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At least 1,531 records · Page 85

Ultraviolet absorption lines associated with the Vela supernova remnant

Two stars behind the Vela supernova remnant and two stars offset from the remnant have been observed with the UV spectrometer aboard the Copernicus satellite. Over 200 interstellar atomic and molecular absorption features between 1000 and 1400 A have been identified and measured for radial velocity and equivalent width. In many cases, additional information was obtained by studying the detailed shapes of the recorded profiles. Most of the stars show several absorption components, with clouds of the highest radial velocity appearing in the spectra of stars behind the remnant. For each component, column densities were derived using velocity dispersion parameters which yielded the most self-consistent results. Qualitatively, the gas toward the remnant exhibits a number of unusual properties, when compared with normal interstellar material. First, abnormally high radial velocities were evident. Second, the degree of ionization of some elements suggested the existence of ionizing processes significantly more potent than those found in general regions of space. Finally, an investigation of electron densities shows that much of the gas, especially that at high velocity, must exist in the form of relatively thin sheets or filaments. If cosmic abundances prevail, the column densities of high-velocity excited material suggest that H-alpha emission measures could be as large as 100 sq cm/cu pc.

Jenkins, E. B.↗

Ultraviolet absorption spectrum of chlorine nitrite, ClONO

The near-ultraviolet absorption spectrum of chlorine nitrite (ClONO) has been quantitatively investigated over the wavelength range 230-400 nm at 231 K. An absorption maximum was observed at 290 nm with a cross section of 1.5 by 10 to the -18th power sq cm. The calculated lifetime against photodissociation for ClONO in the atmosphere is 2 to 3 minutes. The large photolysis rate indicates that ClONO does not play a significant role in the stratosphere as a temporary holding tank for chlorine.

Molina, L. T.↗

Electronic absorption spectra of lunar minerals

Techniques for obtaining information on the crystal chemistry of transition-metal ions from measurement of the electronic absorption spectra of lunar minerals are reviewed along with the theory of spectral interpretation. Typical polarized absorption spectra are examined for lunar pyroxenes, pyroxferroite, olivine, and plagioclase feldspars. Oxidation states of Fe, Ti, and Cr in lunar minerals are discussed, and conditions under which they crystallized are considered. It is shown how information on the gross mineralogy and petrology of different regions of the moon's surface may be extracted from remote reflectivity measurements of that surface.

Vaughan, D. J.↗

Laser absorption spectroscopy - Method for monitoring complex trace gas mixtures

A frequency stabilized CO2 laser was used for accurate determinations of the absorption coefficients of various gases in the wavelength region from 9 to 11 microns. The gases investigated were representative of the types of contaminants expected to build up in recycled atmospheres. These absorption coefficients were then used in determining the presence and amount of the gases in prepared mixtures. The effect of interferences on the minimum detectable concentration of the gases was measured. The accuracies of various methods of solution were also evaluated.

Green, B. D.↗

Absorption of CO2-laser radiation in a hypocycloidal-pinch plasma

Absorption of a 50-J pulsed CO2 laser beam in the plasma produced in a hypocycloidal-pinch apparatus was studied. The apparatus consists of three disk electrodes with a 5-cm hole on the axis. The current sheets are snow-plowed toward the center of the hole to produce a plasma with a density greater than 10 to the 18th/cu cm and a temperature near 1 keV which emits soft X rays for 5 microsec. IR detectors measured the laser radiation incident onto, transmitted through, and scattered from the plasma as functions of time. For a period up to 70 microsec from the onset of X-ray emission, neither transmitted nor scattered laser radiation was observed above the detector threshold of 0.3% of the incident flux. This indicates effective absorption of the laser beam (greater than 99%) and that the particle confinement time extends far beyond the energy confinement time of 5 microsec. Thus, the plasma in this apparatus appears much more amenable to laser heating than that in a theta pinch.

Lee, J. H.↗

Absorption of sound in air - High-frequency measurements

The absorption of sound in air at frequencies from 4 to 100 kHz in 1/12 octave intervals, for temperatures from 255.4 K (0 F) to 310.9 K (100 F) in 5.5 K (10 F) intervals, and at 10% relative-humidity increments between 0% and saturation has been measured. The values of free-field absorption have been analyzed to determine the relaxation frequency of oxygen for each of the 92 combinations of temperature and relative humidity studied and the results are compared to an empirical expression. The relaxation frequencies of oxygen have been analyzed to determine the microscopic energy-transfer rates.

Bass, H. E.↗

High resolution absorption cross sections for the A2Pi-X2Pi system of ClO

High-resolution ultraviolet absorption cross-sections for the ClO molecule are obtained, with the aim of facilitating studies of ozone depletion resulting from the injection of chlorofluorocarbons into the atmosphere. The spectroscopic analysis, which involves a frequency-doubled tunable dye laser with a bandwidth of 0.015 A, is described. Studies of the rotational lines of the ClO A 2Pi 3/2-X2Pi 3/2 9-10 band were conducted. Peak cross-sections for the P and R lines of the 9-0 band are found to be 10.0, 9.6, 8.6, 10.6, 10.3, and 9.2 times ten to the negative seventeenth power cm squared, with estimated accuracy of plus or minus 25%. Problems in distinguishing between Cl-35 and Cl-37 absorption are also considered.

Wine, P. H.↗

Measured performance of a 3-ton LiBr absorption water chiller and its effect on cooling system operation

A 3-ton lithium bromide absorption water chiller was tested for a number of conditions involving hot-water input, chilled water, and the cooling water. The primary influences on chiller capacity were the hot water inlet temperature and the cooling water inlet temperature. One combination of these two parameters extended the output to as much as 125% of design capacity, but no combination could lower the capacity to below 60% of design. A cooling system was conceptually designed so that it could provide several modes of operation. Such flexibility is needed for any solar cooling system to be able to accommodate the varying solar energy collection and the varying building demand. It is concluded that a 3-ton absorption water chiller with the kind of performance that was measured can be incorporated into a cooling system such as that proposed, to provide efficient cooling over the specified ranges of operating conditions.

Namkoong, D.↗

The economics of solar powered absorption cooling

Analytic procedure evaluates cost of combining absorption-cycle chiller with solar-energy system in residential or commercial application. Procedure assumes that solar-energy system already exists to heat building and that cooling system must be added. Decision is whether to cool building with conventional vapor-compression-cycle chiller or to use solar-energy system to provide heat input to absorption chiller.

Bartlett, J. C.↗

Atlas of Infrared Absorption Lines

This atlas of infrared absorption line contains absorption line parameters (line strength vs. wavenumber) from 500 to 7000 cm(exp-1) for 15 gases: H2O, CO2, O3, N2O, CO, CH4, O2, SO2, NO, NO2, NH3, HCl, HF, HNO3 and CH3Cl.

Park, J. H.↗

Absorption strength measurement of the nu-1 band of methyl chloride

The absorption strengths of the Q-branch manifolds of the nu-1 band of methyl chloride were measured. The results were used to deduce the band strength, which is 32.1 plus or minus 2.9 per sq cm-atm at 297 K. The P-branch absorptions were investigated to assess the possibility of determining a vibration-rotation factor for the band. This factor is approximately 1.026.

Margolis, J. S.↗

Ultraviolet absorption spectrum of hydrogen peroxide vapor

The ultraviolet absorption cross sections of hydrogen peroxide vapor have been determined over the wavelength range 210 to 350 nm at 296 K. At the longer wavelengths, the gas phase absorptivities are significantly larger than the corresponding values in condensed phase. The atmospheric H2O2 photodissociation rate for overhead sun at the earth's surface is estimated to be about 1.3 x 10 to the -5th/sec.

Molina, L. T.↗

A comparison of neutral hydrogen 21 cm observations with UV and optical absorption-line measurements

Several absorption components detected in visible or UV lines have been identified with emission features in new high-resolution, high signal-to-noise 21 cm observations. Stars for which direct overlap is obtained are HD 28497, lambda Ori, mu Col, HD 50896, rho Leo, HD 93521, and HD 219881. With the use of the inferred H I column densities from 21 cm profiles, rather than the integrated column densities obtained from L-alpha, more reliable densities can be derived from the existence of molecular hydrogen. Hence the cloud thicknesses are better determined; and 21 cm emission maps near these stars can be used to obtain dimensions on the plane of the sky. It is now feasible to derive detailed geometries for isolated clumps of gas which produce visual absorption features.

Giovanelli, R.↗

Ultraviolet absorption cross sections of hydrogen peroxide

Absorption cross-sections of hydrogen peroxide vapor and of neutral aqueous solutions of hydrogen peroxide were measured in the wavelength range from 195 to 350 nm at 296 K. The spectrophotometric procedure is described, and the reported cross-sections are compared with values obtained by other researchers. Photodissociation coefficients of atmospheric H2O2 were calculated for direct absorption of unscattered solar radiation, and the vertical distributions of these coefficients are shown for various solar zenith angles.

Lin, C. L.↗

On the dissociation of nitrogen by electron impact and by EUV photo-absorption

The dissociation of N2 by electron impact and by absorption of EUV photons was studied experimentally. It was shown that most of the N2 molecules excited to singlet states in the 12.5-14.86 eV range are depopulated by predissociation and not by the emission of EUV photons and that this is the principal mechanism by which N2 is dissociated by solar EUV absorption and by electron impact. The experiments provide a physical explanation for the near absence of N2 band radiation in airglow and auroral EUV spectra, and rule out the excitation of EUV radiation as a major factor in the overall energy economy of an auroral substorm.

Zipf, E. C.↗

Differential laser absorption monitoring of the atmosphere

In the airborne detection system of atmospheric constituents and pollutants described, double-ended differential absorption measurement is accomplished by rapidly current tuning the wavelength of a PbSSe diode laser across a single line of the species under consideration. As the laser wavelength sweeps periodically across the absorption line, the laser beam is amplitude modulated and is then synchronously detected. With this technique, a minimum detectable differential transmission of 0.02 percent is obtained for a 1-sec integration time.

Rubin, B.↗

Absorption strength of the perturbed nu-4 band of CH3Cl

The nu-4 band of CH3Cl interacts strongly with the 3 nu-6 band. Levels of both bands are mixed and both appear strongly in absorption. The strengths of both bands have been measured taking into account the mixing of the levels. The absorption strengths of both bands can be related to a single parameter, namely, the strength of the unperturbed nu-4 band. This was calculated to be 41.8 per sq cm/atm at 297 K.

Margolis, J. S.↗

Low absorptance porcelain-on-aluminum coating

Porcelain thermal-control coating for aluminum sheet and foil has solar absorptance of 0.22. Specially formulated coating absorptance is highly stable, changing only 0.03 after 1,000 hours of exposure to simulated sunlight and can be applied by standard commercial methods.

Leggett, H.↗