of the sapphire optical sensor and materials designed sensor packaging.

47 OTHER INSTRUMENTATION↗

Discovering the desirable alleles contributing to the lignocellulosic biomass traits in Saccharum germplasm collections for energy cane improvement

1) The success in crop improvement programs depends largely on the extent of genetic variability available. Germplasm collections assembles all the available genetic resources and are critical for long-term crop improvement. This world sugarcane germplasm collection contains enormous genetic variability for various morphological traits, biomass yield components, adaptation and many quality traits, prospectively imbeds a large number of valuable alleles for biofuel traits such as high biomass yield, quantity and quality of lignocelluloses, stress tolerance, and nutrient use efficiency. The germplasm collection is of little value unless it is characterized and utilized for crop improvement. In this project, we phenotypically and genotypically characterized the sugarcane world germplasm collection (The results were published in two papers already and another two papers are to be published). This data will be made available for public to refer to for germplasm unitization specifically in the sugarcane and energy cane breeding programs. In addition, we are identifying the alleles contributing to the biomass traits in sugarcane germplasm. This part of project is very challenging due to the large genome and highly polyploid level of this crop. We firstly established a high throughput sugarcane genotyping pipeline in the genome and bioinformatics era (a paper is published in 2016). We identified and modified a software for genome-wide association analysis of polyploid species. The results of the alleles associated to the biomass traits will be published soon, which will help the scientific community understand the genetic makeup of the biomass components of sugarcane. Molecular breeders can develop markers for marker assisted selection of biomass traits improvement. Further, the development and release of new energy cane cultivars through this project not only improved genetic diversity but also improved dry biomass yields and resistance to diseases. These new cultivars were tested on marginal soils in Florida and showed very promising yield potential that is important for the successful use of energy cane as a dedicated feedstock for lignocellulosic ethanol production. 2) Multiple techniques at different project progress stages were utilized. For example, for the whole world germplasm accession genotyping, a cheap widely used SSR marker genotyping platform was utilized due to the large number of samples (over thousand). But the throughput of this technique is low in generating data points. However, the purpose the genotyping is to form a core collection for further high throughput genotyping. Thus the results from the SSR genotyping was quite good enough to generated the core collection. To genotype the few hundred core collection accessions, an target enrichment sequencing technology was used, which is not only high throughput in generating large number of genotyping data, but also has the candidate genes targeted to genotyping. The data generated would be sufficient in identifying the alleles contributing to the traits of interests. All the techniques used in this project are effective though extensive time was invested specifically for establish the pipeline in the experimental design, data analysis, and different approach comparison. 3) the research can benefit to the public in polyploid genotyping and new and cost efficient genotyping platform development

59 BASIC BIOLOGICAL SCIENCES↗

Status Report on the High-Temperature Steam Electrolysis Plant Model Developed in the Modelica Framework (FY17)

This report has been prepared as part of an effort to design and build a modeling and simulation (M&S) framework to assess the economic viability of a nuclear-renewable hybrid energy system (N-R HES). In order to facilitate dynamic M&S of such an integrated system, research groups in multiple national laboratories have been developing various subsystems as dynamic physics-based components using the Modelica programming language. In fiscal year 2015 (FY15), Idaho National Laboratory (INL) performed a dynamic analysis of two region-specific N-R HES configurations, including the gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) and brackish water reverse osmosis desalination plants as industrial processes. In FY16, INL developed two additional subsystems in the Modelica framework: (1) a high-temperature steam electrolysis (HTSE) plant as a high priority industrial plant to be integrated with a light water reactor (LWR) within an N-R HES and (2) a gas turbine power plant as a secondary energy supply. In FY17, five new components (i.e., a feedwater pump, a multi-stage compression system, a sweep-gas turbine, flow control valves, and pressure control valves) have been incorporated into the HTSE system proposed in FY16, aiming to better realistically characterize all key components of concern. Special attention has been given to the controller settings based on process models (i.e., direct synthesis method), aiming to improve process dynamics and controllability. A dynamic performance analysis of the improved LWR/HTSE integration case was carried out to evaluate the technical feasibility (load-following capability) and safety of such a system operating under highly variable conditions requiring flexible output. The analysis (evaluated in terms of the step response) clearly shows that the FY17 model resulted in superior output responses with much smaller settling times and less oscillatory behavior in response to disturbances in the electric load than those observed with the FY16 model. Simulation results involving several case studies show that the suggested control scheme could maintain the controlled variables (including the steam utilization factor, cathode stream inlet composition, and temperatures and pressures of the process streams at various locations) within desired limits under various plant operating conditions. The results also indicate that the proposed HTSE plant could provide operational flexibility to participate in energy management at the utility scale by dynamically optimizing the use of excess plant capacity within an N-R HES.

08 HYDROGEN↗

Development of a Low Cost 10kW Tubular SOFC Power System

The DOE program funded from 2003 through early 2013 has brought the Acumentrics SOFC program from an early stage R&D program to an entry level commercial product offering. The development work started as one of the main core teams under the DOE Solid State Energy Conversion Alliance (SECA) program administered by the National Energy Technology Laboratory (NETL) of the DOE. During the first phase of the program, lasting approximately 3-4 years, a 5kW machine was designed, manufactured and tested against the specification developed by NETL. This unit was also shipped to NETL for independent verification testing which validated all of the results achieved while in the laboratory at Acumentrics. The Acumentrics unit passed all criteria established from operational stability, efficiency, and cost projections. Passing of the SECA Phase I test allowed the program to move into Phase II of the program. During this phase, the overall objective was to further refine the unit meeting a higher level of performance stability as well as further cost reductions. During the first year of this new phase, the NETL SECA program was refocused towards larger size units and operation on coal gasification due to the severe rise in natural gas prices and refocus on the US supply of indigenous coal. At this point, the program was shifted to the U.S. DOE’s Energy Efficiency and Renewable Energy (EERE) division located in Golden, Colorado. With this shift, the focus remained on smaller power units operational on gaseous fuels for a variety of applications including micro combined heat and power (mCHP). To achieve this goal, further enhancements in power, life expectancy and reductions in cost were necessary. The past 5 years have achieved these goals with machines that can now achieve over 40% electrical efficiency and field units that have now operated for close to a year and a half with minimal maintenance. The following report details not only the first phase while under the SECA program and the key achievements but also the results while under EERE’s leadership and the transition to an early commercial product offering.

10 SYNTHETIC FUELS↗

A hybrid 3D/2D field response calculation for liquid argon detectors with PCB based anode plane

Liquid Argon Time Projection Chamber (LArTPC) technology is commonly utilized in neutrino detector designs. It enables detailed reconstruction of neutrino events with high spatial precision and low energy threshold. Its field response (FR) model describes the time-dependent electric currents induced in the anode-plane electrodes when ionization electrons drift nearby. An accurate and precise FR is a crucial input to LArTPC detector simulations and charge reconstruction. Established LArTPC designs have been based on parallel wire planes. It allows accurate and computationally economic two-dimensional (2D) FR models utilizing the translational symmetry along the direction of the wires. Recently, novel LArTPC designs utilize electrodes formed on printed circuit board (PCB) in the shape of strips with through holes. The translational symmetry is no longer a good approximation near the electrodes and a new FR calculation that employs regions with three dimensions (3D) has been developed. Extending the 2D models to 3D would be computationally expensive. Fortuitously, the nature of strips with through holes allows for a computationally economic approach based on the finite-difference method (FDM). In this paper, we present a new software package pochoir that calculates LArTPC field response for these new strip-based anode designs. This package combines 3D calculations in the volume near the electrodes with 2D far-field solutions to achieve fast and precise field response computation. We apply the resulting FR to simulate and reconstruct samples of cosmic-ray muons and 39 Ar decays from a Vertical Drift (VD) detector prototype operated at CERN. We find the difference between real and simulated data within 5%. Current state-of-the-art LArTPC software requires a 2D FR which we provide by averaging over one dimension and estimate that variations lost in this average are smaller than 7%.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation

Hydrogenase enzymes provide inspiration for investigations of molecular catalysts utilizing structural and functional mimics of the active site. However, the resulting active site mimics cannot match the combination of high rates and low overpotentials of the enzyme, suggesting that the rest of the protein scaffold, i.e., the outer coordination sphere, is necessary for the efficiency of hydrogenase. Therefore, inclusion of outer coordination sphere elements onto molecular catalysts may enable us to achieve and ultimately surpass the overall enzymatic efficiency. In an effort to identify and include the missing enzymatic features, there has been recent effort to understand the effect of outer coordination sphere elements on molecular catalysts for hydrogen oxidation and production. Our focus has been to utilize amino acid or peptide based scaffolds on an active functional mimic for hydrogen oxidation and production, [Ni(PR2NR’2)2]2+. This bottom-up approach, i.e, building an outer coordination sphere around a functional molecular catalyst, has allowed us to evaluate individual contributions to catalysis, including enhancing proton movement, concentrating substrate and introducing structural features to control reactivity. Collectively, these studies have resulted in catalysts that can operate faster, can operate at lower overpotentials, have enhanced water solubility, and/or can provide more stability to oxygen or extreme conditions such as strongly acidic or basic conditions than their unmodified parent complexes. Common mechanisms have yet to be defined to predictably control these processes but our growing knowledge in this area is essential for the eventual mimicry of enzymes for developing efficient molecular catalysts for practical use. This account reviews previously published work supported by the US DOE Basic Energy Sciences (BES), Physical Bioscience program, the Office of Science Early Career Research Program through the USDOE, BES, the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US DOE, Office of Science, Office of BES. Part of the research was conducted at the W.R. Wiley Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by U.S. DOE’s Office of Biological and Environmental Research program located at Pacific Northwest National Laboratory (PNNL). PNNL is operated by Battelle for the U.S. Department of Energy.

bioinspired↗

Advanced Aqueous Separation Systems for Actinide Partitioning

One of the most challenging aspects of advanced processing of used nuclear fuel is the separation of transplutonium actinides from fission product lanthanides. This separation is essential if actinide transmutation options are to be pursued in advanced fuel cycles, as lanthanides compete with actinides for neutrons in both thermal and fast reactors, thus limiting efficiency. The separation is difficult because the chemistry of Am 3+ and Cm 3+ is nearly identical to that of the trivalent lanthanides (Ln 3+ ). The prior literature teaches that two approaches offer the greatest probability of devising a successful group separation process based on aqueous processes: 1) the application of complexing agents containing ligand donor atoms that are softer than oxygen (N, S, Cl - ) or 2) changing the oxidation state of Am to the IV, V, or VI state to increase the essential differences between Am and lanthanide chemistry (an approach utilized in the PUREX process to selectively remove Pu 4+ and UO 2 2+ from fission products). The latter approach offers the additional benefit of enabling a separation of Am from Cm, as Cm(III) is resistant to oxidation and so can easily be made to follow the lanthanides. The fundamental limitations of these approaches are that 1) the soft(er) donor atoms that interact more strongly with actinide cations than lanthanides form substantially weaker bonds than oxygen atoms, thus necessitating modification of extraction conditions for adequate phase transfer efficiency, 2) soft donor reagents have been seen to suffer slow phase transfer kinetics and hydro-/radiolytic stability limitations and 3) the upper oxidation states of Am are all moderately strong oxidants, hence of only transient stability in media representative of conventional aqueous separations systems. There are examples in the literature of both approaches having been described. However, it is not clear at present that any extant process is sufficiently robust for application at the scale necessary for commercial fuel processing supporting transmutation of transplutonium elements. This research project continued basic themes investigated by this research group during the past decade. In the Fuel Cycle Research and Development program at DOE, the current favorite process for accomplishing the separation of trivalent actinides from fission product lanthanides is the TALSPEAK process. TALSPEAK is a solvent extraction method (developed at Oak Ridge National Lab in the 1960s) based on the combination of a cation exchanging extractant (e.g., HDEHP), an actinide-selective aminopolycarboxylate complexing agent (e.g., DTPA), and a carboxylic acid buffer to control pH in the range of 3-4. Considerable effort has been expended in this research group during the past 8 years to elaborate the details of TALSPEAK in the interest of developing improved approaches to the operation of TALSPEAK-like systems. In this project we focused on defining aggregation phenomena in conventional TALSPEAK separations, on supporting the development of Advanced TALSPEAK processes, on profiling the aqueous complexation kinetics of lanthanides in TALSPEAK relevant aqueous media, on the design of new diglycolamide and N-donor extractants, and on characterizing cation-cation complexes of pentavalent actinides.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Residential Building Energy Efficiency Field Studies: Low-Rise Multifamily

In recent years, the U.S. Department of Energy (DOE) has conducted a series of research studies to validate energy efficient building technologies in the field. Much of the work has focused on single-family construction, and some has also addressed commercial energy codes. The work detailed in this DOE-funded study (EE0007616) focuses on low-rise multifamily buildings (three stories or fewer above grade) in various regions of the United States, and reports on how state-level building codes are being implemented, both in terms of observed characteristics and also in terms of estimated energy impacts. Nearly 100 buildings across four states—Illinois, Minnesota, Oregon, and Washington—were sampled, which represent a range of climate types from mild temperature to very cold continental. Both common entry and outdoor entry buildings were included, and a parallel research project evaluated envelope air tightness and current still-evolving air tightness testing methods. Finally, a set of structured interviews of building designers and other relevant professionals was carried to out to gain more insight into this market. To the greatest extent possible, the methodology developed under the project for low-rise multifamily buildings mirrored the approach established by Pacific Northwest National Laboratory (PNNL) for single-family residential buildings (https://www.energy.gov/eere/buildings/downloads/residential-building-energy-code-field-study). This included the general approach to sampling, recruitment, and data collection, as well as data analysis and presentation. The range of permitting dates for the sites encompassed two energy code cycles in most regions. All states in the study had adopted a variation of the International Energy Conservation Code (IECC) for the structure of their state code. The low-rise multifamily occupancy presents a hybrid building type: most of the building’s conditioned floor area was covered by the residential chapter of the code while portions of the building (such as corridors and common spaces) fell under the commercial code chapter. The key items assessed in this work were: Building Shell—exterior wall insulation, ceiling insulation, foundation insulation, windows. Common Areas—HVAC and lighting. Living Units—lighting, ventilation. A few items were not assessed in detail, given their relative paucity in this occupancy type; these included duct leakage, pipe insulation, and hot water circulation controls. Building characteristics were collected via a combination of architectural, mechanical, electrical, and plumbing plan reviews and field inspections, and entered into a spreadsheet-based tool that was later queried to build a database. Data went through quality control both upon arrival and via a later semi-automated review and assurance process. Most of the data are presented graphically so that the reader can quickly assess compliance with the applicable energy codes (both by state and by code year). As a final step, EnergyPlus™ simulations were created for all buildings in the study to estimate both the as-found energy use intensity (EUI) and the energy and CO 2 that could be saved if features that were found to not meet code minimums were brought up to code. The savings estimates were tabulated for each of the four states in the study. The research team found that the single-family approach was largely applicable to low-rise multifamily buildings. This applies to both the data collection and the prototype EUI analysis. Most of the occupied space is living units and falls under residential energy codes, and many characteristics use similar envelope construction and relatively straightforward mechanical systems and lighting. One of the most challenging aspects of this work was to build an effective spreadsheet-based data collection instrument that could allow efficient collection of both building plan and field data. The research team is of the view that other methods could be equally effective if the work is done carefully with diligent quality control. The primary findings for the work center around the thermal envelope and mechanical systems and lighting at the sites: For thermal envelope components, the majority of buildings met or were better than the prescriptive code.This suggests that building designers and builders are aware of code requirements. In some cases, surveyed buildings were designed to qualify for energy efficiency certification programs. These buildings made up at least 20% of sampled buildings in each state. Almost all buildings met mechanical system efficiency requirements (for both living units and common areas). In some cases, sites employed systems that were considerably more efficient than required by the applicable energy code. Dwelling units had a majority of high-efficacy lighting, often in excess of the state’s residential code requirements. While high-efficacy fixtures were also typical in common areas (corridors and stairwells), lighting power densities (LPDs) in these areas were sometimes higher than levels dictated by the applicable part of the state commercial energy code. The simulation models run on a series of low-rise multifamily prototypes, informed by a composite of the field data collected, calculated annual EUIs of between 20 and 50 kBtu/ft2-yr, with the range representing the effects of both building characteristics and building location (climate zone). A detailed process (based on simulations of prototype buildings) was used to estimate the amount of avoided energy use that would occur if 100% adherence to energy codes were attained. The results indicated modest savings are attainable for items such as window thermal performance and common area lighting. The result is overall only a modest potential for additional energy savings, averaging about 10% of EUI.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Minimization of Nuclear Waste using AHWR Reactor Technology

Nuclear sciences have grown from creating reactors to a greater understanding of how to dispose off the waste exhibited by the nuclear activities. Various methodologies have been proposed and are being used in order to do the same. This poster poses great attention to 'Using a fuel cycle dedicated to the production of the lower quantity of minor actinides, is one of the key targets in reducing nuclear waste in india'. A significant fraction of thorium is utilized as a fertile host in the Advanced Heavy Water Reactor (AHWR300-LEU) fuel. Being lower in the periodic table, it leads to a reduction of minor actinides. It produces only half of the minor actinides as a waste as compared to modern LWRs. As thorium oxide has inert nature, it benefits in its prolonged storage. Therefore, safe disposal of spent fuel is achieved due to the inert matrix, on completion of one fuel cycle mode. AHWR is a 300 MWe, vertical, pressure-tube type, boiling light water-cooled, and heavy water-moderated reactor. Employs natural circulation for removal of heat from the reactor core. In-situ conversion of {sup 232}Th into {sup 233}U. The reactor design permits flexible fuel cycle options. There are two types of AHWR depending upon the fuel cycle options. Uses thorium-based oxide fuels: two fuel cycle options. With the adoption of thorium fuel cycle, AHWR300-LEU produces less minor actinides. As compared to modern LWRSs, it produces almost 37% less amount of actinides for the same amount of energy production, which in turn minimizes the burden on waste disposal requirements. But, it is associated with radionuclides such as {sup 231}Pa (produced through absorption of one neutron and emission of two neutrons). Since, the reaction rate of (n,2n) reactions is very low in thermal neutron reactors, thus making the fuel cycle the favorable one. Thorium oxide (ThO{sub 2}) is chemically stable and is the highest oxidation state of thorium, therefore the inert nature of the matrix is advantageous for safe disposal of spent fuel in case of adoption of open fuel cycle mode and offers prolonged storage of spent fuel. The AHWR is thorium fueled Indian nuclear reactor that assimilates several new features with diminished environmental concern due to reduced waste generation. Since thorium fuel cycle produces less long lived nuclear waste, thus it can possibly bring the world cleaner and more sustainable nuclear energy. Currently, India being the only country with large scale research program of thorium nuclear power serves a platform for the development and demonstration of all technologies and advanced safety systems.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Gaussian Process Optimization of Sensitivity-Based Similarity Metrics between New Nuclear Applications and New/Existing Benchmarks

Confidently designing safe, new nuclear criticality experiments requires expert judgement, which could take years of experience. Sensitivity/uncertainty (S/U) analysis can be utilized by less experienced individuals to conservatively estimate uncertainties in important parameters, such as k eff , in newly proposed nuclear applications. This type of analysis relies on matching new nuclear applications with existing benchmark experiments. The Whisper-1.1 software package included in MCNP6.2 ®1 contains more than 1,100 International Criticality Safety Benchmark Evaluation Project (ICSBEP) benchmarks. These benchmarks however rarely match new nuclear applications. The number of benchmarks available to match a given set of materials or geometric configurations varies significantly. Furthermore, recently performed benchmark experiments may not have had enough time to be properly documented and published. Benchmarks are vital for determining the accuracy of nuclear data and can assist nuclear physics and evaluators in improving nuclear data libraries. Exhaustively exploring the parameter space using simulations with software such as MCNP is too computationally expensive. In this work, Gaussian process optimization was implemented to reduce the number of simulations needed for optimization over multiple parameters. This optimization scheme was designed to selectively generate new benchmarks with high sensitivity-based similarity metrics to user-defined nuclear applications. Two benchmark models of spherically nested shells containing plutonium, uranium, tantalum, and water were used in the optimization to match an application containing plutonium plates, stacked in a tantalum reflector, surrounded by water.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Laboratory Evaluation and Field Demonstration of High Rotor Switched Reluctance Motor (HRSRM) Technology

In this project, a new motor technology based on a novel design called a High Rotor Pole Switched Reluctance Motor (HRSRM) was demonstrated and evaluated. The HRSRM system combines an innovative electric motor design with a programmable variable-speed drive and a controller that provides real time monitoring and cloud-based connectivity. Unlike induction or permanent-magnet motor designs, this motor uses a switched reluctance (SR) design that purports to be simpler to manufacture and more reliable and efficient to operate. Several of the stated benefits of the HRSRM system were evaluated as part of this project. First, the technology is claimed to offer greater energy efficiency than any motor currently on the market. Second, according to the manufacturer, the motor can be dropped into an existing pump or heating, ventilation, and air-conditioning application in less than 30 minutes, and has controls that can be pre-programmed to interact with the application’s existing control structure. Third, the control system allows the HRSRM to replace a constant-speed motor with one that provides variable-speed capabilities without requiring the installation of a variable-speed drive. The evaluation of a 10 hp HRSRM system was conducted in two parts. One portion of the evaluation consisted of performance tests conducted in a tightly controlled laboratory environment in which the performance of the HRSRM system was compared with that of a premium efficiency induction motor with a variable-frequency drive. The other portion of the evaluation was conducted at a field location within a General Services Administration facility in which the HRSRM system replaced an existing motor system in a 10 hp chilled water pump. The performance of the HRSRM system was compared with that of the incumbent motor system that was supplied with the pump from the manufacturer. The overall project and performance objectives for this motor evaluation are defined in Table ES.1.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Nuclear-Renewable Energy Systems Secondary Product Market Analysis Study

In order to properly create a program surrounding the development of any technological concept it is necessary to fully understand the market in which it is being developed. In the case of Integrated Nuclear-Renewable Hybrid Energy Systems (HES), there are two economic markets in which it must be able to participate in: the electricity market and the secondary product market associated with the specific system. The purpose of the present report is to characterize the secondary product market in the U.S. and to provide recommendations for further developing the HES program. While HESs have been discussed in depth in many other reports, it is helpful to discuss them briefly in the present work [REF]. The concept of the HES can be deduced to a system, featuring a combination of a nuclear power plant, a renewable energy source, and an industrial manufacturing plant . The system is designed in a fashion that allows it either to produce electricity or to manufacture a secondary product as needed. The primary benefit of this concept lies in its ability to maximize economic performance of the integrated system and to manufacture products in a carbon-free manner. A secondary benefit is the enhanced supply-side flexibility gained by allowing the HES to economically provide grid services. A key tenant to nuclear power plant economics in today’s electricity market is their ability to operate at a very high capacity factor. Unfortunately, in regions with a high penetration of renewable energy, the carbon free energy produced by nuclear power may not be needed at all times. This forces the nuclear power plant to find a user for its excess capacity. This may include paying the electric grid to find a user, releasing energy to the environment by ‘dumping steam’, or reducing power. If the plant is unable to economically or safely do any of these actions, the plant is at risk of being shutdown. In order to allow for nuclear power plants to continue to contribute carbon free electricity to the grid in a future with high renewable energy penetration, HESs allow for excess capacity to be diverted to a chemical process. If the chemical products sold on the market replace those sold previously – which would be the case if a currently operating manufacturing plant was modified to be a HES component – then the products would now be produced with reduced emission of carbon and other greenhouse gases. There are several key economic barriers that must be surmounted for HESs to be developed. The two primary barriers are the increased capital cost associated with coupling and controlling the HES components and the decreased utilization of the manufacturing plant capital due to intermittent energy delivery . Because of this, manufacturing plants that are less complex and have smaller non-variable operations and capital costs may be more attractive for integration. A secondary economic barrier for the HES is the market availability for its products. The system must operate a region where there is either an intermittent demand for its electricity, an intermittent demand for its secondary product, or both. In a region with an intermittent demand, product prices should shift accordingly, making it less attractive to produce one of the products. The HES then can shift production in order to maximize profit. Without an intermittent demand for at least one of its products, there would be little need for it to expend the extra capital required for integration as an HES.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗