Results for “Spectroscopy” — Page 85

NASA NTRS2018

Constraints on the chemical enrichment history of the Perseus Cluster of galaxies from high-resolution X-ray spectroscopy

High-resolution spectroscopy of the core of the Perseus Cluster of galaxies, using the Hitomi satellite above 2 keV and the XMM–Newton Reflection Grating Spectrometer at lower energies, provides reliable constraints on the abundances of O, Ne, Mg, Si, S, Ar, Ca, Cr, Mn, Fe, and Ni. Accounting for all known systematic uncertainties, the Ar/Fe, Ca/Fe, and Ni/Fe ratios are determined with a remarkable precision of less than 10 per cent, while the constraints on Si/Fe, S/Fe, and Cr/Fe are at the 15 per cent level, and Mn/Fe is measured with a 20 percent uncertainty. The average biases in determining the chemical composition using archival CCD spectra from XMM–Newton and Suzaku typically range from 15 to 40 per cent. A simple model in which the enrichment pattern in the Perseus Cluster core and the protosolar nebula are identical gives a surprisingly good description of the high-resolution X-ray spectroscopy results, with X^2=10.7 for 10 degrees of freedom. However, this pattern is challenging to reproduce with linear combinations of existing supernova nucleosynthesis calculations, particularly given the precise measurements of intermediateα-elements enabled by Hitomi. We discuss in detail the degeneracies between various supernova progenitor models and explosion mechanisms, and the remaining uncertainties in these theoretical models. We suggest that including neutrino physics in the core-collapse supernova yield calculations may improve the agreement with the observed pattern ofα-elements in the Perseus Cluster core. Our results provide a complementary benchmark for testing future nucleosynthesis calculations required to understand the origin of chemical elements.

A Simionescu↗

NASA NTRS2019

Near-infrared Spectroscopy of Galaxies During Reionization: Measuring C III] in a Galaxy at z = 7.5

We present Keck/MOSFIRE H-band spectroscopy targeting C III] λ1907, 1909 in a z = 7.5056 galaxy previously identified via Lyα emission. We detect strong line emission at 1.621 ± 0.002 mm with a line flux of (2.63 ± 0.52) × 10−18 erg s−1cm−2. We tentatively identify this line as [C III] λ1907, but we are unable to detect C III] λ1909 owing to sky emission at the expected location. This gives a galaxy systemic redshift, zsys = 7.5032 ± 0.0003, with a velocity offset to Lyα of DvLya = 88 ± 27 km s−1. The ratio of combined C III]/Lyα is 0.30–0.45, one of the highest values measured for any z > 2 galaxy. We do not detect Si III] λλ1883, 1892, and place an upper limit on Si III]/C III] < 0.35 (2σ). Comparing our results to photoionization models, the C III] equivalent width (WC III] = 16.23 ± 2.32 Å), low Si III]/C III] ratio, and high implied [O III] equivalent width (from the Spitzer/IRAC [3.6]–[4.5] ~- 0.8 mag color) require subsolar metallicities (Z ~- 0.1–0.2 Zsun) and a high ionization parameter, log U >~ 1.5. These results favor models that produce higher ionization, such as the BPASS models for the photospheres of high-mass stars, and that include both binary stellar populations and/or an IMF that extends to 300 Me. The combined C III] equivalent width and [3.6]–[4.5] color are more consistent with ionization from young stars than active galactic nuclei (AGNs); however, we cannot rule out ionization from a combination of an AGN and young stars. We make predictions for James Webb Space Telescope spectroscopy using these different models, which will ultimately test the nature of the ionizing radiation in this source.

reionization↗

NASA NTRSDate not supplied

Stratigraphy of the Apollo 17 Landslide Core 73002 From FMR Maturity and VNIR and Mössbauer Spectroscopy

A suite of samples from the Apollo missions to the Moon (1969-1973) were set aside and stored under controlled conditions to have unexamined lunar samples available decades later for analyses that take advantage of evolved sample handling techniques, maturation of then existing instrumentation, and development of new analytical techniques and instrumentation [e.g., 1]. One preserved sample is the Apollo 17 double drive tube core (73001/2) that was driven into the lunar surface on the landslide deposit at Station 3 on the South Massif in the Taurus-Littrow valley [2]. The deeper section (73001) was stored frozen in a Core Sample Vacuum Container (CSVC) to maximize preservation of lunar volatiles. We report here, as a part of the Apollo Next Generation Sample Analysis (ANGSA) Initiative [1,3], stratigraphy for the upper core section (73002) with respect to maturity (ferromagnetic resonance (FMR) maturity index Is/FeO [4-6]), visible-near-IR (VNIR) spectroscopy, and, for representative samples, grain-size analysis and Mössbauer spectroscopy. Stratigraphy provides data to model the dynamics of lunar landslide deposits and their post-emplacement evolution in comparison to impact-driven mixing on an airless body and stratigraphic context for volatile and (if any) organic behavior. Reported by [7] are preliminary results for multispectral imaging and hyperspectral scanning of the first dissection pass of 73002.

R. V. Morris↗

NASA NTRS2020

Spectroscopy of the first resolved strongly lensed Type Ia supernova iPTF16geu

We report the results from spectroscopic observations of the multiple images of the strongly lensed Type Ia supernova (SN Ia), iPTF16geu, obtained with ground-based telescopes and the Hubble Space Telescope (HST). From a single epoch of slitless spectroscopy with HST, we resolve spectra of individual lensed supernova images for the first time. This allows us to perform an independent measurement of the time-delay between the two brightest images, Δt = 1.4 ± 5.0 d, which is consistent with the time-delay measured from the light curves. We also present measurements of narrow emission and absorption lines characterizing the interstellar medium in the SN Ia host galaxy at z = 0.4087, as well as in the foreground lensing galaxy at z = 0.2163. We detect strong Na ID absorption in the host galaxy, indicating that iPTF16geu belongs to a subclass of SNe Ia displaying ‘anomalously’ large Na ID column densities compared to dust extinction derived from light curves. For the lens galaxy, we refine the measurement of the velocity dispersion, σ = 129 ± 4 km/s, which significantly constrains the lens model. We use ground-based spectroscopy, boosted by a factor ∼70 from lensing magnification, to study the properties of a high-z SN Ia with unprecedented signal-to-noise ratio. The spectral properties of the supernova, such as pseudo-Equivalent widths of several absorption features and velocities of the Si II-line, indicate that iPTF16geu is a normal SN Ia. We do not detect any significant deviations of the SN spectral energy distribution from microlensing of the SN photosphere by stars and compact objects in the lensing galaxy.

J Johansson↗

NASA NTRSDate not supplied

Rotational Spectroscopy is SubLIME: Site-Specific Identification of Compounds Formed on UV-photolyzed Cosmcs Ice

A variety of organic compounds has been detected in comets, meteorites, and the cold gas enveloping infant stars. These compounds display a range of complexity and include so-called complex organic molecules that may have astrobiological implications. Laboratory studies of photolyzed and nonirradiated interstellar, planetary, and cometary ices have demonstrated many astrochemical formation routes and require sensitive analytical techniques to identify the composition of ice and gas products formed. The unique identification of organics can be challenging and often requires structure-specific techniques to identify structural isomers, conformers, and isotopologues. We present the approaches used in SubLIME, the Sublimation of Laboratory Ices Millimeter/submillimeter Experiment, which uses the structure-specificity of rotational spectroscopy to identify the composition and abundances of sublimated products of UV-photolyzed ice samples. Ices are formed and photolyzed at low temperature (~10 K) and slowly heated to 300 K to sublimate the volatile products. The gas mixture is then investigated with millimeter/submillimeter spectroscopy, and the resulting spectra compared to observational spectra collected with submillimeter/far-IR telescopes. We present the experimental set-up and results of UV-photolyzed interstellar ice analogues containing water (H O) and carbon monoxide (CO). Formation routes for identified molecules are proposed for follow-up experimental and theoretical investigations.

Olivia H. Wilkins↗

NASA NTRSDate not supplied

Surface-Enhanced Raman Spectroscopy (SERS) for Venus Atmospheric Characterization and Trace Organics Identification

The chemical composition of Venus’ clouds has attracted considerable attention since the first atmospheric probes entered the planet in the early 1980s. We know from these early studies that cloud aerosols consist of micron and submicron droplets of sulfuric acid (~85%) and water (~15%), but outstanding questions still exist regarding their trace chemical composition, especially the identity of the unknown UV absorber(s) and the possible presence of organic material (Spacek & Benner, 2021). Veritas and DaVinci will launch at the end of the decade to advance our understanding of Venus’ surface and atmosphere, however these missions are not designed to sample and analyze cloud aerosols at trace levels. Raman spectroscopy is an ideal candidate for characterizing aerosols and has a track record in studies of Earth’s atmosphere. Raman provides broad chemical screening of organic and inorganic molecules within seconds, and Raman instrumentation can be miniaturized to meet the stringent size, weight, and power (SWaP) constraints of an atmospheric probe while retaining sensitivity and specificity that allow spectral fingerprinting of compounds and functional groups. Raman alone is insufficient to characterize trace constituents however, as limits of detection are typically in the 10s to 100s of ppm at best for planetary Raman spectrometers. Surface-Enhanced Raman Spectroscopy (SERS), a method that utilizes nanoscale materials interacting with a sample to enhance weak Raman signals by orders of magnitude when probed by a laser, has the potential to drastically improve the sensitivity of a Raman instrument while adding little-to-no SWaP nor complexity to a scientific payload. We aim to de-risk SERS technology for rapid infusion in future planetary science missions by developing custom SERS substrates tailored towards Venus atmospheric exploration. We have developed SERS substrates consisting of nanotextured silver films and tested them on potential Venus-relevant organic compounds, with preliminary results indicating sub-ppm sensitivity. Additionally, we have planned tests to investigate durability, longevity, and other key characteristics that impact SERS substrate performance to prepare SERS technology for flight.

Venus↗

NASA NTRSDate not supplied

Examination of Mars2020 Shock-Layer Conditions Via Infrared Emission Spectroscopy of CO2

A new test series was performed in the Electric Arc Shock Tube (EAST) facility, with the aim of reproducing flight conditions encountered during the Mars2020 mission entry into Mars atmosphere. For this test series, the EAST facility was instrumented with two spectrometers for Optical Emission Spectroscopy (OES) measurements and three mid-infrared lasers for Tunable Diode Laser Absorption Spectroscopy (TDLAS). This study focuses on the spectrally and spatially resolved radiance measured with OES. Comparison with CEA/NEQAIR and DPLR/NEQAIR simulations were made. For velocity above 2.7 km/s, measurements are found to lie between the different tested kinetic models, within ± 10%. Below 2.7 km/s, the chemistry appears to be frozen and measured radiance profiles are typically 10% above CEA predictions. This difference is explained by shock deceleration effects. Finally, comparison between OES and TDLAS data are made and show a good agreement on the measured temperature and CO2 number density profiles using the two diagnostics, typically within 10 and 5%, respectively.

Augustin C Tibere-Inglesse↗

NASA NTRSDate not supplied

Laser Absorption Spectroscopy Measurements of Post-Shock Non-Equilibrium Species in the NASA Ames Electric Arc Shock Tube

The NASA Ames Electric Arc Shock Tube (EAST) is a unique facility capable of generating high enthalpy, shock-heated impulse gas flows representative of the kinetic and radiative conditions encountered by atmospheric entry vehicles. The facility maintains a successful history with emission spectroscopy, providing measurements of absolute radiance upon which various validation studies are anchored. The central objective of this work is to develop a comprehensive tunable diode laser absorption spectroscopy (TDLAS) sensing capability to provide complementary experimental insights to existing emission techniques. More specifically, a fast-scanning TDLAS-based diagnostic targeting the cyano radical (CN) in the near-infrared(near-IR) near 926.6 nm is employed in mixtures of 2.2% CH4in N2by mole for a sweep of incident shock velocities ranging 3.0-5.5 km/s and fill pressures 0.3-1.15 Torr. Laser scan rates up to 500 kHz probe multiple absorption features to provide quantitative measurements of temperature and species number density profiles behind the incident shock. In all instances, the temperature trend is consistent between emission-inferred and TDLAS-inferred measurements. However, at the lower-velocity conditions, there is an appreciable offset between the Data Parallel Line Relaxation Code (DPLR) simulation and experimental measurements. A similar behavior is observed in number density profiles, with emission measurements providing inferences of the CN(B) and CN(A) state, while TDLAS measurements provide an additional inference of the CN(X) state. In the fast-scanned experiments, measurement inferred number densities suggest a much faster production of CN at early times than captured by the model. This discrepancy motivates ongoing, additional spectroscopic and kinetics CN experiments to resolve the accuracy of modeling assumptions.

Efaine Chang↗

NASA NTRSDate not supplied

Examination of Mars2020 Shock-Layer Conditions Via Infrared Emission Spectroscopy of CO2

A new test series was performed in the Electric Arc Shock Tube (EAST) facility, with the aim of reproducing flight conditions encountered during the Mars2020 mission entry into Mars atmosphere. For this test series, the EAST facility was instrumented with two spectrometers for Optical Emission Spectroscopy (OES) measurements and three mid-infrared lasers for Tunable Diode Laser Absorption Spectroscopy (TDLAS). This study focuses on the spectrally and spatially resolved radiance measured with OES. Comparison with CEA/NEQAIR and DPLR/NEQAIR simulations were made. For velocity above 2.7 km/s, measurements are found to lie between the different tested kinetic models, within ± 10%. Below 2.7 km/s, the chemistry appears to be frozen and measured radiance profiles are typically 10% above CEA predictions. This difference is explained by shock deceleration effects. Finally, comparison between OES and TDLAS data are made and show a good agreement on the measured temperature and CO2 number density profiles using the two diagnostics, typically within 10 and 5%, respectively.

Augustin Tibère-Inglesse↗

NASA NTRS2022

Direct Imaging and Spectroscopy of Exoplanetary Systems with the JWST Early Release Science Program

The direct characterization of exoplanetary systems with high contrast imaging is among the highest priorities for the broader exoplanet community. As large space missions will be necessary for detecting and characterizing exo-Earth twins, developing the techniques and technology for direct imaging of exoplanets is a driving focus for the community. For the first time, JWST will directly observe extrasolar planets at mid-infrared wavelengths beyond 5 μm, deliver detailed spectroscopy revealing much more precise chemical abundances and atmospheric conditions, and provide sensitivity to analogs of our solar system ice-giant planets at wide orbital separations, an entirely new class of exoplanet. However, in order to maximise the scientific output over the lifetime of the mission, an exquisite understanding of the instrumental performance of JWST is needed as early in the mission as possible. In this paper, we describe our 55-hour Early Release Science Program that will utilize all four JWST instruments to extend the characterisation of planetary mass companions to ∼15-20 μm as well as image a circumstellar disk in the mid-infrared with unprecedented sensitivity. Our program will also assess the performance of the observatory in the key modes expected to be commonly used for exoplanet direct imaging and spectroscopy, optimize data calibration and processing, and generate representative datasets that will enable a broad user base to effectively plan for general observing programs in future cycles.

Michael W McElwain↗

NASA NTRSDate not supplied

Verification and Calibration of Spectroscopy and Polarization modes for the Roman Coronagraph Instrument

As part of its technology demonstration, the Nancy Grace Roman Space Telescope Coronagraph Instrument (CGI) will demonstrate point source spectroscopy and polarization measurements of disks. The spectroscopy mode is a zero-deviation Amici prism and slit to a confirmed planet after an imaging detection. The Wollaston prism polarization optics allow for imaging two orthogonal polarization states simultaneously. The CGI spectral characterization modes, designed and built at Goddard Space Flight Center (GSFC), have a spectral resolution of R50 in two 15% bandpass centered at 660nm and 730nm intended to capture key methane absorption features. There are duplicate Wollaston prism channels, clocked 45 degrees with respect to one another covering 10% bandpasses at 575 and 825nm, but the optics meet performance requirements across the full CGI bandpass. The Wollaston design and optical elements are a contribution by the Japanese Aerospace Exploration Agency, with final alignment and testing being done at GSFC. We highlight the requirements for these modes, the ground-to-orbit calibration process, and the operations required to use a deployable slit on a CGI point source in the presence of pointing error. We also provide further detail on the optomechanical design, testing results from the final as-built flight units, verification process, and performance of the as-built flight assemblies.

Tyler D. Groff↗

NASA NTRSDate not supplied

Recent Advances in Soft Matter Characterization Capabilities Developed at NASA GRC for Lunar Exploration: Differential Dynamic Microscopy to Spectroscopy to Computer Vision

In 1991, famous French scientist Pierre-Gilles de Genes was awarded Nobel prize for his impactful research in soft matter, more specifically polymers. He is defined as the founding father of soft matter. In his Nobel lecture (https://www.nobelprize.org/uploads/2018/06/gennes-lecture.pdf ) he described soft matter aka complex fluids as materials with two primary features – (a) complexity and (b) flexibility. The sub-categories of soft matter (e.g.- granular materials, polymers, foams, colloids etc.) are defined on the basis of Pierre-Gilles de Gennes’ definition. At NASA GRC, we are pushing the boundaries for fundamental study of soft matter on Lunar Surface. With regard to Lunar surface science, we are focusing on developing capabilities pertaining to granular materials and bio-soft/active matter to facilitate future efforts in ISRU and bio-ISRU capabilities. In order to achieve fundamental goals of soft matter research within the limitations of Lunar environment, the scientific capabilities need to be small, flexible, modular, off the shelf and the focus needs to be more on developing an interdisciplinary capability that leverages the recent growth in AI/ML and Computer Vision to augment our understanding of fundamental science. This strategy would allow us to reduce our resource requirement during launch, installation, and occupied real estate footprint on Lunar surface In this talk, we will go over 3 different capabilities that we have developed in house and in close collaboration – (a) Differential Dynamic Microscopy (DDM), (b) Portable In-situ Chemical Spectroscopy (PICS) and (c) Computer Vision Enabled Observation. At very high level, Differential Dynamic Microscopy (DDM) allows us to study the structure-property-process relation (microrheology) of bio-soft/active matter using optical microscope and improved image analysis capabilities. PICS uses AI/ML-based advanced signal deconvolution and analysis technique that can work with existing portable spectroscopy tools to perform materials analysis (e.g.- granular materials and bio-soft/active matter) inspection on the go. Finally, computer vision enabled analysis allows us to use simple camera images for 3D reconstruction of experimental process and tracking of objects of interest in an experiment. We expect that this detailed process will allow us reach a thorough understanding of soft matter in Lunar environment. The capabilities developed by us will help to validate and establish fundamental understanding in Lunar environment. This will, in turn, allow us to guide future space exploration missions and expand the knowledge base of the scientific and engineering communities.

Suman Sinha Ray↗

NASA NTRSDate not supplied

Recent Advances in Soft Matter Characterization Capabilities Developed at NASA GRC for Lunar Exploration: Differential Dynamic Microscopy to Spectroscopy to Computer Vision

In 1991, famous French scientist Pierre-Gilles de Genes was awarded Nobel prize for his impactful research in soft matter, more specifically polymers. He is defined as the founding father of soft matter. In his Nobel lecture (https://www.nobelprize.org/uploads/2018/06/gennes-lecture.pdf ) he described soft matter aka complex fluids as materials with two primary features – (a) complexity and (b) flexibility. The sub-categories of soft matter (e.g.- granular materials, polymers, foams, colloids etc.) are defined on the basis of Pierre-Gilles de Gennes’ definition. At NASA GRC, we are pushing the boundaries for fundamental study of soft matter on Lunar Surface. With regard to Lunar surface science, we are focusing on developing capabilities pertaining to granular materials and bio-soft/active matter to facilitate future efforts in ISRU and bio-ISRU capabilities. In order to achieve fundamental goals of soft matter research within the limitations of Lunar environment, the scientific capabilities need to be small, flexible, modular, off the shelf and the focus needs to be more on developing an interdisciplinary capability that leverages the recent growth in AI/ML and Computer Vision to augment our understanding of fundamental science. This strategy would allow us to reduce our resource requirement during launch, installation, and occupied real estate footprint on Lunar surface. In this talk, we will go over 3 different capabilities that we have developed in house and in close collaboration – (a) Differential Dynamic Microscopy (DDM), (b) Portable In-situ Chemical Spectroscopy (PICS) and (c) Computer Vision Enabled Observation. At very high level, Differential Dynamic Microscopy (DDM) allows us to study the structure-property-process relation (microrheology) of bio-soft/active matter using optical microscope and improved image analysis capabilities. PICS uses AI/ML-based advanced signal deconvolution and analysis technique that can work with existing portable spectroscopy tools to perform materials analysis (e.g.- granular materials and bio-soft/active matter) inspection on the go. Finally, computer vision enabled analysis allows us to use simple camera images for 3D reconstruction of experimental process and tracking of objects of interest in an experiment. We expect that this detailed process will allow us reach a thorough understanding of soft matter in Lunar environment. The capabilities developed by us will help to validate and establish fundamental understanding in Lunar environment. This will, in turn, allow us to guide future space exploration missions and expand the knowledge base of the scientific and engineering communities.

Suman Sinha-Ray↗

NASA NTRSDate not supplied

Recent Advances in Soft Matter Characterization Capabilities Developed at NASA GRC for Lunar Exploration: Differential Dynamic Microscopy to Spectroscopy to Computer Vision

In 1991, famous French scientist Pierre-Gilles de Genes was awarded Nobel prize for his impactful research in soft matter, more specifically polymers. He is defined as the founding father of soft matter. In his Nobel lecture (https://www.nobelprize.org/uploads/2018/06/gennes-lecture.pdf ) he described soft matter aka complex fluids as materials with two primary features – (a) complexity and (b) flexibility. The sub-categories of soft matter (e.g.- granular materials, polymers, foams, colloids etc.) are defined on the basis of Pierre-Gilles de Gennes’ definition. At NASA GRC, we are pushing the boundaries for fundamental study of soft matter on Lunar Surface. With regard to Lunar surface science, we are focusing on developing capabilities pertaining to granular materials and bio-soft/active matter to facilitate future efforts in ISRU and bio-ISRU capabilities. In order to achieve fundamental goals of soft matter research within the limitations of Lunar environment, the scientific capabilities need to be small, flexible, modular, off the shelf and the focus needs to be more on developing an interdisciplinary capability that leverages the recent growth in AI/ML and Computer Vision to augment our understanding of fundamental science. This strategy would allow us to reduce our resource requirement during launch, installation, and occupied real estate footprint on Lunar surface In this talk, we will go over 3 different capabilities that we have developed in house and in close collaboration – (a) Differential Dynamic Microscopy (DDM), (b) Portable In-situ Chemical Spectroscopy (PICS) and (c) Computer Vision Enabled Observation. At very high level, Differential Dynamic Microscopy (DDM) allows us to study the structure-property-process relation (microrheology) of bio-soft/active matter using optical microscope and improved image analysis capabilities. PICS uses AI/ML-based advanced signal deconvolution and analysis technique that can work with existing portable spectroscopy tools to perform materials analysis (e.g.- granular materials and bio-soft/active matter) inspection on the go. Finally, computer vision enabled analysis allows us to use simple camera images for 3D reconstruction of experimental process and tracking of objects of interest in an experiment. We expect that this detailed process will allow us reach a thorough understanding of soft matter in Lunar environment. The capabilities developed by us will help to validate and establish fundamental understanding in Lunar environment. This will, in turn, allow us to guide future space exploration missions and expand the knowledge base of the scientific and engineering communities.

Suman Sinha Ray↗

NASA NTRSDate not supplied

Solar Coronal Phenomenon: Imaging Spectroscopy

The Sun's outer atmosphere, known as the corona, is significantly hotter than its surface, presenting a long-standing scientific mystery. One hypothesis is that small, frequent bursts of energy, called nanoflares, may be responsible for this heating, though the exact mechanism remains unclear. Additionally, certain elements in the corona appear more abundant than expected, a phenomenon termed the "FIP effect," which might also be linked to coronal heating processes. Imaging X-ray spectroscopy offers a powerful method for investigating these solar mysteries. In this talk, we will explore these intriguing questions about the Sun and discuss how imaging X-ray spectroscopy can provide insights. We will introduce the Marshall Grazing Incidence X-ray Imaging Spectrometer (MaGIXS) sounding rocket experiment and its recent successful flight, designed to probe these enigmatic aspects of the Sun.

solar corona↗

DOE OSTI2017

Full information acquisition in scanning probe microscopy and spectroscopy

Apparatus and methods are described for scanning probe microscopy and spectroscopy based on acquisition of full probe response. The full probe response contains valuable information about the probe-sample interaction that is lost in traditional scanning probe microscopy and spectroscopy methods. The full probe response is analyzed post data acquisition using fast Fourier transform and adaptive filtering, as well as multivariate analysis. The full response data is further compressed to retain only statistically significant components before being permanently stored.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Wide-field Multi-object Spectroscopy to Enhance Dark Energy Science from LSST

LSST will open new vistas for cosmology in the next decade, but it cannot reach its full potential without data from other telescopes. Cosmological constraints can be greatly enhanced using wide-field ($>20$ deg$^2$ total survey area), highly-multiplexed optical and near-infrared multi-object spectroscopy (MOS) on 4-15m telescopes. This could come in the form of suitably-designed large surveys and/or community access to add new targets to existing projects. First, photometric redshifts can be calibrated with high precision using cross-correlations of photometric samples against spectroscopic samples at $0 < z < 3$ that span thousands of sq. deg. Cross-correlations of faint LSST objects and lensing maps with these spectroscopic samples can also improve weak lensing cosmology by constraining intrinsic alignment systematics, and will also provide new tests of modified gravity theories. Large samples of LSST strong lens systems and supernovae can be studied most efficiently by piggybacking on spectroscopic surveys covering as much of the LSST extragalactic footprint as possible (up to $\sim20,000$ square degrees). Finally, redshifts can be measured efficiently for a high fraction of the supernovae in the LSST Deep Drilling Fields (DDFs) by targeting their hosts with wide-field spectrographs. Targeting distant galaxies, supernovae, and strong lens systems over wide areas in extended surveys with (e.g.) DESI or MSE in the northern portion of the LSST footprint or 4MOST in the south could realize many of these gains; DESI, 4MOST, Subaru/PFS, or MSE would all be well-suited for DDF surveys. The most efficient solution would be a new wide-field, highly-multiplexed spectroscopic instrument in the southern hemisphere with $>6$m aperture. In two companion white papers we present gains from deep, small-area MOS and from single-target imaging and spectroscopy.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2019

Electron Emission Spectroscopy of III-N Semiconductor Devices

Gallium nitride (GaN) has proven to be a semiconductor material system that is ideal for the development of lasers and light-emitting diodes (LEDs) with emission wavelengths spanning the visible spectrum. In particular, the prevalence of white LEDs has been made possible by pairing GaN-based optoelectronic devices emitting at 450 nm (blue) with phosphors for down-conversion. The efficiency of these devices, although better than alternatives, is limited at high current densities (efficiency droop), elevated temperatures (thermal droop) and is markedly worse at longer wavelengths. Understanding the physical origins of these efficiency problems can provide a pathway for engineering solutions to these long-standing issues. Despite extensive efforts to improve and understand these limitations, the unambiguous identification of these efficiency loss mechanisms has remained an open topic of research. Most studies of the efficiency loss mechanisms in GaN LEDs rely on an indirect measurement of carrier dynamics by analysis of the emitted light. The inadequacy of these indirect measurements has motivated the development of an electron spectroscopy technique, capable of directly probing several electron transport and recombination mechanisms in GaN-based optoelectronic devices. In 2013, electron emission spectroscopy (EES) was used for the first time to measure high energy electrons generated via Auger recombination in the active region of an LED. This result brought an end to the longstanding controversy over the causes for efficiency droop at high carrier densities. Our analysis of the kinetic energy of vacuum emitted electrons from GaN-based LEDs xiii has unambiguously identified carrier overshoot as the dominant mechanism responsible for thermal droop. Control experiments from p-n diodes show evidence for a previously unknown hot carrier generating process, likely trap-assisted Auger recombination (TAAR) occurring in AlGaN/GaN barrier heterostrucutres. We also discuss the possibility of TAAR occurring in InGaN quantum wells through examination of low-efficiency LEDs grown by molecular beam epitaxy. Finally, we discuss preliminary EES results regarding long wavelength GaN LEDs as well as the first EES measurements from semipolar ($20\bar2\bar1$) GaN LEDs and p-n diodes.

light emitting diodes, solid state lighting↗