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Studies of the structure and dynamics of a light harvesting complex from photosynthetic bacteria are described. Using Nuclear Magnetic Resonance methods, we explored the idea that optical properties are modulated via a conformational switch in the BChl chromophores, in a way that provides benefits for the efficiency of energy conversion.
A review of literature indicates that there will be a 20% increase in utilization of glass/glass PV modules by 2023. Common degradation modes reported in literature of glass/glass modules are: Encapsulant delamination, Encapsulant browning, corrosion and glass cracks. There is a strong need to investigate the reliability of glass/glass modules in detail to identify and overcome any potential failures in the future constructions. This work presents a preliminary literature review on the reliability of old generation glass/glass modules in the field.
Concentrating Solar Power (CSP) generation is an attractive option for low-emission power generation; however, the high costs of thermal storage associated with concentrating solar create a large barrier for their use and adaptation into modern life. Lowering their operation costs, while maintaining high thermal storage and transfer performance is essential. Solid particle-based heat exchange systems can reduce CSP cost but are often less efficient. Efforts to increase their performance have led to use of binary size particle mixes. Presented is an optical-based thermal analysis technique used to measure near-wall thermal conductivity of particle beds essential in determining their heat exchanger efficiency. Modulated Photothermal Radiometry is used to make dynamic temperature measurements, allowing for the extraction of the most relevant thermal properties like thermal conductivity, specific heat, and effusivity. The system uses a modulated laser source causing a damped periodic heat flux, resulting in a frequency and thermal property dependent surface temperature, of which is measured using radiometry. Lock-In techniques are used to extrapolate the amplitude of the signal. Plotting the amplitude against the root angular frequency allows for effusivity measurement by ratio to a known sample. Using specific heat measurements from literature and density measurements, the thermal conductivity of the particle mixes can be calculated. The simplicity of MPTR to probe through the depth of the bed is ideal for use in CSP for dynamic thermal performance monitoring.
Accelerated weathering and material compatibility testing for polymeric and asphaltic materials. NLR will be testing the durability of the polymeric materials proposed for use in the supporting structures designed by TESCI solar. This will include the bare materials and coupons attached to asphalt shingles. The exposure will be in damp heat and separately heat, humidity and UV light, all followed by mechanical evaluation. Modification 1 is an extension of the first round of testing with both a continuation of some of the same testing and addition of new testing methods and materials. The testing of materials in the condition of A3 looking at mechanical durability will be continued looking at the materials used in the mounting brackets. We will be adding in testing of the silicone adhesive to the module and of the module itself. For the mounting brackets, testing will also be conducted at multiple temperatures and humidity levels to allow for extrapolation to the field.
Rotation is a directly observable stellar property, and it drives magnetic field generation and activity through a magnetic dynamo. Main-sequence stars with masses below approximately 0.35 M{sub ⊙} (mid-to-late M dwarfs) are fully convective, and are expected to have a different type of dynamo mechanism than solar-type stars. Measurements of their rotation rates provide insight into these mechanisms, but few rotation periods are available for these stars at field ages. Using photometry from the MEarth Project, we measure rotation periods for 387 nearby, mid-to-late M dwarfs in the northern hemisphere, finding periods from 0.1 to 140 days. The typical rotator has stable, sinusoidal photometric modulations at a semi-amplitude of 0.5%–1%. We find no period–amplitude relation for stars below 0.25 M{sub ⊙} and an anticorrelation between period and amplitude for higher-mass M dwarfs. We highlight the existence of older, slowly rotating stars without Hα emission that nevertheless have strong photometric variability. We use parallaxes, proper motions, radial velocities, photometry, and near-infrared metallicity estimates to further characterize the population of rotators. The Galactic kinematics of our sample is consistent with the local population of G and K dwarfs, and rotators have metallicities characteristic of the solar neighborhood. We use the W space velocities and established age–velocity relations to estimate that stars with P < 10 days have ages of on average <2 Gyr, and that those with P > 70 days have ages of about 5 Gyr. The period distribution is dependent on mass: as the mass decreases, the slowest rotators at a given mass have longer periods, and the fastest rotators have shorter periods. We find a lack of stars with intermediate rotation periods, and the gap between the fast and slow rotators is larger for lower masses. Our data are consistent with a scenario in which these stars maintain rapid rotation for several gigayears, then spin down quickly, reaching periods of around 100 days by a typical age of 5 Gyr.
The Energy Commission called on the National Renewable Energy Laboratory's (NREL)'s Solar Technical Assistance Team to explore various pathways for supporting continued evolution of the list. NREL staff utilized the Database of State Incentives for Renewables and Efficiency (DSIRE), California Solar Initiative (CSI) data, and information from in-depth interviews to better understand the impact of a lack of an updated list and suggest potential solutions. A total of 18 people from state energy offices, rebate program administrators, utilities, national testing laboratories, private companies, nonprofit organizations, and the federal government were interviewed between July and September 2013. CSI data were analyzed to illustrate the monetary benefits of the algorithm behind calculating performance of PV modules included on the list. The primary objectives of this study are to: 1) Determine the impact of not maintaining the list, and 2) Explore alternatives to the State of California's maintenance of the list.
The Solar Decathlon Building Science Education series is designed to educate students and working professionals on building science principles that are paramount to the successful design of high-performance, energy-efficient buildings. Instructional content is presented in modules, covering specific topics. Altogether, this series aims to educate viewers on: 1) where/how energy is used in buildings; 2) how to define zero energy buildings; 3) how to apply the fundamentals of thermodynamics to building envelope design; 4) how to explain the science of how/why buildings use energy; 5) how to apply this knowledge to design comfortable energy efficient buildings. Students and working professionals can use this educational information at no cost to complement academic curriculum and continuing education activities. This is Module 7 which focuses on embodied environmental carbon.
As PV modules continue to trend toward larger, thinner, and more flexible forms they grow more susceptible to damage from dynamic wind loading. As a result, understanding the impact of wind on PV systems, particularly when mounted on compliant solar-tracking hardware, and identifying robust, stable array layouts and stow strategies is becoming increasingly important for the PV community. We are developing an open-source software package, PVade (PV aerodynamic design engineering), to simulate the cascading fluid-structure interaction that occurs within single-axis, solar-tracking arrays to enable researchers to test hardware, layout, and tracker control changes, leading to enhanced stability and a reduction in wind-driven damage. We will give an overview of the PVade software and present the latest outcomes from our ongoing validation campaign in which we compare time series and statistical structural responses with field data. From there, we will present simulated results from a larger, multi-row array and highlight the effect of varying tracker angles on stability and the differences between positive and negative tilt angles.
Halide perovskites with bandgaps of 1.70–1.85 eV are of interest for multijunction photovoltaics. Mixing halides on the X site of the ABX3-structured perovskite system is a common way to reach these bandgaps, but this method introduces phase segregation pathways, limiting photovoltage. Recently, a new strategy for increasing the bandgap has been introduced, where cations normally too large to fit into the lattice, but compensated by smaller cations, are substituted on the A site. The mechanism underlying the increase of the bandgap with this strategy remained an open question. Here, we show that by partial substitution of the large dimethylammonium (DMA) cation at the A site of FA x Cs 1–x PbI y Br 3–y perovskites, a bandgap increase is observed not only when DMA is compensated by smaller Cs cations but also when only DMA is added, which is accompanied by an expansion of the crystal lattice. Our experimental findings suggest that adding DMA is causing an unexpected tilt in the perovskite octahedra, increasing the bandgap. Efficient solar cells based on 1.73 eV DMA-incorporated materials are extremely stable, retaining 96% of their original efficiency over 2200 h at 85 °C in the dark and 92% of their original efficiency after operation at 60 °C for 500 h. Finally, this octahedral tilting strategy is a promising route for attaining efficient and stable wide bandgap perovskite solar cells.
Here, we report on an electrical conduction mechanism for series resistance (Rs) degradation observed in a utility-scale photovoltaic power plant by imaging the local resistance at the Ag/Si interface of the c-Si front metallization. Scanning spreading resistance microscopy imaging with nanometer (nm) scale spatial resolution revealed that the number of point or small-area electrical contacts decreased substantially in a degraded cell compared to an unaffected cell, demonstrating the root cause of Rs degradation. The decrease in electrical contacts is likely caused by a structural change - the Ag particles in contact with the Si cell (or via a nm-thickness tunneling glass layer) aggregate into bulk Ag, and a highly resistive glass frit forms a belt shape at the Ag/Si interface. This resistive belt, with a thickness of ~1 um, blocks the current conduction from the cell emitter to the Ag grid. Our microscopy results help to unravel unambiguously the degradation mechanism and demonstrate an example of the multiscale characterization approach for understanding degradation in field-weathered PV module.
Abstract Cellulose nanofibrils are attractive as building blocks for advanced photonic, optoelectronic, microfluidic, and bio‐based devices ranging from transistors and solar cells to fluidic and biocompatible injectable devices. For the first time, an ultrastrong and ultratough cellulose film, which is composed of densely packed bacterial cellulose (BC) nanofibrils with hierarchical fibril alignments, is successfully demonstrated. The molecular level alignment stems from the intrinsic parallel orientation of crystalline cellulose molecules produced by Acetobacter xylinum. These aligned long‐chain cellulose molecules form subfibrils with a diameter of 2–4 nm, which are further aligned to form nanofibril bundles. The BC film yields a record‐high tensile strength (≈1.0 GPa) and toughness (≈25 MJ m −3 ). Being ultrastrong and ultratough, yet the BC film is also highly flexible and can be folded into desirable shapes. The BC film exhibits a controllable manner of alignment and is highly transparent with modulated optical properties, paving the way to enabling new functionalities in mechanical, electrical, fluidic, photonics, and biocompatible applications.
The Discrete Fourier transform (DFT) based measurement algorithms are one of the most common measurement algorithms for grid parameter estimation such as rms, phase angle, frequency. Over the past few years, many DFT based algorithms have been developed to enhance its measurement accuracy under steady-state and/or dynamic grid conditions. For example, an adaptive band-pass filter utilizing exponential modulation filter has been proposed to reduce measurement errors at the presence of large frequency deviations. Measurement accuracy of different algorithms including FIR filter, extended Kalman filtering (EKF), and enhanced DFT method have been compared in detail under different grid conditions. Two artificial signals that have 90-degree phase difference were constructed by the Clarke transformation to address the frequency spectrum leakage of DFT. A multi-module approach was developed to enhance both steady-state and dynamic measurement accuracies, in which each module was developed to eliminate some specific errors. Besides DFT-based measurement algorithms, some signal model-based algorithms have been developed to further improve the accuracy under dynamic conditions. However, a key drawback of the state-of-the-art algorithms is that they cannot perform measurements accurately during system transient faults. In the Blue Cut Fire event, there was a phase angle jump of about 26 degrees in the voltage waveform during the transient fault. The phase angle jump fault will cause waveform discontinuity, and these algorithms will fail to provide reliable measurements during this period because they typically assume the waveform to be measured is continuous, no matter what method (DFT, PLL, EKF, FIR, or Taylor WLS) is used for estimation. In fact, the measurement errors during the system transient faults like phase-jump is not required in the IEEE Standard. As a result, although a measurement instrument can pass the strict IEEE Standard, it could still be the source of the problem in the future if we have similar system transient faults, which could happen again. Therefore, developing the fault-tolerant measurement technology is the key to solve the problem.
Concentrated solar power (CSP) plants have the potential to provide 24 h, renewable electricity. Current CSP systems have high capital and operational costs which makes the levelized cost of electricity uncompetitive with conventional techniques. Recent experimental research has shown the potential of small unit cells (up to 2 × 2 cm) containing micropin arrays (D H < 1 mm) to operate efficiently at high incident flux (>140 W cm -2 ) using supercritical carbon dioxide as the working fluid. Applying this technology to CSP systems would result in a smaller central receiver, which would reduce thermal losses, increase receiver efficiency and reduce the capital cost of the receiver component. This study investigates and addresses the practical thermal and hydraulic issues in numbering up these small unit cells into numerous parallel cells within an integrated module design. A thermal hydraulic network model is developed to quantify the distribution and the overall receiver efficiency of an integrated module. This model is used to specify maximum allowable unit cell size and header dimensions to maintain acceptable thermal performance and pressure loss. Once a module design was finalized, parametric studies were performed to study the effects of varying incident flux on flow distribution and thermal performance of the module. Finally, the results show that an integrated module design can be achieved with less than 5% flow maldistribution and a pressure drop acceptable to the remainder of the system.
Nonuniform irradiance on the rear side of bifacial photovoltaic (PV) systems can cause additional mismatch loss, which may not be appropriately captured in PV energy production estimates and software. We evaluated several scenarios including horizontal single-axis tracking (HSAT) over natural ground-cover and rooftop-mounted systems over high albedo reflective roofs. We found mismatch losses of up to 1.5% annual loss for very close-mounted (0.15 m) rooftop systems, but losses for HSAT systems and high-ground-clearance rooftop systems were lower (<0.5%). A simplified empirical relationship was found that links the spatial variation of irradiance (specifically, the mean absolute difference of irradiance) to the resulting mismatch loss factor, with an R 2 better than .99. Furthermore, this approximate relationship was experimentally validated on mismatched PV modules, and it provides a basis for rapidly estimating bifacial mismatch loss factors for use in hourly PV performance simulations such as PVSyst or SAM. Additional parameters investigated include (a) climate dependence and module orientation, which were not found to have a strong impact on bifacial mismatch losses and (b) PV module fill factor and bifaciality ratio, which did have a strong linear impact on mismatch losses.
Renewable energy generation has experienced significant cost reductions during the past decades, and it has become more accepted by the global population. In the beginning, wind generation dominated the development and deployment of renewable energy; however, during recent decades, photovoltaic (PV) generation has grown at a very significant pace due to the tremendous decrease in the cost of PV modules. The focus on renewable energy generation has now expanded to include new types with promising future applications, such as river and tidal generation. The input water flow to these types of resources is more predictable than wind or solar generation. The data used in this paper is representative of a typical river or tidal generator. The analysis is based on a generator with a power rating of 40 kW. The tidal generator under consideration is driven by two sets of helical turbines connected to each side of the generator located in between the turbines. The generator is operated in variable speed, and it is controlled to maximize the energy harvested as well as the operation of the turbine generator. The electrical system consists of a three-phase permanent magnet generator connected to a three-phase passive rectifier. The output of the rectifier is connected to a DC-DC converter to match the rectifier output to the DC bus voltage of the DC-AC inverter. The three-phase inverter is connected to the grid, and it is controlled to provide a good interface with the grid. One important aspect of river and tidal generation is the braking mechanism. In a tidal generator, the braking mechanism is important to avoid a runaway condition in case the connection to the grid is lost when there is a fault in the lines. A runaway condition may lead to an overspeed condition and cause extreme stresses on the turbine blade structure and eventual disintegration of the mechanical structure. In this paper, the concept of the dynamic braking system is developed and investigated for normal and abnormal operations. The main objective is to optimize the performance under emergency braking while designing the system to be as simple as possible to avoid overdesigning the power electronics or exceeding the target budget.
Photovoltaic (PV) energy production is currently increasing at a significant rate. A novel module architecture has been demonstrated that has potential for reducing manufacturing cost while improving module reliability and recycling for c-Si PV which utilizes an edge-seal. Referred to as Edge Sealed Module (ESM), this architecture eliminates the vacuum lamination process and cross-linked encapsulants on the interior of the module. Functioning prototypes of c-Si have been fabricated for stress testing in collaboration with National Renewable Energy Laboratories (NREL). These modules are being tested and compared to traditionally manufactured modules. Based on preliminary results, this module architecture is a potentially viable solution for improving the manufacturing cost and recyclability of PV modules while enhancing module performance.
We present an evolution of wave localization and magnetic power spectra in solar wind plasma using kinetic Alfvén waves (AWs) and fast AWs. We use a two-fluid model to derive the dynamical equations of these wave modes and then numerically solve these nonlinear dynamical equations to analyze the power spectra and wave localization at different times. The ponderomotive force associated with the kinetic AW (or pump) is responsible for the wave localization, and these thin slabs (or sheets) become more chaotic as the system evolves with time until the modulational instability (or oscillating two-stream instability) saturates. From our numerical results, we notice a steepening of the spectra from the inertial range (k{sup −1.67}) to the dispersion range (k{sup −3.0}). The steepening of the spectra could be described as the energy transference from longer to smaller scales. The formation of complex magnetic thin slabs and the change of the spectral index may be considered to be the main reason for the charged particles acceleration in solar wind plasma.