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At least 1,567 records · Page 87

Current status of biogas upgrading for direct biomethane use: A review

Anaerobic digestion produces biogas, a mixture of CH 4 and CO 2 , where CH 4 is a low cost, environmentally friendly, and renewable energy source. The application of biogas production is increasing rapidly as a means of reducing the pollution impact of organic biomasses. However, biogas contains unwanted elements such as hydrogen sulfide, carbon monoxide, siloxanes, and carbon dioxide. To remove these elements, several biogas upgrading technologies like water scrubbing, amine scrubbing, pressure swing adsorption, and membrane separation have been developed and are being used at various commercial scales. Problems with these methods are high energy consumption, the use of expensive chemicals, and high operating cost. Therefore, a major effort is currently underway to improve the design of existing methods as well as developing innovative new upgrading technologies such as cryogenic separation and biological upgrading. Here, this review intends to provide a comprehensive overview of the limitations with the existing upgrading technologies along with recent advances in physical, chemical, and biological biogas upgrading technologies (e.g., pressure swing adsorption, membrane separation, biochar adsorption and CO 2 conversion by biological organisms) and further into possible future solutions, such as hybrid systems. Comparative studies of process complexities and associated economic concerns are also provided, and future perspectives that may facilitate research into sustainable biogas upgrading technologies are discussed, focusing in particular on cryogenic separation, novel biological techniques, biochar based upgrading and hybrid technologies incorporating two or more different methods seamlessly integrated.

09 BIOMASS FUELS↗

The stability of steady motion of magnetic domain wall: Role of higher-order spin-orbit torques

The steady motion of magnetic domain wall driven by spin-orbit torques is investigated analytically in the heavy/ferromagnetic metal nanowires for three cases with a current transverse to the in-plane and perpendicular easy axis, and along the in-plane easy axis. By the stability analysis of Walker wall profile, we find that if including the higher-order spin-orbit torques, the Walker breakdown can be avoided in some parameter regions of spin-orbit torques with a current transverse to or along the in-plane easy axis. However, in the case of perpendicular anisotropy, even considering the higher-order spin-orbit torques, the velocity of domain wall cannot be efficiently enhanced by the current. Furthermore, the direction of wall motion is dependent on the configuration and chirality of domain wall with a current along the in-plane easy axis or transverse to the perpendicular one. Especially, the direction of motion can be controlled by the initial chirality of domain wall. So, if only involving the spin-orbit mechanism, it is preferable to adopt the scheme of a current along the in-plane easy axis for enhancing the velocity and controlling the direction of domain wall.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Detecting electron neutrinos from solar dark matter annihilation by JUNO

We explore the electron neutrino signals from light dark matter (DM) annihilation in the Sun for the large liquid scintillator detector JUNO. In terms of the spectrum features of three typical DM annihilation channels χχ→νν-bar,τ{sup +}τ{sup −},bb-bar, we take two sets of selection conditions to calculate the expected signals and atmospheric neutrino backgrounds based on the Monte Carlo simulation data. Then the JUNO sensitivities to the spin independent DM-nucleon and spin dependent DM-proton cross sections are presented. It is found that the JUNO projected sensitivities are much better than the current spin dependent direct detection experimental limits for the νν-bar and τ{sup +}τ{sup −} channels. In the spin independent case, the JUNO will give the better sensitivity to the DM-nucleon cross section than the LUX and CDMSlite limits for the νν-bar channel with the DM mass lighter than 6.5 GeV. If the νν-bar or τ{sup +}τ{sup −} channel is dominant, the future JUNO results are very helpful for us to understand the tension between the DAMA annual modulation signal and other direct detection exclusions.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Stackable bipolar pouch cells with corrosion-resistant current collectors enable high-power aqueous electrochemical energy storage

A critical bottleneck in the development of aqueous electrochemical energy storage systems is the lack of viable complete cell designs. Here, we report a metal-free, bipolar pouch cell designed with carbon black/polyethylene composite film (CBPE) current collectors as a practical cell architecture. The light-weight, corrosion-resistant CBPE provides stable operation in a variety of aqueous electrolytes over a ~2.5 V potential range. Because CBPE is heat-sealable, it serves simultaneously as both the pouch cell packaging and seal in addition to its use as a current collector. Although this non-metallic composite has a low electrical conductivity relative to metal foils, current travels only a short distance in the through-plane direction of the current collector in the bipolar cell configuration. This shorter path length lowers the effective electrical resistance, making the design suitable for high-power applications. We test the cell architecture using an aqueous ZnBr 2 battery chemistry and incorporate tetrabutylammonium cations to improve the intrinsic low Coulombic efficiency and fast self-discharge of non-flow ZnBr 2 cells. These devices demonstrate a cell-level energy density of 50 W h L -1 at a 10C rate (0.5 kW L -1 ), with less than 1% capacity loss over 500 cycles. A large-area (>6 cm 2 ) 4-cell stack is built to illustrate that the pouch cells are scalable to practical dimensions and stackable without sacrificing performance. The device operates in the range of 6–7 V and has an internal self-balancing mechanism that prevents any individual cell in the stack from overcharging. The results thus demonstrate both a conceptually new cell architecture that is broadly applicable to many aqueous electrolyte chemistries and a specific high-performance example thereof.

25 ENERGY STORAGE↗

Regulator Circuit For Bilateral Source/Load Power System

Circuit regulates output voltage whether current flows from left source/load to right load/source or vice versa. Overall system characterized as voltage-controlled current source with bilateral current capability. Additional feature of control circuit is that maximum current in either direction limited by limiting excursion of output voltage from zero-current value. Thus, external current-limiting circuitry not necessary.

Madden, George↗

Direct air capture of CO2: from insights into the current and emerging approaches to future opportunities

The rapid development of direct air capture (DAC) technologies has become critical in order to remove CO 2 from the atmosphere and limit global warming to a maximum of 1.5°C. In this perspective, we provide a mini review of the current research on the emerging liquid- and solid-based sorbent materials to capture CO 2 , summarize the existing challenges of DAC technologies, and suggest future research directions to accelerate the development of DAC systems. In particular, the desired properties for a breakthrough sorbent that efficiently captures CO 2 from the air and releases it for sequestration are described.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Complementarity between nonstandard Higgs boson searches and precision Higgs boson measurements in the MSSM

Precision measurements of the Higgs boson properties at the LHC provide relevant constraints on possible weak-scale extensions of the Standard Model (SM). In the context of the minimal supersymmetric Standard Model (MSSM) these constraints seem to suggest that all the additional, non-SM-like Higgs bosons should be heavy, with masses larger than about 400 GeV. This article shows that such results do not hold when the theory approaches the conditions for “alignment independent of decoupling,” where the lightest CP-even Higgs boson has SM-like tree-level couplings to fermions and gauge bosons, independently of the nonstandard Higgs boson masses. In addition, the combination of current bounds from direct Higgs boson searches at the LHC, along with the alignment conditions, have a significant impact on the allowed MSSM parameter space yielding light additional Higgs bosons. In particular, after ensuring the correct mass for the lightest CP-even Higgs boson, we find that precision measurements and direct searches are complementary and may soon be able to probe the region of non-SM-like Higgs boson with masses below the top quark pair mass threshold of 350 GeV and low to moderate values of tanβ.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Combinatorial Discovery and Optimization of the Composition, Doping and Morphology of New Oxide Semiconductors for Efficient Photoelectrochemical Water Splitting

The increasing need for carbon free energy has focused renewed attention on solar energy conversion. Although photovoltaic cells excel at directly converting of solar energy to electricity, they do not directly produce stored energy or fuels that account for more than 75% of current energy use. Direct photoelectrolysis of water has the advantage of converting solar energy directly to hydrogen, an ideal non-carbon and nonpolluting energy carrier, by replacing both a photovoltaic array and an electrolysis unit with one potentially inexpensive device. Unfortunately no materials are currently known to efficiently photoelectrolyze water that are, efficient, inexpensive and stable under illumination in electrolytes for many years. Nanostructured semiconducting metal oxides could potentially fulfill these requirements, making them the most promising materials for solar water photoelectrolysis, however no oxide semiconductor has yet been discovered with all the required properties. We have developed a simple, high-throughput combinatorial approach to prepare and screen many multi component metal oxides for water photoelectrolysis activity. The approach uses ink jet printing of overlapping patterns of soluble metal oxide precursors onto conductive glass substrates. Subsequent pyrolysis produces metal oxide phases that are screened for photoelectrolysis activity by measuring photocurrents produced by scanning a laser over the printed patterns in aqueous electrolytes. Several promising and unexpected compositions have been identified.

36 MATERIALS SCIENCE↗

Urbanization Impact on Regional Climate and Extreme Weather: Current Understanding, Uncertainties, and Future Research Directions

Abstract Urban environments lie at the confluence of social, cultural, and economic activities and have unique biophysical characteristics due to continued infrastructure development that generally replaces natural landscapes with built-up structures. The vast majority of studies on urban perturbation of local weather and climate have been centered on the urban heat island (UHI) effect, referring to the higher temperature in cities compared to their natural surroundings. Besides the UHI effect and heat waves, urbanization also impacts atmospheric moisture, wind, boundary layer structure, cloud formation, dispersion of air pollutants, precipitation, and storms. In this review article, we first introduce the datasets and methods used in studying urban areas and their impacts through both observation and modeling and then summarize the scientific insights on the impact of urbanization on various aspects of regional climate and extreme weather based on more than 500 studies. We also highlight the major research gaps and challenges in our understanding of the impacts of urbanization and provide our perspective and recommendations for future research priorities and directions.

54 ENVIRONMENTAL SCIENCES↗

Structure of Longitudinal and Transverse Currents in Current Sheets

The structure of magnetic fields and currents in current sheets formed in 2D and 3D magnetic configurations with an X line is analyzed using experimental data. It is found that, in addition to the main (longitudinal) current, transverse currents comparable in magnitude with the main current are also generated in current sheets. Relations between the longitudinal and transverse currents in current sheets formed in different magnetic configurations are obtained. The vectors of the total currents and their deviations from the direction of the main current in different regions of the sheet are determined. It is shown that the total magnetic fields and currents in current sheets have a 3D structure.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Direct measurements of the atmospheric conduction current

A method of measuring the atmospheric conduction current above the ground has been employed to obtain data for 12 weeks during the first half of 1974. The instrument consists of a split aluminum sphere suspended by insulated wires to a wooden frame. The measuring electronics and the transmitter are enclosed within the spherical structure. The interaction of the instrument with its atmospheric electrical environment is analyzed, and it is shown that in steady state conditions, predictable differences in the instrumentally measured currents and the atmospheric conduction current will be less than 5% and in the nonsteady state situations the difference is less than 20%. Diurnal variations, a probable winter-summer variation, sunrise, and fog effects were observed for the data obtained during fair-weather conditions. Disturbed weather data are interpreted for the effects of low clouds on the atmospheric current. The charge concentrations within overcast clouds sufficient to produce the observed reversed atmospheric currents are estimated to be small in relation to values in thunderclouds.

Burke, H. K.↗

Multiple strike slip faults sets: A case study from the Dead Sea transform

In many strike slip tectonic settings, large rotations of crust blocks about vertical axes have been inferred from paleomagnetic data. These blocks are bounded by sets of parallel faults which presumably accommodate the relative motion between the blocks as regional deformation progress. A mechanical model by Nur et al., (1986) suggests that rotations greater than phi sub c equals 25 to 45 degrees must be accommodated by more than one set of faults, with angle phi sub c between their direction; consequently the sum of the angles between sets must be roughly equal to the total tectonic material rotation. To test this model, the authors investigated the fault geometry and field relation of fault sets in the Mt. Hermon area in northern Israel, where paleomagnetic declination implies data 69 degrees plus or minus 13 degrees counter-clockwise block rotation. The statistical and field relation analysis of over 315 faults shows that the faulting is predominantly right lateral strike slip consisting of three distinct sets. The oldest set strikes 253 degrees, the second oldest set strikes 293 degrees and the youngest strikes 339 degrees. This last direction is consistent also with the current north-south direction of the maximum principle stress axis. The angle phi sub c between the first and second sets is 39 degrees and between the second and third sets 46 degrees, in good agreement with the phi sub c angle predicted from mechanical considerations. The sum of the two angles is 85 degrees, in good agreement with the 69 degrees plus or minus 13 degrees CCW paleomagnetically derived rotation. The results suggest specifically that the sequential development of multiple intersecting fault sets is responsible for the faulting in the Mt. Hermon area; and generally that the model of block rotation with multiple faults provides very good simple rules for analyzing very complex fault patterns.

Ron, Hagai↗

Current status and some future test directions for the U.S. National Transonic Facility

The construction of the National Transonic Facility was completed in September 1982 and the start-up and checkout of the tunnel systems were performed over the following two years. In August 1984, the facility was declared operational for final checkout of cryogenic instrumentation and control systems, and for the aerodynamics calibration and testing to commence. Since 1984 several operational problems have been identified and successfully solved which is demonstrated by the fact that the facility has operated the last year with no significant facility down times. Also during this time period, development of test techniques and instrumentation has continued. This paper will review some of the recent test techniques and instrumentation developments, and will briefly review the status of the facility.

Gloss, Blair B.↗

Scanning Tunneling Optical Resonance Microscopy

Scanning tunneling optical resonance microscopy (STORM) is a method, now undergoing development, for measuring optoelectronic properties of materials and devices on the nanoscale by means of a combination of (1) traditional scanning tunneling microscopy (STM) with (2) tunable laser spectroscopy. In STORM, an STM tip probing a semiconductor is illuminated with modulated light at a wavelength in the visible-to-near-infrared range and the resulting photoenhancement of the tunneling current is measured as a function of the illuminating wavelength. The photoenhancement of tunneling current occurs when the laser photon energy is sufficient to excite charge carriers into the conduction band of the semiconductor. Figure 1 schematically depicts a proposed STORM apparatus. The light for illuminating the semiconductor specimen at the STM would be generated by a ring laser that would be tunable across the wavelength range of interest. The laser beam would be chopped by an achromatic liquid-crystal modulator. A polarization-maintaining optical fiber would couple the light to the tip/sample junction of a commercial STM. An STM can be operated in one of two modes: constant height or constant current. A STORM apparatus would be operated in the constant-current mode, in which the height of the tip relative to the specimen would be varied in order to keep the tunneling current constant. In this mode, a feedback control circuit adjusts the voltage applied to a piezoelectric actuator in the STM that adjusts the height of the STM tip to keep the tunneling current constant. The exponential relationship between the tunneling current and tip-to-sample distance makes it relatively easy to implement this mode of operation. The choice of method by which the photoenhanced portion of the tunneling current would be measured depends on choice of the frequency at which the input illumination would be modulated (chopped). If the frequency of modulation were low enough (typically < 10 Hz) that the feedback circuit could respond, then the voltage applied to the piezoelectric tip-height actuator could be measured by use of a lock-in amplifier locked to the modulation (chopping) signal. However, at a high modulation frequency (typically in the kilohertz range or higher), the feedback circuit would be unable to respond. In this case, the photoenhanced portion of the tunneling current could be measured directly. For this purpose, the tunneling current would be passed through a precise resistor and the voltage drop would be measured by use of the lock-in amplifier.

Bailey, Sheila↗

Deformations of the spin currents by topological screw dislocation and cosmic dispiration

We study the spin currents induced by topological screw dislocation and cosmic dispiration. By using the extended Drude model, we find that the spin dependent forces are modified by the nontrivial geometry. For the topological screw dislocation, only the direction of spin current is bent by deforming the spin polarization vector. In contrast, the force induced by cosmic dispiration could affect both the direction and magnitude of the spin current. As a consequence, the spin-Hall conductivity does not receive corrections from screw dislocation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Acoustically Enhanced Electroplating Being Developed

In cooperation with the NASA Glenn Research Center, Alchemitron Corp. is developing the Acoustically Enhanced Electroplating Process (AEEP), a new technique of employing nonlinear ultrasonics to enhance electroplating. The applications range from electroplating full-panel electronic circuit boards to electroplating microelectronics and microelectromechanical systems (MEMS) devices. In a conventional plating process, the surface area to be plated is separated from the nonplated areas by a temporary mask. The mask may take many forms, from a cured liquid coating to a simple tape. Generally, the mask is discarded when the plating is complete, creating a solid waste product that is often an environmental hazard. The labor and materials involved with the layout, fabrication, and tooling of masks is a primary source of recurring and nonrecurring production costs. The objective of this joint effort, therefore, is to reduce or eliminate the need for masks. AEEP improves selective plating processes by using directed beams of high-intensity acoustic waves to create nonlinear effects that alter the fluid dynamic and thermodynamic behavior of the plating process. It relies on two effects: acoustic streaming and acoustic heating. Acoustic streaming is observed when a high-intensity acoustic beam creates a liquid current within the beam. The liquid current can be directed as the beam is directed and, thus, users can move liquid around as desired without using pumps and nozzles. The current of the electroplating electrolyte, therefore, can be directed at distinct target areas where electroplating is desired. The current delivers fresh electrolyte to the target area while flushing away the spent electrolyte. This dramatically increases the plating rate in the target area. In addition, acoustic heating of both the liquid in the beam and the target surface increases the chemical reaction rate, which further increases the plating rate. The combined effects of acoustic streaming and heating accelerate the deposition of plating in that area and, thus, provide an effect similar to a mask but without the costs of masking. AEEP further improves the plating process by clearing debris and bubbles from the surface by acoustic radiation pressure and acoustic streaming.

Oeftering, Richard C.↗