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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,531 records · Page 85

High Power Density, Carbon Neutral Electrical Power Generation for Air Vehicles

The synergistic integration of a Solid Oxide Fuel Cell-Combustor (SOFC-C) with a turbogenerator (TG) will provide a very high fuel-to-electricity conversion efficiency while maintaining high power-to-weight ratio during high-altitude flight. The proposed SOFC-C-TG power generation technology exceeds the REEACH technical performance targets (TPT). This unique concept addresses many of the challenges faced in all electric propulsion-based aviation. The system has high part-load efficiency (more than 65% lower heating value (LHV)) during long cruise times, load following capability, high-power capacity at high altitudes adapting to low temperatures and pressures, rapid startup time of less than 30 minutes (proven with current SOFC technology), high power density (more than 3.2 kW/kg), efficient thermal management, and a foundation for a compact, efficient electrical storage and power generation system (ESPG). The SOFC-C concept achieves the technology targets by reducing the complexity of traditional fuel cell-gas turbine hybrid systems (FC-GT). The SOFC-C does not require heat exchangers and dramatically reduces the balance of plant increasing power density and performance in efficiency. The reduction in mass through elimination of heat exchangers, external reformer, and other components dramatically decreases the overall thermal dampening of the system which enables rapid startup and load following capability. Direct control of the cathode inlet temperature of the SOFC-C enables rapid warm-up of the SOFC tubes with the ability to reach operating temperature and full power in less than 30 minutes.

03 NATURAL GAS↗

Multi-Fluid Modeling of Low-Recycling Divertor Regimes

Here, the low-recycling regimes of divertor operation in a single-null NSTX magnetic configuration are studied using computer simulations with the edge plasma transport code UEDGE. The edge plasma transport properties pertinent to the low-recycling regimes are demonstrated. These include the flux-limited character of the parallel heat transport and the high plasma temperatures with the flattened profiles in the scrape-off-layer. It is shown that to maintain the balance of particle fluxes at the core interface the deuterium gas puffing rate should increase as the divertor recycling coefficient decreases. The radial profiles of the heat load to the outer divertor plate, the upstream radial plasma profiles, and the effects of the cross-field plasma transport in the low-recycling regimes are discussed. It is also shown that recycling of lithium impurities evaporating from the divertor plate at high surface temperatures can reverse the low-recycling divertor operational regime to the high-recycling one and may cause thermal instability of the divertor plate.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Primary Heat Transport System Design Considerations for Xcimer Energy’s Athena Fusion Pilot Plant

Fusion energy promises a reliable, carbon-free source of power; however, significant challenges remain before it can be deployed as an economical energy source. In addition to achieving fusion conditions, power plants must operate under extreme temperatures, radiation, and mechanical loads while maintaining high efficiency and availability. These requirements place strong demands on engineering design and plant operation. This work focuses on the engineering challenges associated with balance of plant analysis for inertial fusion energy systems. In particular, this paper examines the design considerations for primary heat transfer systems in fusion pilot plants employing molten fluoride salt coolants, with particular emphasis on system layout optimization and the balance between competing design objectives using the Xcimer Energy Athena inertial pilot plant design as a case study. Through systematic analysis of candidate system configurations and parametric sensitivity studies, we identify key engineering trade-offs governing salt inventory, pumping power requirements, and operational flexibility. The analysis employs system-level modeling tools to explore the design space and establish relationships between geometric parameters and system performance metrics.

Greenwood, Scott [ORNL] (ORCID:0000000333480736)↗

Model estimates of dissolved organic carbon, runoff, snowmelt, and snow water equivalent from 1981-2010 across the western Arctic

This dataset contains estimates of dissolved organic carbon (DOC) yield (mg C m-2), runoff (mm day-1), snow water equivalent (SWE, mm day-1), and snowmelt (mm day-1) from a simulation of the Permafrost Water Balance Model (PWBM v4). The simulation effectively quantifies snowpack accumulation and melt, runoff, and DOC leaching, and broadly capture the seasonal cycle in DOC concentration and mass loadings. Daily air temperature, precipitation, and wind speed data from the Modern-Era Retrospective Analysis for Research and Applications (MERRA) were used for meteorological forcings. The model outputs are organized by grid and day of the month in gzipped ASCII text files contained within each archived ZIP file. No special software is required to work with these data. The basin and domain information files are also ASCII text. The gridded estimates are most useful for analyses of the spatial and temporal variations in terrestrial hydrology and leachate DOC concentrations and loadings across parts of the western Arctic. A manuscript describing the data and associated analysis has been accepted for publication in Journal of Geophysical Research - Biogeosciences (Rawlins et al., 2021).

54 ENVIRONMENTAL SCIENCES↗

US Hybrid Northeast Demonstration and Deployment of FCRxNV200 (DE-EE0007276 Final Report)

In this project, US Hybrid and other strategic project partners, collaborated to build a fuel cell range extended plug-in hybrid utility vehicle and demonstrate it in real-world operation. The base vehicle platform to be modified to the hybrid platform was the Nissan e-NV200, which is an all-electric version of the NV200 commercial cargo van. This is a Class 1 vehicle with a GVWR of approx. 4,900 lbs., wheelbase of 115 inches, and cargo capacity of approx. 122ft. The 80kW/254N-m electric powertrain is the same as Nissan’s LEAF, but with a revised final drive ratio (9.301 vs. 8.194) to accommodate higher payloads with lower top speed. US Hybrid utilized a purpose built, freeze capable, integrated fuel cell engine FCe™10 to hybridize and range-extend the existing e-NV200 vehicle with OEM drivetrain. The eNV200 has the same size battery as the LEAF with a different rear axle ratio. Fuel cell stack size and balance of plant (BOP) configuration were designed for compact under the hood vehicle packaging. Engine design took into consideration the need for high efficiency (>50% at all loads & up to 62% at partial power), optimal heat recovery for cabin heating, and low maintenance. The technology of the isolated DC-DC converter operating at >100kHz enables extremely high efficiency (ZVS and SIC power devices) and robust performance while reducing system complexity, weight, and volume. This enables an extended vehicle range of up to 250 miles and an operational life that should provide lower total cost of ownership (TCO) to the end user.

33 ADVANCED PROPULSION SYSTEMS↗

Deployment Potential of Concentrating Solar Power Technologies in California

As states within the United States respond to future grid development goals, there is a growing demand for reliable and resilient nighttime generation that can be addressed by low-cost, long-duration energy storage solutions. This report studies the potential of including concentrating solar power (CSP) in the technology mix to support California’s goals as defined in Senate Bill 100. A joint agency report study that determined potential pathways to achieve the renewable portfolio standard set by the bill did not include CSP, and our work provides information that could be used as a follow-up. This study uses a capacity expansion model configured to have nodal spatial fidelity in California and balancing-area fidelity in the Western Interconnection outside of California. The authors discovered that by applying current technology cost projections CSP fulfills nearly 15% of the annual load while representing just 6% of total installed capacity in 2045, replacing approximately 30 GWe of wind, solar PV, and standalone batteries compared to a scenario without CSP included. The deployment of CSP in the results is sensitive to the technology’s cost, which highlights the importance of meeting cost targets in 2030 and beyond to enable the technology’s potential contribution to California’s carbon reduction goals.

14 SOLAR ENERGY↗

Equilibrium and Sudden Events in Chemical Evolution

We present new analytic solutions for one-zone (fully mixed) chemical evolution models that incorporate a realistic delay time distribution for Type Ia supernovae (SNe Ia) and can therefore track the separate evolution of αelements produced by core collapse supernovae (CCSNe) and iron peak elements synthesized in both CCSNe and SNe Ia. Our solutions allow constant, exponential, or linear–exponential (te{sup -t/τsfh}) star formation histories, or combinations thereof. In generic cases, α and iron abundances evolve to an equilibrium at which element production is balanced by metal consumption and gas dilution, instead of continuing to increase over time. The equilibrium absolute abundances depend principally on supernova yields and the outflow mass loading parameter η, while the equilibrium abundance ratio [α/Fe] depends mainly on yields and secondarily on star formation history. A stellar population can be metal-poor either because it has not yet evolved to equilibrium or because high outflow efficiency makes the equilibrium abundance itself low. Systems with ongoing gas accretion develop metallicity distribution functions (MDFs) that are sharply peaked, while “gas starved” systems with rapidly declining star formation, such as the conventional “closed box” model, have broadly peaked MDFs. A burst of star formation that consumes a significant fraction of a system’s available gas and retains its metals can temporarily boost [α/Fe] by 0.1–0.3 dex, a possible origin for rare, α-enhanced stars with intermediate age and/or high metallicity. Other sudden transitions in system properties can produce surprising behavior, including backward evolution of a stellar population from high to low metallicity.

79 ASTRONOMY AND ASTROPHYSICS↗

Development of organic non-flammable spacecraft potting, encapsulating and conformal coating compounds

The overall program objective was to develop a flexible compound which not only functioned in a manned aerospace environment as an effective electrical insulation, but whose flammability characteristics in 16.5 psia, 60% oxygen/40% nitrogen were evidenced by rapid self-extinguishment and minimal thermal (pyrolysis) degradation. The following polymeric matrices were examined in depth: fluoroelastomers, modified fluoroelastomers, silicone RTV's, and modified silicone and fluorosilicone RTV's. Almost none of these systems burned in air, but all burned in 6.2 psia oxygen. Inorganic, organic, and inorganic/organic additives were evaluated in conjunction with these polymers in order to achieve the required survival in the 16.5 psia 60/40 environment. Depending upon formulations, it was possible to achieve nonflammable products when tested in the 1/4 in. x 1/4 in. x 1 in. configuration, even up to and including 16.5 psia oxygen. However, in order to assure this level of flame resistance, it was found necessary to heavily load the matrix with the additives. This resulted in a significant reduction in mechanical properties and large increases in viscosities. Optimization of formulations to obtain a suitable balance between these properties and flammability resistance led to the final selection of Formulation 387 as the primary system.

Lieberman, S. L.↗

Design of hydraulic output Stirling engine

A hydraulic output system for the RE-1000 free piston stirling engine (FPSE) was designed. The hydraulic output system can be readily integrated with the existing hot section of RE-1000 FPSE. The system has two simply supported diaphragms which separate the engine gas from the hydraulic fluid, a dynamic balance mechanism, and a novel, null center band hydraulic pump. The diaphragms are designed to endure more than 10 billion cycles, and to withstand the differential pressure load as high as 14 MPa. The projected thermodynamic performance of the hydraulic output version of RE-1000 FPSE is 1.87 kW at 29/7 percent brake efficiency.

Toscano, W. M.↗

The MANTA: An RPV design to investigate forces and moments on a lifting surface

The overall goal was to investigate and exploit the advantages of using remotely powered vehicles (RPV's) for in-flight data collection at low Reynold's numbers. The data to be collected is on actual flight loads for any type of rectangular or tapered airfoil section, including vertical and horizontal stabilizers. The data will be on a test specimen using a force-balance system which is located forward of the aircraft to insure an undisturbed air flow over the test section. The collected data of the lift, drag and moment of the test specimen is to be radioed to a grand receiver, thus providing real-time data acquisition. The design of the mission profile and the selection of the instrumentation to satisfy aerodynamic requirements are studied and tested. A half-size demonstrator was constructed and flown to test the flight worthiness of the system.

Bryan, Kevin↗

Multidisciplinary Analysis of a Hypersonic Engine

The objective is to develop high fidelity tools that can influence ISTAR design In particular, tools for coupling Fluid-Thermal-Structural simulations RBCC/TBCC designers carefully balance aerodynamic, thermal, weight, & structural considerations; consistent multidisciplinary solutions reveal details (at modest cost) At Scram mode design point, simulations give details of inlet & combustor performance, thermal loads, structural deflections.

Suresh, Ambady↗

Experimental Evaluation of the Micro-Environmental Control System in Maintaining Thermal Comfort

The micro-environment in this study refers to the air space and environment around a person that directly impacts his/her thermal sensation. Most existing HVAC systems condition the air of the entire room including the unoccupied space, which leaves a big potential to save energy. This study aims at evaluating the performance of three existing air terminal devices (ATDs) and two heating delivering devices (HDDs) to manage the thermal balance so as not to sacrifice thermal comfort when the ambient unoccupied space temperature is expanded from 21.1-23.9 °C to 18.9-26.1 °C to reduce HVAC load. A 20-segment thermal manikin was put in a full-scale stainless-steel chamber to test with selected ATDs and HDDs. Results show that all the three ATDs with only 50 W cooling power and the heating mat with a reflective box using 60 W heating power were able to recover the thermal comfort in a room of expanded temperature set-point. The cooling performance of the jet was increased more by increasing the supply airflow rate than reducing the supply air temperature, and 8.0 L/s flow rate could remove more than 15.6 W from the manikin. A heating mat that heated the feet by conduction was more efficient than the heating bulb, and with 60 W heating power, it could reduce the heat loss from the manikin by more than 12.2 W.

Kong, Meng↗

Hydrogen Storage for Flexible Fossil Fuel Power Generation: Integration of Underground Hydrogen Storage with Gas Turbine (Final Report)

As the nation continues to encourage, through market structures and financial incentives, the proliferation of intermittent renewable electricity, how to optimize the ever-changing electric grid and identify means to retain and improve resilience, while ensuring continued reductions in GHG emissions, will be critical. According to Bloomberg, wind & solar generated 10.5% of US electricity in 2020 and that percentage continues to grow. In support of expanding renewable energy use, and to address its intermittent nature, this project will develop the Hydrogen Storage for Flexible Fossil Fuel Power Generation platform that is dispatchable, reliable, repeatable and have the ability to produce zero or negative carbon power while interfacing with geology capable of CO2 and hydrogen storage. GTI Energy (GTIE) and team members Illinois State Geological Survey (ISGS), Mitsubishi Heavy Industries America (MHIA), Ameren Illinois, Hexagon Purus, and the Low Carbon Resources Initiative (LCRI) completed a Phase I Conceptual Study under contract DE-FE0032012 for Hydrogen Storage for Flexible Fossil Fuel Power Generation: Integration of Underground Hydrogen Storage with Gas Turbine. The Hydrogen Storage for Flexible Fossil Fuel Power Generation platform addresses the intermittent nature of the expanding use of Variable Renewable Energy (VRE) generation. The low cost of the electricity (COE) generated results in greater dispatch and more operation at higher power levels (higher efficiency), fewer short intervals, and fewer start/stop cycles. The reliable, resilient system can produce zero carbon power and store hydrogen. It will demonstrate hydrogen storage in geologic formations like those used in natural gas underground storage thus enabling large scale storage of hydrogen in sedimentary strata across the United States rather than in geographically restricted salt caverns. The Phase I study confirmed the system is feasible and generates power at lower cost than other low carbon approaches. The demonstration defines the pathway for broad commercial application and will accelerate the development of larger systems suitable for centralized utility scale electricity production. The study advanced the maturity of the H 2 storage-based system with flexible power generation by completing a Pre-FEED study (Phase II). The Pre-FEED focused on the selected Energy Farm on the University of Illinois Urbana-Champaign (UIUC) site that includes above ground and underground hydrogen storage, low-carbon hydrogen production (GTI’s Compact Hydrogen Generator, CHG) with underground CO2 sequestration, and a 40-MW class gas turbine. The Pre-FEED addressed the entire system and its interconnection to the natural gas and electric grid and mitigation of key risks, such as storage behavior, load-following, and system operation. During Phase 1 of the project, the team completed key tasks, which moved the entire demonstration project, specific components and approaches closer to commercialization. These Phase I Accomplishments include: Completing System Requirements Review; Completing System Layout and Modeling - Heat & Mass Balance and Process Flow Diagram; Completing modelling of 9 turbine performance cases; Evaluating rock strata for underground storage of hydrogen and sequestration of carbon dioxide; Completing initial modelling of underground storage of hydrogen and withdrawal with evaluation of loss and water production; Identifying roadable storage for above ground hydrogen storage; Identifying existing electrical infrastructure for receiving/delivering electricity; Identifying existing gas supply infrastructure for receiving natural gas; Document concept design/development plans in required reports. Conclusions: The 12-month Feasibility study in Phase I study was completed and confirmed the system is feasible and generates power at lower cost than other low carbon approaches and even lower cost than the reference NGCC plant without carbon capture when taking advantage of 45Q carbon credits. The study enabled the fidelity of the concept to be improved and allowed identification of the requirements for the system. Defining the individual system and component requirements was performed via the system requirements review with the whole team. These requirements were then incorporated into and iterated with our Heat & Mass Balance process model and process flow diagrams were generated to reflect the overall system. This information was then used to complete the TEA and show economic feasibility. Large scale non-salt geologic storage of hydrogen is an enabling technology for a hydrogen-fired turbine that can be retrofitted into large-scale electric generating units (EGU). Our demonstration will include 428 MWh or ~4 hours full load of hydrogen storage (above and underground). Carbon capture inherent to the CHG process can capture 90% CO 2 (with upgrades to >98%). This system provides a COE of 23% savings relative to an NGCC with a post combustion amine system. Our proposed storage system decouples carbon capture and hydrogen production from power production; therefore, we expect our proposed system’s efficiency and variable COE to be superior resulting in overall higher dispatch and reduced deep cycling. Our demonstration will be full to multi-day hydrogen storage and has the potential for longer (seasonal) duration commercially. The demonstration defines the pathway for broad commercial application and will accelerate the development of larger systems suitable for centralized utility scale electricity production.

03 NATURAL GAS↗

Integrated energy balance analysis for Space Station Freedom

An integrated simulation model is described which characterizes the dynamic interaction of the energy transport subsystems of Space Station Freedom for given orbital conditions and for a given set of power and thermal loads. Subsystems included in the model are the Electric Power System (EPS), the Internal Thermal Control System (ITCS), the External Thermal Control System (ETCS), and the cabin Temperature and Humidity Control System (THC) (which includes the avionics air cooling, cabin air cooling, and intermodule ventilation systems). Models of the subsystems were developed in a number of system-specific modeling tools and validated. The subsystem models are then combined into integrated models to address a number of integrated performance issues involving the ability of the integrated energy transport system of Space Station Freedom to provide power, controlled cabin temperature and humidity, and equipment thermal control to support operations.

Tandler, John↗

Assessment of the methane oxidation capacity of compacted soils intended for use as landfill cover materials

The microbial oxidation of methane in engineered cover soils is considered a potent option for the mitigation of emissions from old landfills or sites containing wastes of low methane generation rates. A laboratory column study was conducted in order to derive design criteria that enable construction of an effective methane oxidising cover from the range of soils that are available to the landfill operator. Therefore, the methane oxidation capacity of different soils was assessed under simulated landfill conditions. Five sandy potential landfill top cover materials with varying contents of silt and clay were investigated with respect to methane oxidation and corresponding soil gas composition over a period of four months. The soils were compacted to 95% of their specific proctor density, resulting in bulk densities of 1.4-1.7 g cm{sup -3}, reflecting considerably unfavourable conditions for methane oxidation due to reduced air-filled porosity. The soil water content was adjusted to field capacity, resulting in water contents ranging from 16.2 to 48.5 vol.%. The investigated inlet fluxes ranged from 25 to about 100 g CH{sub 4} m{sup -2} d{sup -1}, covering the methane load proposed to allow for complete oxidation in landfill covers under Western European climate conditions and hence being suggested as a criterion for release from aftercare. The vertical distribution of gas concentrations, methane flux balances as well as stable carbon isotope studies allowed for clear process identifications. Higher inlet fluxes led to a reduction of the aerated zone, an increase in the absolute methane oxidation rate and a decline of the relative proportion of oxidized methane. For each material, a specific maximum oxidation rate was determined, which varied between 20 and 95 g CH{sub 4} m{sup -2} d{sup -1} and which was positively correlated to the air-filled porosity of the soil. Methane oxidation efficiencies and gas profile data imply a strong link between oxidation capacity and diffusive ingress of atmospheric air. For one material with elevated levels of fine particles and high organic matter content, methane production impeded the quantification of methane oxidation potentials. Regarding the design of landfill cover layers it was concluded that the magnitude of the expected methane load, the texture and expected compaction of the cover material are key variables that need to be known. Based on these, a column study can serve as an appropriate testing system to determine the methane oxidation capacity of a soil intended as landfill cover material.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Multicriteria cost–benefit assessment of tannery production: The need for breakthrough process alternatives beyond conventional technology optimization

The worldwide use of chromium-based processes in tanneries generates increased concerns about their related environmental burdens. Cleaner production alternatives for leather production are being proposed, based on the optimization of specific aspects or criteria, for instance, reducing demand for specific materials and energy, or reducing local toxicological emissions. While improvement on individual characteristics of the process is certainly to be favored, a more comprehensive evaluation of alternatives is also needed to prevent the risk of shifting the burden to increase global load while addressing one specific critical factor of production. This work aims to discuss the importance of a multicriteria, multiscale approach to address cleaner production strategy costs and benefits. For this, materials balance, an economic approach, and emergy (with an “m”) accounting methods are applied to selected unhairing/liming, pickling/tanning and wastewater treatment steps in a tannery process, which was chosen as a case study. Results show that the assessed recycling cleaner production strategies assessed allow the manufacturer to reduce by one half the amount of water used and the demand for chemicals up to 4% with respect to the business-as-usual process, at the expense of increasing electricity demand by 10%. Economic cost-to-benefit ratio was 25$ benefits per 1$ invested, as well as an emergy-based cost-to-benefit of 33Em$ per 1Em$ invested, of course these improvements were limited to the three investigated process steps. The improvement in cost/benefit ratios indicates that converting scenario #0 into #1 is favorable under economic and emergy views. However, when the two scenarios are investigated from the point of view of the imbalance in local and renewable resource use versus imported and nonrenewable use, the emergy method shows a small overall increase in renewability (from 3.51% to 3.85%), a low, but expected, emergy yield ratio equal to 1, and a high environmental loading ratio (24.95 and 27.47). While the environmental cost–benefit ratio shows that recycling is a favorable option, the emergy performance indicators highlight that the efficiency of recycling is still insufficient and improvements in the tanning processes are needed to ensure renewability and sustainability. A number of process chemicals were involved in the investigated tannery operations, which required emergy evaluations. As a side result of this study, the Unit Emergy Values (UEVs) of SO{sub 2}, H{sub 2}SO{sub 4} Na{sub 2}SO{sub 4}, HCL, Na{sub 2}S, NaOH, CaO, Ca(OH){sub 2}, Cr{sub 2}O{sub 3}, MnSO{sub 4}, and Al(OH){sub 3}, were also calculated thus adding to the emergy database about chemicals. - Highlights: • Cleaner production strategies for tannery processes are presented and evaluated. • Local and global scales are considered under economical and biophysical approaches. • A multicriteria approach should be considered for decision making. • Recycling strategies have better indicators than traditional processes. • Emergy integrates energy and monetary indicators for more comprehensive assessment.

54 ENVIRONMENTAL SCIENCES↗

Numerical Investigation of High Delta T Sensible Storage Integrated CO2 Heat Pump: Preprint

To assist building heating electrification, this paper numerically investigates a load flexible heat pump system for commercial buildings. The system consists of a CO2 vapor compression cycle, a sensible thermal storage tank, and an air handling unit. The thermal storage medium is inexpensive, non-toxic and stable anti-freeze solution (30% potassium acetate). The air handing unit has an indoor coil and a ventilation coil. The system can be used to manage building electric load. During peak hours, the heat pump is off and the hot solution water is discharged from the tank to heat up the indoor air and ventilation air. During the hour of charge, the heat pump delivers hot solution water to the tank and to the air. The tank can also stand by while the heat pump provides space heating directly. We selected a medium sized office building located in Minnesota as the representative building and used EnergyPlus to obtain its 24 hour load data. We designed three storage tank volumes assuming 50 degrees C, 65 degrees C and 80 degrees C tank temperatures to independently provide the building load for 4 hours in the morning. The higher the tank temperature, the smaller the required volume, and thus higher energy density. The effective energy density is 78 with an 80 degrees C tank, and 40 kWhth/m3 with 50 degrees C. We simulated the tank integrated heat pump performance subjected to the 24-hour building load profile and ambient data. The baseline is the same system without storage tank. There was a trade-off between the storage energy density and the charging COP. The charge hour COP was 2.77 to charge the tank to 80 degrees C, and 3.01 to 50 degrees C. The proposed system could shift building load from the peak hours (8:00 - 12:00) to off-business hour (23:00 - 7:00+1). It eliminated 100% compressor electricity use during the peak hours, and avoided a peak electric power of 34 kW. The 65 degrees C tank saved 9.5 kWhe (4%) considering all day operation, which was the best balance between energy density and the system operation efficiency among the three options.

CO2 heat pump↗