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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,549 records · Page 86
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Leveling coatings for reducing the atomic oxygen defect density in protected graphite fiber epoxy composites

Pinholes or other defect sites in a protective oxide coating provide pathways for atomic oxygen in low Earth orbit to reach underlying material. One concept for enhancing the lifetime of materials in low Earth orbits is to apply a leveling coating to the material prior to applying any reflective and protective coatings. Using a surface tension leveling coating concept, a low viscosity epoxy was applied to the surface of several composite coupons. A protective layer of 1000 A of SiO2 was deposited on top of the leveling coating, and the coupons were exposed to an atomic oxygen environment in a plasma asher. Pinhole populations per unit area were estimated by counting the number of undercut sites observed by scanning electron microscopy. Defect density values of 180,000 defects/sq cm were reduced to about 1000 defects/sq cm as a result of the applied leveling coating. These improvements occur at a mass penalty of about 2.5 mg/sq cm.

Jaworske, D. A.↗
NASA NTRS1992

Leveling coatings for reducing the atomic oxygen defect density in protected graphite fiber epoxy composites

Pinholes or other defect sites in a protective oxide coating provide pathways for atomic oxygen in low Earth orbit to reach underlying material. One concept of enhancing the lifetime of materials in low Earth orbit is to apply a leveling coating to the material prior to applying any reflective and protective coatings. Using a surface tension leveling coating concept, a low viscosity epoxy was applied to the surface of several composite coupons. A protective layer of 1000 A of SiO2 was deposited on top of the leveling coating, and the coupons were exposed to an atomic oxygen environment in a plasma asher. Pinhole populations per unit area were estimated by counting the number of undercut sites observed by scanning electron microscopy. Defect density values of 180,000 defects/sq cm were reduced to about 1000 defects/sq cm as a result of the applied leveling coating. These improvements occur at a mass penalty of about 2.5 mg/sq cm.

Jaworske, D. A.↗
NASA NTRS1999

Thermal Infrared Spectroscopy from Mars Landers and Rovers: A New Angle on Remote Sensing

The MINUTES instrument of the Athena Precursor Experiment (APEX) on the Mars Surveyor 2001 lander mission will perform the first thermal infrared remote sensing observations from the surface of another planet. Experience gained from this experiment will be used to guide observations from identical instruments mounted on the Athena rovers, to be launched in 2003 and 2005. The utility of infrared spectrometers in determining the mineralogic composition of geologic surfaces from airborne and spaceborne platforms has been amply demonstrated. However, relatively little experience exists in using functionally similar instruments on the ground in the context of planetary science. What work has been done on this problem has mostly utilized field spectrometers that are designed to look down on nearby target rocks. While many Mini-TES observations will be made with this type of geometry, it is likely that other observations will be made looking horizontally at the more vertically-oriented facets of rock targets, to avoid spectral contamination from dust mantles. On rover missions, the Mini-TES may also be pointed horizontally at rocks several meters away, to determine if they are worthy of approaching for in situ observations and possible sample cacheing. While these observations will undoubtedly prove useful, there are important, and perhaps unappreciated, differences between horizontal-viewing, surface-based spectroscopy and the more traditional nadir-viewing, orbit or aircraft-based observations. Plans also exist to step the Mini-TES in a rastering motion to build hyperspectral scenes. Horizontal viewing hyperspectral cubes also possess unique qualities that call for innovative analysis techniques. The effect of viewing geometry: In thermal emission spectroscopy, regardless of whether an instrument is looking down on or horizontally at a target, the same basic equation governs the radiance reaching the sensor .

Moersch, J.↗
NASA NTRS2012

Elements of Nondestructive Examination for the Visual Inspection of Composite Structures

Visual inspection (VI) of composite structures provides an effective, wide field survey to ensure design and material compliance is maintained for the entire service life of the manufactured component. Visual inspection is one of the most commonly used nondestructive inspection methods to assess surface defects on composites. By applying visual inspection elements, mechanical damage that could affect component residual strength can be identified and a disposition reached before a potentially catastrophic event occurs. This technique is non-contact and applied at all stages of the composite structure s processing and use. Additionally, VI is required to be performed in all service environments until decommission. By following Level I and Level II damage accept/reject criteria set forth in this document, the material review (MR) process can be initiated. This nondestructive evaluation (NDE) method should be complemented with additional NDE methods to best understand the nature of the observed indications. When VI identification is followed by interrogation using effective complimentary NDE methods, the final Material Review Board (MRB) disposition of the component can be effectively achieved. Although elements of the visual inspection method are discussed and expressly required by the various range standards (KNPR 8715.3 and AFSPCMAN 91-710), emphasis should be placed on supporting the interpretation of recorded visual observations. Sound engineering practices and procedures should be applied with the interpretation of nondestructive testing (NDT) results when the residual strength data specific to a vessel design is incomplete or absent.

Tommy B. Yoder↗
NASA NTRS2020

Widespread carbon-bearing materials on near-Earth asteroid (101955) Bennu

(101955) Bennu is a dark, Earth orbit-crossing, asteroid thought to be assembled from the fragments of an ancient collision. Spatially-resolved visible and near-infrared spectra of Bennu provide details about its surface properties and composition. In addition to a hydrated phyllosilicate band, we detect a ubiquitous 3.4-micron absorption feature, which we attribute to a mix of organic and carbonate materials. The shape and depth of this absorption feature vary across Bennu’s surface, spanning the range seen among similar main-belt asteroids. Its distribution does not correlate with the temperature, reflectance, spectral slope, or hydrated minerals although those characteristics correlate with each other in some cases. The deepest 3.4-micron absorptions occur on individual boulders. The variations may be due to differences in abundance, recent exposure, or space weathering.

Amy A. Simon↗
NASA NTRS1975

ESCA studies of lunar surface chemistry

We have used ESCA to compare the composition of the natural exterior surface in lunar fines samples with that of the interior surface exposed by crushing. Even though the exterior surfaces have been exposed to air a significant amount of Fe in them is reduced. In addition, Ca, Al, and Mg are strongly depleted in exterior surfaces relative to Si, Ti, and Fe. Preferential sputtering by the solar wind is a possible explanation for these changes.

Housley, R. M.↗
NASA NTRS2000

Validity of VO(2 max) in predicting blood volume: implications for the effect of fitness on aging

A multiple regression model was constructed to investigate the premise that blood volume (BV) could be predicted using several anthropometric variables, age, and maximal oxygen uptake (VO(2 max)). To test this hypothesis, age, calculated body surface area (height/weight composite), percent body fat (hydrostatic weight), and VO(2 max) were regressed on to BV using data obtained from 66 normal healthy men. Results from the evaluation of the full model indicated that the most parsimonious result was obtained when age and VO(2 max) were regressed on BV expressed per kilogram body weight. The full model accounted for 52% of the total variance in BV per kilogram body weight. Both age and VO(2 max) were related to BV in the positive direction. Percent body fat contributed <1% to the explained variance in BV when expressed in absolute BV (ml) or as BV per kilogram body weight. When the model was cross validated on 41 new subjects and BV per kilogram body weight was reexpressed as raw BV, the results indicated that the statistical model would be stable under cross validation (e.g., predictive applications) with an accuracy of +/- 1,200 ml at 95% confidence. Our results support the hypothesis that BV is an increasing function of aerobic fitness and to a lesser extent the age of the subject. The results may have implication as to a mechanism by which aerobic fitness and activity may be protective against reduced BV associated with aging.

NASA Discipline Cardiopulmonary↗
NASA NTRSDate not supplied

Orion Artemis-1 Post-Flight Characterization

This abstract discusses the post-flight characterization of the heatshield used in the Orion Artemis-1 mission, which is a significant milestone in human space exploration. The Artemis-1 heatshield is a crucial component designed to protect the spacecraft during re-entry into Earth's atmosphere. It experiences extreme temperatures and forces as it encounters the intense heat generated by the friction between the spacecraft and the atmospheric gases. The post-flight characterization of the Artemis-1 heatshield involves analyzing its surface morphology and elemental composition. This analysis provides valuable insights into the performance and durability of the heatshield during the mission. By utilizing techniques such as Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDX), a detailed examination of the heatshield’s surface features, and elemental composition can be conducted. The SEM analysis offers high-resolution imaging capabilities, enabling detailed observations of the heatshield’s surface morphology. EDX analysis provides elemental analysis, allowing for an assessment of any compositional changes induced by the thermal and environmental conditions experienced during the mission. This information is crucial for understanding the material's response to the extreme conditions and identifying any potential issues or degradation. Furthermore, density profiling analysis is performed to measure density variations across the depth of the heatshield material. This analysis offers insights into the effects of the mission on the heatshield, such as potential ablation, or changes in material porosity. Understanding these density variations helps to evaluate the heatshield's structural integrity and its ability to withstand future missions. This knowledge contributes to the ongoing development of advanced heatshield designs, enhancing their thermal protection capabilities and ensuring the safety of future manned missions to the Moon and beyond.

Tane Boghozian↗
DOE OSTI2017

Effect of Melt Temperature on Surface Films Formed on Molten AZ91D Alloy Protected by Graphite Powder

Graphite powder was adopted to prevent AZ91D alloy from oxidizing during melting and casting. The microstructure of the resultant surface films, formed at 933 K, 973 K, 1013 K, and 1053 K (660 °C, 700 °C, 740 °C, and 780 °C) for 30 minutes, was investigated by scanning electron microscopy, energy dispersive spectrometer, and X-ray diffraction, and the phase composition of the surface films was analyzed by the standard Gibbs free energy change of the reactions between the graphite powder, the alloy melt, and the ambient atmosphere. The effect and mechanism of melt temperature on the resultant surface films were also discussed. The results indicated that the surface films, of which the surface morphology comprised folds and wrinkles, were composed of a protective layer and MgF{sub 2} particles. The protective layer was contributive to the prevention of the molten alloy from oxidizing, and consisted of magnesium, oxygen, fluorine, carbon, and a small amount of aluminium existing in the form of MgO, MgF{sub 2}, C, and MgAl{sub 2}O{sub 4}. The layer thickness was 200 to 900 nm. The melt temperature may affect the surface films through the increased interaction between the graphite powder, the melt, and the ambient atmosphere. The oxygen content and thickness of the protective layer decreased and then increased, while the height of the folds increased with melt temperature.

36 MATERIALS SCIENCE↗
DOE OSTI2023

The diversity of aluminum-based drinking water treatment residuals for use in environmental remediation

Drinking water treatment residuals (DWTRs) are complex mixtures of organic and inorganic phases generally disposed of as waste materials. However, their strong sorptive properties could be further exploited to immobilize contaminants. To characterize these materials, we applied a range of analytical techniques to a set of aluminum-based DWTRs. Here we determined surface areas, elemental compositions using CHNS analysis and X-ray fluorescence (XRF), performed thermogravimetric analyses paired with mass spectrometry (TGA-MS), and used synchrotron-based methods: X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS). Elemental analyses and specific surface area measurements – that vary between 7.23 ± 0.03 and 197.6 ± 0.9 m 2 g –1 – indicate that non-coagulant additives must play an important role in controlling sorption. High resolution powder XRD reveals the presence of only a few crystalline minerals mostly derived from source waters or additives. Fe was detected by XRF in all samples, whereas Mn was present in significant levels in samples with potassium permanganate as additive. The chemical speciation of these elements was characterized by performing spectral decompositions of XAS spectra. The spectral features of Fe are consistent with iron(III) oxides/hydroxides and structural iron in clays. On the other hand, Mn is predominantly present under its reduced form, Mn(II).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Compact quantum dot surface modification to enable emergent behaviors in quantum dot-DNA composites

Quantum dot (QD) biological imaging and sensing applications often require surface modification with single-stranded deoxyribonucleic acid (ssDNA) oligonucleotides. Furthermore, ssDNA conjugation can be leveraged for precision QD templating via higher-order DNA nanostructures to exploit emergent behaviors in photonic applications. Use of ssDNA-QDs across these platforms requires compact, controlled conjugation that engenders QD stability over a wide pH range and in solutions of high ionic strength. However, cur-rent ssDNA-QD conjugation approaches suffer from limitations, such as the requirement for thick coatings, low control over ssDNA labeling density, requirement of large amounts of ssDNA, or low colloidal or photostability, restraining implementation in many applications. Here, we combine thin, multidentate, phytochelatin-3 (PC3) QD passivation techniques with strain-promoted copper-free alkyne-azide click chemistry to yield functional ssDNA-QDs with high stability. This process was broadly applicable across QD sizes (i.e.,λ em = 540, 560, 600 nm), ssDNA lengths (i.e., 10–16 base pairs, bps), and sequences (poly thymine, mixed bps). The resulting compacts sDNA-QDs displayed a fluorescence quenching efficiency of up to 89% by hybridization with complementary ssDNA-AuNPs. Further-more, ssDNA-QDs were successfully incorporated with higher-order DNA origami nanostructure templates. Finally, this approach, combining PC3 passivation with click chemistry, generates ssDNA-PC3-QDs that enable emergent QD properties in DNA-based devices and applications.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2020

Surface modification of bamboo fiber with sodium hydroxide and graphene oxide in epoxy composites

Bamboo fibers (BFs) have high mechanical properties and are candidate reinforcement for epoxy matrix composites. However, to improve performance, good fiber-matrix interaction is required. In this work, unidirectional long BF reinforced epoxy composites at fiber volume content of 22%, 40%, and 50% were made by compression molding. The 40 v% untreated BF reinforced composites exhibited 107% and 439% increase for flexural strength and modulus, respectively, compared to neat epoxy. Sodium hydroxide (NaOH) treatment was used to modify the surface of the BFs, and then the NaOH modified BFs were coated with graphene oxide (GO). The 40 v% NaOH modified BF composites showed an improvement from 259.9 to 327.5 MPa for flexural strength and from 16.7 to 21.5 GPa for flexural modulus, compared to 40 v% untreated BF composites. Slight improvement in properties up to 334.6 MPa for flexural strength and up to 23.8 GPa for flexural modulus was achieved for composites made of 40 v% NaOH/GO modified BF. Surface modification of BF after the NaOH and NaOH/GO treatment was confirmed by X-ray photoelectron spectroscopy and by scanning electron microscopy, which showed differences on the fiber surface morphology and on the composite fracture surface. This BF surface modification approach with GO has potential to impart other properties beyond mechanical to produce multifunctional composite and lead to the use of sustainable plant fibers as alternatives to synthetic fibers.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Multifunctional transition metal doped titanium dioxide reduced graphene oxide composites as highly efficient adsorbents and photocatalysts

A series of novel, mesoporous transition metal doped titanium dioxide-reduced graphene oxide composites are synthesized where the dopants were Mn, Co, Ni, Mo, and W. An in-situ synthesis method was used which involves a green, economic, hydrothermal process which can be scaled up easily. The composites show high surface areas (165–245 m 2 /g) and monomodal pore size distributions with average pore diameters in the range of 3–5 nm. The homogeneous distributions of the dopants are seen in SEM-EDX mapping data. The indirect band gaps of the composite materials are in the range of 2.20–2.48 eV. The composites show excellent dye adsorption activities where 100% adsorption of Rhodamine B occurs within 5 min when Mo–TiO 2 /rGO composite is used. Furthermore, the adsorbed dye can either be desorbed or photocatalytically degraded and the composite is reusable up to 10 cycles without losing significant activity. Mo–TiO 2 /rGO composite showed excellent adsorption of both cationic and anionic dyes at neutral pH.

36 MATERIALS SCIENCE↗