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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,531 records · Page 85
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Oxidation state and coordination environment of Pb in U-bearing minerals

This study examines the oxidation and coordination of lead (Pb) in the uranium (U) minerals uraninite (UO 2 ), coffinite (USiO 4 ), and brannerite (UTi 2 O 6 ), and minerals that have U as a minor constituent, zircon (ZrSiO 4 ) and titanite (CaTiSiO 5 ). The characterization of Pb was conducted through a combination of micro-synchrotron X-ray fluorescence mapping (µSXRF) and micro-X-ray absorption spectroscopy (µXAS), collected at the Pb L II and L III edge on characterized grains (electron microscopy and X-ray diffraction) from a range of geological settings and ages. For all minerals considered in this study, Pb L II and L III X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) data indicate that Pb exists as Pb 2+ . In the case of uraninite, DFT structure optimization calculations suggest that the substitution of Pb 2+ for U 4+ is facilitated by the stereochemically active electron lone pair indicative of Pb 2+ , which effectively takes the place of an oxygen vacancy (coupled substitution Pb 2+ + = U 4+ + O 2- ). In detail, however, the EXAFS and XANES data, supported by first principle calculations of the XANES associated with Pb 2+ replacing U 4+ in the crystal lattice of uraninite, indicate that Pb 2+ is present in a less distorted coordination than suggested by DFT, which may reflect a yet to be characterized link between interstitial oxygen defects and Pb 2+ incorporation, rather than a simple oxygen vacancy. For coffinite, the XANES data demonstrate that Pb exists mainly as Pb 2+ in the form of galena, indicating limited stability of the isomorphous substitution in coffinite. In contrast, Pb is homogeneously distributed in the metamict mineral brannerite, which displays a distinct XANES spectrum suggestive of Pb 2+ bonded to oxygens in a highly distorted coordination environment. Pb L II XANES indicate that radiogenic Pb exists predominantly as Pb 2+ within the crystal lattice of zircon and as distinct mineral PbO nano-scale inclusions or domains. Additionally, Pb L II XANES measurements also indicate that Pb 2+ exists within titanite although the coordination environment is unclear. Overall, these data suggest that the previous indications of the presence of Pb 4+ in radioactive minerals need to be reconsidered. The nature of radiogenic Pb 2+ incorporation in U-bearing minerals controls the mobilization of Pb in hydrothermal fluids and the utility of a mineral as a geochronometer. The Pb valence and coordination data presented in this study provide fundamental constraints imperative for our understanding of the controls governing the mobilization of radiogenic Pb during water-rock interaction and metamorphism.

58 GEOSCIENCES↗
DOE OSTI2026

PIXE – State of the Art, Systems, Challenges

Particle-induced X-ray emission (PIXE) is an analytical technique for elemental analysis in which a charged-particle beam (most commonly protons, but also alpha particles or heavier ions) ionizes inner-shell electrons in target atoms. When these vacancies are filled by outer-shell electrons, the atom emits characteristic X-rays (e.g., Kα, Kβ, L-series) whose energies are unique to each element. Measuring the X-ray spectrum therefore enables identification of the elements present and, with appropriate calibration and modeling, their concentration. PIXE provides rapid, simultaneous, quantitative multi-element detection with trace-level sensitivity for many mid- to high-Z elements, often with minimal sample preparation. It is widely used across materials science (thin films, alloys, corrosion), geology (mineral chemistry, provenance) and environmental monitoring (aerosols, particulates, soils); semiconductor contamination analysis (wafer surface/trace metals), cultural heritage (pigments, inks, archaeological artifacts) and forensics (gunshot residue, glass/pain), and biological/medical studies (tissue/biomaterial trace-element mapping).

47 OTHER INSTRUMENTATION↗
NASA NTRS1973

Mineral resources, geologic structure, and landform surveys

The use of ERTS-1 imagery for mineral resources, geologic structure, and landform surveys is discussed. Four categories of ERTS imagery application are defined and explained. The types of information obtained by the various multispectral band scanners are analyzed. Samples of land use maps and tectoning and metallogenic models are developed. It is stated that the most striking features visible on ERTS imagery are regional lineaments, or linear patterns in the topography, which reflect major fracture zones extending upward from the basement of the earth.

Lattman, L. H.↗
NASA NTRS1974

A demonstration of ERTS-1 analog and digital techniques applied to strip mining in Maryland and West Virginia

The largest contour strip mining operations in western Maryland and West Virginia are located within the Georges Creek and the Upper Potomac Basins. These two coal basins lie within the Georges Creek (Wellersburg) syncline. The disturbed strip mine areas were delineated with the surrounding geological and vegetation features using ERTS-1 data in both analog (imagery) and digital form. The two digital systems used were: (1) the ERTS-Analysis system, a point-by-point digital analysis of spectral signatures based on known spectral values, and (2) the LARS Automatic Data Processing System. The digital techniques being developed will later be incorporated into a data base for land use planning. These two systems aided in efforts to determine the extent and state of strip mining in this region. Aircraft data, ground verification information, and geological field studies also aided in the application of ERTS-1 imagery to perform an integrated analysis that assessed the adverse effects of strip mining. The results indicated that ERTS can both monitor and map the extent of strip mining to determine immediately the acreage affected and indicate where future reclamation and revegetation may be necessary.

Anderson, A. T.↗
NASA NTRS1976

ERTS-1 data applied to strip mining

Two coal basins within the western region of the Potomac River Basin contain the largest strip-mining operations in western Maryland and West Virginia. The disturbed strip-mine areas were delineated along with the surrounding geological and vegetation features by using ERTS-1 data in both analog and digital form. The two digital systems employed were (1) the ERTS analysis system, a point-by-point digital analysis of spectral signatures based on known spectral values and (2) the LARS automatic data processing system. These two systems aided in efforts to determine the extent and state of strip mining in this region. Aircraft data, ground-verification information, and geological field studies also aided in the application of ERTS-1 imagery to perform an integrated analysis that assessed the adverse effects of strip mining. The results indicated that ERTS can both monitor and map the extent of strip mining to determine immediately the acreage affected and to indicate where future reclamation and revegetation may be necessary.

Anderson, A. T.↗
NASA NTRS1977

Application of aerial photography to water-related programs in Michigan

Aerial photography and information system technology were used to generate information required for the effective operation of three water-related programs in Michigan. Potential mosquito breeding sites were identified from specially acquired low altitude 70 mm color photography for the city of Lansing; the inventory identified 35% more surface water areas than indicated on existing field maps. A comprehensive inventory of surface water sources and potential access sites was prepared to assist fire departments in Antrim County with fire truck water-recharge operations. Remotely-sensed land cover/use data for Windsor Township, Eaton County, were integrated with other resource data into a computer-based information system for regional water quality studies. Eleven thematic maps focusing on landscape features affecting non-point water pollution and waste disposal were generated from analyses of a four-hectare grid-based data file containing land cover/use, soils, topographic and geologic (well-log) data.

Enslin, W. R.↗
NASA NTRS1984

Reports of Planetary Geology Program, 1983

Several areas of the Planetary Geology Program were addressed including outer solar system satellites, asteroids, comets, Venus, cratering processes and landform development, volcanic processes, aeolian processes, fluvial processes, periglacial and permafrost processes, geomorphology, remote sensing, tectonics and stratigraphy, and mapping.

Henry E Holt↗
NASA NTRS1984

Shuttle Experimental Radar for Geological Exploration (SERGE) project: Field work relating to the Shuttle Experimental Radar A (SIR-A) in Brazil (phase 2)

The ground observations undertaken over the northern position of Minas Gerais State, and part of Distrito Federal from 7 to 12 December 1982, along the Space Shuttle 2 flying orbit 22 of November 1981 are described. Field data related mostly with lithology, geological structures and forest cover, and specific geomorphological and pedological aspects were collected. Ground data are applied to evaluate the SIR-A Experiment, developed in the Space Shuttle-2 mission for natural resources mapping and prospecting.

Balieiro, M. G.↗
NASA NTRS2004

Using AVIRIS In The NASA BAA Project To Evaluate The Impact Of Natural Acid Drainage On Colorado Watersheds

The Colorado Geological Survey and the co-authors of this paper were awarded one of 15 NASA Broad Agency Announcement (BAA) grants in 2001. The project focuses on the use of hyperspectral remote sensing to map acid-generating minerals that affect water quality within a watershed, and to identify the relative contributions of natural and anthropogenic sources to that drainage. A further objective is to define the most cost-effective remote sensing instrument configuration for this application.

Hauff, Phoebe L.↗
NASA NTRS2006

Miniature Ground Penetrating Radar, CRUX GPR

Under NASA instrument development programs (PIDDP 2000-2002, MIPD 2003-2005, ESR and T, 2005) we have been developing miniature ground penetrating radars (GPR) for use in mapping subsurface stratigraphy from planetary rovers for Mars and lunar applications. The Mars GPR is for deeper penetration (up to 50 m depth) into the Martian subsurface at moderate resolution (0.5 m) for a geological characterization. As a part of the CRUX (Construction and Resource Utilization Explorer) instrument suite, the CRUX GPR is optimized for a lunar prospecting application. It will have shallower penetration (5 m depth) with higher resolution (10 cm) for construction operations including ISRU (in-situ resource utilization).

ground penetrating radars (GPR↗
DOE OSTI2020

Characterizing the diverse hydrogeology underlying rivers and estuaries using new floating transient electromagnetic methodology

We report the hydrogeology below large surface water features such as rivers and estuaries is universally under-informed at the long reach to basin scales (tens of km+). This challenge inhibits the accurate modeling of fresh/saline groundwater interfaces and groundwater/surface water exchange patterns at management-relevant spatial extents. Here we introduce a towed, floating transient electromagnetic (TEM) system (i.e. FloaTEM) for rapid (up to 15 km/h) high resolution electrical mapping of the subsurface below large water bodies to depths often a factor of 10 greater than other towed instruments. The novel FloaTEM system is demonstrated at a range of diverse 4th through 6th-order riverine settings across the United States including 1) the Farmington River, near Hartford, Connecticut; 2) the Upper Delaware River near Barryville, New York; 3) the Tallahatchie River near Shellmound, Mississippi; and, 4) the Eel River estuary, on Cape Cod, near Falmouth, Massachusetts. Airborne frequency-domain electromagnetic and land-based towed TEM data are also compared at the Tallahatchie River site, and streambed geologic scenarios are explored with forward modeling. A range of geologic structures and pore water salinity interfaces were identified. Process-based interpretation of the case study data indicated FloaTEM can resolve varied sediment-water interface materials, such as the accumulation of fines at the bottom of a reservoir and permeable sand/gravel riverbed sediments that focus groundwater discharge. Bedrock layers were mapped at several sites, and aquifer confining units were defined at comparable resolution to airborne methods. Terrestrial fresh groundwater discharge with flowpaths extending hundreds of meters from shore was also imaged below the Eel River estuary, improving on previous hydrogeological characterizations of that nutrient-rich coastal exchange zone. In summary, the novel FloaTEM system fills a critical gap in our ability to characterize the hydrogeology below surface water features and will support more accurate prediction of groundwater/surface water exchange dynamics and fresh-saline groundwater interfaces.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Ratio maps of iron ore deposits Atlantic City district, Wyoming

Preliminary results of a spectral rationing technique are shown for a region at the southern end of the Wind River Range, Wyoming. Digital ratio graymaps and analog ratio images have been produced for the test site, but ground truth is not yet available for thorough interpretation of these products. ERTS analog ratio images were found generally better than either ERTS single-channel images or high altitude aerial photos for the discrimination of vegetation from non-vegetation in the test site region. Some linear geological features smaller than the ERTS spatial resolution are seen as well in ERTS ratio and single-channel images as in high altitude aerial photography. Geochemical information appears to be extractable from ERTS data. Good preliminary quantitative agreement between ERTS-derived ratios and laboratory-derived reflectance ratios of rocks and minerals encourage plans to use lab data as training sets for a simple ratio gating logic approach to automatic recognition maps.

Vincent, R. K.↗
DOE OSTI2019

Mid-Atlantic U.S. Offshore Carbon Storage Resource Assessment Project (Final Technical Report)

The greatest potential for carbon storage in the northeastern United States lies in the offshore geologic formations comprising the outer continental shelf (Monteverde et al., 2011). Offshore storage can be linked to large point-sources of carbon dioxide (CO 2 ) while avoiding many of the logistical difficulties and potential risks encountered when siting onshore projects, especially in densely populated areas of the East Coast. Offshore CO 2 storage assessment and research in the United States is underway to address uncertainty in potential storage resources, particularly in the mid- and north-Atlantic offshore area. Given the current knowledge base and access to publicly available data, the objectives of the Mid-Atlantic U.S. Offshore Carbon Storage Resource Assessment Project (MAOCSRAP) were fourfold: (1) complete a systematic carbon storage resource assessment of the mid-Atlantic offshore coastal region from the Georges Bank Basin (GBB) through the Long Island Platform (LIP) to the southern Baltimore Canyon Trough (BCT); (2) define key input parameters to reduce uncertainty for offshore storage resource and efficiency estimates; (3) perform a preliminary assessment of risk factors, uncertainties, and data gaps; and (4) engage industry and regulatory stakeholders through development of a Road Map to assist future project planning and implementation. The MAOCSRAP project has compiled, inventoried, and assimilated various publicly available data sets to provide a strong technical basis on which future carbon storage studies and applications can be built. The knowledge infrastructure necessary to support the development of full-scale offshore carbon storage include: Defining the geologic characteristics of candidate storage sites (Chapter 2). Using existing seismic data to better define the continuity of the storage zones and seals (Chapter 3). Cataloguing the hydrogeologic properties of mid-Atlantic offshore storage sites (Chapter 4). Calculating prospective CO 2 storage resources using net effective pore volumes and fluid displacement properties specific to offshore lithologies (Chapter 5). Examining risk factors related to offshore storage (Chapter 6). Communicating with industry and other stakeholders about the future prospects for offshore storage (Chapter 7). Ensuring technology transfer to industry and other stakeholders (Chapter 8). Led by Battelle, this project was conducted by public and private entities with expertise in offshore geology and resources for the study region, including state geological surveys of Delaware, Maryland, and Pennsylvania; United States Geological Survey-Woods Hole Coastal and Marine Science Center and Haifa University; Rutgers University; Harvard University; and Lamont-Doherty Earth Observatory (LDEO) at Columbia University. The storage resource assessment was completed for a broad region offshore of the U.S. East Coast, from Massachusetts to Virginia. The results include high-level storage resource estimates for areas not previously characterized and improved storage resource estimates for geographically expansive portions of offshore geologic units. Results of the project provide a foundation for developing CO 2 storage along offshore areas of the mid-Atlantic United States. A combination of information was used to provide confidence in project results. Key findings of the major project tasks are summarized as follows. Subsurface Data Analysis: Legacy seismic, well-log, core, and biostratigraphic data were digitized, reprocessed, and analyzed using modern techniques, augmenting previous characterization efforts. The sequence stratigraphic framework for the Cretaceous and Jurassic strata was developed by correlating well-log depositional sequences to seismic reflectors identified in the BCT, LIP, and GBB. The integration of well-log stratigraphy with seismic stratigraphy and petrophysical analysis helped to identify and map potential storage zones within sequences of the Logan Canyon (LC), Missisauga, and Mohawk formations, as well as the regionally extensive caprock comprised of the Dawson Canyon shale. Approximately 4,000 kilometers (km) of seismic data was reprocessed to create a structural framework that was used to tie together all available well data, constrain sequence stratigraphic interpretations, and make regional assessments of offshore carbon storage resources. Prospective storage resource estimates were 150 to 1136 megatons (Mt) for the combined storage zones. This suggests mid-Atlantic U.S. offshore formations can store decades of CO 2 from industrial sources in the region. Preliminary local reservoir simulations suggest that injection rates of 1 Mt CO 2 /year may be sustained for 30 years in single injection wells in the BCT. Advanced geologic modeling and new data acquisition are needed to address data gaps and advance carbon capture and storage (CCS) in key offshore areas selected for further investigation. Offshore Risk Factors: Offshore geologic risk factors include soft sediment deformation, unit continuity, sedimentological and structural features, seismicity and hydrates. CO 2 storage risks include inadequate seals, migration/leakage, and chemical interactions leading to decreased storage. Sensitive habitats, environmental impacts, disturbance to seafloor, and other risks need to be identified in advance of project activities and integrated into detailed mitigation plans for all project phases. Stakeholder Engagement: Input and participation from government, industry, and environmental groups provided input into the Road Map and address next steps needed for project deployment. Early engagement and ongoing communication, as well as policy framework development, is key to large-scale deployment of CCS. Next Steps: This project represents an important first step by completing a high-level CO 2 storage resource assessment and building the knowledge infrastructure necessary to improve quantitative storage resource estimates. The data sets that have been curated under this project provide an opportunity to conduct research and development (R&D) needed to address data gaps and reduce risk and uncertainty. Offshore characterization and validation strategies that are systematically designed to provide data and infrastructure that can be upscaled to meet commercial requirements could be developed off of this foundation.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
NASA NTRS1972

Application of ecological, geological and oceanographic ERTS-1 imagery to Delaware's coastal resources planning

The author has identified the following significant events. Coastal vegetation species appearing in the ERTS-1 image taken of the Southern Coast of Delaware, during orbit 333 on August 16, 1972, have been correlated with ground truth vegetation maps, and imagery obtained from high altitude RB-57 and U-2 overflights. The vegetation maps of the entire Delaware Coast were prepared using data collected on foot, in small boats, and from low altitude aircraft. Multispectral analysis of high altitude RB-57 and U-2 photographs indicated that five vegetation species could be clearly discriminated from 60,000 feet altitude, including: (1) salt marsh cord grass (Spartina alterniflora); (2) salt marsh hay and spike grass (Spartina patens and Distichlis spicata); (3) reed grass (Phragmites communis); (4) high tide bush and sea myrtle (Iva species and Baccharus halimifolia); and (5) a group of fresh water species found in impounded areas built to attract water fowl. Major Spartina alterniflora and Spartina patens communities within the tidal marshes can be identified in the ERTS-1 imagery. Phragmites, and other species however, occur in smaller, more dispersed groupings and are difficult to discriminate within the resolution capability of the ERTS-1 scanner. Similarly, major impounded areas, built to attract water fowl can be detected; however, mosquito drainage ditches, covering many of Delaware's marshes, are too narrow and not long enough to be resolved by ERTS-1 sensors. High-marsh and dune communities dominated by high tide bush (Iva frutescens) and sea myrtle (Baccharus halimifolia) can be distinguished from adjacent maritime forest and beach grass communities.

Klemas, V.↗
NASA NTRS1974

Identification of Geostructures of the Continental Crust Particularly as They Relate to Mineral Resource Evaluation

The author has identified the following significant results. A pattern of very old geostructures was recognized, reflecting structures in the crust. This pattern is not peculiar to Alaska, but can be recognized throughout the northern cordillera. A new metallogenic hypothesis for Alaska was developed, based on the relationship of space image linears to known mineral deposits. Using image linear analysis, regional geologic features were also recognized; these features may be used to guide in the location of undiscovered oil and/or gas accumulations in northern Alaska. The effectiveness of ERTS data in enhancing medium and small scale mapping was demonstrated. ERTS data were also used to recognize and monitor the state of large scale vehicular scars on Arctic tundra.

Lathram, E. H.↗
NASA NTRS1977

Application of aerial photography to water-related programs in Michigan

The paper describes the use of aerial photography and information system technology in the provision of information required for the effective operation of three water-related programs in Michigan. Potential mosquito breeding sites were identified from specially acquired low altitude 70 mm color photography for the City of Lansing Vector Control Area. A comprehensive inventory of surface water sources and potential access sites was prepared to assist fire departments in Antrim County with fire truck water-recharge operations. Remotely-sensed land cover/use data for Windsor Township, Eaton County were integrated with other resource data into a computer-based information system for regional water quality studies. Eleven thematic maps specifically focussed on landscape features affecting non-point water pollution and waste disposal were generated from analyses of a four-hectare grid-based data file containing land cover/use, soils, topographic and geologic (well-log) data.

Enslin, W. R.↗
NASA NTRS1991

Chronology of glaciation in the Hellas region of Mars

The Hellas Impact Basin is one of the oldest features on Mars, as indicated by the high density of large impact craters in parts of the basin. The highly degraded condition of Hellas seems consistent with great antiquity. However, many of the most strikingly modified landscapes in the basin, believed to be glaciogenic, also appear to be geologically youthful. Stratigraphic relations suggest two episodes of glaciation. Chronologic constraints are imposed on glaciation based on the impact cratering record, the focus of which is the southwestern portion of Hellas. Major terrain units are mapped. The lineated terrain and ridged plains form the summit and flanks of a large shield volcano, Amphitrites Patera, which was superimposed over the southwestern rim of Hellas toward the end of heavy bombardment. The ridged plains and lineated terrain are crossed by numerous wrinkle ridges. The lineated terrain is distinguished by a pervasive system of deep erosional troughs and sharp ridges thought to have been glacially sculpted by the Hellas Lobe. It is concluded that glaciation in Hellas occurred during the Middle Amazonian, roughly coeval with glaciation in Argyre.

Johnson, N.↗
NASA NTRS1993

Do it yourself remote sensing: Generating an inexpensive, high tech, real science lake mapping project for the classroom

The utilization of modest equipment and software revealed bottom contours and water column conditions of a dynamic water body. Classroom discussions of field techniques and equipment capabilities followed by exercises with the data sets in cause-and-effect analysis all contributed to participatory education in the process of science. This project is presented as a case study of the value of engaging secondary and collegiate level students in planning, executing and appraising a real world investigation which they can directly relate to. A 1 km wide bay, experiencing marsh inflow, along an 8 km long lake situated 120 km north of Ottawa, Canada, on the glaciated Canadian Precambrian Shield was mapped in midsummer for submerged topography, bottom composition, temperature profile, turbudity, dissolved oxygen and biota distribution. Low level aerial photographs scanned into image processing software are permitting spatial classification of bottom variations in biology and geology. Instrumentation consisted of a portable sport fishing SONAR depth finder, an electronic lead line multiprobe with photocell, thermistor and dissolved oxygen sensors, a selective depth water sampler, portable pH meter, an underwater camera mounted on a home-made platform with a bottom-contact trigger and a disposable underwater camera for shallow survey work. Sampling transects were referenced using a Brunton hand transit triangulating several shore markers.

Metzger, Stephen M.↗