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Composition Quantification of SiGeSn Alloys Through Time-of-Flight Secondary Ion Mass Spectrometry: Calibration Methodologies and Validation With Atom Probe Tomography

Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) is a powerful technique for elemental compositional analysis and depth profiling of materials. However, it encounters the problem of matrix effects that hinder its application. In this work, we introduce a pioneering ToF-SIMS calibration method tailored for SixGeySnz ternary alloys. SixGe1-x and Ge1-zSnz binary alloys with known compositions are used as calibration reference samples. Through a systematic SIMS quantification study of SiGe and GeSn binary alloys, we unveil a linear correlation between secondary ion intensity ratio and composition ratio for both SiGe and GeSn binary alloys, effectively mitigating the matrix effects. Extracted relative sensitivity factor (RSF) value from SixGe1-x (0.07 < x < 0.83) and Ge1-zSnz (0.066 < z < 0.183) binary alloys are subsequently applied to those of SixGeySnz (0.011 < x < 0.113, 0.863 < y < 0.935 and 0.023 < z < 0.103) ternary alloys for elemental compositions quantification. These values are cross-checked by Atom Probe Tomography (APT) analysis, an indication of the great accuracy and reliability of as-developed ToF-SIMS calibration process. Furthermore, the proposed method and its reference sample selection strategy in this work provide a low-cost as well as simple-to-follow calibration route for SiGeSn composition analysis, thus driving the development of next-generation multifunctional SiGeSn-related semiconductor devices.

36 MATERIALS SCIENCE↗

Intrinsic Correlations for Flaring Blazars Detected by Fermi

Blazars are an extreme subclass of active galactic nuclei. Their rapid variability, luminous brightness, superluminal motion, and high and variable polarization are probably due to a beaming effect. However, this beaming factor (or Doppler factor) is very difficult to measure. Currently, a good way to estimate it is to use the timescale of their radio flares. In this Letter, we use multiwavelength data and Doppler factors reported in the literature for a sample of 86 flaring blazars detected by Fermi to compute their intrinsic multiwavelength data and intrinsic spectral energy distributions and investigate the correlations among observed and intrinsic data. Quite interestingly, intrinsic data show a positive correlation between luminosity and peak frequency, in contrast with the behavior of observed data, and a tighter correlation between γ -ray luminosity and the lower-energy ones. For flaring blazars detected by Fermi , we conclude that (1) observed emissions are strongly beamed; (2) the anti-correlation between luminosity and peak frequency from the observed data is an apparent result, the correlation between intrinsic data being positive; and (3) intrinsic γ -ray luminosity is strongly correlated with other intrinsic luminosities.

79 ASTRONOMY AND ASTROPHYSICS↗

Strategic Energy Management Program Persistence and Cost Effectiveness An Analysis of the SEM Program Landscape

This study examines the relationship between strategic energy management (SEM) programs and their persistence and cost effectiveness, with analysis based on interview data from 24 SEM program administrators, SEM program evaluations, and other reports. The 80 interview questions focused on the topics of program design, energy savings, energy savings persistence, cost effectiveness, and customer SEM persistence. The generosity of interview respondents provided a wealth of data, resulting in a report of sufficient length to warrant inclusion of this brief guide of the report structure. The major sections are listed below with brief descriptions. Individual sections of this report are mainly stand-alone and do not require reading of other sections. As a result, there is some duplication between sections, but with differing levels of detail. Executive Summary: Presents three key conclusions of this work with a short description of potential actions to advance the understanding of each key finding. Brief Observations: Lists a large number of bulleted observations resulting from this research, arranged by the five major topic areas included in the interviews. Analysis details are provided in the Analysis of Interview Results section. Foundations for this Research: Provides an overview of SEM, SEM frameworks, SEM programs, the topics of persistence and cost effectiveness, and the focus of this research. Methodology: Details the approach and strategy of this research, providing background information relevant to the formulation of interview questions and the identification of which SEM programs to interview. Observations from Compiled Evaluations and Other Reports: Reports observations from the collection and analysis of program evaluations, annual reports, utility planning documents, and SEM-related white papers. This section, presented in bullet form, highlights challenges in data collection and ultimately a comparison of program practices as they pertain to persistence and cost effectiveness. Analysis of Interview Results: Presents detailed analysis of responses from SEM program administrators, arranged by the five major categories examined: program design, energy savings, energy savings persistence, cost effectiveness, and customer SEM persistence. Interview questions are generally grouped together into subsections when it makes sense to examine them together. SEM Programs Challenge Traditional Cost-Effectiveness Metrics: Details an analysis based on five key factors showing that applying traditional cost-effectiveness metrics to SEM programs is not straightforward. This invites the opportunity to consider whether traditional cost-effectiveness metrics are applicable to SEM programs, either individually or at large. Resolution of Research Hypotheses: Tabulates a set of hypotheses that were developed to address the fundamental nature of the research at hand. Analysis of responses to multiple questions informs an understanding of each hypothesis and can be used to better understand the SEM program environment at large.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Inhibition of FGF signaling accelerates neural crest cell differentiation of human pluripotent stem cells

Neural crest (NC) is a transient population, arising during embryonic development and capable of differentiating into various somatic cells. The defects of neural crest development leads to neurocristopathy. Several signaling pathways were revealed their significance in NC cell specification. Fibroblast growth factor (FGF) is recognized as an important signaling during NC development, for instance Xenopus and avian; however, its contributions in human species are remained elusive. Here we used human pluripotent stem cells (hPSCs) to investigate the consequences of FGF inhibition during NC cell differentiation. The specific-FGF receptor inhibitor, SU5402, was used in this investigation. The inhibition of FGF did not found to affect the proliferation or death of hPSC-derived NC cells, but promoted hPSCs to commit NC cell fate. NC-specific genes, including PAX3, SLUG, and TWIST1, were highly upregulated, while hPSC genes, such as OCT4, and E-CAD, rapidly reduced upon FGF signaling blockage. Noteworthy, TFAP-2α, a marker of migratory NC cells, abundantly presented in SU5402-induced cells. This accelerated NC cell differentiation could be due to the activation of Notch signaling upon the blockage of ERK1/2 phosphorylation, since NICD was increased by SU5402. Altogether, this study proposed the contributions of FGF signaling in controlling human NC cell differentiation from hPSCs, the crosstalk between FGF and Notch, and might imply to the influences of FGF signaling in neurocristophatic diseases.

60 APPLIED LIFE SCIENCES↗

Environmental licensing in Brazilian's crushed stone industries

Highlights: • Failures in environmental reporting compromise the effectiveness of the environmental license process • The infrastructure of environmental agencies must be improved • The participation of society is essential for monitoring industries - Abstract: The crushed stone industries' activities are characterized by the extraction and processing of stones for use as aggregates in construction. The sector causes environmental impacts that can be mitigated by the implementation of control instruments, namely, environmental licensing, whose purpose is to carry out monitoring of potentially polluting activities. In this paper, it was analyzed the environmental studies of three industries located in Monsenhor Gil, Piauí, Brazil, elaborated as requisites for obtaining the environmental and mineral licenses. There were made visits to the State Department of Environment and Water Resources (SEMAR) and to the National Department of Mineral Production (DNPM) to verify the environmental reports and the environmental and mineral licensing processes. There were also made visits to the analyzed industries, with the aim of comparing the information contained in the studies, with the reality and verifying the implementation of the mitigating measures proposed in them, through the observation of the industries operation, and interviews with the responsible managers. Furthermore, it was made a research in the scientific literature, to know the licensing process in other countries, to compare with the Brazilian reality. From the research, in Brazilian industries, it was observed that, although all the legal steps to obtain the licenses have been fulfilled, the environmental reports have elaboration failures, such as the lack of a multidisciplinary team and the fact that some data diverge from the reality, decreasing the reliability of the evaluation of the environmental impacts caused by the projects. Also, the environmental replacement cost is not accounted in the final value of the product, and any of the industries have started the implementation of the proposed mitigation measures since they do not have mineral depletion areas. SEMAR was delayed in issuing licenses within the period established by law, and there are no periodic inspections by both the environmental agency and DNPM. It should also be pointed out that the community did not claim public hearings and there is no participation in environmental education projects, factors that compromise the effectiveness of the environmental licensing process. Regarding the process in other parts of the world, in some countries, such as Uruguay and Paraguay, the agency responsible for licensing and inspection is federal. In Argentina, as in Brazil and USA, states have autonomy to legislate on environmental issues. There is also divergence in the period of execution of the licenses, being 12 months in Brazil, while in Thailand it can be up to 56 days. In Peru, the society participation is much more representative than in Brazil, and there is differentiation in the collection form of environmental compensation fees, among countries. The failures pointed out in the Brazilian process, as well as the system of other countries, can serve as parameters for the improvement of the process' effectiveness, both in Brazil and in other parts of the world, aiming at the conservation of the environment.

54 ENVIRONMENTAL SCIENCES↗

Experimental Determination of the Recovery Factor and Analytical Solution of the Conical Flow Field for a 20 deg Included Angle Cone at Mach Numbers of 4.6 and 6.0 and Stagnation Temperatures to 2600 degree R

The local recovery factor was determined experimentally along the surface of a thin-walled 20 deg included angle cone for Mach numbers near 6.0 at stagnation temperatures between 1200 deg R and 2600 deg R. In addition, a similar cone configuration was tested at Mach numbers near 4.5 at stagnation temperatures of approximately 612 deg R. The local Reynolds number based on flow properties at the edge of the boundary layer ranged between 0.1 x 10(exp 4) and 3.5 x 10(exp 4) for tests at temperatures above 1200 deg R and between 6 x 10(exp 4) and 25 x 10(exp 4) for tests at temperatures near 612 deg R. The results indicated, generally, that the recovery factor can be predicted satisfactorily using the square root of the Prandtl number. No conclusion could be made as to the necessity of evaluating the Prandtl number at a reference temperature given by an empirical equation, as opposed to evaluating the Prandtl number at the wall temperature or static temperature of the gas at the cone surface. For the tests at temperatures above 1200 deg R (indicated herein as the tests conducted in the slip-flow region), two definite trends in the recovery data were observed - one of increasing recovery factor with decreasing stagnation pressure, which was associated with slip-flow effects and one of decreasing recovery factor with increasing temperature. The true cause of the latter trend could not be ascertained, but it was shown that this trend was not appreciably altered by the sources of error of the magnitude considered herein. The real-gas equations of state were used to determine accurately the local stream properties at the outer edge of the boundary layer of the cone. Included in the report, therefore, is a general solution for the conical flow of a real gas using the Beattie-Bridgeman equation of state. The largest effect of temperature was seen to be in the terms which were dependent upon the internal energy of the gas. The pressure and hence the pressure drag terms were unaffected.

Pfyl, Frank A.↗

Applying Gaussian Process Machine Learning and Modern Probabilistic Programming to Satellite Data to Infer CO 2 Emissions

Satellite data provides essential insights into the spatiotemporal distribution of CO 2 concentrations. However, many atmospheric inverse models fail to adequately incorporate the spatial and temporal correlations inherent in satellite observations and often lack rigorous methods for estimating parameters like spatial length scales. We introduce an inference model that processes the spatiotemporal covariance in satellite data and estimates hyperparameters such as covariance length scales. Our approach uses the Gaussian process (GP) machine learning (ML) and modern probabilistic programming languages (PPLs) to perform atmospheric inversions of emissions from satellite data. We develop a GP ML inversion system based on modern PPLs and the GEOS-Chem chemical transport model, simulating atmospheric CO 2 concentrations corresponding to the Orbiting Carbon Observatory-2/3 (OCO-2/3) data for July 2020. In our supervised learning framework, we treat the GEOS-Chem simulated data set as the target, with predictors derived by scaling the target with sector-specific factors hidden from the GP machine. Our results show that the GP model, combined with GPU-enabled PPLs, effectively retrieves true emission scaling factors and infers noise levels concealed within the data. This suggests that our method could be applied over larger areas with more complex covariance structures, enabling comprehensive analysis of the spatiotemporal patterns observed in OCO-2/3 and similar satellite data sets.

54 ENVIRONMENTAL SCIENCES↗

Fully coupled simulation of cosmic reionization. II. Recombinations, clumping factors, and the photon budget for reionization

We use a fully coupled cosmological simulation including dark matter dynamics, multispecies hydrodynamics, nonequilibrium chemical ionization, flux-limited diffusion radiation transport, and a parameterized model of star formation and feedback (thermal and radiative) to investigate the epoch of hydrogen reionization in detail. In this paper, the first of several application papers, we investigate the mechanics of reionization from stellar sources forming in high-z galaxies, the utility of various formulations for the gas clumping factor on accurately estimating the effective recombination time in the intergalactic medium (IGM), and the photon budget required to achieve reionization. We also test the accuracy of the static and time-dependent models of Madau et al. as predictors of reionization completion/maintenance. We simulate a WMAP7 ΛCDM cosmological model in a 20 comoving Mpc cube, resolved with 800{sup 3} uniform fluid cells and dark matter particles. By tuning our star formation recipe to approximately match the observed high-redshift star formation rate density and galaxy luminosity function, we have created a fully coupled radiation hydrodynamical realization of hydrogen reionization, which begins to ionize at z ≈ 10 and is completed at z ≈ 5.8 without further tuning. We find that roughly two ionizing photons per H atom are required to convert the neutral IGM to a highly ionized state. After reionization concludes, we find that the quantity n-dot{sub ion}×(1 Gyr)/n{sub H} is ∼9 at z = 5, in rough agreement with measurements of the ionizing emissivity by Becker and Bolton. The complicated events during reionization that lead to this number can be generally described as inside-out, but in reality, the narrative depends on the level of ionization of the gas one attributes as being ionized. We find that the formula for the ionizing photon production rate needed to maintain the IGM in an ionized state derived by Madau et al. should not be used to predict the epoch of reionization completion because it ignores history-dependent terms in the global ionization balance which are not ignorable. We find that the time-dependent model for the ionized volume fraction Q{sub HII} is more predictive, but overestimates the redshift of reionization completion z{sub reion} by Δz ≈ 1. We propose a revised formulation of the time-dependent model that agrees with our simulation to a few percent accuracy. Finally, we use our simulation data to measure the absorption of ionizing radiation due to circumgalactic gas resolved on our mesh and find f-bar{sub esc}(CGM)≈0.7.

79 ASTRONOMY AND ASTROPHYSICS↗

Radiation pressure acceleration: The factors limiting maximum attainable ion energy

Radiation pressure acceleration (RPA) is a highly efficient mechanism of laser-driven ion acceleration, with near complete transfer of the laser energy to the ions in the relativistic regime. However, there is a fundamental limit on the maximum attainable ion energy, which is determined by the group velocity of the laser. The tightly focused laser pulses have group velocities smaller than the vacuum light speed, and, since they offer the high intensity needed for the RPA regime, it is plausible that group velocity effects would manifest themselves in the experiments involving tightly focused pulses and thin foils. However, in this case, finite spot size effects are important, and another limiting factor, the transverse expansion of the target, may dominate over the group velocity effect. As the laser pulse diffracts after passing the focus, the target expands accordingly due to the transverse intensity profile of the laser. Due to this expansion, the areal density of the target decreases, making it transparent for radiation and effectively terminating the acceleration. The off-normal incidence of the laser on the target, due either to the experimental setup, or to the deformation of the target, will also lead to establishing a limit on maximum ion energy.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The in-medium effects on the neutrino reaction in dense matter

The nucleon form factors in free space are usually thought to be modified when a nucleon is bound in a nucleus or immersed in a nuclear medium. We investigated effects of the density-dependent axial and weak-vector form factors on the electro-neutrino (ν{sub e}) and anti-electro-neutrino (¯ν{sub e}) reactions with incident energy E{sub v} ≤ 80 MeV via neutral current (NC) and charged current (CC) for a nucleon in a nuclear medium or ¹²C. For the density-dependent form factors, we exploited the quark-meson-coupling (QMC) model, and apply them to the ν{sub e} and ¯ν{sub e} induced reactions by NC and CC. In CC reaction, about 5 % decrease of the electro neutrino (ν{sub e}) reaction cross section on the nucleon is shown to be occurred in normal density, ρ=ρ{sub 0}~0.15fm⁻³, and also about 5 % reduction of total ν{sub e} cross section on ¹²C is obtained by the modification of the weak form factors for bound nucleons. Density effects for both cases are relatively small, but they are as large as the effect by the Coulomb distortion of outgoing leptons in the ν-reaction. However, density effects in the anti-electro neutrino (¯ν{sub e}) reaction reduced significantly about 30 % the cross sections for both the nucleon and ¹²C cases. For NC, about 12 % decrease of the total cross section by the ν{sub e} reaction on the nucleon is obtained at normal density, ρ=ρ₀~0.15fm⁻³, as well as about 18 % reduction of the total ν{sub e} cross section on ¹²C, by the modification of the weak form factors of the bound nucleon. However, similarly to the CC reaction, effects of the nucleon property change in the ¯ν{sub e} reaction reduce significantly the cross sections about 30 % for the nucleon in matter and ¹²C cases. In this talk, we address that such a large asymmetry in the ¯ν{sub e} cross sections in both reactions is originated from the different helicities of ¯ν{sub e} and ν{sub e}.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Applying cumulative effects to strategically advance large-scale ecosystem restoration

Programs restoring large terrestrial-aquatic ecosystems are expected to increase in area and number over the next decade. Factors ensuring long-term effectiveness at the program scale differ from those at the individual restoration project scale, necessitating a new synthesis. Here we contextualize hydrological, geomorphological, and biological effects of large-scale ecosystem restoration activities within a cumulative-effects paradigm. Evidence of eight modes of cumulative effects benefiting species and ecosystems was elucidated by reviewing restoration efforts in the greater Florida Everglades, Gulf Coast, lower Columbia River and estuary, Puget Sound estuary, Missouri River, northeastern coastal states, San Francisco Bay and Sacramento Delta. Additive and nonlinear cumulative effects of interacting restoration projects propagated across landscape and regional geographic scales, and throughout trophic levels, affecting population structures. Applying a cumulative-effects paradigm to planning, implementing, and evaluating large-scale restoration will avoid countervailing effects and capitalize on positive feedback, advancing evidence-based programs to recover priority species and ecosystems.

54 ENVIRONMENTAL SCIENCES↗

Stochastic Parameterization for Light Absorption by Internally Mixed BC/dust in Snow Grains for Application to Climate Models

A stochastic approach to model the positions of BC/dust internally mixed with two snow-grain types has been developed, including hexagonal plate/column (convex) and Koch snowflake (concave). Subsequently, light absorption and scattering analysis can be followed by means of an improved geometric-optics approach coupled with Monte Carlo photon tracing to determine their single-scattering properties. For a given shape (plate, Koch snowflake, spheroid, or sphere), internal mixing absorbs more light than external mixing. The snow-grain shape effect on absorption is relatively small, but its effect on the asymmetry factor is substantial. Due to a greater probability of intercepting photons, multiple inclusions of BC/dust exhibit a larger absorption than an equal-volume single inclusion. The spectral absorption (0.2 – 5 um) for snow grains internally mixed with BC/dust is confined to wavelengths shorter than about 1.4 um, beyond which ice absorption predominates. Based on the single-scattering properties determined from stochastic and light absorption parameterizations and using the adding/doubling method for spectral radiative transfer, we find that internal mixing reduces snow albedo more than external mixing and that the snow-grain shape plays a critical role in snow albedo calculations through the asymmetry factor. Also, snow albedo reduces more in the case of multiple inclusion of BC/dust compared to that of an equal-volume single sphere. For application to land/snow models, we propose a two-layer spectral snow parameterization containing contaminated fresh snow on top of old snow for investigating and understanding the climatic impact of multiple BC/dust internal mixing associated with snow grain metamorphism, particularly over mountains/snow topography.

climate models↗

An empirical study of the distribution of earthquakes with respect to rock type and depth

Whether fault slip occurs seismically or aseismically depends on the frictional properties of the fault, which might be expected to depend on rock type and depth, as well as other factors. To view the effect of rock type and depth on the distribution of earthquakes, we compare geologic models of the San Francisco Bay and the Southern California regions to the distribution of seismicity. We normalize the number of earthquakes within each rock type and depth interval by the corresponding volume to determine the earthquake density. Earthquake density is confirmed primarily by depth, while whether the rock is sedimentary or basement has only a secondary, depth-dependent effect on the earthquake density. At very shallow depths, there is no difference in earthquake density between sedimentary and basement rocks. The earthquake density of basement rocks increases with depth more rapidly than that of sedimentary rocks to a similar but shallower maximum.

3‐D geologic models↗

Effect of Ring‐Fusion on Miscibility and Domain Purity: Key Factors Determining the Performance of PDI‐Based Nonfullerene Organic Solar Cells

Abstract Compared to the rapid development of nonfullerene organic solar cells (OSCs) based on the state‐of‐the‐art indacenodithiophene (IDT)‐based small molecule acceptors (SMAs), the progress for perylene diimide (PDI)‐based electron acceptors has lagged behind owing to the lack of understanding on the structure–morphology–performance relationship of PDI SMAs. Given the ease of synthesis for PDIs and their high intrinsic electron mobility, it is crucial to identify key material parameters that influence the polymer:PDI blend morphology and to develop rational approaches for molecular design toward high‐performance PDI‐based SMAs. In this study, three pairs of PDI‐based SMAs with and without ring‐fusion are investigated and it is found that ring‐fusion and domain purity are the key structural and morphological factors determining the fill factors (FFs) and efficiencies of PDI‐based nonfullerene OSCs. This data shows that nonfullerene OSCs based on the ring‐fused PDI‐based SMAs exhibit much higher average domain purity and thus increased charge mobilities, which lead to enhanced FFs compared to those solar cells based on nonfused PDIs. This is explained by higher Florry Huggins interaction parameters as observed by melting point depression measurements. This study suggests that increasing repulsive molecular interactions to lower the miscibility between the polymer donor and PDI acceptor is the key to improve the FF and performance of PDI‐based devices.

Hu, Huawei↗

Reduced type-A carbohydrate-binding module interactions to cellulose I leads to improved endocellulase activity

Dissociation of nonproductively bound cellulolytic enzymes from cellulose is hypothesized to be a key rate-limiting factor impeding cost-effective biomass conversion to fermentable sugars. However, the role of carbohydrate-binding modules (CBMs) in enabling nonproductive enzyme binding is not well understood. Here, we examine the subtle interplay of CBM binding and cellulose hydrolysis activity for three models type-A CBMs (Families 1, 3a, and 64) tethered to multifunctional endoglucanase (CelE) on two distinct cellulose allomorphs (i.e., cellulose I and III). We generated a small library of mutant CBMs with varying cellulose affinity, as determined by equilibrium binding assays, followed by monitoring cellulose hydrolysis activity of CelE–CBM fusion constructs. Finally, kinetic binding assays using quartz crystal microbalance with dissipation were employed to measure CBM adsorption and desorption rate constants kon and koff, respectively, towards nanocrystalline cellulose derived from both allomorphs. Overall, our results indicate that reduced CBM equilibrium binding affinity towards cellulose I alone, resulting from increased desorption rates (koff) and reduced effective adsorption rates (nkon), is correlated to overall improved endocellulase activity. Future studies could employ similar approaches to unravel the role of CBMs in nonproductive enzyme binding and develop improved cellulolytic enzymes for industrial applications.

59 BASIC BIOLOGICAL SCIENCES↗

An apparatus and method for directly measuring the depth-dependent gain and spatial resolution of turbid scintillators

Turbid (powder or columnar–structured) scintillators are widely used in indirect flat panel detectors (I–FPDs) for scientific, industrial, and medical radiography. Light diffusion and absorption within these scintillators is expected to cause depth–dependent variations in their x ray conversion gain and spatial blur. Furthermore, these variations degrade the detective quantum efficiency of I–FPDs at all spatial frequencies. Despite their importance, there are currently no established methods for directly measuring scintillator depth effects. This work develops the instrumentation and methods to achieve this capability.

47 OTHER INSTRUMENTATION↗

Estimation of full-field dynamic strains from digital video measurements of output-only beam structures by video motion processing and modal superposition

Strain is an necessary quantity to characterize local structural behaviors and directly correlates with structural damage initiation and development that is within local regions. Strain measurement at high spatial resolution (density) locations is thus required to characterize local structural behaviors and detect potential local damage. Traditional contact-type strain gauges are mostly discrete point-wise sensors that can only be placed in a limited number of positions. Distributed optical fiber sensing techniques can measure strains at spatially dense measurement points, but their instrumentation is a time- and labor-intensive process associated with the issue of the fragility of fibers. Noncontact optical measurement techniques, such as a family of interferometry techniques using laser beams (e.g., laser Doppler vibrometers), can provide vibration measurement at high density spatial points without the need to install sensors on the structure. Yet, these measurement devices are active sensing methods that are relatively expensive and vulnerable to ambient motion. Photogrammetry is an alternative noncontact optical measurement method using (passive) white-light imaging of digital video cameras that are relatively low-cost, agile, and provides simultaneous measurements at high spatial density locations where every pixel becomes a measurement point. Among others, digital image correlation can achieve full-field deformation measurements and subsequently estimate the full-field strains. However, it is computationally extensive. This research develops a new efficient approach to estimate the full-field (as many measurement points as the pixel number of the video frame on the structure) dynamic strains at high-spatial (pixel)-resolution/density location points from the digital video measurement of output-only vibrating structures. The developed approach is based on phase-based video motion estimation and modal superposition of structural dynamic response. Moreover, the method is augmented by a high-fidelity finite element model, which is updated with the full-field experimental modal parameters “blindly” identified from the video measurement of the output-only structure. Laboratory experiments are conducted to validate the method on a bench-scale cantilever beam structure. Results demonstrate that the full-field dynamic strain estimated by the developed approach from the video measurement of the output-only vibrating beam match very well those directly measured by the strain gauges (at discrete measurement points). Some factors associated with the effectiveness of the method are experimentally studied and discussed.

47 OTHER INSTRUMENTATION↗

A Comparison of Pre‐Construction and Operational Wake Loss Estimates for Land‐Based Wind Plants

The overall bias between pre‐construction energy yield assessment (EYA) estimates of wind plant energy production and the achieved operational production is improving in the wind industry, but uncertainty remains high for individual wind plants. Wake effects within wind plants are one of the largest sources of energy loss considered in the EYA process, and previous work shows wake loss estimates to be a major source of disagreement among wind energy consultants who perform EYAs. To better understand the accuracy of wake loss predictions, we compare overall operational wake loss estimates based on supervisory control and data acquisition data to pre‐construction estimates provided by six wind energy consultants for five land‐based wind plants in North America. By augmenting existing approaches for quantifying operational wake losses, we estimate wake losses during the period of record for which operational data are available as well as the expected long‐term wake losses, based on historical reanalysis weather data, to which the EYA estimates are compared. To account for power variations at different turbine locations caused by terrain‐induced wind resource heterogeneity, we correct the operational wake loss estimates using predicted freestream wind speed variations from the Wind Systems Engineering Reynolds‐averaged Navier–Stokes (RANS) tool. We identify long‐term corrected operational wake losses between 1.9% and 6.4% for the five plants, with a mean loss of 4%. For the project deemed most acceptable for operational wake loss assessment, which is located in the simplest terrain and isolated from neighboring plants, the mean EYA wake loss estimate is within 0.7 percentage points of the operational value of 6.4%. For most of the remaining plants, results suggest that wake losses are generally overpredicted by 2.6–6.3 percentage points. However, operational wake losses may be underestimated for many of these projects because of spatial wind resource variations not captured by the RANS model, external wake effects that are unaccounted for in the estimation process, and wind plant blockage effects. To better understand factors that contribute to the observed wake losses, we investigate operational wake losses as a function of wind direction and wind speed. As expected, wake losses are generally concentrated near wind directions that are aligned with rows of closely spaced turbines and at below‐rated wind speeds; however, for some projects, the energy produced by the wind plant exceeds the estimated potential energy of the plant without wake interactions for certain wind directions and wind speeds, suggesting inaccurate assumptions in the wake loss estimation method for those plants. Lastly, we compare predicted and operational wake losses for individual wind turbines, finding that even when overall wake losses are predicted accurately, large uncertainty exists at the turbine level.

17 WIND ENERGY↗