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At least 1,513 records · Page 84

Partial Surface Selenization of Cobalt Sulfide Microspheres for Enhancing the Hydrogen Evolution Reaction

Electrocatalysis of water is a scalable and easily available source of the production of hydrogen (H 2 ), the future energy carrier. This drive for clean energy inspired us to develop an inexpensive, readily producible, highly active, and stable catalyst to replace current state of the art platinum catalysts. Building on the promising hydrogen evolution reaction (HER) activity of many pyrites, their structural tuning by different metals and nonmetals has been found to be effective in several instances. We present here one such effort by partial surface selenization of mesoporous cobalt sulfide material, which displayed long-term operational stability (for at least 25 h) besides attaining a current density of 100 mA cm –2 at an overpotential of 160 mV versus the reversible hydrogen electrode (RHE) (in acidic media). A low Tafel slope (of 52 mV dec –1 ) and high exchange current density ( j 0 ) (of 70 μA cm –2 ) make our catalyst better to most existing systems. More importantly, using a variety of analytical techniques, electrochemical measurements, and theoretical calculations, we have analyzed the morphology of the material and rationalized the key to the enhanced intrinsic activity (as compared to the meso-CoS 2 ) per active site. This study is expected to explain similar systems and modify approaches to enhancing the electrochemical activity of metal chalcogenides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Explanation of Dramatic pH-Dependence of Hydrogen Binding on Noble Metal Electrode: Greatly Weakened Water Adsorption at High pH

Hydrogen oxidation reaction (HOR) and hydrogen evolution reaction (HER) are both 2 orders slower in alkaline electrolyte than in acidic electrolyte, but no explanation has been provided. The first step toward understanding this dramatic pH-dependent HOR/HER performance is to explain the pH-dependent hydrogen binding to the electrode, a perplexing behavior observed experimentally. In this work, we carried out Quantum Mechanics Molecular Dynamics (QMMD) with explicit considerations of solvent and applied voltage ( U ) to in situ simulate water/Pt(100) interface in the condition of under-potential adsorption of hydrogen ( H UPD ). We found that as U is made more negative, the electrode tends to repel water, which in turn increases the hydrogen binding. We predicted a 0.13 eV increase in hydrogen binding from pH = 0.2 to pH = 12.8 with a slope of 10 meV/pH, which is close to the experimental observation of 8 to 12 meV/pH. Thus, we conclude that the changes in water adsorption are the major causes of pH-dependent hydrogen binding on a noble metal. Furthermore, the new insight of critical role of surface water in modifying electrochemical reactions provides a guideline in designing HER/HOR catalyst targeting for the alkaline electrolyte.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Model Resolution Sensitivity of the Simulation of North Atlantic Oscillation Teleconnections to Precipitation Extremes

We evaluate a high-resolution (0.25°), four-member ensemble simulation of the global climate (1979–2005) with the U.S. Department of Energy's Energy Exascale Earth System Model v0.3—forced with observed ocean surface temperatures and sea ice extent—for its ability to represent the North Atlantic Oscillation (NAO) teleconnections to winter precipitation extremes over western Europe. As compared to the low-resolution model (1°), it simulates a stronger impact of NAO on daily precipitation extremes over the western slopes of mountain ranges over southwestern Norway, northwestern United Kingdom, and the Western Balkan states. Precipitation extremes and their linear relationship with NAO are quantified using the generalized extreme value distribution. NAO-dependent large-scale (stratiform) precipitation intensity strengthens in the high-resolution model on seasonal time scales and plays a dominant role during simulated daily precipitation extremes. Improvements in the high-resolution model over these varied-topography regions largely appear to be due to finer resolved scales of motion that amplify NAO-dependent seasonal vertical moisture fluxes and enhance stable condensation. However, the high-resolution model simulates a weaker than observed impact of NAO on extratropical cyclone activity and total precipitable water, generally underperforming the low-resolution model These effects possibly offset the impact of enhanced vertical moisture fluxes on NAO-dependent precipitation extremes in the high-resolution model in these regions. Over the southwestern Iberian peninsula, the high-resolution model underperforms the low-resolution model simulating weaker than observed impact of NAO on precipitation extremes. Finally, this appears to be due to the reduction in total precipitable water despite an increase in NAO-dependent extratropical activity there.

54 ENVIRONMENTAL SCIENCES↗

Stellar splashback: the edge of the intracluster light

We examine the outskirts of galaxy clusters in the C-EAGLE simulations to quantify the ‘edges’ of the stellar and dark matter distribution. The radius of the steepest slope in the dark matter, commonly used as a proxy for the splashback radius, is located at $\sim \, r_{200 \rm m}$; the strength and location of this feature depends on the recent mass accretion rate, in good agreement with previous work. Interestingly, the stellar distribution (or intracluster light, ICL) also has a well-defined edge, which is directly related to the splashback radius of the halo. Thus, detecting the edge of the ICL can provide an independent measure of the physical boundary of the halo, and the recent mass accretion rate. We show that these caustics can also be seen in the projected density profiles, but care must be taken to account for the influence of substructures and other non-diffuse material, which can bias and/or weaken the signal of the steepest slope. This is particularly important for the stellar material, which has a higher fraction bound in subhaloes than the dark matter. Finally, we show that the ‘stellar splashback’ feature is located beyond current observational constraints on the ICL, but these large projected distances (>> 1 Mpc) and low surface brightnesses (μ>>32 mag arcsec -2 ) can be reached with upcoming observational facilities such as the Vera C. Rubin Observatory, the Nancy Grace Roman Space Telescope, and Euclid.

79 ASTRONOMY AND ASTROPHYSICS↗

Traction behavior of two traction lubricants

In the analysis of rolling-sliding concentrated contacts, such as gears, bearings and traction drives, the traction characteristics of the lubricant are of prime importance. The elastic shear modulus and limiting shear stress properties of the lubricant dictate the traction/slip characteristics and power loss associated with an EHD contact undergoing slip and/or spin. These properties can be deducted directly from the initial slope m and maximum traction coefficient micron of an experimental traction curve. In this investigation, correlation equations are presented to predict m and micron for two modern traction fluids based on the regression analysis of 334 separate traction disk machine experiments. The effects of contact pressure, temperature, surface velocity, ellipticity ratio are examined. Problems in deducing lubricant shear moduli from disk machine tests are discussed.

Loewenthal, S. H.↗

Elastic model of the traction behavior of two traction lubricants

In the analysis of rolling-sliding concentrated contacts, such as gears, bearings and traction drives, the traction characteristics of the lubricant are of prime importance. The elastic shear modulus and limiting shear stress properties of the lubricant dictate the traction/slip characteristics and power loss associated with an EHD contact undergoing slip and/or spin. These properties can be deducted directly from the initial slope m and maximum traction coefficient micron of an experimental traction curve. In this investigation, correlation equations are presented to predict m and micron for two modern traction fluids based on the regression analysis of 334 separate traction disk machine experiments. The effects of contact pressure, temperature, surface velocity, ellipticity ratio are examined. Problems in deducing lubricant shear moduli from disk machine tests are discussed. Previously announced in STAR as N83-20116

Loewenthal, S. H.↗

Curvature continuity of cubic Bezier curves in the solid modeling aerospace research tools design software

Preliminary results are presented of an investigation into the development of a procedure to provide curvature continuity between biparametric cubic Bezier surface patches in the computer-aided design package known as SMART (Solid Modeling Aerospace Research Tools). This initial effort was aimed at providing the designer with the ability to locally impose curvature continuity at the intersection of two Bezier curves without disrupting either the curvature or slope continuity that may exist at the ends of these curves. Such a method was found if the original Bezier control points are all coplanar. If they are not, then it is possible to find a minimum deviation from exact curvature continuity. In cases where this is not sufficient, then an entire piecewise curve must be made curvature continuous simultaneously. A method was developed based on cubic splines which is very fast. The procedure returns new Bezier control points which have both slope and curvature continuity.

Roach, Robert L.↗

4D PhaseCam(Trade Mark) Capabilities: Modal Analysis and Multiple-Wavelength Mirror Phasing

The PhaseCam is a dynamic phase shifting interferometer system manufactured by 4D Technology Corporation that is capable of very fast data acquisition. This rapid acquisition extends the capability of conventional interferometry to enable measurement in unstable environments, the generation of phase movies of surface shape and to facilitate modal analysis of structures. The PhaseCam hardware and software have been modified for MSFC to include synchronous modal optical measurement and analysis. These modifications will be discussed and data presented. The dynamic range of a phase shifting measurement is limited by local slope and pixel sampling to lambda/4 wave steps. Two-wavelength techniques can increase the effective measurement wavelength from microns to tens of centimeters and permit the phasing of mirror segments. A two wavelength PhaseCam will be discussed and measurement results presented.

Millerd, James E.↗

Polar Dunes Resolved by the Mars Orbiter Laser Altimeter Gridded Topography and Pulse Widths

The Mars Orbiter Laser Altimeter (MOLA) polar data have been refined to the extent that many features poorly imaged by Viking Orbiters are now resolved in densely gridded altimetry. Individual linear polar dunes with spacings of 0.5 km or more can be seen as well as sparsely distributed and partially mantled dunes. The refined altimetry will enable measurements of the extent and possibly volume of the north polar ergs. MOLA pulse widths have been recalibrated using inflight data, and a robust algorithm applied to solve for the surface optical impulse response. It shows the surface root-mean-square (RMS) roughness at the 75-m-diameter MOLA footprint scale, together with a geological map. While the roughness is of vital interest for landing site safety studies, a variety of geomorphological studies may also be performed. Pulse widths corrected for regional slope clearly delineate the extent of the polar dunes. The MOLA PEDR profile data have now been re-released in their entirety (Version L). The final Mission Experiment Gridded Data Records (MEGDR's) are now provided at up to 128 pixels per degree globally. Densities as high as 512 pixels per degree are available in a polar stereographic projection. A large computational effort has been expended in improving the accuracy of the MOLA altimetry themselves, both in improved orbital modeling and in after-the-fact adjustment of tracks to improve their registration at crossovers. The current release adopts the IAU2000 rotation model and cartographic frame recommended by the Mars Cartography Working Group. Adoption of the current standard will allow registration of images and profiles globally with an uncertainty of less than 100 m. The MOLA detector is still operational and is currently collecting radiometric data at 1064 nm. Seasonal images of the reflectivity of the polar caps can be generated with a resolution of about 300 m per pixel.

Gregory A Neumann↗

Ice Sheet Change Detection by Satellite Image Differencing

Differencing of digital satellite image pairs highlights subtle changes in near-identical scenes of Earth surfaces. Using the mathematical relationships relevant to photoclinometry, we examine the effectiveness of this method for the study of localized ice sheet surface topography changes using numerical experiments. We then test these results by differencing images of several regions in West Antarctica, including some where changes have previously been identified in altimeter profiles. The technique works well with coregistered images having low noise, high radiometric sensitivity, and near-identical solar illumination geometry. Clouds and frosts detract from resolving surface features. The ETM(plus) sensor on Landsat-7, ALI sensor on EO-1, and MODIS sensor on the Aqua and Terra satellite platforms all have potential for detecting localized topographic changes such as shifting dunes, surface inflation and deflation features associated with sub-glacial lake fill-drain events, or grounding line changes. Availability and frequency of MODIS images favor this sensor for wide application, and using it, we demonstrate both qualitative identification of changes in topography and quantitative mapping of slope and elevation changes.

Bindschadler, Robert A.↗

A Numerical Study on the Effect of Facesheet-Core Disbonds on the Buckling Load of Curved Honeycomb Sandwich Panels

A numerical study on the effect of facesheet-core disbonds on the post-buckling response of curved honeycomb sandwich panels is presented herein. This work was conducted as part of the development of a damage tolerance approach for the next-generation Space Launch System heavy lift vehicle payload fairing. As such, the study utilized full-scale fairing barrel segments as the structure of interest. The panels were composed of carbon fiber reinforced polymer facesheets and aluminum honeycomb core. The panels were analyzed numerically using the finite element method. Facesheet and core nodes in a predetermined circular region were detached to simulate a disbond induced via low-speed impact between the outer mold line facesheet and honeycomb core. Surface-to-surface contact in the disbonded region was invoked to prevent interpenetration of the facesheet and core elements. The diameter of this disbonded region was varied and the effect of the size of the disbond on the post-buckling response was observed. A significant change in the slope of the edge load-deflection response was used to determine the onset of global buckling and corresponding buckling load.

structural failure↗

Validation of IASI Satellite Ammonia Observations at the Pixel Scale Using In Situ Vertical Profiles

Satellite ammonia (NH 3 ) observations provide unprecedented insights into NH3 emissions, spatiotemporal variabilities and trends, but validation with in situ measurements remains lacking. Here, total columns from the Infrared Atmospheric Sounding Interferometer (IASI) were intercompared to boundary layer NH 3 profiles derived from aircraft- and surface-based measurements primarily in Colorado, USA, in the summer of 2014. IASI-NH 3 version 3 near real-time data set compared well to in situ derived columns (windows ±15 km around centroid, ±1 h around overpass time) with a correlation of 0.58, a slope of 0.78 ± 0.14 and an intercept of 2.1 × 10 15 ±1.5 × 10 15 molecules cm −2 . Agreement degrades at larger spatiotemporal windows, consistent with the short atmospheric lifetime of NH 3 . We also examined IASI version 3R data, which relies on temperature retrievals from the ERA Reanalysis, and a third product generated using aircraft-measured temperature profiles. The overall agreement improves slightly for both cases, and neither is biased within their combined measurement errors. Thus, spatiotemporal averaging of IASI over large windows can be used to reduce retrieval noise. Nonetheless, sampling artifacts of airborne NH 3 instruments result in significant uncertainties of the in situ-derived columns. For example, large validation differences exist between ascent and descent profiles, and the assumptions of the free tropospheric NH 3 profiles used above the aircraft ceiling significantly impact the validation. Because short-lived species like NH 3 largely reside within the boundary layer with complex vertical structures, more comprehensive validation is needed across a wide range of environments. More accurate and widespread in situ NH 3 data sets are therefore required for improved validations of satellite products.

Ammonia↗

Retrieving Particulate Matter Concentrations over the Contiguous United States Using CALIOP Observations

Using twelve years (2007-2018) of NASA Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) near-surface 532 nm aerosol extinction retrievals, multi-year mean and trends of particulate matter (PM) concentrations are derived over the contiguous United States (CONUS). Different from past studies that use column integrated aerosol optical thickness, here only near-surface CALIOP aerosol extinction is used for deriving near-surface PM with aerodynamic diameters less than 2.5 µm (PM2.5) concentrations using an innovative, bulk-mass-modeling-based method. Compared against ground based PM2.5 measurements from the U.S. Environmental Protection Agency (EPA), an encouraging relationship between CALIOP-derived PM2.5 and EPA-observed PM2.5 (Deming slope = 0.89; RMSE = 3.42 µg/m3; mean bias = -1.00 µg/m3) is found using combined daytime/nighttime CALIOP data. Also, comparable trends in PM2.5 concentrations from the EPA and daytime and nighttime CALIOP data are found for most of the eastern CONUS and imply that air quality is generally improving over this region for the study period. Over the western CONUS, a seasonal analysis reveals that PM2.5 trends are positive during the more active wildfire season (June through November) but negative for other months. This study suggests that lidar data show promise in their use for obtaining PM2.5 estimates and provides motivation to further explore aerosol extinction-based PM concentration retrievals in anticipation of future space-based lidar missions.

CALIOP↗

A study of heavy precipitation events in Taiwan during 10-13 August, 1994: mesoscale model simulations

Heavy rainfall occurred over the western side of Taiwan's complex terrain from August 10 to 13, 1994 after Typhoon Doug moved northward from the East China Sea into Taiwan and on towards the Yellow Sea. On August 10, most of the rainfall fell over sloped areas. The heaviest daily rainfall totals were in excess of 200 mm over southwestern as well as central Taiwan. However, not much rainfall occurred over northern Taiwan. The lack of rainfall over northern Taiwan also occurred on August 11, 12 and 13. The larger rainfall amounts shifted westward from the sloped areas on August 10 toward lower terrain on August 11. On August 12 and 13, most of the higher rainfall amounts were found over the coastal area in southwestern Taiwan. Notably, about 300 to 400 mm per day fell over the coastal area in southwest Taiwan on August 12 and 13. The distribution of rainfall amount was different on August 10 and 11 (termed as Case 1) compared to August 12 and 13 (termed as Case 2). The environmental situation and precipitation characteristics are analyzed using EC/TOGA data, ground-based radar data, surface rainfall patterns, surface wind data, and upper air soundings. Chen at al. (2001) also categorized the precipitation pattern into two types, propagating and quasi-stationary. For the propagating type of precipitation, rainrates increased or remained the same as systems went from the plains to mountainous regions. With the quasi-stationary type of precipitation, however, rainrates decreased as precipitation propagated across the plains and into the mountains. The focus of this study is to understand what causes the h1aher amounts of rainfall over Taiwan, and what factors influence where the higher amounts of rainfall will occur, over sloped areas or over coastal areas.

Tao, W.-K.↗

HERSCHEL EXPLOITATION OF LOCAL GALAXY ANDROMEDA (HELGA). III. THE STAR FORMATION LAW IN M31

We present a detailed study of how the star formation rate (SFR) relates to the interstellar medium (ISM) of M31 at {approx}140 pc scales. The SFR is calculated using the far-ultraviolet and 24 {mu}m emission, corrected for the old stellar population in M31. We find a global value for the SFR of 0.25{sup +0.06}{sub -0.04} M{sub sun} yr{sup -1} and compare this with the SFR found using the total far-infrared luminosity. There is general agreement in regions where young stars dominate the dust heating. Atomic hydrogen (H I) and molecular gas (traced by carbon monoxide, CO) or the dust mass is used to trace the total gas in the ISM. We show that the global surface densities of SFR and gas mass place M31 among a set of low-SFR galaxies in the plot of Kennicutt. The relationship between SFR and gas surface density is tested in six radial annuli across M31, assuming a power law relationship with index, N. The star formation (SF) law using total gas traced by H I and CO gives a global index of N = 2.03 {+-} 0.04, with a significant variation with radius; the highest values are observed in the 10 kpc ring. We suggest that this slope is due to H I turning molecular at {Sigma}{sub Gas} {approx} 10 M{sub Sun} pc{sup -2}. When looking at H{sub 2} regions, we measure a higher mean SFR suggesting a better spatial correlation between H{sub 2} and SF. We find N {approx} 0.6 with consistent results throughout the disk-this is at the low end of values found in previous work and argues against a superlinear SF law on small scales.

79 ASTRONOMY AND ASTROPHYSICS↗

Tracing the source of soil organic matter eroded from temperate forest catchments using carbon and nitrogen isotopes

Here, soil erosion continuously redistributes soil and associated soil organic matter (SOM) on the Earth's surface, with important implications for biogeochemical cycling of essential elements and terrestrial carbon sequestration. Despite the importance of soil erosion, surprisingly few studies have evaluated the sources of eroded carbon (C). We used natural abundance levels of the stable and radioactive isotopes of C ( 13 C and 14 C) and stable isotope of nitrogen ( 15 N) to elucidate the origins of SOM eroded from low-order catchments along the western slopes of the Sierra Nevada of California, USA. Our work was conducted in two relatively undisturbed catchments (low elevation = 1800 m, and high elevation = 2300 m) of the Kings River Experimental Watersheds (KREW) in the Sierra National Forest. Sediment captured in basins at the outlet of each gauged watershed were compared to possible source materials, which included: upland surficial organic horizons (i.e., forest floor) and mineral soils (0–0.6 m) from three landform positions (i.e., crest, backslope, and toeslope), stream bank soils (0–0.6 m), and stream-bed materials (0–0.05 m). We found that most of the organic matter (OM) in the captured sediments was composed of O-horizon material that had high C concentrations. Radiocarbon analyses also showed that the captured OM is composed of modern (post-1950) C, with fraction modern values at or above 1.0. Our results suggest that surface (sheet) erosion, as opposed to channeling through established streams and episodic mass wasting events, is likely the largest source of sediment exported out of these minimally disturbed, headwater catchments. The erosional export of sediment with a high concentration of C, especially in the form of relatively undecomposed litter from the O horizon, suggests that a large fraction of the exported C is likely to be decomposed during or after erosion; hence, it is unlikely that soil erosion acts as a significant net sink for atmospheric CO 2 in these low-order, temperate forest catchments.

54 ENVIRONMENTAL SCIENCES↗

Proposed Mars Surveyor Landing Sites in Northern Meridiani Sinus, Southern Elysium Planitia, and Argyre Planitia

Our objective is to propose two landing sites that the Mars Surveyor 2001 Lander and Athena Rover could go to on Mars that should meet the safety requirements of the spacecraft landing system and optimize surface operations (chiefly driven by power and communications requirements). An additional site within Argyre Planitia, initially proposed by Parker to the Mars Surveyor Landing Site program, is also proposed for potential consideration for post-2001 missions to Mars, as it is well outside the current latitude limits for the Athena Rover. All three sites are designed to be situated as close to a diversity of geologic units within a few kilometers of the landing site so that diversity can be placed in a geologic context. This objective is very different from the Mars Pathfinder requirement to land at a site with a maximum chance for containing a diversity of rocks within a few tens of meters of the lander. That requirement was driven by the Sojourner mobility limit of a few tens of meters. It can be argued that the Athena project, with its much larger mobility capability, might actually want to avoid such a site, because placing collected samples in geologic context would be difficult. While it has been argued, both before and after the Mars Pathfinder landing, that the provenance for local blocks may be determined by orbiter spectra, primarily from the MGS TES instrument, our ability to do so has yet to be demonstrated. Indeed, several months after conclusion of the Pathfinder mission, we have yet to reach a consensus on the composition of local materials. Our primary data set for selecting a landing site within the latitude and elevation constraints of the 2001 mission is the Viking Orbiter image archive. The site must be selected to place the landing ellipse so as to avoid obvious hazards, such as steep slopes, large or numerous craters, or abundant large knobs. For this purpose, we chose a resolution limit of better than 50 m/pixel. This necessarily excludes from the present study images from current and future orbiter spacecraft, until such data does become readily available. Within each proposed region, it may be possible to identify additional sites once these data become available. Second, the fine-component thermal inertia data, should be greater than about 5 or 6 cgs Units (10(exp -3) cal/sq cm s(exp -0.5)/K). Low thermal inertias imply dusty environments, which could pose a mobility hazard. Similarly, the albedo of the site should not be particularly high, which would also suggest dusty surfaces. Low albedos are preferred, as they often coincide with low Viking red:violet ratios and indicate less dusty surfaces. Next, the Modeled Block Abundance should also not be too high or too low. Based on the Viking Lander and Mars Pathfinder experiences, percentages of blocks should be on the order of 5-25%. Too many blocks could pose a hazard to the landing and mobility. Too few blocks could also indicate a dusty surface. Primary Landing Site: Northern Meridiani Sinus (Proposed by T. J. Parker and K., S. Edgett) Vital Statistics: (1) Latitude, Longitude: 0-3 N, 350-2 W. *Elevation (Viking): about0.5-1.5 Ian. (2) Viking Orbiter Image coverage: Excellent coverage by 15 - 25 m/pixel images (orbits 709A and 410B). Possible stereo coverage in region where two orbits overlap (probably small parallax angle, as these orbits are not listed in NASA Contractor Report 3501) (3) Albedo: about .18 -.26 (4) Block Abundance: 5-26% (5)Fine-Component Thermal Inertia: 5-9 cgs units This region consists of bright deposits similar to those described by Edgett et al, that also lie within a prominent dark albedo region. These deposits are flat-lying, to such a degree that they ramp against topography rather than draping over it. This led Edgett and Parker to suggest that they may be subaqueous sediments, possibly lacustrine or marine evaporites, laid down sometime from the late Noachian to middle Hesperian (age determination pending crater counts). A contact between this material and elevated, dissected highlands to the south was identified , and is described by Edgett et al. Our desire in proposing this landing site is to sample the edge of this deposit where it has been exposed through etching, presumably eolian deflation (the deposit, though in the highlands, is itself only lightly to moderately cratered). This should enable access to in situ stratigraphy. The actual landing site will be selected where slopes are not expected to be steep, such that the rover itself should be able to traverse them and sample layered materials on the way, either up or down the slope. Perhaps due to uncertainties at this time as to the friability or meter-scale roughness of the deposit, it might make sense to place the landing ellipse on the exhumed highland surface adjacent to the deflated margin of the deposit and plan on driving to the deposit rather than landing on it and driving downslope. This should also enable imaging the margin for evidence of layering should it prove too difficult to climb. A target ellipse on the highland surface should also allow Athena access to ancient Noachian highland materials, particularly if placed near crater ejecta or an inlier of knobby material. Secondary Landing Site: Southern Elysium Planitia (Proposed by T. J. Parker) Vital Statistics: (1) Latitude, Longitude: 1.5-3.5 S, 195-198 W. (2) Elevation (Viking): -1.0 km. (3) Viking Orbiter Image coverage: Excellent coverage by 15 - 25 m/pixel images (orbit 725). Possible stereo coverage between images from beginning and end of orbit that overlap (probably small parallax angle) (4) Albedo: about .27-.28 (5) Block Abundance: 4-7% (6) Fine-Component Thermal Inertia: about 3 cgs units This region consists of eroded knobby material, probably of Noachian age, though much of the crater population has been destroyed, that is onlapped at a sharp contact by an extensive plains unit in southern Elysium Planitia that is Amazonian in age. The plains materials have been attributed to unusually low-viscosity flood lavas from fissures south of the Elysium volcanic rise, or to lacustrine materials associated with a large, Amazonian lake at the source of Marte Vallis. Parker and Schenk presented evidence in support of the latter interpretation, though they attributed the putative shore morphology to an embayment of a northern plains ocean into the southern Elysium region. Detailed examination of the margin of the deposit, showing erosion, not simply burial, of small crater rims and fluidized ejecta blankets, also points to lacustrine or marine sedimentation rather than volcanic plains burial. The plains surface exhibits a "crusty" appearance that many researchers have attributed to pressure ridges in lava flows. In a lacustrine context, they also resemble pressure ridges in desiccated evaporite deposits and salt-rimmed pools (now dry) similar in scale and morphology to spectacular, hundred meter-scale pool rims in alkaline Lake Natron, East African Rift. The eroded highland margin surface adjacent to these plains appears to be fairly smooth, even at 15 m/pixel. Isolated knob inliers are scattered from a few kilometers to several tens of "kilometers apart. Heights of the knobs have not been measured yet but, based on experience with similar features in the Pathfinder landing ellipse, are probably typically on the order of several tens of meters high and smaller, though some of the largest knobs in the region are probably up to a few hundred meters high. Two craters larger than a kilometer in diameter, with fluidized deposits, lie nearby the proposed landing site. Very high-resolution images from MOC should help to determine whether a landing site navigable by the Athena rover could be placed in this region. The space between knobs and craters is large enough to enable placement of a target landing ellipse between them but still provide access to one or more of them and to the margin of the Elysium plains material. Post-2001 Mars Surveyor Landing Site: Argyre Planitia (Proposed by T. J. Parker) Vital Statistics: (1) Latitude, Longitude: 55-56 S, 41-43 W. (2) Elevation (Viking): 1.0 km. (3) Viking Orbiter Image coverage: Excellent coverage by 40 m/pixel images (orbits 567B, 568B, and 569B). Excellent stereo coverage with large parallax angles over the entire landing site region, and much of central and southern Argyre. (4) Albedo: about .23-.24 (5) Block Abundance: No data (6) Fine-Component Thermal Inertia: No data The floors of both the Argyre and Hellas basins contain etched layered materials that are probably thick accumulations of channel or lacustrine sediments. The deposits in Hellas are much more eroded than those in Argyre, and Hellas lacks a channel outlet. Argyre is unique in that Uzboi Vallis flowed out of the basin, requiring overflow of a standing body of water within Argyre. This makes it the largest impact basin on Mars with channels both draining into it and flowing out from it. Hellas' channels may be catastrophic flood channels, whereas Argyre was fed by modest-scale valley networks, though the outlet at Uzboi Vallis was a catastrophic flood Highland craters and basins of this kind should be high-priority landing targets for missions intended to focus on the search for either prebiotic organic materials or even simple fossil microorganisms. Basins with internally-draining valley networks should be preferred over flood channels, as they could have provided the long-term influx of water favorable to the origin of life. (Catastrophic floods are not conducive to fossil preservation, due to their very short durations and high transportation energies). They also afford an opportunity to study the evolution of the planet's climate and volatiles during the period of time between the late Noachian and early Hesperian, when a drastic change from a proposed early warm, wet climate to one more closely resembling the modern environment is thought to have occurred. Large basin

Parker, T. J.↗

Land management effects on wet aggregate stability and carbon content

Land management affects soil structure and many other soil properties and processes. Our objectives were to evaluate soil organic C (SOC), aggregate size distribution, aggregate-associated C, and soil structure as affected by long-term land management and slope. A chronosequence of 38 on-farm sites with low to high (5–18%) slopes was selected to evaluate 5–40 yr of management. The sites were classified as business as usual (BAU) cropland (BAU-Crop), BAU pasture (BAU-Past), newly established conservation reserve program (CRP) areas (CRP-New), and established CRP (CRP-Old). Soil samples were collected from the 0-to-5- and 5-to-15-cm depth increments and processed for soil property measurements including fractionation by wet sieving into five aggregate size classes (>2,000, 1,000–2,000, 500–1,000, 250–500, and 53–250 μm). Within the surface 5 cm, mean weight diameter (MWD) and geometric mean diameter (GMD) were used to characterize soil structural stability. The BAU-Past and CRP-Old sites had 79% more macroaggregates (>2,000, 1,000–2,000, and 500–1,000 μm), 123% higher MWD, 38% higher GMD, and 47% higher SOC than BAU-Crop or CRP-New sites. The 5-to-15-cm depth increment showed a similar but lower magnitude response. Aggregate-associated C was quantified using a constant soil mass that reflected aggregate size distribution to prevent overestimating C content. Lower-slope locations had more SOC, more macroaggregates, more C associated with macroaggregates, and higher GMD and MWD compared with high-slope locations across all management classifications and soil depths. The results support our hypothesis that the high-slop soils may benefits from specific management decisions than the lower-sloping soils as a function of landscape property. We recommend reestablishing grassland on sloping land that is susceptible to excessive soil erosion, although those practices will likely take a long time to restore soil structural stability and SOC content to precultivation levels.

54 ENVIRONMENTAL SCIENCES↗