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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,549 records · Page 86

Uncertainty quantification for evaluating impacts of caprock and reservoir properties on pressure buildup and ground surface displacement during geological CO2 sequestration

A series of numerical test cases reflecting broad and realistic ranges of geological formation properties was developed to systematically evaluate and compare the impacts of those properties on geomechanical responses to CO2 injection. A coupled hydro-geomechanical subsurface transport simulator, STOMP (Subsurface Transport over Multiple Phases), was adopted to simulate the CO2 migration process and geomechanical behaviors of the surrounding geological formations. A quasi-Monte Carlo sampling method was applied to efficiently sample a high-dimensional parameter space consisting of injection rate and 14 subsurface formation properties, including porosity, permeability, entry pressure, irreducible gas and aqueous saturation, Young’s modulus, and Poisson’s ratio for both reservoir and caprock. Generalized cross-validation and analysis of variance methods were used to quantitatively measure the significance of the 15 input parameters. Reservoir porosity, permeability, and injection rate were found to be among the most significant factors affecting the geomechanical responses to the CO2 injection. We used a quadrature generalized linear model to build a reduced-order model that can estimate the geomechanical response instantly instead of running computationally expensive numerical simulations.

CO2 geological sequestration↗

Experimental Investigation of Laws during Deformation of Circular Roadway in 10° Inclined Layered Rock

In order to analyze the deformation characteristics and mechanisms caused by high tectonic stress in gentle dip strata, a physical modeling with circular tunnel was designed. The model was constructed by the so-called “Physically Finite Elemental Slab Assemblage (PFESA)” to bring about the structural effect of the deep strata. The gravity was fixed while the lateral pressure increased step by step to mimic high tectonic stress. In order to observe the displacement in different area, the sketches of monitoring points and frame in the model surface were drawn down through video pictures in different periods and to be compared. For the sake of analyzing the deformation and failure mechanism of layers, rock structural mechanics models were set up for the left side and right side in the same stratum, respectively. For verifying the experimental phenomenon and its mechanism, infrared images were utilized based on the temperature variation mechanisms of material. Through systematic study, this paper enriches the research methods of model test and can provide a certain reference for practical engineering of similar conditions.

42 ENGINEERING↗

Instrumentation Cables Test Plan

A fire at a nuclear power plant (NPP) has the potential to damage structures, systems, and components important to safety, if not promptly detected and suppressed. At Browns Ferry Nuclear Power Plant on March 22, 1975, a fire in the reactor building damaged electrical power and control systems. Damage to instrumentation cables impeded the function of both normal and standby reactor coolant systems, and degraded the operators’ plant monitoring capability. This event resulted in additional NRC involvement with utilities to ensure that NPPs are properly protected from fire as intended by the NRC principle design criteria (i.e., general design criteria 3, Fire Protection). Current guidance and methods for both deterministic and performance based approaches typically make conservative (bounding) assumptions regarding the fire-induced failure modes of instrumentation cables and those failure modes effects on component and system response. Numerous fire testing programs have been conducted in the past to evaluate the failure modes and effects of electrical cables exposed to severe thermal conditions. However, that testing has primarily focused on control circuits with only a limited number of tests performed on instrumentation circuits. In 2001, the Nuclear Energy Institute (NEI) and the Electric Power Research Institute (EPRI) conducted a series of cable fire tests designed to address specific aspects of the cable failure and circuit fault issues of concern1. The NRC was invited to observe and participate in that program. The NRC sponsored Sandia National Laboratories to support this participation, whom among other things, added a 4-20 mA instrumentation circuit and instrumentation cabling to six of the tests. Although limited, one insight drawn from those instrumentation circuits tests was that the failure characteristics appeared to depend on the cable insulation material. The results showed that for thermoset insulated cables, the instrument reading tended to drift and fluctuate, while the thermoplastic insulated cables, the instrument reading fell off-scale rapidly. From an operational point of view, the latter failure characteristics would likely be identified as a failure from the effects of fire, while the former may result in inaccurate readings.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Optimizing Deep Geothermal Drilling for Energy Sustainability in the Appalachian Basin

This study investigates the geological and geomechanical characteristics of the MIP 1S geothermal well in the Appalachian Basin to optimize drilling and address the wellbore stability issues encountered. Data from well logs, sidewall core analysis, and injection tests were used to derive elastic and rock strength properties, as well as stress and pore pressure profiles. A robust 1D-geomechanical model was developed and validated, correlating strongly with wellbore instability observations. This revealed significant wellbore breakout, widening the diameter from 12 ¼ inches to over 16 inches. Advanced technologies like Cerebro Force™ In-Bit Sensing were used to monitor drilling performance with high accuracy. This technology tracks critical metrics such as bit acceleration, vibration in the x, y, and z directions, Gyro RPM, stick-slip indicators, and bending on the bit. Cerebro Force™ readings identified hole drag caused by poor hole conditions, including friction between the drill string and wellbore walls and the presence of cuttings or debris. This led to higher torque and weight on bit (WOB) readings at the surface compared to downhole measurements, affecting drilling efficiency and wellbore stability. Optimal drilling parameters for future deep geothermal wells were determined based on these findings.

Environmental Sciences & Ecology↗

Structural integrity and durability for Space Shuttle main engine and future reusable space propulsion systems

NASA is conducting a program which will establish a technology base for the orderly evolution of reusable space propulsion systems. As part of that program, NASA initiated a Structural Integrity and Durability effort for advanced high-pressure oxygen-hydrogen rocket engine technology. That effort focuses on the development of: (1) accurate analytical models to describe flow fields; aerothermodynamic loads; structural responses; and fatigue/fracture, from which life prediction codes can be evolved; and (2) advanced instrumentation with capabilities to verify the codes in an SSME-like environment as well as the potential for future use as diagnostic sensors for real-time condition monitoring of critical engine components.

Marsik, S. J.↗

Structural integrity and durability for Space Shuttle main engine and future reusable space propulsion systems

NASA is conducting a program which will establish a technology base for the orderly evolution of reusable space propulsion systems. As part of that program, NASA initiated a Structural Integrity and Durability effort for advanced high-pressure oxygen-hydrogen rocket engine technology. That effort focuses on the development of: (1) accurate analytical models to describe flow fields; aerothermodynamic loads; structural responses; and fatigue/fracture, from which life prediction codes can be evolved; and (2) advanced instrumentation with capabilities to verify the codes in an SSME-like environment as well as the potential for future use as diagnostic sensors for real-time condition monitoring of critical engine components.

Marsik, S. J.↗

Using optical-microwave synergy for estimating surface energy fluxes over semi-arid rangeland

First results of the Walnut Gulch '92 (Arizona, U.S.) experiment concerning the combined use of radar backscattering (ERS-1) and thermal infrared (LANDSAT TM (Thematic Mapper)) data to estimate surface sensible heat flux are reported. The first step investigates the potential use of ERS-1 SAR (Synthetic Aperture Radar) images for surface soil moisture monitoring of the watershed using five calibrated images acquired during the year 1992 (dry to wet conditions). Results show that despite the typical low level of biomass of semi arid rangeland, an attenuation of the soil backscatter (up to 2 dB) can occur during the rainy season mainly due to the vegetation characteristics. A statistical relationship is then used to retrieve the volumetric surface soil moisture from ERS-1 backscattering (sensitivity of 0.23 dB/% moisture) with a resulting root mean square error of 1.3% of soil moisture. In a second step a semi empirical approach based on energy balance relates soil temperatures to this estimated surface soil moisture. Vegetation temperature is then deduced from soil temperatures and LANDSAT TM composite temperature in order to estimate sensible heat flux according to a two layer type model providing an RMSE of 29 W/sq m.

Troufleau, D.↗

Evaluating Crystallinity in Thermoplastic Composites for Aerospace Applications

Polymer matrix composites (PMCs) offer many benefits for the aerospace industry due to their potential for weight reduction when compared to metal or ceramic based materials. Most PMCs currently in flight use thermoset matrices, however, thermoplastic resins are being explored as alternatives due to their ability to be remelted, which is of particular interest due to the potential for in-situ repair and faster production. Most thermoplastic resins are semicrystalline polymers. The properties of semicrystalline thermoplastics are directly influenced by their crystallinity, which can vary due to many factors including thermal treatments, environmental conditions, and mechanical deformation. Within thermoplastic PMC parts, crystallinity gradients can arise due to variations in part geometry, across part thicknesses, and along bonded joints. Monitoring the crystallinity of thermoplastic composites is key to ensuring these materials meet the high demands required for aerospace. Several different analytical techniques exist that can be used to characterize the bulk crystallinity of thermoplastic materials. However, many existing methods lack the specificity required to identify the subtle variations in crystallinity that may play a significant role in the performance and durability of PMC parts. Because of this, a significant amount of work is still required to fully characterize and understand the crystallinity profiles of thermoplastic PMCs and the resulting impact to material properties. This talk discusses the use of multiple techniques such as Differential Scanning Calorimetry, Polarized Light Optical Microscopy, and Fourier-Transform Infrared Spectroscopy to characterize the crystallinity in carbon fiber/thermoplastic composites. Samples of different crystallinity profiles were manufactured using various cooling procedures. This work aims to provide the fundamental data necessary to understand the effects of crystallinity on thermoplastic PMCs, which is key to advancing their use in aerospace applications.

Thermoplastics↗

The Initial Development of a Computerized Operator Support System

A computerized operator support system (COSS) is a collection of resilient software technologies to assist operators in monitoring overall nuclear power plant performance and making timely, informed decisions on appropriate control actions for the projected plant condition. The COSS provides rapid assessments, computations, and recommendations to reduce workload and augment operator judgment and decision-making during fast- moving, complex events. A prototype COSS for a chemical volume control system at a nuclear power plant has been developed in order to demonstrate the concept and provide a test bed for further research. The development process identified four underlying elements necessary for the prototype, which consist of a digital alarm system, computer-based procedures, piping and instrumentation diagram system representations, and a recommender module for mitigation actions. An operational prototype resides at the Idaho National Laboratory (INL) using the U.S. Department of Energy’s (DOE) Light Water Reactor Sustainability (LWRS) Human Systems Simulation Laboratory (HSSL). Several human-machine interface (HMI) considerations are identified and incorporated in the prototype during this initial round of development.

99 GENERAL AND MISCELLANEOUS↗

Microbial sensor system for monitoring the environment and surfaces

A microbial sensor, system and method that can be used to determine the biochemical conditions of waters, saturated sediments, unsaturated soils, rhizosphere and other environments is disclosed. The flexibility of the microbial sensor design allows for the monitoring of surfaces (skin, ventilation conduits, etc.). An electrochemical microbial sensor system is composed of an indicator electrode(s) and a reference electrode. The reference electrode employs a hydrogen permeable membrane. The electrochemical system is interfaced into a signal/communication module allowing the manual or automated collection of data from field deployments and laboratory investigations. The data is transmitted using various communication technologies including Bluetooth™, cellular, satellite and radio telemetry to cloud-based data management systems. The stored data may be downloaded by users using open-source dashboard and visualization software to image the various environments and/or surfaces investigated.

Burge, Scott R.↗

Evaluation of a Model-Based Groundwater Drought Indicator in the Conterminous U.S.

Monitoring groundwater drought using land surface models is a valuable alternative given the current lack of systematic in situ measurements at continental and global scales and the low resolution of current remote sensing based groundwater data. However, uncertainties inherent to land surface models may impede drought detection, and thus should be assessed using independent data sources. In this study, we evaluated a groundwater drought index (GWI) derived from monthly groundwater storage output from the Catchment Land Surface Model (CLSM) using a GWI similarly derived from in situ groundwater observations. Groundwater observations were obtained from unconfined or semi-confined aquifers in eight regions of the central and northeastern U.S. Regional average GWI derived from CLSM exhibited strong correlation with that from observation wells, with correlation coefficients between 0.43 and 0.92. GWI from both in situ data and CLSM was generally better correlated with the Standard Precipitation Index (SPI) at 12 and 24 month timescales than at shorter timescales, but it varied depending on climate conditions. The correlation between CLSM derived GWI and SPI generally decreases with increasing depth to the water table, which in turn depends on both bedrock depth (a CLSM parameter) and mean annual precipitation. The persistence of CLSM derived GWI is spatially varied and again shows a strong influence of depth to groundwater. CLSM derived GWI generally persists longer than GWI derived from in situ data, due at least in part to the inability of coarse model inputs to capture high frequency meteorological variability at local scales. The study also showed that groundwater can have a significant impact on soil moisture persistence where the water table is shallow. Soil moisture persistence was estimated to be longer in the eastern U.S. than in the west, in contrast to previous findings that were based on models that did not represent groundwater. Assimilation of terrestrial water storage data from the Gravity Recovery and Climate Experiment (GRACE) satellite mission improved the correlation between CLSM based regional average GWI and that based on in situ data in six of the eight regions. Practical issues regarding the application of GRACE assimilated groundwater storage for drought detection are discussed. An important conclusion of this study is that model parameters that control the depth to the water table, including bedrock depth, strongly influence the evolution and persistence of simulated groundwater and require careful configuration for drought monitoring.

Evaluation↗

Evaluation of a Model-Based Groundwater Drought Indicator in the Conterminous U.S.

Monitoring groundwater drought using land surface models is a valuable alternative given the current lack of systematic in situ measurements at continental and global scales and the low resolution of current remote sensing based groundwater data. However, uncertainties inherent to land surface models may impede drought detection, and thus should be assessed using independent data sources. In this study, we evaluated a groundwater drought index (GWI) derived from monthly groundwater storage output from the Catchment Land Surface Model (CLSM) using a GWI similarly derived from in situ groundwater observations. Groundwater observations were obtained from unconfined or semi-confined aquifers in eight regions of the central and northeastern U.S. Regional average GWI derived from CLSM exhibited strong correlation with that from observation wells, with correlation coefficients between 0.43 and 0.92. GWI from both in situ data and CLSM was generally better correlated with the Standard Precipitation Index (SPI) at 12 and 24 month timescales than at shorter timescales, but it varied depending on climate conditions. The correlation between CLSM derived GWI and SPI generally decreases with increasing depth to the water table, which in turn depends on both bedrock depth (a CLSM parameter) and mean annual precipitation. The persistence of CLSM derived GWI is spatially varied and again shows a strong influence of depth to groundwater. CLSM derived GWI generally persists longer than GWI derived from in situ data, due at least in part to the inability of coarse model inputs to capture high frequency meteorological variability at local scales. The study also showed that groundwater can have a significant impact on soil moisture persistence where the water table is shallow. Soil moisture persistence was estimated to be longer in the eastern U.S. than in the west, in contrast to previous findings that were based on models that did not represent groundwater. Assimilation of terrestrial water storage data from the Gravity Recovery and Climate Experiment (GRACE) satellite mission improved the correlation between CLSM based regional average GWI and that based on in situ data in six of the eight regions. Practical issues regarding the application of GRACE assimilated groundwater storage for drought detection are discussed. An important conclusion of this study is that model parameters that control the depth to the water table, including bedrock depth, strongly influence the evolution and persistence of simulated groundwater and require careful configuration for drought monitoring.

hydrology↗

Summary of Gas Generation Behavior Observed in 3013 Surveillance and Monitoring Program Shelf-Life Experiments

Gas generation experiments have been conducted in small- and full-scale test containers at Los Alamos National Laboratory on samples of plutonium oxide material collected from plutonium processes across the DOE complex and tested at the bounding conditions for the Department of Energy 3013 Standard. The gas composition and pressures in the sealed experimental containers were measured over periods of months to years. These experiments have provided results for the formation and consumption of hydrogen and other gases. The conditions supporting the formation of flammable gas mixtures of hydrogen and oxygen in flammable gas mixtures were also determined. Different behaviors were observed between the materials tested based on their compositions, the stabilization performed on the material, and the post stabilization handling of the material. Many of the experiments are still ongoing. This report summarizes the results obtained for the gas generation behavior for high-purity plutonium oxides and salt-bearing impure plutonium oxides in sealed containers.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Cost‐effective monitoring of biological invasions under global change: a model‐based framework

Summary Ecological monitoring programmes are designed to detect and measure changes in biodiversity and ecosystems. In the case of biological invasions, they can contribute to anticipating risks and adaptively managing invaders. However, monitoring is often expensive because large amounts of data might be needed to draw inferences. Thus, careful planning is required to ensure that monitoring goals are realistically achieved. Species distribution models ( SDM s) can provide estimates of suitable areas to invasion. Predictions from these models can be applied as inputs in optimization strategies seeking to identify the optimal extent of the networks of areas required for monitoring risk of invasion under current and future environmental conditions. A hierarchical framework is proposed herein that combines SDM s, scenario analysis and cost analyses to improve invasion assessments at regional and local scales. We illustrate the framework with Acacia dealbata Link. (Silver‐wattle) in northern Portugal. The framework is general and applicable to any species. We defined two types of monitoring networks focusing either on the regional‐scale management of an invasion, or management focus within and around protected areas. For each one of these two schemes, we designed a hierarchical framework of spatial prioritization using different information layers (e.g. SDM s, habitat connectivity, protected areas). We compared the performance of each monitoring scheme against 100 randomly generated models. In our case study, we found that protected areas will be increasingly exposed to invasion by A. dealbata due to climate change. Moreover, connectivity between suitable areas for A. dealbata is predicted to increase. Monitoring networks that we identify were more effective in detecting new invasions and less costly to management than randomly generated models. The most cost‐efficient monitoring schemes require 18% less effort than the average networks across all of the 100 tested options. Synthesis and applications . The proposed framework achieves cost‐effective monitoring networks, enabling the interactive exploration of different solutions and the combination of quantitative information on network performance with orientations that are rarely incorporated in a decision support system. The framework brings invasion monitoring closer to European legislation and management needs while ensuring adaptability under rapid climate and environmental change.

Vicente, Joana R.↗

RECORD-SETTING COSMIC-RAY INTENSITIES IN 2009 AND 2010

We report measurements of record-setting intensities of cosmic-ray nuclei from C to Fe, made with the Cosmic Ray Isotope Spectrometer carried on the Advanced Composition Explorer in orbit about the inner Sun-Earth Lagrangian point. In the energy interval from {approx}70 to {approx}450 MeV nucleon{sup -1}, near the peak in the near-Earth cosmic-ray spectrum, the measured intensities of major species from C to Fe were each 20%-26% greater in late 2009 than in the 1997-1998 minimum and previous solar minima of the space age (1957-1997). The elevated intensities reported here and also at neutron monitor energies were undoubtedly due to several unusual aspects of the solar cycle 23/24 minimum, including record-low interplanetary magnetic field (IMF) intensities, an extended period of reduced IMF turbulence, reduced solar-wind dynamic pressure, and extremely low solar activity during an extended solar minimum. The estimated parallel diffusion coefficient for cosmic-ray transport based on measured solar-wind properties was 44% greater in 2009 than in the 1997-1998 solar-minimum period. In addition, the weaker IMF should result in higher cosmic-ray drift velocities. Cosmic-ray intensity variations at 1 AU are found to lag IMF variations by 2-3 solar rotations, indicating that significant solar modulation occurs inside {approx}20 AU, consistent with earlier galactic cosmic-ray radial-gradient measurements. In 2010, the intensities suddenly decreased to 1997 levels following increases in solar activity and in the inclination of the heliospheric current sheet. We describe the conditions that gave cosmic rays greater access to the inner solar system and discuss some of their implications.

79 ASTRONOMY AND ASTROPHYSICS↗

Demonstrating resonant ultrasound spectroscopy as a viable technique to characterize thermally conditioned high explosive materials

We present results of resonant ultrasound spectroscopy (RUS) measurements applied to granular high explosive materials at different bulk pressing densities and degree of thermal conditioning. The material chosen in this study is a ubiquitously used explosive material known as pentaerythritol tetranitrate (PETN), which is used commercially in civil and defense applications both as a binderized plastic bonded explosive material and an unbinderized neat material. However, changes in granular PETN bulk elastic properties due to thermal conditioning, which could have implications for better understanding environmental aging-related effects, have not been well studied even though it is believed that elasticity may play an important role in explosive material initiation mechanisms. Furthermore, monitoring elastic property changes in granular explosive pressings has not yet been demonstrated using RUS, which is an appealing non-destructive characterization tool that requires only dry point contact with the explosive material. To this end, we report the first study using RUS to quantify the elastic properties of binderized and neat PETN pressings as well as to quantify changes in elastic properties as a function of both thermal conditioning and bulk pressing density. Elastic stiffness coefficients, sometimes more commonly referred to as elastic constants, calculated from the RUS measurements on the different PETN-based materials show a significant increase for the post-conditioned samples compared to the pre-conditioned samples. This trend of increasing elastic properties with thermal conditioning was consistent for different density pressings, different thermal exposure conditions, and even different neat PETN pressings of differing average crystal sizes and/or specific surface areas.

36 MATERIALS SCIENCE↗

Secondary Ion Mass Spectrometry Bias on Isotope Ratios in Dolomite-Ankerite, Part II: δ 13 C Matrix Effects

Here, this study is Part II of a series that documents the development of a suite of calibration reference materials for in situ SIMS analysis of stable isotope ratios in Ca-Mg-Fe carbonates. Part I explored the effects of Fe 2+ substitution on SIMS δ18O bias measured from the dolomite–ankerite solid solution series [CaMg(CO3)2–CaFe(CO 3 ) 2 ], whereas this complementary work explores the compositional dependence of SIMS δ 13 C bias (calibrated range: Fe# = 0.004–0.789, where Fe# = molar Fe/(Mg+Fe)). Under routine operating conditions for carbonate δ 13 C analysis at WiscSIMS (CAMECA IMS 1280), the magnitude of instrumental bias increased exponentially by 2.5–5.5‰ (session-specific) with increasing Fe-content in the dolomite structure, but appeared insensitive to minor Mn substitution [< 2.6 mole % Mn/(Ca+Mg+Fe+Mn)]. The compositional dependence of bias (i.e., the matrix effect) was expressed using the Hill equation, yielding calibration residual values ≤ 0.3‰ relative to CRM NBS-19 for eleven carbonate reference materials (6-μm-diameter spot size measurements). Based on the spot-to-spot repeatability of a drift monitor material that ‘bracketed’ each set of ten sample-spot analyses, the analytical precision was ± 0.6–1.2‰ (2s, standard deviations). The analytical uncertainty for individual sample analyses was approximated by combining the precision and calibration residual values (propagated in quadrature), suggesting an uncertainty of ± 1.0–1.5‰ (2s).

58 GEOSCIENCES↗

Electrochemical Response of Alkaline Batteries Subject to Quasi-Static and Dynamic Loading

We report electrochemical changes were successfully monitored through the coupling of external loading, electrochemical impedance spectroscopy (EIS), and distribution of relaxation times (DRT) analysis. The development of the testing methods allows for detailed observation of changes due to mechanical loading and distinguishes responses between different cell geometries. Comparison of the force vs displacement, voltage vs displacement, and distribution of relaxation times plots to the different cell geometries display failure modes specific to geometry as well as the impact of different loading profiles. Numerical modeling confirmed the movement within individual cells and predicted locations with the most deformation based on the external loading condition applied. The results gathered from combining mechanical loading, electrochemical response, and numerical modeling, yield a viable approach to establishing an improved understanding of the effects of mechanical loading on the electrochemical response of multiple battery geometries and the methods herein may be extensible to additional battery chemistries.

25 ENERGY STORAGE↗