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At least 1,531 records · Page 85

Synergic Effects of Surface Chemistry and Applied Potentials on the Kinetics of the Electrocatalytic Oxygen Evolution Reaction in IrO 2

Improving the efficacy of the oxygen evolution reaction (OER) through water oxidation is critical for advancing photoelectrochemical water splitting. Among the catalysts, IrO 2 exhibits a high OER catalytic activity and stability under acidic conditions. The OER mechanism in this system has been a topic of intense research; however, many mechanistic understandings are lacking. In this work, we carried out first-principles calculations with an implicit solvation model at a constant potential to study the OER behavior on the IrO 2 (110) surface. We find that the surface hydrogen coverage has a significant effect on OER kinetics and transition states. We then develop a microkinetics model that accounts for the continuous evolution of both OER activation energy and hydrogen coverage as a function of an applied potential. We show that this inclusion leads to significant improvement in the simulated Tafel plot compared to available experiments. In conclusion, our results point to a complex interplay between surface chemistry and the applied potential on OER kinetics.

08 HYDROGEN↗

Evaluating Implementations of the Immersed Boundary Method in the Weather Research and Forecasting Model

The terrain-following coordinate system used by many atmospheric models can cause numerical instabilities due to discretization errors as resolved terrain slopes increase and the grid becomes highly skewed. The immersed boundary (IB) method, which does not require the grid to conform to the terrain, has been shown to alleviate these errors, and has been used successfully for high-resolution atmospheric simulations over steep terrain, including vertical building surfaces. Since many previous applications of IB methods to atmospheric models have used very fine grid resolution (5 m or less), the present study seeks to evaluate IB method performance over a range of grid resolutions and aspect ratios. Two classes of IB algorithms, velocity reconstruction and shear stress reconstruction, are tested within the common framework of the Weather Research and Forecasting (WRF) Model. Performance is evaluated in two test cases, one with flat terrain and the other with the topography of Askervein Hill, both under neutrally stratified conditions. WRF-IB results are compared to similarity theory, observations, and native WRF results. Despite sensitivity to the location at which the IB intersects the model grid, the velocity reconstruction IB method shows consistent performance when used with a hybrid RANS/LES surface scheme. The shear stress reconstruction IB method is not sensitive to the grid intersection, but is less consistent and near-surface velocity errors can occur at coarse resolutions. This study represents an initial investigation of IB method variability across grid resolutions in WRF. Future work will focus on improving IB method performance at intermediate to coarse resolutions.

54 ENVIRONMENTAL SCIENCES↗

An advanced terrain modeler for an autonomous planetary rover

A roving vehicle capable of autonomously exploring the surface of an alien world is under development and an advanced terrain modeler to characterize the possible paths of the rover as hazardous or safe is presented. This advanced terrain modeler has several improvements over the Troiani modeler that include: a crosspath analysis, better determination of hazards on slopes, and methods for dealing with missing returns at the extremities of the sensor field. The results from a package of programs to simulate the roving vehicle are then examined and compared to results from the Troiani modeler.

Hunter, E. L.↗

Quantitative non-destructive evaluation of porous composite materials based on ultrasonic wave propagation

Two complementary ultrasonic techniques for characterizing porosity in fiber-reinforced composite laminates are evaluated. Five uniaxial graphite-fiber/epoxy-matrix composites having a range of 1 to 8 percent volume fraction of solid glass inclusions to model porosity were investigated. In one technique, signal loss was measured in transmission mode and slope of attenuation, obtained from the first order coefficient of a two-parameter polynomial fit about the center frequency of the useful bandwidth, was used as the ultrasonic parameter to characterize the porosity. The results of these transmission mode measurements displayed a good correlation between the volume fraction of porosity and the slope of attenuation. Integrated polar backscatter was used as a second ultrasonic parameter for the characterization of the porosity in these samples. A single transducer insonified the samples and measured the resulting backscatter at a polar angle of 30 deg with respect to the normal of the sample surface with the azimuthal angles centered at 0 deg with respect to the fiber orientation (i.e., along the fibers). Integrated polar backscatter also displayed good correlation with the volume fraction of porosity.

Miller, James G.↗

The UV spectrum of Pluto-Charon - IUE observations from 2600 to 3100 A

Observations of the UV spectra of the Pluto-Charon system were obtained between 1987 and 1988 using the large aperture of the IUE long-wavelength prime spectrograph. At the resolution and SNR of the data, no gas-phase spectral identifications were made. The present data indicate a geometric albedo of 0.35 + or - 0.05. Curve fitting the geometric albedo from 2600-3100 A, a blue slope is found which corresponds to a decrease of about 12 percent per 1000 A. An albedo reversal or trough between about 3000 A and the shortest ground-based data (at about 3500 A) is noted which may be due to a spectral absorption feature on the surface.

Stern, S. Alan↗

Gravitational spreading of high terrain in Ishtar Terra, Venus

A plane-strain viscoelastic finite element algorithm derived by Melosh and Rafesky (1980, 1983) is used to model the gravitational spreading of the high topography of Ishtar Terra. Brittle failure and relaxation of topographic relief are predicted as functions of time for ranges of crustal thickness and thermal gradient and for observed ranges in topographic elevation and slope. For a crustal thickness greater than 10 km, a thermal gradient of 15 K/km or more, and average values of relief (3 km) and slope (3 deg), the topography relaxes to 25 percent of its original height in less than 10 m.y. Although initial failure, in the form of normal faulting on the highlands and margin and occasional shallow thrusting in the lowlands, is predicted to occur much earlier, values of horizontal surface strain that are likely to be observable (about 1 percent) do not accumulate until significant relaxation of relief begins.

Smrekar, Suzanne E.↗

Solar Power System Evaluated for the Human Exploration of Mars

The electric power system is a crucial element of any mission for the human exploration of the Martian surface. The bulk of the power generated will be delivered to crew life support systems, extravehicular activity suits, robotic vehicles, and predeployed in situ resource utilization (ISRU) equipment. In one mission scenario, before the crew departs for Mars, the ISRU plant operates for 435 days producing liquefied methane and oxygen for ascent-stage propellants and water for crew life support. About 200 days after ISRU production is completed, the crew arrives for a 500-day surface stay. In this scenario, the power system must operate for a total of 1130 days (equivalent to 1100 Martian "sols"), providing 400 MW-hr of energy to the ISRU plant and up to 18 kW of daytime user power. A photovoltaic power-generation system with regenerative fuel cell (RFC) energy storage has been under study at the NASA Glenn Research Center at Lewis Field. The conceptual power system is dominated by the 4000- m2 class photovoltaic array that is deployed orthogonally as four tent structures, each approximately 5 m on a side and 100-m long. The structures are composed of composite members deployed by an articulating mast, an inflatable boom, or rover vehicles, and are subsequently anchored to the ground. Array panels consist of thin polymer membranes with thin-film solar cells. The array is divided into eight independent electrical sections with solar cell strings operating at 600 V. Energy storage is provided by regenerative fuel cells based on hydrogen-oxygen proton exchange membrane technology. Hydrogen and oxygen reactants are stored in gaseous form at 3000 psi, and the water produced is stored at 14.7 psi. The fuel cell operating temperature is maintained by a 40-m2 deployable pumped-fluid loop radiator that uses water as the working fluid. The power management and distribution (PMAD) architecture features eight independent, regulated 600-Vdc channels. Power management and distribution power cables use various gauges of copper conductors with ethylene tetrafluoroethylene insulation. To assess power system design options and sizing, we developed a dedicated Fortran code to predict detailed power system performance and estimate system mass. This code also modeled the requisite Mars surface environments: solar insolation, Sun angles, dust storms, dust deposition, and thermal and ultraviolet radiation. Using this code, trade studies were performed to assess performance and mass sensitivities to power system design parameters (photovoltaic array geometry and orientation) and mission parameters (landing date and landing site latitude, terrain slope, and dust storm activity). Mission analysis cases were also run. Power results are shown in this graph for an analysis case with a September 1, 2012, landing date; 18.95 North latitude landing site; two seasonal dusts storms; and tent arrays. To meet user load requirements and the ISRU energy requirement, an 8-metric ton (MT) power system and 4000-m2 photovoltaic array area were required for the assumed advanced CuInS2 thin-film solar cell technology. In this figure, the top curve is the average daytime photovoltaic array power, the middle curve is average daytime user load power, and the bottom curve is nighttime power. At mission day 1, daytime user power exceeds 120 kW before falling off to 80 kW at the end of the mission. Throughout the mission, nighttime user power is set to the nighttime power requirement. In this analysis, "nighttime" is defined as the 13- to 15-hr period when array power output is below the daytime power requirement. During dust storms, power system capability falls off dramatically so that by mission day 900, a daily energy balance cannot be maintained. Under these conditions, the ISRU plant is placed in standby mode, and the regenerative fuel cell energy storage is gradually discharged to meet user loads.

Kerslake, Thomas W.↗

Assessment of dual-point drag reduction for an executive-jet modified airfoil section

This paper presents aerodynamic characteristics and pressure distributions for an executive-jet modified airfoil and discusses drag reduction relative to a baseline airfoil for two cruise design points. A modified airfoil was tested in the adaptive-wall test section of the NASA Langley 0.3-Meter Transonic Cryogenic Tunnel (0.3-m TCT) for Mach numbers ranging from 0.250 to 0.780 and chord Reynolds numbers ranging from 3.0 x 10(exp 6) to 18.0 x 10(exp 6). The angle of attack was varied from minus 2 degrees to almost 10 degrees. Boundary-layer transition was fixed at 5 percent of chord on both the upper and lower surfaces of the model for most of the test. The two design Mach numbers were 0.654 and 0.735, chord Reynolds numbers were 4.5 x 10(exp 6) and 8.9 x 10(exp 6), and normal-force coefficients were 0.98 and 0.51. Test data are presented graphically as integrated force and moment coefficients and chordwise pressure distributions. The maximum normal-force coefficient decreases with increasing Mach number. At a constant normal-force coefficient in the linear region, as Mach number increases an increase occurs in the slope of normal-force coefficient versus angle of attack, negative pitching-moment coefficient, and drag coefficient. With increasing Reynolds number at a constant normal-force coefficient, the pitching-moment coefficient becomes more negative and the drag coefficient decreases. The pressure distributions reveal that when present, separation begins at the trailing edge as angle of attack is increased. The modified airfoil, which is designed with pitching moment and geometric constraints relative to the baseline airfoil, achieved drag reductions for both design points (12 and 22 counts). The drag reductions are associated with stronger suction pressures in the first 10 percent of the upper surface and weakened shock waves.

Allison, Dennis O.↗

Extremely Small Sizes for Faint z ∼ 2–8 Galaxies in the Hubble Frontier Fields: A Key Input for Establishing Their Volume Density and UV Emissivity

We provide the first observational constraints on the sizes of the faintest galaxies lensed by the Hubble Frontier Fields (HFF) clusters. Ionizing radiation from faint galaxies likely drives cosmic reionization, and the HFF initiative provides a key opportunity to find such galaxies. However, we cannot assess their ionizing emissivity without a robust measurement of their sizes, since this is key to quantifying both their prevalence and the faint-end slope to the UV luminosity function. Here we provide the first size constraints with two new techniques. The first utilizes the fact that the detectability of highly magnified galaxies as a function of shear is very dependent on a galaxy’s size. Only the most compact galaxies remain detectable in high-shear regions (versus a larger detectable size range for low shear), a phenomenon we quantify using simulations. Remarkably, however, no correlation is found between the surface density of faint galaxies and the predicted shear, using 87 high-magnification (μ=10–100) z∼2–8 galaxies seen behind the first four HFF clusters. This can only be the case if faint (∼−15 mag) galaxies have significantly smaller sizes than more luminous galaxies, i.e., ≲30 mas or 160–240 pc. As a second size probe, we rotate and stack 26 faint high-magnification sources along the major shear axis. Less elongation is found even for objects with an intrinsic half-light radius of 10 mas. Together, these results indicate that extremely faint z∼2–8 galaxies have near point-source profiles (half-light radii <30 mas and perhaps 5–10 mas). These results suggest smaller completeness corrections and hence shallower faint-end slopes for the z∼2–8 LFs than derived in some recent studies (by Δα≳0.1–0.3).

79 ASTRONOMY AND ASTROPHYSICS↗

Iron and iron-bound phosphate accumulate in surface soils of ice-wedge polygons in arctic tundra

Phosphorus (P) is a limiting or co-limiting nutrient to plants and microorganisms in diverse ecosystems that include the arctic tundra. Certain soil minerals can adsorb or co-precipitate with phosphate, and this mineral-bound P provides a potentially large P reservoir in soils. Iron (Fe) oxyhydroxides have a high capacity to adsorb phosphate; however, the ability of Fe oxyhydroxides to adsorb phosphate and limit P bioavailability in organic tundra soils is not known. In this study, we examined the depth distribution of soil Fe and P species in the active layer (<30 cm) of low-centered and high-centered ice-wedge polygons at the Barrow Environmental Observatory on the Alaska North Slope. Soil reservoirs of Fe and P in bulk horizons and in narrower depth increments were characterized using sequential chemical extractions and synchrotron-based X-ray absorption spectroscopy (XAS). Organic horizons across all polygon features ( e.g. , trough, ridge, and center) were enriched in extractable Fe and P relative to mineral horizons. Soil Fe was dominated by organic-bound Fe and short-range ordered Fe oxyhydroxides, while soil P was primarily associated with oxides and organic matter in organic horizons but apatite and/or calcareous minerals in mineral horizons. Iron oxyhydroxides and Fe-bound inorganic P (P i ) were most enriched at the soil surface and decreased gradually with depth, and Fe-bound P i was >4× greater than water-soluble P i . These results demonstrate that Fe-bound P i is a large and ecologically important reservoir of phosphate. We contend that Fe oxyhydroxides and other minerals may regulate P i solubility under fluctuating redox conditions in organic surface soils on the arctic tundra.

54 ENVIRONMENTAL SCIENCES↗

Morphologies of ∼190,000 galaxies at z = 0–10 revealed with HST legacy data. I. size evolution

We present the redshift evolution of the galaxy effective radius r{sub e} obtained from the Hubble Space Telescope (HST) samples of ∼190,000 galaxies at z = 0–10. Our HST samples consist of 176,152 photo-z galaxies at z = 0–6 from the 3D-HST+CANDELS catalog and 10,454 Lyman break galaxies (LBGs) at z = 4–10 identified in the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey (CANDELS), HUDF 09/12, and HFF parallel fields, providing the largest data set to date for galaxy size evolution studies. We derive r{sub e} with the same technique over the wide redshift range of z = 0–10, evaluating the optical-to-UV morphological K correction and the selection bias of photo-z galaxies+LBGs as well as the cosmological surface-brightness dimming effect. We find that r{sub e} values at a given luminosity significantly decrease toward high z, regardless of statistics choices (e.g., r{sub e}∝(1+z){sup −1.10±0.06} for median). For star-forming galaxies, there is no evolution of the power-law slope of the size–luminosity relation and the median Sérsic index (n∼1.5). Moreover, the r{sub e} distribution is well represented by log-normal functions whose standard deviation σ{sub lnr{sub e}} does not show significant evolution within the range of σ{sub lnr{sub e}}∼0.45−0.75. We calculate the stellar-to-halo size ratio from our r{sub e} measurements and the dark-matter halo masses estimated from the abundance-matching study, and we obtain a nearly constant value of r{sub e}/r{sub vir}=1.0%−3.5% at z = 0–8. The combination of the r{sub e}-distribution shape+standard deviation, the constant r{sub e}/r{sub vir}, and n∼1.5 suggests a picture in which typical high-z star-forming galaxies have disk-like stellar components in a sense of dynamics and morphology over cosmic time of z∼0−6. If high-z star-forming galaxies are truly dominated by disks, the r{sub e}/r{sub vir} value and the disk-formation model indicate that the specific angular momentum of the disk normalized by the host halo is j{sub d}/m{sub d}≃0.5−1. These are statistical results for major stellar components of galaxies, and the detailed study of clumpy subcomponents is presented in the paper II.

79 ASTRONOMY AND ASTROPHYSICS↗

Alignment Implementation for Manufacturing using Fringe Analysis Slope Technique (AIMFAST) 2018.11.20

AIMFAST is a software code used to align facets on a dish or heliostat solar concentrator to a specific aimpoint strategy to minimize peak fluxes and maximize system optical performance. AIMFAST uses a large monitor or projection screen to display fringe patterns, and a machine vision camera to image the reflection of these patterns in the subject dish mirrors. From these images, a detailed map of surface normals can be generated and compared to design or fitted mirror shapes. This fitted comparison is then used to develop a single vector representing the orientation of the facets relative to the design orientation and provide near-real-time adjustment information to a communicating computer. The communicating computer can display adjustments or directly interface with adjustment tools.

Yellowhair, Julius↗

Diagenesis is key to unlocking outcrop fracture data suitable for quantitative extrapolation to geothermal targets

Exceptionally large, well-exposed sandstone outcrops in New York provide insights into folds, deformation bands, and fractures that could influence permeability, heat exchange, and stimulation outcomes of geothermal reservoir targets. Cambrian Potsdam Sandstone with <5% porosity contains decimeter-scale open, angular-limbed monoclines <0.5 km apart with associated low-porosity mm-wide cataclastic deformation bands. Crossing and abutting relationships among sub-vertical opening-mode fractures show four chronological Sets A–D, striking NNW, NE, NW, and ENE, respectively. Fracture lengths and heights range from millimeters to tens of meters. Sets A and C macro-fractures, and possibly B and D, contain quartz deposits. All sets have abundant associated quartz cemented microfractures that also record set orientations and crosscutting relations. Quartz cement deposits—evidence of diagenesis—are the key to identifying attributes of outcrop fractures suitable for extrapolation to geothermal targets in sandstones because they show which fractures formed in the subsurface. Set A fluid inclusion homogenization temperatures (120°C–129°C) are compatible with fracture at >3 km depth. Fractures are stiff and those ≥0.05 mm (Set C) and ≥0.1 mm (Set A) are open and potentially conducive to flow. Sets A and D are abundant in outcrops with close fracture spacing—0.18 m and 0.68 m, respectively—and define a rectangular connectivity network dominated by crossing and abutting X and Y nodes. Set A aperture distributions follow a power law with slope –0.8 up to 0.15 mm; other sets have lognormal distributions. Set A and D microfractures are weakly clustered, while macro-fractures commonly have 1D anticlustered (regular or periodic) arrangements at shorter length scales (<0.2 m). Sub-horizontal fractures are barren and may have formed near the surface. Fracture heights, lengths, and spatial arrangements show good trace connectivity but low open connectivity. For geothermal applications, outcrop results predict low initial well-test permeabilities owing to quartz disconnecting open fractures, but stimulation of closely spaced microfractures and partly open macro-fractures could yield high surface area for heat exchange. Quantitative extrapolation of key fracture attributes like abundance, orientation, spatial arrangement, length, and open fracture connectivity is possible from outcrops to fractured reservoirs if differing thermal histories and diagenesis are accounted for.

02 PETROLEUM↗

The process of crater removal in the lunar maria, part P

Near-terminator photography from the Apollo 14 and 15 missions is used as a basis to evaluate the processes by which craters disappear from the lunar surface. From observations and analyses it is concluded that: (1) The erosion of lunar craters in the size range of 10 m to 1 km is effected principally by small impacts producing minute changes in crater form up to the point where the crater is worn to an interior slope of approximately 1 degree. Below that slope, the annihilation process is dominated by the formation of younger overlapping craters. (2) The distribution of shapes of craters in this size range can be explained as resulting from impact generated processes.

Soderblom, L. A.↗

The first UV spectrum of Triton - IUE observations from 2600 to 3200 A

The results of the first observations of Triton's spectrum below 3300 A are reported. Triton's 2700 A geometric albedo is found to be 0.28 + or - 0.04. The albedo increases monotonically from 2600 to 3200 A, with a slope of 0.13 + or - 0.03 per 1000 A. This positive slope is qualitatively similar to, but shallower than, Triton's visible albedo slope and argues against a strong Rayleigh scattering signature. Triton's integrated flux is found to be 1.5 times Pluto's, indicating Triton to be either more reflective in the UV, or bigger, or both. The redness of Triton's visible and UV colors argues against an extremely bright surface and for a larger radius than Pluto's. A lower limit on the radius of 1240 + or - 90 km is derived. The spectrum observed by IUE is consistent with either an icy surface or a suspended aerosol layer which preferentially absorbs UV light.

Stern, S. Alan↗

Scientific rationale for selecting northwest Isidis Planitia (14 deg - 17 deg N latitude, 278 deg - 281 deg longitude) as a potential Mars Pathfinder landing site

The northwest Isidis Basin offers a unique opportunity to land near a fretted terrain lowland/upland boundary that meets both the latitudinal and elevation requirements imposed on the spacecraft. The landing site lies east of erosional scarps and among remnant massif inselbergs of the Syrtis Major volcanic plains. The plains surface throughout Isidis exhibits abundant, low-relief mounds that are the local expression of the 'thumbprint terrain' that is common within a few hundred kilometers of the lowland/upland boundary. The massif inselbergs are not as numerous nor as massive as those fretted terrains to the northwest, so local slopes are not expected to be steep. Neither feature should pose a serious threat to the lander. Landing on or adjacent to one of these features would enhance the science return and would help to pinpoint the landing site in Viking and subsequent orbiter images by offering views of landmarks beyond the local horizon.

Parker, Tim J.↗

Comparison of Inflation Processes at the 1859 Mauna Loa Flow, HI, and the McCartys Flow Field, NM

Basaltic lavas typically form channels or tubes during flow emplacement. However, the importance of sheet flow in the development of basalt ic terrains received recognition over the last 15 years. George Walke r?s research on the 1859 Mauna Loa Flow was published posthumously in 2009. In this paper he discusses the concept of endogenous growth, or inflation, for the distal portion of this otherwise channeldominated lava flow. We used this work as a guide when visiting the 1859 flow to help us better interpret the inflation history of the McCartys flow field in NM. Both well preserved flows display similar clues about the process of inflation. The McCartys lava flow field is among the you ngest (approx.3000 yrs) basaltic lava flows in the continental United States. It was emplaced over slopes of <1 degree, which is similar to the location within the 1859 flow where inflation occurred. Although older than the 1859 flow, the McCartys is located in an arid environ ment and is among the most pristine examples of sheet flow morphologies. At the meter scale the flow surface typically forms smooth, undula ting swales that create a polygonal terrain. The literature for simil ar features includes multiple explanatory hypotheses, original breakouts from adjacent lobes, or inflation related upwarping of crust or sa gging along fractures that enable gas release. It is not clear which of these processes is responsible for polygonal terrains, and it is po ssible that one explanation is not the sole cause of this morphology between all inflated flows. Often, these smooth surfaces within an inflated sheet display lineated surfaces and occasional squeeze-ups alon g swale contacts. We interpret the lineations to preserve original fl ow direction and have begun mapping these orientations to better interpret the emplacement history. At the scale of 10s to 100s of meters t he flow comprises multiple topographic plateaus and depressions. Some depressions display level floors with surfaces as described above, while some are bowl shaped with floors covered in broken lava slabs. Th e boundaries between plateaus and depressions are also typically smoo th, grooved surfaces that have been tilted to angles sometimes approaching vertical. The upper margin of these tilted surfaces displays lar ge cracks, sometimes containing squeeze-ups. The bottom boundary with smooth floored depressions typically shows embayment by younger lavas. It appears that this style of terrain represents the emplacement of an extensive sheet that experiences inflation episodes within prefer red regions where lateral spreading of the sheet is inhibited, thereby forming plateaus. Depressions are often the result of non-inflation and can be clearly identified by lateral squeeze-outs along the pit walls that form when the rising crust exposes the still liquid core of the sheet. Our current efforts are focused on.

Bleacher, Jacob E.↗