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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,531 records · Page 85
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Degradation Of Reflectors And Dielectrics

Report describes important degrading effects of atmosphere and outer-space environments on reflective surfaces and dielectrics. For reflective surfaces, terrestrial effects include soiling on glass surfaces and changing with time. Space effects include ultraviolet enhancement of contamination and possible surface erosion due to solar radiation, impact of debris, and interactions with atomic oxygen. Dielectrics similarly affected in both environments.

Bouquet, Frank L.↗
NASA NTRS1990

Evaluation of sensible heat flux, latent heat flux, and effective aerodynamic roughness at the land surface from a combination of satellite and in-situ data

A simple method is presented for using the daytime rise of the PBL height, combined with coincident satellite skin temperature measurements, to evaluate sensible heating and the effective surface roughness for heat transfer at synoptic locations. Multiple runs of a combination surface layer-mixed layer model are made in the central U.S., varying the values of surface moisture and roughness length around climatological means, and initializing the model with a set of atmospheric conditions from the synoptic report. The results, shown in figures and tables, are quite reasonable and spatially coherent, and depict well the sharp change in surface moisture and roughness which is known to take place across the central U.S.

Diak, George R.↗
NASA NTRS1987

Effects of aerosols and surface shadowing on bidirectional reflectance measurements of deserts

Desert surfaces are probably one of the most stable of the Earth's natural targets for remote sensing. The bidirectional reflectance properties of the Saudi Arabian desert was investigated during the Summer Monsoon Experiment (Summer Monex). A comparison of high-altitude with near-surface measurements of the White Sands desert showed significant differences. These discrepancies have been attributed to forward scattering of the dust-laden atmosphere prevalent during Summer Monex. This paper is concerned in general with modeling the effects of atmospheric aerosols and surface shadowing on the remote sensing of bidirectional reflectance factors of desert targets, and in particular with comparing the results of these models with flight results. Although it is possible to approximate the latter, it is felt that a surface reflectance model with a smaller specular component would have permitted using a more realistic set of atmospheric conditions in the simulations.

Bowker, David E.↗
DOE OSTI2014

Effect of multipole excitations in electron energy-loss spectroscopy of surface plasmon modes in silver nanowires

We have characterized the surface plasmon resonance (SPR) in silver nanowires using spatially resolved electron energy loss spectroscopy (EELS) in the scanning transmission electron microscope. Non-symmetric EELS spectra due to high-k SPR propagation along the nanowire and spectral shifts due to higher-order mode excitation are observed when the beam is positioned near the tip of the nanowire. When the beam is far from the tip region and on the side of nanowire, no spectral shifts are observed as the beam is scanned in the radial direction of the nanowire. The experimental spectra are compared with three different theoretical approaches: direct numerical calculation of the energy loss, analytical models for energy loss, and numerical simulations using an optical model. All three models reproduce the spectral shifts as the electron beam approaches the cap of the nanowire. The analytical model reveals the origin of the shifts in high-order plasmon mode excitation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Nanofabrication of silicon surfaces for reduced virus adhesion

Nanofabrication is a remarkably effective technique to create desirable nanoscale patterns. Here, the effect of surface nanofabrication on altering virus adhesion to the substrates was examined. Arrays of nanoholes, 50 nm in diameter, 22 nm deep, and 100 nm in pitch distance, were created on silicon (Si) wafers by electron-beam lithography and reactive ion etching. MS2 coliphage, which is 26 ± 2 nm in diameter and is frequently used as a surrogate for human viruses, was applied to investigate the interaction between the virions and smooth or nanostructured Si surfaces. Scanning electron microscopy and atomic force microscopy along with surface wettability analyses revealed that the nanofabrication had the effect of reducing not only the number of viruses attached but also the strength of virus adhesion. These effects were ascribed to the presence of nanoholes, which were inaccessible to the virions due to the unique surface topographical parameters and the surface chemistry, resulting in the decrease of the overall solid contact area for MS2 attachment. The periodic spacing of the nanoholes also limited the unit landing area for MS2 particles, restricting the formation of MS2 aggregates and leading to the reduced amount of MS2 attachment. We anticipate that smart design of a surface’s chemical composition and nanostructure will offer a feasible solution to improve mitigations for controlling viral adhesion and transmission to and from food contact surfaces.

36 MATERIALS SCIENCE↗
NASA NTRS1984

Evaluation of surface sensible heat flux effects on the generation and modification of mesoscale circulations

Mesoscale thermal-induced circulations generated by horizontal gradients in surface characteristics as well as significant perturbations on land and sea breezes and mountain-valley winds due to substantial modifications in the thermal forcing are introduced. It is suggested that these types of mesoscale situations are generally ignored in forecasting but that they may have important implications in very short range predictions.

Segal, M.↗
NASA NTRS2004

Examination of Surface Roughness on Light Scattering by Long Ice Columns by Use of a Two-Dimensional Finite-Difference Time-Domain Algorithm

Natural particles such as ice crystals in cirrus clouds generally are not pristine but have additional micro-roughness on their surfaces. A two-dimensional finite-difference time-domain (FDTD) program with a perfectly matched layer absorbing boundary condition is developed to calculate the effect of surface roughness on light scattering by long ice columns. When we use a spatial cell size of 1/120 incident wavelength for ice circular cylinders with size parameters of 6 and 24 at wavelengths of 0.55 and 10.8 mum, respectively, the errors in the FDTD results in the extinction, scattering, and absorption efficiencies are smaller than similar to 0.5%. The errors in the FDTD results in the asymmetry factor are smaller than similar to 0.05%. The errors in the FDTD results in the phase-matrix elements are smaller than similar to 5%. By adding a pseudorandom change as great as 10% of the radius of a cylinder, we calculate the scattering properties of randomly oriented rough-surfaced ice columns. We conclude that, although the effect of small surface roughness on light scattering is negligible, the scattering phase-matrix elements change significantly for particles with large surface roughness. The roughness on the particle surface can make the conventional phase function smooth. The most significant effect of the surface roughness is the decay of polarization of the scattered light.

Sun, W.↗
DOE OSTI2020

Hydrogen Adsorption on Ordered and Disordered Pt-Ni Alloys

The bulk properties and chemical reactivity of disordered Pt-Ni alloys in the A1 ( fcc ) structure are investigated herein using different methods: Virtual Crystal Approximation (VCA), Korringa–Kohn–Rostoker Coherent Potential Approximation (KKR-CPA), and large explicit supercells generated using Super-Cell Random Approximates (SCRAPs). While VCA predicts lattice constants that closely follow Vegard’s law, the large supercells and KKR-CPA predict lattice constants that are consistently larger than Vegard’s law. KKR-CPA results closely agree with those from the large supercells for the disordered alloys, producing similar projected density of states and magnetic moment across the composition range. For instance, while VCA predicts the disordered alloys to be non-magnetic at a Pt concentration ( x Pt ) ≥ 0.5, KKR-CPA and SCRAPs predict the disordered alloys to remain ferromagnetic to higher Pt concentrations. As x Pt decreases, the adsorption of H becomes more exothermic on bulk-terminated (111) surfaces but less exothermic on Pt monolayer-terminated (111) surfaces due largely to strain effects. (111) surfaces cut from the large supercells predict average H adsorption energies on the disordered alloys similar to those on the ordered phases of the same compositions, while VCA predicts H adsorption to be more exothermic.

36 MATERIALS SCIENCE↗
DOE OSTI2015

The role of electrostatic charge in the adhesion of spherical particles onto planar surfaces in atmospheric systems

In this study, the influence of electrostatic charge on the adhesive force between spherical particles and planar surfaces in atmospheric systems was studied using atomic force microscopy. Electrical bias was applied to modify the surface charge, and it was found that application of a stronger positive bias to a particle induces a stronger total adhesive force. The sensitivity of the system to changes in the bias depended on the surface charge density. For larger-size particles, the contribution of the electrostatic force decreased, and the capillary force became the major contributor to the total adhesive force. The influence of water adsorption on the total adhesive force and, specifically, on the contribution of the electrostatic force depended on the hydrophobicity of interacting surfaces. For a hydrophilic surface, water adsorption either attenuated the surface charge or screened the effect of surface potential. An excessive amount of adsorbed water provided a path to surface charge leakage, which might cancel out the electrostatic force, leading to a reduction in the adhesive force. Theoretically calculated forces were comparable with measured adhesive forces except for mica which has a highly localized surface potential. The results of this study provide information on the behavior of charged colloidal particles in atmospheric systems.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Engineering surface charges of nanofiltration membranes to maximize Li + /Mg 2+ separation properties

Polyamide-based nanofiltration (NF) membranes are attractive for Li + /Mg 2+ separation for lithium recovery from salt brine (containing mainly Mg 2+ ). However, Li + and Mg 2+ have similar hydration radii, resulting in a low separation factor (SF Li/Mg ). Herein, we demonstrate that SF Li/Mg can be significantly enhanced by optimizing the membrane surface positive charges. This results in an unexpected maximum SF Li/Mg at a solution pH slightly below its isoelectric point (IEP). Specifically, NF270 membrane was surface-grafted with 2-(methacryloyloxy)ethyltrimethylammonium chloride (META) or polyethylenimine (PEI) using bio-adhesive dopamine, forming a thin, stable, charged layer (20–40 nm) on the surface. The effects of solution pH and surface modification on the surface zeta potential (ZP) and single- and mixed-salt Li + /Mg 2+ separation properties are thoroughly investigated. For example, the META grafting increases the ZP from 9.2 to 16 mV and SF Li/Mg by 130 % from 35 to 80 at pH 4, superior to the state-of-the-art commercial NF membranes. Furthermore, this surface modification occurs at ≈22 °C in aqueous solutions and can be utilized to enhance commercial modules for practical applications.

Li+/Mg2+ separation↗
DOE OSTI2017

Efficient Carrier Multiplication in Colloidal Silicon Nanorods

In this study, auger recombination lifetimes, absorption cross sections, and the quantum yields of carrier multiplication (CM), or multiexciton generation (MEG), were determined for solvent-dispersed silicon (Si) nanorods using transient absorption spectroscopy (TAS). Nanorods with an average diameter of 7.5 nm and aspect ratios of 6.1, 19.3, and 33.2 were examined. Colloidal Si nanocrystals of similar diameters were also studied for comparison. The nanocrystals and nanorods were passivated with organic ligands by hydrosilylation to prevent surface oxidation and limit the effects of surface trapping of photoexcited carriers. All samples used in the study exhibited relatively efficient photoluminescence. The Auger lifetimes increased with nanorod length, and the nanorods exhibited higher CM quantum yield and efficiency than the nanocrystals with a similar band gap energy E g . Beyond a critical length, the CM quantum yield decreases. Finally, nanorods with the aspect ratio of 19.3 had the highest CM quantum yield of 1.6 ± 0.2 at 2.9E g , which corresponded to a multiexciton yield that was twice as high as observed for the spherical nanocrystals.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Energetics of CO 2 and H 2 O adsorption on alkaline earth metal doped TiO 2

The process of CO 2 and H 2 O adsorption on the surface of nano-oxide semiconductors is important in the overall performance of artificial photosynthesis and other applications. In this study, we explored the thermodynamics of CO 2 and H 2 O adsorption on TiO 2 as a function of surface chemistry. We applied gas adsorption calorimetry to investigate the energetics of adsorption of those molecules on the surface of anatase nanoparticles. In an attempt to increase TiO 2 surface affinity to CO 2 and H 2 O, TiO 2 was doped with alkaline earth metals (MgO, CaO, SrO, and BaO) by manipulating the chemical synthesis. Adsorption studies using diffuse reflectance infrared spectroscopy at different temperatures indicate that due to the segregation of alkaline earth metals on the surface of TiO 2 nanoparticles, both CO 2 and subsequent H2O adsorption amounts could be increased. CO 2 adsorbs in two different manners, forming carbonates which can be removed at temperatures lower than 700 °C, and a more stable linear adsorption that remains even at 700 °C. Additionally to the surface energetic effects, doping also increased specific surface area, resulting in further improvement in net gas adsorption.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1985

Application of Modern Aperture Integration (AI) and Geometrical Theory of Diffraction (GTD) Techniques for Analysis of Large Reflector Antennas

The application of aperture integration (AI) and geometrical theory of diffraction (GTO) techniques to analyze large reflector antennas is outlined. The following techniques were used: computer modeling, validation of analysis and computer codes, computer aided design modifications, limitation on the conventional aperture integration (AIC) method, extended aperture integration (AIE) method, the AIE method for feed scattering calculations, near field probing predictions for 15 meter model, limitation on AIC for surface tolerance effects, aperture integration on the surface (AIS) method, and AIC and GTD calculations for compact range reflector.

Rudduck, R. C.↗
NASA NTRS1985

Ground Reflectance Measurements from Thematic Mapper Data

Satellite radiance data are measures of solar radiation that has been reflected by the Earth's surface and scattered and absorbed by atmospheric gases and aerosols. Of concern to geologists are the surface reflectance and the degrading effects on surface resolution and albedo contrast introduced by atmospheric phenomena. The objects of this research have been to: (1) provide an empirical relationship between scanner radiance and ground reflectance allowing interpretation of the satellite data in terms of the surface parameter, and (2) assess the precision with which surface spectral reflectance may be recovered from LANDSAT-4 TM data in the presence of perturbing atmospheric and instrumental factors. The approach is field-oriented, and utilizes ground observations of surface spectral reflectance with portable spectrometers and radiometers to develop the required empirical relationships.

Conel, J. E.↗
NASA NTRS1989

Microwave remote sensing and radar polarization signatures of natural fields

Theoretical models developed for simulation of microwave remote sensing of the Earth surface from airborne/spaceborne sensors are described. Theoretical model calculations were performed and the results were compared with data of field measurements. Data studied included polarimetric images at the frequencies of P band, L band, and C band, acquired with airborne polarimeters over a agricultural field test site. Radar polarization signatures from bare soil surfaces and from tree covered fields were obtained from the data. The models developed in this report include: (1) Small perturbation model of wave scatterings from randomly rough surfaces, (2) Physical optics model, (3) Geometrical optics model, and (4) Electromagnetic wave scattering from dielectric cylinders of finite lengths, which replace the trees and branches in the modeling of tree covered field. Additionally, a three-layer emissivity model for passive sensing of a vegetation covered soil surface is also developed. The effects of surface roughness, soil moisture contents, and tree parameters on the polarization signatures were investigated.

Mo, Tsan↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Outer Solar System

The session 'Outer Solar System" inlcuded:Monte Carlo Modeling of [O I] 630 nm Auroral Emission on Io; The Detection of Iron Sulfide on Io; Io and Loki in 2003 as Seen from the Infrared Telescope Facility Using Mutual Satellite and Jupiter Occultations; Mapping of the Zamama-Thor Region of Io; First Solar System Results of the Spitzer Space Telescope; Mapping the Surface of Pluto with the Hubble Space Telescope; Experimental Study on Fischer-Tropsch Catalysis in the Circum-Saturnian Subnebula; New High-Pressure Phases of Ammonia Dihydrate; Gas Hydrate Stability at Low Temperatures and High Pressures with Applications to Mars and Europa; Laboratory UV Photolysis of Planetary Ice Analogs Containing H2O + CO2 (1:1); The OH Stretch Infrared Band of Water Ice and Its Temperature and Radiation Dependence; Band Position Variations in Reflectance Spectra of the Jovian Satellite Ganymede; Comparison of Porosity and Radar Models for Europa s Near Surface; Combined Effects of Diurnal and Nonsynchronous Surface Stresses on Europa; Europa s Northern Trailing Hemisphere: Lineament Stratigraphic Framework; Europa at the Highest Resolution: Implications for Surface Processes and Landing Sites; Comparison of Methods to Determine Furrow System Centers on Ganymede and Callisto; Resurfacing of Ganymede by Liquid-Water Volcanism; Layered Ejecta Craters on Ganymede: Comparisons with Martian Analogs; Evaluation of the Possible Presence of CO2-Clathrates in Europa s Icy Shell or Seafloor; Geosciences at Jupiter s Icy Moons: The Midas Touch; Planetary Remote Sensing Science Enabled by MIDAS (Multiple Instrument Distributed Aperture Sensor); and In Situ Surveying of Saturn s Rings.

Source record↗