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DOE OSTI2017

Using Dynamic Line Rating to Enhance Flexibility of Wind-involved Hybrid Energy System

By providing real-time overhead line ampacity, Dynamic Line Rating (DLR) is a potential technique to solve the transmission congestion issues that are threatening NPPs, especially when a nuclear plant is coupled with wind turbine generators. First, DLR can utilize the concurrent cooling effect and dynamic monitors on transmission lines to increase the line carry capacity and reduce congestion. Second, more frequent interactions between transmission lines and operators can increase the flexibility and create a more dynamic and responsive hybrid system. In general, DLR can increase the flexibility and optimize the efficiency of a hybrid system utilizing wind energy. DLR helps meet continuously fluctuating electricity demands with real-time observation of transmission lines for more accurate estimation of line carry capacity. For the fuel energy, DLR can contribute greatly in saving fuels and reducing carbon emission by providing timely information for adjusting generation levels. For HES's including NPPs, transmission congestion could be more serious and needs attention. Therefore, by providing additional transmission capacity, DLR can contribute to alleviate the congestion and congestion pricing impact that is threatening the current NPPs and prevent potential congestion that may constrain the operation of future hybrid system involved with a nuclear plant. However, either a fuel plant or nuclear plant is better coupled with a wind turbine to take advantage of the concurrent cooling effect and dynamic monitoring. The research team at Idaho National Laboratory, currently focused on the benefit of DLR technology to assist wind generation, is now exploring the feasibility of implementing the same technology into such HES and NPP. Future work will focus on the analysis of technique feasibility, challenges and benefit-cost analysis of integrating DLR into HES. Detailed studies are anticipated to evaluate the benefits of DLR on HES and NPP with transmission constraints. This paper explores a potential utilization of DLR in hybrid energy systems, especially those involving traditional fossil fuels or nuclear power coupled with wind energy. The goal is to increase the efficiency and flexibility of these types of hybrid systems in order to provide more secure, reliable and low-carbon energy.

17 WIND ENERGY↗
DOE OSTI2017

An Evaluation of Energy Storage Options for Nuclear Power

The dynamics of energy generation, delivery, and consumption in the United States continue to change as new energy sources come online and consumers purchase more energy-intensive devices. The percentage of electricity generation from variable renewable energy sources like wind and solar power has grown year after year. Meanwhile, the evolution of electric vehicles, smart devices, and consumer appliances is changing the way that electricity is used. As a result of these trends, nuclear power plants (NPPs) are being asked to operate more flexibly. Newly constructed, advanced nuclear power plants (A-NPPs) will likely need to adapt their business models with these market shifts in mind. In the future, A-NPPs might operate in an electricity system that values flexibility (e.g. fast ramping) more than stability (e.g. baseload supply). The current fleet of NPPs is struggling to remain economically viable in competitive markets that favor low natural gas prices and renewable energy sources with low marginal costs. Rising construction costs and ambiguous national policies have only added to the challenges facing plant operators. The industry as a whole is in decline, with 19 reactors in the process of being decommissioned and 5 of these plants retiring in the past decade. However, NPPs also provide several performance and environmental benefits by maintaining a high capacity factor and generating almost zero greenhouse gas (GHG) emissions over the life cycle of the plant. As more areas of energy consumption in the United States are electrified, NPPs could potentially replace coal and natural gas as a source of heat and power to help decarbonize the U.S. energy mix. Improving the flexibility of newly constructed A-NPPs to increase revenue through market hedging and reduce costs via stable operation was explored in this analysis. The increasing penetration of variable energy resources could contribute to the uncertainty of electricity demand, which could in turn increase the need for dispatchable electricity generating units. This role is currently filled by inexpensive natural gas combined cycle (NGCC) plants, whereas coal and NPPs have traditionally been called upon to provide baseload power by maintaining a constant power output. As wholesale electricity prices continue to fall due to low natural gas prices and federally subsidized renewable energy, this business model has begun to fail, resulting in incidences of NPPs selling electricity at a loss. Since it has not been economically favorable for NPPs to operate flexibly in this situation in the past, due to their low variable costs compared to fossil fuel power plants, NPPs in the United States were not built with this purpose in mind. Therefore, legacy NPPs have had difficulty adapting to these shifting dynamics due to regulatory and technical constraints, coupled with a lack of meaningful experience. NPPs in France have operated in this manner for years, due to a much higher percentage of baseload generators and a lower percentage of fast-ramping NGCC plants. The integration of energy storage technologies (ESTs) alongside newly constructed A-NPPs will be investigated in this analysis as an alternative method for helping NPPs resolve the economic challenges they currently face. Although the deregulation of energy markets in the United States is responsible for much of the increased competition from natural gas and renewable energy that has negatively impacted NPPs, this process has also led to the creation of ancillary service markets. ESTs can provide many of these services, so an integrated energy storage system could supplement both the reliability of the electricity grid and the economic performance of a NPP by bidding into these markets. However, many technical, financial, and regulatory barriers still prevent ESTs from operating profitably in this space. The purpose of this body of work is to compile a transparent database of metrics for available ESTs and identify barriers to widespread deployment. An analytical selection methodology was also developed to identify favorable technologies for integration with specific NPPs based on information supplied by an interested developer. These tools could help reduce the perceived risk surrounding investment in energy storage systems, which could help both NPPs in need of economic assistance and ESTs in need of further research and development.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2024

Size Up or Size Down? National Analysis of Heat Pump Sizing and Impacts

Electrification of on-site fossil fuel combustion in buildings is recognized as a key component of achieving global greenhouse gas emissions targets. Air-source heat pumps are an efficient approach for space heating electrification. However, a major barrier to heat pump adoption is the high installation cost relative to furnaces and air conditioners. Because the installation cost of heat pumps - especially cold climate models - is dependent on their size, it is important to understand the distribution of heat pump sizes using different sizing methods and factors that impact heat pump sizing. In this study, we use sub-hourly physics simulations of 550,000 statistically representative dwelling units to analyze the distribution of heat pump size in the U.S. for three different efficiency levels of heat pumps, with and without building insulation and air sealing upgrades. We will present results from the national analysis of different factors affecting heat pump sizing along with the impact of sizing decisions on upgrade costs and operating costs.

electrification↗
DOE OSTI2010

ADVANCED CERAMIC MATERIALS FOR NEXT-GENERATION NUCLEAR APPLICATIONS

Rising global energy demands coupled with increased environmental concerns point to one solution; they must reduce their dependence on fossil fuels that emit greenhouse gases. As the global community faces the challenge of maintaining sovereign nation security, reducing greenhouse gases, and addressing climate change nuclear power will play a significant and likely growing role. In the US, nuclear energy already provides approximately one-fifth of the electricity used to power factories, offices, homes, and schools with 104 operating nuclear power plants, located at 65 sites in 31 states. Additionally, 19 utilities have applied to the US Nuclear Regulatory Commission (NRC) for construction and operating licenses for 26 new reactors at 17 sites. This planned growth of nuclear power is occurring worldwide and has been termed the 'nuclear renaissance.' As major industrial nations craft their energy future, there are several important factors that must be considered about nuclear energy: (1) it has been proven over the last 40 years to be safe, reliable and affordable (good for Economic Security); (2) its technology and fuel can be domestically produced or obtained from allied nations (good for Energy Security); and (3) it is nearly free of greenhouse gas emissions (good for Environmental Security). Already an important part of worldwide energy security via electricity generation, nuclear energy can also potentially play an important role in industrial processes and supporting the nation's transportation sector. Coal-to-liquid processes, the generation of hydrogen and supporting the growing potential for a greatly increased electric transportation system (i.e. cars and trains) mean that nuclear energy could see dramatic growth in the near future as we seek to meet our growing demand for energy in cleaner, more secure ways. In order to address some of the prominent issues associated with nuclear power generation (i.e., high capital costs, waste management, and proliferation), the worldwide community is working to develop and deploy new nuclear energy systems and advanced fuel cycles. These new nuclear systems address the key challenges and include: (1) extracting the full energy value of the nuclear fuel; (2) creating waste solutions with improved long term safety; (3) minimizing the potential for the misuse of the technology and materials for weapons; (4) continually improving the safety of nuclear energy systems; and (5) keeping the cost of energy affordable.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2014

U.S. emissions of HFC-134a derived for 2008-2012 from an extensive flask-air sampling network: US emissions of HFC-134a

U.S. national and regional emissions of HFC-134a are derived for 2008-2012 based on atmospheric observations from ground and aircraft sites across the U.S. and a newly developed regional inverse model. Synthetic data experiments were first conducted to optimize the model assimilation design and to assess model-data mismatch errors and prior flux error covariances computed using a maximumlikelihood estimation technique. The synthetic data experiments also tested the sensitivity of derived national and regional emissions to a range of assumed prior emissions, with the goal of designing a system that was minimally reliant on the prior. We then explored the influence of additional sources of error in inversions with actual observations, such as those associated with background mole fractions and transport uncertainties. Estimated emissions of HFC-134a range from 52 to 61 Gg yr -1 for the contiguous U.S. during 2008-2012 for inversions using air transport from Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model driven by the 12km resolution meteorogical data from North American Mesoscale Forecast System (NAM12) and all tested combinations of prior emissions and background mole fractions. Estimated emissions for 2008-2010 were 20% lower when specifying alternative transport from Stochastic Time-Inverted Lagrangian Transport (STILT) model driven by the Weather Research and Forecasting (WRF) meteorology. Our estimates (for HYSPLIT-NAM12) are consistent with annual emissions reported by U.S. Environmental Protection Agency for the full study interval. The results suggest a 10-20% drop in U.S. national HFC-134a emission in 2009 coincident with a reduction in transportation-related fossil fuel CO 2 emissions, perhaps related to the economic recession. All inversions show seasonal variation in national HFC-134a emissions in all years, with summer emissions greater than winter emissions by 20-50%.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

The response of ENSO flavors to mid‐Holocene climate: Implications for proxy interpretation

Abstract The response of El Niño–Southern Oscillation (ENSO) to mid‐Holocene boundary conditions remains an open question: paleoclimate proxies and climate model simulations do not agree in the magnitude of the reduction of ENSO variability, while recent proxy evidence from fossil corals from the central Pacific show that the reduction in mid‐Holocene ENSO variability compared to the end of the twentieth century is not different from the reduction during other Holocene time intervals. This is inconsistent with the interpretation of lake and ocean sediment records from the eastern Pacific, which show a significant reduction compared to all other Holocene periods. In order to reconcile the seemingly conflicting proxy evidence from the eastern and central Pacific, we hypothesize that ENSO remained active during the mid‐Holocene; however, there was a change in the spatial pattern of the sea surface temperature anomalies, also known as ENSO flavors. Using National Center for Atmospheric Research's Community Climate System Model version 4 forced with mid‐Holocene orbital conditions, we find that the frequency of occurrence of the strongest eastern Pacific (EP) events decreases in the mid‐Holocene and their variance is reduced by ∼30%, while the frequency of central Pacific (CP) events slightly increases and their variance does not change. We also find a shift in the seasonality of EP events, but not in that of CP events. Lastly, mid‐Holocene EP events develop more slowly and decay faster. The differential response of ENSO flavors to mid‐Holocene forcing is remotely forced by the West Pacific, where a weakening of the trade winds in early boreal spring in the mid‐Holocene initiates an anomalous downwelling annual Kelvin wave, which reaches the eastern Pacific during the ENSO development season, weakens the upper ocean stratification, and results in reduced ENSO upwelling feedback. The simulated reduction in the EP flavor versus the CP flavor in the mid‐Holocene is consistent with proxy evidence: The teleconnection patterns of the two flavors with temperature, precipitation, and salinity are distinct, and proxies from different regions of the Pacific might be recording variability associated with only one of the flavors, or some combination of their relative effects.

Karamperidou, Christina↗
DOE OSTI2016

Uncertainty in gridded CO 2 emissions estimates

We are interested in the spatial distribution of fossil-fuel-related emissions of CO 2 for both geochemical and geopolitical reasons, but it is important to understand the uncertainty that exists in spatially explicit emissions estimates. Working from one of the widely used gridded data sets of CO 2 emissions, we examine the elements of uncertainty, focusing on gridded data for the United States at the scale of 1° latitude by 1° longitude. Uncertainty is introduced in the magnitude of total United States emissions, the magnitude and location of large point sources, the magnitude and distribution of non-point sources, and from the use of proxy data to characterize emissions. For the United States, we develop estimates of the contribution of each component of uncertainty. At 1° resolution, in most grid cells, the largest contribution to uncertainty comes from how well the distribution of the proxy (in this case population density) represents the distribution of emissions. In other grid cells, the magnitude and location of large point sources make the major contribution to uncertainty. Uncertainty in population density can be important where a large gradient in population density occurs near a grid cell boundary. Uncertainty is strongly scale-dependent with uncertainty increasing as grid size decreases. In conclusion, uncertainty for our data set with 1° grid cells for the United States is typically on the order of ±150%, but this is perhaps not excessive in a data set where emissions per grid cell vary over 8 orders of magnitude.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Increased influence of nitrogen limitation on CO 2 emissions from future land use and land use change

Abstract In the latest projections of future greenhouse gas emissions for the Intergovernmental Panel on Climate Change (IPCC), few Earth System Models included the effect of nitrogen limitation, a key process limiting forest regrowth. Few included forest management (wood harvest). We estimate the impacts of nitrogen limitation on the CO 2 emissions from land use and land use change (LULUC), including wood harvest, for the period 1900–2100. We use a land surface model that includes a fully coupled carbon and nitrogen cycle and accounts for forest regrowth processes following agricultural abandonment and wood harvest. Future projections are based on the four Representation Concentration Pathways used in the IPCC Fifth Assessment Report, and we account for uncertainty in future climate for each scenario based on ensembles of climate model outputs. Results show that excluding nitrogen limitation will underestimate global LULUC emissions by 34–52 PgC (20–30%) during the 20th century (range across three different historical LULUC reconstructions) and by 128–187 PgC (90–150%) during the 21st century (range across the four IPCC scenarios). The full range for estimated LULUC emissions during the 21st century including climate model uncertainty is 91 to 227 PgC (with nitrogen limitation included). The underestimation increases with time because (1) projected annual wood harvest rates from forests summed over the 21st century are 380–1080% higher compared to those of the 20th century, resulting in more regrowing secondary forests; (2) nitrogen limitation reduces the CO 2 fertilization effect on net primary production of regrowing secondary forests following wood harvest and agricultural abandonment; and (3) nitrogen limitation effect is aggravated by the gradual loss of soil nitrogen from LULUC disturbance. Our study implies that (1) nitrogen limitation of CO 2 uptake is substantial and sensitive to nitrogen inputs; (2) if LULUC emissions are larger than previously estimated in studies without nitrogen limitation, then meeting the same climate mitigation target would require an equivalent additional reduction of fossil fuel emissions; (3) the effectiveness of land‐based mitigation strategies will critically depend on the interactions between nutrient limitations and secondary forests resulting from LULUC; and (4) it is important for terrestrial biosphere models to consider nitrogen constraint in estimates of the strength of future land carbon uptake.

Meiyappan, Prasanth↗
DOE OSTI2016

Measurements and modeling of contemporary radiocarbon in the stratosphere

Measurements of the 14 C content of carbon dioxide in air collected by high-altitude balloon flights in 2003–2005 reveal the contemporary radiocarbon distribution in the northern midlatitude stratosphere, four decades after the Limited Test Ban Treaty restricted atmospheric testing of nuclear weapons. Comparisons with results from a 3-D chemical-transport model show that the 14 CO 2 distribution is now largely governed by the altitude/latitude dependence of the natural cosmogenic production rate, stratospheric transport, and propagation into the stratosphere of the decreasing radiocarbon trend in tropospheric CO 2 due to fossil fuel combustion. From the observed correlation of 14 CO 2 with N 2 O mixing ratios, an annual global mean net flux of 14 CO 2 to the troposphere of 1.6(±0.4) × 10 17 ‰ mol CO 2 yr –1 and a global production rate of 2.2(±0.6) × 10 26 atoms 14 C yr –1 are empirically derived. Furthermore, the results also indicate that contemporary 14 CO 2 observations provide highly sensitive diagnostics for stratospheric transport and residence times in models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

A space-based, high-resolution view of notable changes in urban NO x pollution around the world (2005-2014)

Nitrogen oxides (NO x = NO + NO 2 ) are produced during combustion processes and, thus may serve as a proxy for fossil fuel-based energy usage and coemitted greenhouse gases and other pollutants. We use high-resolution nitrogen dioxide (NO 2 ) data from the Ozone Monitoring Instrument (OMI) to analyze changes in urban NO 2 levels around the world from 2005 to 2014, finding complex heterogeneity in the changes. We discuss several potential factors that seem to determine these NO x changes. First, environmental regulations resulted in large decreases. The only large increases in the United States may be associated with three areas of intensive energy activity. Second, elevated NO 2 levels were observed over many Asian, tropical, and subtropical cities that experienced rapid economic growth. Two of the largest increases occurred over recently expanded petrochemical complexes in Jamnagar (India) and Daesan (Korea). Third, pollution transport from China possibly influenced the Republic of Korea and Japan, diminishing the impact of local pollution controls. However, in China, there were large decreases over Beijing, Shanghai, and the Pearl River Delta, which were likely associated with local emission control efforts. Fourth, civil unrest and its effect on energy usage may have resulted in lower NO 2 levels in Libya, Iraq, and Syria. Fifth, spatial heterogeneity within several megacities may reflect mixed efforts to cope with air quality degradation. We also show the potential of high-resolution data for identifying NO x emission sources in regions with a complex mix of sources. Lastly, intensive monitoring of the world's tropical/subtropical megacities will remain a priority, as their populations and emissions of pollutants and greenhouse gases are expected to increase significantly.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2016

A three-dimensional sectional representation of aerosol mixing state for simulating optical properties and cloud condensation nuclei

Light absorption by black carbon (BC) particles emitted from fossil fuel combustion depends on the how thickly they are coated with non-refractory species such as ammonium, sulfate, nitrate, organics, and water. The cloud condensation nuclei (CCN) activation property of a particle depends on its dry size and the hygroscopicities of all the individual species mixed together. It is therefore necessary to represent both size and mixing state of aerosols to reliably predict their climate-relevant properties in atmospheric models. Here we describe and evaluate a novel sectional framework in the Model for Simulating Aerosol Interactions and Chemistry, referred to as MOSAIC-mix, that represents the mixing state by resolving aerosol dry size (D dry ), BC dry mass fraction (w BC ), and hygroscopicity (κ). Using ten idealized urban plume scenarios in which different types of aerosols evolve over 24 hours under a range of atmospherically relevant environmental conditions, we examine errors in CCN concentrations and optical properties with respect to a more explicit aerosol mixing state representation. We find that only a small number of w BC and κ bins are needed to achieve significant reductions in the errors, and propose a configuration consisting of 24 D dry bins, 2 w BC bins, and 2 κ bins that gives 24-hour average errors of about 5% or less in CCN concentrations and optical properties, 3-4 times lower than those from size-only-resolved simulations. Here, these results show that MOSAIC-mix is suitable for use in regional and global models to examine the effects of evolving aerosol mixing states on aerosol-radiation-cloud feedbacks.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Bayesian-information-gap decision theory with an application to CO 2 sequestration

Decisions related to subsurface engineering problems such as groundwater management, fossil fuel production, and geologic carbon sequestration are frequently challenging because of an overabundance of uncertainties (related to conceptualizations, parameters, observations, etc.). Because of the importance of these problems to agriculture, energy, and the climate (respectively), good decisions that are scientifically defensible must be made despite the uncertainties. We describe a general approach to making decisions for challenging problems such as these in the presence of severe uncertainties that combines probabilistic and non-probabilistic methods. The approach uses Bayesian sampling to assess parametric uncertainty and Information-Gap Decision Theory (IGDT) to address model inadequacy. The combined approach also resolves an issue that frequently arises when applying Bayesian methods to real-world engineering problems related to the enumeration of possible outcomes. In the case of zero non-probabilistic uncertainty, the method reduces to a Bayesian method. Lastly, to illustrate the approach, we apply it to a site-selection decision for geologic CO 2 sequestration.

58 GEOSCIENCES↗
DOE OSTI2017

Geoengineering, marine microalgae, and climate stabilization in the 21st century

Abstract Society has set ambitious targets for stabilizing mean global temperature. To attain these targets, it will have to reduce CO 2 emissions to near zero by mid‐century and subsequently remove CO 2 from the atmosphere during the latter half of the century. There is a recognized need to develop technologies for CO 2 removal; however, attempts to develop direct air‐capture systems have faced both energetic and financial constraints. Recently, BioEnergy with Carbon Capture and Storage ( BECCS ) has emerged as a leading candidate for removing CO 2 from the atmosphere. However, BECCS can have negative consequences on land, nutrient, and water use as well as biodiversity and food production. Here, we describe an alternative approach based on the large‐scale industrial production of marine microalgae. When cultivated with proper attention to power, carbon, and nutrient sources, microalgae can be processed to produce a variety of biopetroleum products, including carbon‐neutral biofuels for the transportation sector and long‐lived, potentially carbon‐negative construction materials for the built environment. In addition to these direct roles in mitigating and potentially reversing the effects of fossil CO 2 emissions, microalgae can also play an important indirect role. As microalgae exhibit much higher primary production rates than terrestrial plants, they require much less land area to produce an equivalent amount of bioenergy and/or food. On a global scale, the avoided emissions resulting from displacement of conventional agriculture may exceed the benefits of microalgae biofuels in achieving the climate stabilization goals.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

The Wintertime Covariation of CO 2 and Criteria Pollutants in an Urban Valley of the Western United States

Numerous mountain valleys experience wintertime particulate pollution events, when persistent cold air pools (PCAPs) develop and inhibit atmospheric mixing, leading to the accumulation of pollutants. Here we examine the relationships between trace gases and criteria pollutants during winter in Utah’s Salt Lake Valley, in an effort to better understand the roles of transport versus chemical processes during differing meteorological conditions as well as insights into how targeted reductions in greenhouse gases will impact local air quality in varying meteorological conditions. CO 2 is a chemically inert gas that is coemitted during fossil fuel combustion with pollutants. Many of these coemitted pollutants are precursors that react chemically to form secondary particulate matter. Thus, CO 2 can serve as a stable tracer and potentially help distinguish transport versus chemical influences on pollutants. During the winter of 2015–2016, we isolated enhancements in CO 2 over baseline levels due to urban emissions (“CO 2ex ”). CO 2ex was paired with similar excesses in other pollutant concentrations. These relationships were examined during different wintertime conditions and stages of pollution episodes: (a) Non-PCAP, (b) beginning, and (c) latter stages of an episode. We found that CO 2ex is a good indicator of the presence of gaseous criteria pollutants and a reasonable indicator of PM2.5. Additionally, the relationships between CO 2ex and criteria pollutants differ during different phases of PCAP events which provide insight into meteorological and transport processes. Lastly, we found a slight overestimation of CO:CO 2 emission ratios and a considerable overestimation of NO x :CO 2 by existing inventories for the Salt Lake Valley.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Electric Vehicles and the Electric Grid

In response to the need for the decarbonization of the transport sector and to reduce the reliance on fossil fuels, it is expected that large fleets of plug-in electric vehicles (PEVs) will constitute an important share of the electricity demand in the not so distant future. These devices can, and would behave as any regular demand if they are allowed to charge as soon as they are connected to the electric grid. If such charging process is allowed, then several adverse impacts on the power grids such as increased system-wide peak demand, and early reinforcements of the distribution, transmission and/or generation systems would be required. However, as opposed to conventional demands, these new devices are equipped with a battery that enables them deferring their needs for electric energy in time. If the pliant nature of this demand is exploited in such a way that the charging of these devices takes place when it is more convenient for the power system, then not only would the adverse impacts to the system would be avoided, but also, a new stream of services could be offered to the electric power grid in the form of demand response, power injections in V2G and regulating reserves. This article discusses the consequences of integrating significant volumes of PEVs into power systems, in both, uncontrolled and controlled manners.

Ortega Vazquez, Miguel A.↗
DOE OSTI2018

Role of Interfaces at Nano-Architectured Photocatalysts for Hydrogen Production from Water Splitting

Hydrogen has been nominated as an ideal energy carrier to replace the heavily engaged fossil fuels. Photocatalytic hydrogen production from the splitting of water is the most energy effective and environmentally preservative strategy. This chapter summarizes the basic principles of the photocatalytic hydrogen evolution reaction (HER) from the splitting of water with focus on the role of interfaces in nanostructured photocatalysts. We review the historical development of photocatalytic water splitting systems consisting of various types of heterojunctions that benefit the photogenerated charge carrier separation during photocatalytic processes. These “interfaces” are generally found in metal–semiconductor and semiconductor–semiconductor composite catalysts built upon nano-architectures made possible with recent advances in nanomaterial synthesis. The mechanisms are also discussed for the enhanced photocatalytic HER yield over the various interfaces in the composite photocatalysts.

Peng, Rui↗
DOE OSTI2017

Effect of Laser Shock Peening on the Microstructures and Properties of Oxide-Dispersion-Strengthened Austenitic Steels

Oxide-dispersion-strengthened (ODS) austenitic steels are promising materials for next-generation fossil and nuclear energy systems. In this study, laser shock peening (LSP) has been applied to ODS 304 austenitic steels, during which a high density of dislocations, stacking faults, and deformation twins are generated in the near surface of the material due to the interaction of laser-driven shock waves and the austenitic steel matrix. The dispersion particles impede the propagation of dislocations. The compressive residual stress generated by LSP increases with successive LSP scans and decreases along the depth, with a maximum value of -369MPa. The hardness on the surface can be improved by 12% using LSP. In situ transmission electron microscopy (TEM) irradiation studies reveal that dislocations and incoherent twin boundaries induced by LSP serve as effective sinks to annihilate irradiation defects. Furthermore, these findings suggest that LSP can improve the mechanical properties and irradiation resistance of ODS austenitic steels in nuclear reactor environments.

36 MATERIALS SCIENCE↗