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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,549 records · Page 86
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Single-cell multimodal imaging uncovers energy conversion pathways in biohybrids

Microbe–semiconductor biohybrids, which integrate microbial enzymatic synthesis with the light-harvesting capabilities of inorganic semiconductors, have emerged as promising solar-to-chemical conversion systems. Improving the electron transport at the nano–bio interface and inside cells is important for boosting conversion efficiencies, yet the underlying mechanism is challenging to study by bulk measurements owing to the heterogeneities of both constituents. Here we develop a generalizable, quantitative multimodal microscopy platform that combines multi-channel optical imaging and photocurrent mapping to probe such biohybrids down to single- to sub-cell/particle levels. We uncover and differentiate the critical roles of different hydrogenases in the lithoautotrophic bacterium Ralstonia eutropha for bioplastic formation, discover this bacterium’s surprisingly large nanoampere-level electron-uptake capability, and dissect the cross-membrane electron-transport pathways. Furthermore, this imaging platform, and the associated analytical framework, can uncover electron-transport mechanisms in various types of biohybrid, and potentially offers a means to use and engineer R. eutropha for efficient chemical production coupled with photocatalytic materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1997

Computational Fluid Dynamics Analysis Method Developed for Rocket-Based Combined Cycle Engine Inlet

Renewed interest in hypersonic propulsion systems has led to research programs investigating combined cycle engines that are designed to operate efficiently across the flight regime. The Rocket-Based Combined Cycle Engine is a propulsion system under development at the NASA Lewis Research Center. This engine integrates a high specific impulse, low thrust-to-weight, airbreathing engine with a low-impulse, high thrust-to-weight rocket. From takeoff to Mach 2.5, the engine operates as an air-augmented rocket. At Mach 2.5, the engine becomes a dual-mode ramjet; and beyond Mach 8, the rocket is turned back on. One Rocket-Based Combined Cycle Engine variation known as the "Strut-Jet" concept is being investigated jointly by NASA Lewis, the U.S. Air Force, Gencorp Aerojet, General Applied Science Labs (GASL), and Lockheed Martin Corporation. Work thus far has included wind tunnel experiments and computational fluid dynamics (CFD) investigations with the NPARC code. The CFD method was initiated by modeling the geometry of the Strut-Jet with the GRIDGEN structured grid generator. Grids representing a subscale inlet model and the full-scale demonstrator geometry were constructed. These grids modeled one-half of the symmetric inlet flow path, including the precompression plate, diverter, center duct, side duct, and combustor. After the grid generation, full Navier-Stokes flow simulations were conducted with the NPARC Navier-Stokes code. The Chien low-Reynolds-number k-e turbulence model was employed to simulate the high-speed turbulent flow. Finally, the CFD solutions were postprocessed with a Fortran code. This code provided wall static pressure distributions, pitot pressure distributions, mass flow rates, and internal drag. These results were compared with experimental data from a subscale inlet test for code validation; then they were used to help evaluate the demonstrator engine net thrust.

Source record↗
NASA NTRS2018

The Jetting Phenomena in Meshed Spur Gears

Rotorcraft gearbox transmissions are required to efficiently transfer power from the turbine engine to the main and tail rotor blades. Losses in transmission efficiency impact mission payload and aircraft range. These systems are expected to deliver high power with high gear pitch line velocities. More recently, shrouding has been employed to reduce windage power losses associated with the high gear rotational speeds. However, recent experimental results from tests conducted by the authors show the negative impact of close clearance shrouds on windage power loss, particularly at the meshed region where flow is ejected, or jetted, from the collapsing tooth spaces. A literature review was conducted to gain further insight into the phenomenon of gear mesh jetting and strategies to mitigate and control the associated losses. An analysis was conducted on windage losses in the mesh region. Test results are given for a modified shroud configuration. Finally, a discussion on observed trends follows with suggestions on future research.

windage↗
NASA NTRS2018

The Jetting Phenomena in Meshed Spur Gears

Rotorcraft gearbox transmissions are required to efficiently transfer power from the turbine engine to the main and tail rotor blades. Losses in transmission efficiency impact mission payload and aircraft range. These systems are expected to deliver high power with high gear pitch line velocities. More recently, shrouding has been employed to reduce windage power losses associated with the high gear rotational speeds. However, recent experimental results from tests conducted by the authors show the negative impact of close clearance shrouds on windage power loss, particularly at the meshed region where flow is ejected, or jetted, from the collapsing tooth spaces. A literature review was conducted to gain further insight into the phenomenon of gear mesh jetting and strategies to mitigate and control the associated losses. An analysis was conducted on windage losses in the mesh region. Test results are given for a modified shroud configuration. Finally, a discussion on observed trends follows with suggestions on future research.

Gear↗
NASA NTRS2018

Jetting Phenomenon in Meshed Spur Gears

Rotorcraft gearbox transmissions are required to efficiently transfer power from the turbine engine to the main and tail rotor blades. Losses in transmission efficiency impacts mission payload and aircraft range. These systems are expected to deliver high power with high gear pitch line velocities. More recently, shrouding has been employed to reduce windage power losses associated with the high gear rotational speeds. However, recent experimental results from tests conducted by the authors show the negative impact of close clearance shrouds on windage power loss, particularly at the meshed region where flow is ejected, or jetted, from the collapsing tooth spaces. A literature review was conducted to gain further insight into the phenomenon of gear mesh jetting and strategies to mitigate and control the associated losses. A discussion on observed trends follows with suggestions on future research.

power loss↗
DOE OSTI2021

Crabtree/Warburg-like aerobic xylose fermentation by engineered Saccharomyces cerevisiae

Bottlenecks in the efficient conversion of xylose into cost-effective biofuels have limited the widespread use of plant lignocellulose as a renewable feedstock. The yeast Saccharomyces cerevisiae ferments glucose into ethanol with such high metabolic flux that it ferments high concentrations of glucose aerobically, a trait called the Crabtree/Warburg Effect. In contrast to glucose, most engineered S. cerevisiae strains do not ferment xylose at economically viable rates and yields, and they require respiration to achieve sufficient xylose metabolic flux and energy return for growth aerobically. Here, we evolved respiration-deficient S. cerevisiae strains that can grow on and ferment xylose to ethanol aerobically, a trait analogous to the Crabtree/Warburg Effect for glucose. Through genome sequence comparisons and directed engineering, we determined that duplications of genes encoding engineered xylose metabolism enzymes, as well as TKL1, a gene encoding a transketolase in the pentose phosphate pathway, were the causative genetic changes for the evolved phenotype. Reengineered duplications of these enzymes, in combination with deletion mutations in HOG1, ISU1, GRE3, and IRA2, increased the rates of aerobic and anaerobic xylose fermentation. Importantly, we found that these genetic modifications function in another genetic background and increase the rate and yield of xylose-to-ethanol conversion in industrially relevant switchgrass hydrolysate, indicating that these specific genetic modifications may enable the sustainable production of industrial biofuels from yeast. We propose a model for how key regulatory mutations prime yeast for aerobic xylose fermentation by lowering the threshold for overflow metabolism, allowing mutations to increase xylose flux and to redirect it into fermentation products.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1985

Ceramic automotive Stirling engine study

A conceptual design study for a Ceramic Automotive Stirling Engine (CASE) is performed. Year 1990 structural ceramic technology is assumed. Structural and performance analyses of the conceptual design are performed as well as a manufacturing and cost analysis. The general conclusions from this study are that such an engine would be 10-26% more efficient over its performance map than the current metal Automotive Stirling Reference Engine (ASRE). Cost of such a ceramic engine is likely to be somewhat higher than that of the ASRE but engine cost is very sensitive to the ultimate cost of the high purity, ceramic powder raw materials required to fabricate high performance parts. When the design study is projected to the year 2000 technology, substantinal net efficiency improvements, on the order of 25 to 46% over the ASRE, are computed.

Musikant, S.↗
DOE OSTI2023

Engineering Enzymes for Environmental Sustainability

The development and implementation of more efficient and sustainable technologies is key to delivering our net–zero targets. Here we review how engineered enzymes, with a focus on those developed using directed evolution, can be deployed to improve the sustainability of numerous processes and help to conserve our environment. Efficient and robust biocatalysts have been engineered to capture carbon dioxide (CO2) and have been embedded into new efficient metabolic CO2 fixation pathways. Enzymes have been refined for bioremediation, enhancing their ability to degrade toxic and harmful pollutants. Biocatalytic recycling is gaining momentum, with engineered cutinases and PETases developed for the depolymerization of the abundant plastic, PET. Finally, biocatalytic approaches for accessing petroleum–based feedstocks and chemicals are expanding, using optimized enzymes to convert plant biomass into biofuels or other high value products. Finally, through these examples, we hope to illustrate how enzyme engineering and biocatalysis can contribute to the development of more environmentally sustainable approaches, in order to protect our planet.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Molecular Fe-N 4 Moieties Coupled with Atomic Co-N 4 Sites Toward Improved Oxygen Reduction Performance

Research on high-efficiency and cost-efficient catalysts for oxygen reduction reaction (ORR) is still a vital but challenging issue for commercializing metal–air batteries. Herein, a single-molecule/atom hybrid catalyst is developed to boost the ORR, in which iron phthalocyanine molecules containing molecular Fe-N 4 moieties couple with atomic Co-N 4 sites on the surface of polyhedral carbon. Density functional theory calculations reveal that face-to-face laminated construction of Fe-N 4 and Co-N 4 in the hybrid catalyst can effectively modulate the electronic structure of active iron atoms and reduce the energy barrier of the rate-determining step for ORR. As a result, this hybrid catalyst demonstrates excellent ORR performance, featuring a half-wave potential of 0.904 V, a peak power density of 238.3 mW cm -2 for zinc–air battery, and outstanding electrocatalytic stability. Here, this work offers a distinctive and robust molecular/atomic engineering approach to creating efficient electrocatalysts, advancing the fields of metal–air batteries.

36 MATERIALS SCIENCE↗
NASA NTRS2005

Nano-engineered Multiwall Carbon Nanotube-copper Composite Thermal Interface Material for Efficient Heat Conduction

Efforts in integrated circuit (IC) packaging technologies have recently been focused on management of increasing heat density associated with high frequency and high density circuit designs. While current flip-chip package designs can accommodate relatively high amounts of heat density, new materials need to be developed to manage thermal effects of next-generation integrated circuits. Multiwall carbon nanotubes (MWNT) have been shown to significantly enhance thermal conduction in the axial direction and thus can be considered to be a candidate for future thermal interface materials by facilitating efficient thermal transport. This work focuses on fabrication and characterization of a robust MWNT-copper composite material as an element in IC package designs. We show that using vertically aligned MWNT arrays reduces interfacial thermal resistance by increasing conduction surface area, and furthermore, the embedded copper acts as a lateral heat spreader to efficiently disperse heat, a necessary function for packaging materials. In addition, we demonstrate reusability of the material, and the absence of residue on the contacting material, both novel features of the MWNT-copper composite that are not found in most state-of-the-art thermal interface materials. Electrochemical methods such as metal deposition and etch are discussed for the creation of the MWNT-Cu composite, detailing issues and observations with using such methods. We show that precise engineering of the composite surface affects the ability of this material to act as an efficient thermal interface material. A thermal contact resistance measurement has been designed to obtain a value of thermal contact resistance for a variety of different thermal contact materials.

Ngo, Quoc↗
DOE OSTI2021

Identification and analysis of sugar transporters capable of co–transporting glucose and xylose simultaneously

Simultaneous co-fermentation of glucose and xylose is a key desired trait of engineered Saccharomyces cerevisiae for efficient and rapid production of biofuels and chemicals. However, glucose strongly inhibits xylose transport by endogenous hexose transporters of S. cerevisiae. We identified structurally distant sugar transporters (Lipomyces starkeyi LST1_205437 and Arabidopsis thaliana AtSWEET7) capable of co-transporting glucose and xylose from previously unexplored oleaginous yeasts and plants. Kinetic analysis showed that LST1_205437 had lenient glucose inhibition on xylose transport and AtSWEET7 transported glucose and xylose simultaneously with no inhibition. Modelling studies of LST1_205437 revealed that Ala335 residue at sugar binding site can accommodates both glucose and xylose. Docking studies with AtSWEET7 revealed that Trp59, Trp183, Asn145, and Asn179 residues stabilized the interactions with sugars, allowing both xylose and glucose to be co-transported. In addition, we altered sugar preference of LST1_205437 by single amino acid mutation at Asn365. Furthermore, our findings provide a new mechanistic insight on glucose and xylose transport mechanism of sugar transporters and the identified sugar transporters can be employed to develop engineered yeast strains for producing cellulosic biofuels and chemicals.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2022

Bioinspired and biomolecular catalysts for energy conversion and storage

Metalloenzymes are remarkable for facilitating challenging redox transformations with high efficiency and selectivity. In the area of alternative energy, scientists aim to capture these properties in bioinspired and engineered biomolecular catalysts for the efficient and fast production of fuels from low-energy feedstocks such as water and carbon dioxide. In this short review, efforts to mimic biological catalysts for proton reduction and carbon dioxide reduction are highlighted. Two important recurring themes are the importance of the microenvironment of the catalyst active site and the key role of proton delivery to the active site in achieving desired reactivity. As a result, perspectives on ongoing and future challenges are also provided.

14 SOLAR ENERGY↗
NASA NTRS1952

Investigation at Mach Numbers 2.98 and 2.18 of Axially Symmetric Free-jet Diffusion with a Ram-jet Engine

An investigation was conducted to determine the effectiveness of a free-jet diffuser in reducing the over-all pressure ratios required to operate a free jet with a large air-breathing engine as a test vehicle. Efficient operation of the free jet was determined with and without the considerations required for producing suitable engine-inlet flow conditions. A minimum operating pressure ration of 5.5 was attained with a ratio of nozzle-exit to engine-inlet area of 1.85. Operation of the free jet with unstable engine-inlet flow (buzz) is also included.

WIND TUNNELS↗
NASA NTRS1956

Effect of an Adjustable Supersonic Inlet on the Performance up to Mach Number 2.0 of a J34 Turbojet Engine

A J34 turbojet engine was investigated at free-stream Mach numbers of 0.12 and 1.6 to 2.0 to determine the effect of supersonic inlet operation on engine performance. With the excepetion of ideal jet thrust, the use of generalized engine parameters correlated the engine data satisfactorily when the exit nozzle was choked. Large total-pressure distortations did not affect compressor efficiency. During inlet pulsing, the engine operated with compressor-inlet total-pressure variations as large as 18 percent of the local average and at frequnecies of 17 plus or minus 2 cycles per second. Total-pressure amplitudes propagated through the engine and caused ideal-gross-thrust changes up to 12 percent.

Beke, Andrew↗
DOE OSTI2018

Modeling occupancy distribution in large spaces with multi-feature classification algorithm

We present that occupancy information enables robust and flexible control of heating, ventilation, and air-conditioning (HVAC) systems in buildings. In large spaces, multiple HVAC terminals are typically installed to provide cooperative services for different thermal zones, and the occupancy information determines the cooperation among terminals. However, a person count at room-level does not adequately optimize HVAC system operation due to the movement of occupants within the room that creates uneven load distribution. Without accurate knowledge of the occupants’ spatial distribution, the uneven distribution of occupants often results in under-cooling/heating or over-cooling/heating in some thermal zones. Therefore, the lack of high-resolution occupancy distribution is often perceived as a bottleneck for future improvements to HVAC operation efficiency. To fill this gap, this study proposes a multi-feature k-Nearest-Neighbors (k-NN) classification algorithm to extract occupancy distribution through reliable, low-cost Bluetooth Low Energy (BLE) networks. An on-site experiment was conducted in a typical office of an institutional building to demonstrate the proposed methods, and the experiment outcomes of three case studies were examined to validate detection accuracy. One method based on City Block Distance (CBD) was used to measure the distance between detected occupancy distribution and ground truth and assess the results of occupancy distribution. Finally, the results show the accuracy when CBD = 1 is over 71.4% and the accuracy when CBD = 2 can reach up to 92.9%.

42 ENGINEERING↗
NASA NTRS2016

Advanced Control Considerations for Turbofan Engine Design

This paper covers the application of a model-based engine control (MBEC) methodology featuring a self tuning on-board model for an aircraft turbofan engine simulation. The nonlinear engine model is capable of modeling realistic engine performance, allowing for a verification of the advanced control methodology over a wide range of operating points and life cycle conditions. The on-board model is a piece-wise linear model derived from the nonlinear engine model and updated using an optimal tuner Kalman Filter estimation routine, which enables the on-board model to self-tune to account for engine performance variations. MBEC is used here to show how advanced control architectures can improve efficiency during the design phase of a turbofan engine by reducing conservative operability margins. The operability margins that can be reduced, such as stall margin, can expand the engine design space and offer potential for efficiency improvements. Application of MBEC architecture to a nonlinear engine simulation is shown to reduce the thrust specific fuel consumption by approximately 1% over the baseline design, while maintaining safe operation of the engine across the flight envelope.

control↗
DOE OSTI2025

Ligation of Single-Site Ruthenium within Perovskite Oxides for Efficient Conversion of Thermodynamically Stable Molecules

Ru cation ligation in SrTiO 3 perovskite and their migration to the surface through exsolution are investigated for the dry reforming of methane (DRM), a chemistry that requires activation of two thermodynamically stable molecules, CH 4 and CO 2 . Compared to a supported 1 wt % Ru/SrTiO 3 benchmark, doped and exsolved Ru-SrTiO 3 demonstrate ≥3× higher CH 4 turnover rates (873 K), with isolated, ligated Ru exhibiting higher reactivity. Reactor studies assert that CH 4 and CO 2 activation are both kinetically relevant for CH 4 turnover rates on exsolved Ru-SrTiO 3 , unlike for supported Ru systems, where H-abstraction from CH 4 is the sole kinetically relevant step. As such, exsolved and doped Ru architectures are responsive toward co-reactant activation strategies, with their consequent reaction networks showing marked departures from those established for supported Ru catalysts. In situ spectroscopy and kinetic analyses propose distinct sensitivity toward CO 2 on Ru-SrTiO 3 systems, where higher CH4 turnover rates result from O-assisted C─H bond activation pathways. These pathways occur on paired Ru-oxygen vacancy sites that are inherent to the perovskite structure and are not readily accessible on supported Ru catalysts. Here, CO 2 is activated on oxygen vacancies directly adjacent to Ru active sites, which facilitates CH 4 C─H bond activation through a surface methoxy intermediate. The high reactivity of Ru-SrTiO 3 systems enables stable CH 4 turnover rates at milder reaction temperatures (673 K), conditions under which the supported counterpart, Ru/SrTiO 3 , is inactive. Overall, this work demonstrates that ligation of catalytically active cations in perovskite oxides facilitates site engineering toward atom-efficient activation of thermodynamically stable feedstocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1926

Fuels for high-compression engines

From theoretical considerations one would expect an increase in power and thermal efficiency to result from increasing the compression ratio of an internal combustion engine. In reality it is upon the expansion ratio that the power and thermal efficiency depend, but since in conventional engines this is equal to the compression ratio, it is generally understood that a change in one ratio is accompanied by an equal change in the other. Tests over a wide range of compression ratios (extending to ratios as high as 14.1) have shown that ordinarily an increase in power and thermal efficiency is obtained as expected provided serious detonation or preignition does not result from the increase in ratio.

Sparrow, Stanwood W↗