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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,567 records · Page 87
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

SiC Composite for Fuel Structure Applications

Extensive evaluation was performed to determine the suitability of using SiC composite as a boiling water reactor (BWR) fuel channel material. A thin walled SiC composite box, 10 cm in dimension by approximately 1.5 mm wall thickness was fabricated using chemical vapor deposition (CVD) for testing. Mechanical test results and performance evaluations indicate the material could meet BWR channel mechanical design requirement. However, large mass loss of up to 21% was measured in in-pile corrosion test under BWR-like conditions in under 3 months of irradiation. A fresh sister sample irradiated in a follow-up cycle under PWR conditions showed no measureable weight loss and thus supports the hypothesis that the oxidizing condition of the BWR-like coolant chemistry was responsible for the high corrosion rate. A thermodynamic evaluation showed SiC is not stable and the material may oxidize to form SiO 2 and CO 2 . Silica has demonstrated stability in high temperature steam environment and form a protective oxide layer under severe accident conditions. However, it does not form a protective layer in water under normal BWR operational conditions due to its high solubility. Corrosion product stabilization by modifying the SiC CVD surface is an approach evaluated in this study to mitigate the high corrosion rate. Titanium and zirconium have been selected as stabilizing elements since both TiSiO 4 and ZrSiO 4 are insoluble in water. Corrosion test results in oxygenated water autoclave indicate TiSiO4 does not form a protective layer. However, zirconium doped test samples appear to form a stable continuous layer of ZrSiO 4 during the corrosion process. Additional process development is needed to produce a good ZrSiC coating to verify functionality of the mitigation concept.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Elucidating Hydrogen Reaction-Induced Water Desorption from Oxide-Passivated Metal Surfaces for Plasma Applications

Elucidating the mechanisms responsible for sub-microsecond desorption of water and other impurities from electrode surfaces at high heating rates is crucial for understanding pulsed power behavior. Ionization of desorbed impurities in the vacuum regions causes power or current loss; devising methods to limit such desorption during the short time scale of pulsed power is needed to improve corresponding applications. Previous molecular modeling studies have strongly suggested that, under high vacuum conditions, the amount of water impurity desorbing from oxide surfaces on metal electrodes is at a sub-monolayer level at room temperature, which appears insufficient to explain observed pulsed power energy losses at high current densities. In this work, we apply Density Functional Theory (DFT) techniques to show that hydrogen trapped inside iron metal can diffuse into hematite (α-Fe 2 O 3 ) on the metal surface, ultimately reacting with the oxide to form Fe(II) and H 2 O. The latter desorbs at elevated temperature and may explain the anomalous amount of desorbed impurity inferred from pulsed-power experiments. We also apply a suite of characterization techniques to demonstrate that when iron metal is heated to 650 °C, the dominant surface oxide component becomes α-Fe 2 O 3 . The oxide facets exposed are found to be a mixture of (0001), (10-10), and others, in agreement with the DFT models used.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1973

A stochastic model of turbulent mixing with chemical reaction: Nitric oxide formulation in a plug-flow burner

A stochastic model of turbulent mixing was developed for a reactor in which mixing is represented by n-body fluid particle interactions. The model was used to justify the assumption (made in previous investigations of the role of turbulent mixing on burner generated thermal nitric oxide and carbon monoxide emissions) that for a simple plug flow reactor, composition nonuniformities can be described by a Gaussian distribution function in the local fuel:air equivalence ratio. Recent extensions of this stochastic model to include the combined effects of turbulent mixing and secondary air entrainment on thermal generation of nitric oxide in gas turbine combustors are discussed. Finally, rate limited upper and lower bounds of the nitric oxide produced by thermal fixation of molecular nitrogen and oxidation of organically bound fuel nitrogen are estimated on the basis of the stochastic model for a plug flow burner; these are compared with experimental measurements obtained using a laboratory burner operated over a wide range of test conditions; good agreement is obtained.

Flagan, R. C.↗
NASA NTRS1956

Experimental Droplet Impingement on Several Two-Dimensional Airfoils with Thickness Ratios of 6 to 16 Percent

The rate and area of cloud droplet impingement on several two-dimensional swept and unswept airfoils were obtained experimentally in the NACA Lewis icing tunnel with a dye-tracer technique. Airfoil thickness ratios of 6 to 16 percent; angles of attack from 0 deg to 12 deg, and chord sizes from 13 to 96 inches were included in the study. The data were obtained at 152 knots and are extended to other conditions by dimensionless impingement parameters. In general, the data show that the total and local collection efficiencies and impingement limits are primary functions of the modified inertia parameter (in which airspeed, droplet size, and body size are the most significant variables) and the airfoil thickness ratio. Local collection efficiencies and impingement limits also depend on angle of attack. Secondary factors affecting impingement characteristics are airfoil shape, camber, and sweep angle. The impingement characteristics obtained experimentally for the airfoils were within +/-10 percent on the average of the characteristics calculated from theoretical trajectories. Over the range of conditions studied, the experimental data demonstrate that a specific method can be used to predict the impingement characteristics of swept airfoils with large aspect ratios from the data for unswept airfoils of the same series.

Gelder, Thomas F.↗
NASA NTRS1991

Mechanical properties of monolithic and particulate composites of L12 forms of Al3Ti

Preliminary studies of simple compressive properties of particulate composites with L1(2)-modified Al3Ti's as the matrices were performed as functions of matrix composition, amount of TiB2, processing technique, temperature, and strain rate. At and below about 900 K the introduction of TiB2 particles overwhelms minor chemical effects, and extremely high-yield strengths (about 2000 MPa at the 20 vol pct TiB2 level) were obtained. As L1(2)-modified Al3Ti has about half the density of the Ni-base superalloys, such values translate to strength/density ratios approximately four times those for superalloys. This advantage is not maintained by the Al3Ti-based composites above about 1000 K, particularly under slow strain rate plastic flow conditions, and it is proposed that this behavior could be due to the dissolution of intermetallic second phases as well as grain boundary creep mechanisms.

Whittenberger, J. D.↗
NASA NTRS1992

A self-consistent model for the particles and fields upstream of an outgassing comet. II - A time-dependent description

In a previous paper, the global variation of the magnetic field and solar wind flow parameters in the unshocked region upstream of an outgassing comet was determined using a kinetic treatment for the cometary ions. Two different assumptions were made concerning the cometary ion distribution function: the pickup cometary ions formed either a velocity space gyrotropic ring distribution or a velocity space isotropic shell distribution in the solar wind frame of reference. In the present paper the general case is considered wherein the newly picked up ions are elastically pitch angle scattered from the initial ring distribution to a shell with some characteristic time scale. Using theoretically determined parameters which reflect the conditions expected at Comet Kopff (a typical short-period comet and a possible target for the CRAF/Cassini mission) for various heliocentric distances, how the pitch angle scattering rate affects the global morphology is determined.

Flammer, K.↗
NASA NTRS1992

Recognition of partially occluded threat objects using the annealed Hopefield network

Recognition of partially occluded objects has been an important issue to airport security because occlusion causes significant problems in identifying and locating objects during baggage inspection. The neural network approach is suitable for the problems in the sense that the inherent parallelism of neural networks pursues many hypotheses in parallel resulting in high computation rates. Moreover, they provide a greater degree of robustness or fault tolerance than conventional computers. The annealed Hopfield network which is derived from the mean field annealing (MFA) has been developed to find global solutions of a nonlinear system. In the study, it has been proven that the system temperature of MFA is equivalent to the gain of the sigmoid function of a Hopfield network. In our early work, we developed the hybrid Hopfield network (HHN) for fast and reliable matching. However, HHN doesn't guarantee global solutions and yields false matching under heavily occluded conditions because HHN is dependent on initial states by its nature. In this paper, we present the annealed Hopfield network (AHN) for occluded object matching problems. In AHN, the mean field theory is applied to the hybird Hopfield network in order to improve computational complexity of the annealed Hopfield network and provide reliable matching under heavily occluded conditions. AHN is slower than HHN. However, AHN provides near global solutions without initial restrictions and provides less false matching than HHN. In conclusion, a new algorithm based upon a neural network approach was developed to demonstrate the feasibility of the automated inspection of threat objects from x-ray images. The robustness of the algorithm is proved by identifying occluded target objects with large tolerance of their features.

Kim, Jung H.↗
NASA NTRS1953

Altitude Operational Characteristics of Prototype J40-WE-8 Turbojet Engine

The altitude operational characteristics of the prototype J40-WE-8 turbojet engine were determined in the NACA Lewis altitude wind tunnel. The operational characteristics that were obtained include (1) compressor surge characteristics, (2) acceleration and deceleration rates, (3) steady-state windmilling-engine characteristics, (4) altitude ignition characteristics, and (5) the effect of two grades of fuel on steady-state engine performance at an altitude of 45,000 feet and a flight Mach number of 0.20. The altitude ignition characteristics determined include the effects of (1) ignition fuel flow, (2) two ignition procedures, (3) fuel temperatures, and (4) two grades of fuel on ignition characteristics. The compressor surge line, when presented as a function of compressor pressure ratio and corrected engine speed, was not affected by changes in flight condition and was independent of engine-inlet installation and of the manner in which surge was approached, rapidly or slowly. Also there was no effect of altitude or engine-inlet installation on the compressor surge recovery line when presented as a function of compressor pressure ratio and corrected engine speed.

FUELS - RELATION TO ENGINE PERFORMANCE↗
NASA NTRS1995

Integrated Cryogenic Satellite Communications Cross-Link Receiver Experiment

An experiment has been devised which will validate, in space, a miniature, high-performance receiver. The receiver blends three complementary technologies; high temperature superconductivity (HTS), pseudomorphic high electron mobility transistor (PHEMT) monolithic microwave integrated circuits (MMIC), and a miniature pulse tube cryogenic cooler. Specifically, an HTS band pass filter, InP MMIC low noise amplifier, HTS-sapphire resonator stabilized local oscillator (LO), and a miniature pulse tube cooler will be integrated into a complete 20 GHz receiver downconverter. This cooled downconverter will be interfaced with customized signal processing electronics and integrated onto the space shuttle's 'HitchHiker' carrier. A pseudorandom data sequence will be transmitted to the receiver, which is in low Earth orbit (LEO), via the Advanced Communication Technology Satellite (ACTS) on a 20 GHz carrier. The modulation format is QPSK and the data rate is 2.048 Mbps. The bit error rate (BER) will be measured in situ. The receiver is also equipped with a radiometer mode so that experiment success is not totally contingent upon the BER measurement. In this mode, the receiver uses the Earth and deep space as a hot and cold calibration source, respectively. The experiment closely simulates an actual cross-link scenario. Since the receiver performance depends on channel conditions, its true characteristics would be masked in a terrestrial measurement by atmospheric absorption and background radiation. Furthermore, the receiver's performance depends on its physical temperature, which is a sensitive function of platform environment, thermal design, and cryocooler performance. This empirical data is important for building confidence in the technology.

Romanofsky, R. R.↗
NASA NTRS2001

Ar Atmosphere: Implications for Structure and Composition of Mercury's Crust

We examine the possibilities of sustaining an argon atmosphere by diffusion from the upper 10 km of crust, and alternatively by effusion from a molten or previously molten area at great depth . Ar-40 in the atmospheres of the planets is a measure of potassium abundance in the interiors since Ar-40 is a product of radiogenic decay of K-40 by electron capture with the subsequent emission of a 1.46 eV gamma-ray. Although the Ar-40 in the earth's atmosphere is expected to have accumulated since the late bombardment, Ar-40 in surface-bounded exospheres is eroded quickly by photoionization and electron impact ionization. Thus, the argon content in the exospheres of the Moon, Mercury and probably Europa is representative of current effusion rather than accumulation over the lifetime of the body. Argon content will be a function of K content, temperature, grain size distribution, connected pore volume and possible seismic activity. Although Mercury and the Moon differ in many details, we can train the solutions to diffusion equations to predict the average lunar atmosphere. Then these parameters can be varied for Hermean conditions. Assuming a lunar crustal potassium abundance of 300 ppm, the observed argon atmosphere requires equilibrium between the argon production in the upper 9 Km of the moon (1.135 x 10(exp -3) cm(exp -3) s(exp -1)) and its loss. Hodges et al. conclude that this loss rate and the observed time variability requires argon release through seismic activity, tapping a deep argon source. An important observation is that the extreme surface of the Moon is enhanced in argon rather than depleted, as one would expect from outgassing of radiogenic argon. Manka and Michel concluded that ion implantation explains the surface enhancement of Ar-40. About half of the argon ions produced in the lunar atmosphere would return to the surface, where they would become embedded in the rocks. Similarly, at Mercury we expect the surface rocks to be enhanced in Ar-40 wherever the magnetosphere has been open over time. Thus the measurement of surface composition will reveal the long-term effects of solar wind-magnetosphere interaction. Additional information is contained in the original extended abstract.

Killen, R. M.↗
NASA NTRS2005

Energetic Metastable Oxygen and Nitrogen Atoms in the Terrestrial Atmosphere

This report summarizes our research performed under NASA Grant NAG5-11857. The three-year grant have been supported by the Geospace Sciences SR&T program. We have investigated the energetic metastable oxygen and nitrogen atoms in the terrestrial stratosphere, mesosphere and thermosphere. Hot atoms in the atmosphere are produced by solar radiation, the solar wind and various ionic reactions. Nascent hot atoms arise in ground and excited electronic states, and their translational energies are larger by two - three orders of magnitude than the thermal energies of the ambient gas. The relaxation kinetics of hot atoms determines the rate of atmospheric heating, the intensities of aeronomic reactions, and the rate of atom escape from the planet. Modeling of the non-Maxwellian energy distributions of metastable oxygen and nitrogen atoms have been focused on the determination of their impact on the energetics and chemistry of the terrestrial atmosphere between 25 and 250 km . At this altitudes, we have calculated the energy distribution functions of metastable O and N atoms and computed non-equilibrium rates of important aeronomic reactions, such as destruction of the water molecules by O(1D) atoms and production of highly excited nitric oxide molecules. In the upper atmosphere, the metastable O(lD) and N(2D) play important role in formation of the upward atomic fluxes. We have computed the upward fluxes of the metastable and ground state oxygen atoms in the upper atmosphere above 250 km. The accurate distributions of the metastable atoms have been evaluated for the day and night-time conditions.

Kharchenko, Vasili↗
DOE OSTI2015

Rapid and Facile Formation of P3HT Organogels via Spin Coating: Tuning Functional Properties of Organic Electronic Thin Films

Poly(3-hexyl thiophene) (P3HT) is widely regarded as the benchmark polymer when studying the physics of conjugated polymers used in organic electronic devices. P3HT can self-assemble via stacking of its backbone, leading to an assembly and growth of P3HT fi brils into 3D percolating organogels. These structures are capable of bridging the electrodes, providing multiple pathways for charge transport throughout the active layer. Here, a novel set of conditions is identified and discussed for P3HT organogel network formation via spin coating by monitoring the spin-coating process from various solvents. The development of organogel formation is detected by in situ static light scattering, which measures both the thinning rate by refl ectance and structural development in the fi lm via off-specular scattering during fi lm formation. Optical microscopy and thermal annealing experiments provide ex situ confi rmation of organogel fabrication. The role of solution characteristics, including solvent boiling point, P3HT solubility, and initial P3HT solution concentration on organogel formation, is examined to correlate these parameters to the rate of film formation, organogel-onset concentration, and overall network size. The correlation of film properties to the fabrication parameters is also analyzed within the context of the hole mobility and density-of-states measured by impedance spectroscopy.

36 MATERIALS SCIENCE↗
NASA NTRS1977

Observed differences in learning ability of heart rate self-regulation as a function of hypnotic susceptibility

Three groups of eight male and female subjects (aged 20-27 yr) categorized by low and high hypnotic susceptibility were taught to control their heart rates by means of an appropriate autogenic therapy/biofeedback technique. The experimental groups were trained by autogenic therapy and biofeedback, while the control group received only biofeedback. Significant differences are observed in all psychological test scores between subjects of high and low hypnotic susceptibility. The results confirm that (1) there are qualitative and quantitative differences between the performance of individuals with high and low hypnotic susceptibility; (2) interindividual-variability tests yield data relevant to individual performance in visceral learning tasks; (3) the combined autogenic therapy/biofeedback/verbal feedback technique is suitable for conditioning large stable autonomic responses in humans; and (4) this kind of conditioning is effective in eliminating or alleviating physiological reactions to some environmental stressors.

Cowings, P. S.↗
DOE OSTI2022

Developing Reaction Chemistry Models from Reactive Molecular Dynamics: TATB

Reactive Molecular Dynamic (RMD) are used to simulate the cook-off chemistry of TATB at a variety of fixed density and fixed temperature conditions. The chemical transformations are monitored using a Coordination Geometry Analysis (CGA) approach which tracks which atom types are bonded to each specific atom. This particularly identifies oxidation state changes that occur during the transformations. Correlations between these different chemical changes are identified using a Non-negative Matrix Factorization (NMF) approach. These identify reduced order chemistry models for the TATB system which contains six components whose concentration profiles are a function of both the temperature and density/pressure. The time histories of these transformations appear to show exponential growth/decay properties that could be fit with Arrhenius rates. These components should form the basis of deflagration rate models for these materials which could then be used in mesoscale simulations to analyze accidental initiation, shock-to-detonation and detonation propagation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

The Majorana Demonstrator calibration system

The Majorana Collaboration is searching for the neutrinoless double-beta decay of the nucleus 76 Ge. The Majorana Demonstrator is an array of germanium detectors deployed with the aim of implementing background reduction techniques suitable for a 1-ton 76 Ge-based search. The ultra low-background conditions require regular calibrations to verify proper function of the detectors. Radioactive line sources can be deployed around the cryostats containing the detectors for regular energy calibrations. When measuring in low-background mode, these line sources have to be stored outside the shielding so they do not contribute to the background. The deployment and the retraction of the source are designed to be controlled by the data acquisition system and do not require any direct human interaction. In this study, we detail the design requirements and implementation of the calibration apparatus, which provides the event rates needed to define the pulse-shape cuts and energy calibration used in the final analysis as well as data that can be compared to simulations.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2019

Close-contact melting on an isothermal surface with the inclusion of non-Newtonian effects

The present study deals with a theoretical investigation of a close-contact melting (CCM) process involving a vertical cylinder on a horizontal isothermal surface, where the liquid phase is a non-Newtonian viscoplastic fluid that behaves according to the Bingham model. Accordingly, a new approach is formulated based on the thin layer approximation and different quasi-steady process assumptions. By analytical derivation, an algebraic equation that relates the molten layer thickness and the solid bulk height is developed. The problem is then solved numerically, coupled with another equation for the melting rate. The new model shows that as the yield stress increases the melting rate decreases and the molten layer thickness increases. It is found that under certain conditions, the model can be reduced to a form that allows an analytical solution. The approximate model predicts an exponential dependence of both the melt fraction and the molten layer thickness. Comparison between the numerical and analytical solutions shows that the analytical approximation provides an excellent estimation for sufficiently large values of the yield stress. Dimensional analysis, which is supported by the analytical model results, reveals the dimensionless groups that govern the problem. For the general case, the melt fraction is a function of two dimensionless groups. For the analytical approximation, it is shown that the melt fraction is governed by a single dimensionless group and that the molten layer thickness is governed by two dimensionless groups.

Mechanics↗
DOE OSTI2024

Influence of Concentration Gradients on Electroconvection at a Cation-Exchange Membrane Surface

Membrane-based systems, such as electrodialysis, play an important role in desalination and industrial separation processes. Electrodialysis uses alternating anion- and cation-exchange membranes with a perpendicular electric field to generate concentrated and diluate streams from a feed solution. It is known that under overlimiting current conditions, reduced charge and mass transfer at the membrane interface leads to regions of high ion depletion generating instability and vortices termed electroconvection. While electroconvective mixing is known to directly impact the separation efficiency of electrodialysis, the influence of ion concentration gradients across the membrane experienced in a functional electrodialysis system is not known. Here, we report the influence of ion concentration gradients across a cation exchange membrane (Nafion) that is both aligned with and opposed to the applied electric field. Experiments were conducted by coflowing NaCl solutions of different concentrations (0.1–100 mM) on each side of the membrane, and electroconvection was visualized with a fluorescence dye (Rhodamine 6G). Here, we obtained concentration profiles from fluorescence image data and systematically measured the thickness of the depletion boundary layer d BL under different conditions. We found smaller d BL values at a higher flow rate both with and without concentration gradients. Our results show that electroconvection is enhanced when the electric field is opposite to the direction of the concentration gradient.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

nn-PINNs: Non-Newtonian physics-informed neural networks for complex fluid modeling

Time- and rate-dependent material functions in non-Newtonian fluids in response to different deformation fields pose a challenge in integrating different constitutive models into conventional computational fluid dynamic platforms. Considering their relevance in many industrial and natural settings alike, robust data-driven frameworks that enable accurate modeling of these complex fluids are of great interest. The main goal is to solve the coupled Partial Differential Equations (PDEs) consisting of the constitutive equations that relate the shear stress to the deformation and fully capture the behavior of the fluid under various flow protocols with different boundary conditions. Here, in this work, we present non-Newtonian physics-informed neural networks (nn-PINNs) for solving systems of coupled PDEs adopted for complex fluid flow modeling. The proposed nn-PINN method is employed to solve the constitutive models in conjunction with conservation of mass and momentum by benefiting from Automatic Differentiation (AD) in neural networks, hence avoiding the mesh generation step. nn-PINNs are tested for a number of different complex fluids with different constitutive models and for several flow protocols. These include a range of Generalized Newtonian Fluid (GNF) empirical constitutive models, as well as some phenomenological models with memory effects and thixotropic timescales. nn-PINNs are found to obtain the correct solution of complex fluids in spatiotemporal domains with good accuracy compared to the ground truth solution. We also present applications of nn-PINNs for complex fluid modeling problems with unknown boundary conditions on the surface, and show that our approach can successfully recover the velocity and stress fields across the domain, including the boundaries, given some sparse velocity measurements.

42 ENGINEERING↗