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At least 1,567 records · Page 87

A simple, validated approach for design of two-dimensional periodic particle patterns via acoustophoresis

Two-dimensional patterning of microparticles enables a wide range of functional materials, including patterned energy storage electrodes, flexible electronics, and sensor arrays. Particle patterning via acoustics offers an attractive path to generate a wide variety of 2D periodic patterns that introduce tailorable hierarchical porosity, useful for controlling surface area, transport distances, and other properties. This method is most effective with micron scale particles and patterns of tens to hundreds of microns. To enable systematic exploration of the broad design space for such patterns, this work develops a model of 2D and 3D assembly of particles at high loadings and validates the obtained patterns against both experiments and more computationally intensive modeling techniques. Using this simple model, connections are mapped between input parameters (like actuation conditions, particle volume fraction, material properties) and output geometrical features (like void size and shape, pattern connectivity, and surface area) so that they can be tailored to given applications. The utility of this simple model is illustrated by predicting and then experimentally demonstrating new hierarchical patterns resulting from multiple waves of different frequencies interacting. These multiscale patterns offer the potential to lift the limits on surface area, diffusion distances, and other features.

42 ENGINEERING↗

Cu-Catalyzed Synthesis of CdZnSe–CdZnS Alloy Quantum Dots with Highly Tunable Emission

Fabrication of quantum dots (QDs) with emission covering a wide spectral region has been persistently intriguing because of their potentials in a range of practical applications such as biological labeling and imaging, solar cells, light-emitting diodes, and next-generation displays. We report the synthesis of CdZnSe–CdZnS core–shell alloy QDs through a Cu-catalyzed solid solution alloying strategy starting from CdSe–CdS core–shell QDs. The resulting CdZnSe–CdZnS alloy QDs exhibit emission profiles covering a wide wavelength range of 470–650 nm while maintaining high photoluminescence quantum yields. In addition, high morphological uniformity of the starting CdSe–CdS QDs can be largely retained in the final alloy QDs. We attribute this alloying process to the high mobility nature of Cu cations in Cd-chalcogenide crystals at elevated reaction temperatures, which allows Cu cations to act as transporting agents to transfer a Zn component into the CdSe–CdS QDs while maintaining the particle integrity. We show that this unique alloying strategy is independent of the shape of the starting QDs and can also be applied to the synthesis of CdZnSe–CdZnS nanorods. We anticipate that our study will instigate the synthesis of various high-quality alloy QDs and other alloy nanocrystals beyond what can be achieved currently.

36 MATERIALS SCIENCE↗

“Intelligent” Pt Catalysts Studied on High-Surface-Area CaTiO 3 Films

CaTiO 3 -supported Pt is sometimes referred to as an “Intelligent” catalyst because Pt can reversibly leave or enter the perovskite lattice following high-temperature reduction or oxidation; however, slow egress-ingress kinetics associated with large perovskite crystallites make these systems impractical. In this study, thin films (~1 nm) of CaTiO 3 were deposited onto MgAl 2 O 4 and then examined as catalyst supports for Pt and Pd. While Pd/CaTiO 3 /MgAl 2 O 4 showed adsorption and CO-oxidation properties that were essentially the same as Pd/MgAl 2 O 4 , the Pt/CaTiO 3 /MgAl 2 O 4 catalyst exhibited evidence for strong support interactions. Pt/CaTiO 3 /MgAl 2 O 4 showed high activity for CO oxidation following reduction at 1073 K, even though CO adsorption was suppressed; but the catalysts were dramatically less active after oxidation at 1073 K and reduction at 773 K. Both Pt/CaTiO 3 /MgAl 2 O 4 and a catalyst formed by ex-solution of CaTi 0.95 Pt 0.05 O 3 exhibited very low rates for toluene hydrogenation in comparison to Pt/MgAl 2 O 4 . Scanning Transmission Electron Microscopy (STEM) and Energy Dispersive Spectroscopy (EDS) showed that the CaTiO 3 films uniformly covered the MgAl 2 O 4 surface after both reduction and oxidation at 1073 K. Pt particles on reduced Pt/CaTiO 3 /MgAl 2 O 4 exhibited an unusual rhombohedral shape and may be flat, a further indication of strong interactions between the metal and the support. Low Energy Ion Scattering (LEIS) indicated that high-temperature reduction caused a restructuring of the CaTiO 3 . Lastly, the implications of these results for understanding catalysts formed by ex-solution of metals from a perovskite lattice are discussed.

36 MATERIALS SCIENCE↗

Automated Sequence Design of 3D Polyhedral Wireframe DNA Origami with Honeycomb Edges

3D polyhedral wireframe DNA nanoparticles (DNA-NPs) fabricated using scaffolded DNA origami offer complete and independent control over NP size, structure, and asymmetric functionalization on the 10–100 nm scale. However, the complex DNA sequence design needed for the synthesis of these versatile DNA-NPs has limited their widespread use to date. While the automated sequence design algorithms DAEDALUS and vHelix-BSCOR apply to DNA-NPs synthesized using either uniformly dual or hybrid single-dual duplex edges, respectively, these DNA-NPs are relatively compliant mechanically and are therefore of limited utility for some applications. Further, these algorithms are incapable of handling DNA-NP edge designs composed of more than two duplexes, which are needed to enhance DNA-NP mechanical stiffness. As an alternative, here we introduce the scaffolded DNA origami sequence design algorithm TALOS, which is a generalized procedure for the fully automated design of wireframe 3D polyhedra composed of edges of any cross section with an even number of duplexes, and apply it to DNA-NPs composed uniformly of single honeycomb edges. We also introduce a multiway vertex design that enables the fabrication of DNA-NPs with arbitrary edge lengths and vertex angles and apply it to synthesize a highly asymmetric origami object. Sequence designs are demonstrated to fold robustly into target DNA-NP shapes with high folding efficiency and structural fidelity that is verified using single particle cryo-electron microscopy and 3D reconstruction. Furthermore, in order to test its generality, we apply TALOS to design an in silico library of over 200 DNA-NPs of distinct symmetries and sizes, and for broad impact, we also provide the software as open source for the generation of custom NP designs.

3D cryo-EM reconstruction↗

Local Cation-Ordered Superlattice Stabilizing Ni-Rich Single-Crystalline Cathodes

Ni-rich single-crystalline cathodes are pivotal for advancing lithium-ion battery technology due to their high energy density and mechanical stability. However, Ni-rich single-crystalline particles face intrinsic structural heterogeneity due to excessively high sintering temperature required to shape micron-sized morphologies─typically over 150 °C above the polycrystalline optimum, leading to rapid electrochemical decay and unsatisfied rate performance that hinder their practical application. Here, in this work, we propose a lithium-deficient presintering strategy to synthesize cation-ordered single-crystalline LiNi 0.83 Co 0.12 Mn 0.05 O 2 (S-NCM83), effectively minimizing lattice chemical heterogeneity and defect formation. The resulting cation-ordered percolation network enhances the structural stability of the bulk, reduces the energy barrier for Li + migration, and stabilizes Li + diffusion pathways. Consequently, S-NCM83 demonstrates significantly improved cycling stability across various operating temperatures and achieves exceptional rate performance, delivering 206 mAh g –1 at 0.1 C and 170 mAh g –1 at 5 C, without requiring surface coatings or doping. This work introduces a universal strategy to address the long-standing structural instability issues in single-crystalline cathodes, paving the way for simplified and scalable approaches to long-life and high-energy lithium-ion batteries.

36 MATERIALS SCIENCE↗

Comparative analysis of the effect of low-dimensional alumina structures on cell lines L929 and Neuro-2a

The paper presents the toxicity evaluation of nanostructures on the basis of alumina of different shape (nanofibers, nanoplates, nanosheets, nanosheet agglomerates) and with similar physical and chemical properties (particle size, specific surface area, phase composition, and zeta potential). The nanostructures were examined by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), low-temperature nitrogen adsorption, and dynamic light scattering (DLS). The cytotoxicity of nanostructures was estimated using L929 fibroblast cells and Neuro-2a tumor cells. It has been found that the L929 cells are less subject to the influence of alumina nanoparticles than the Neuro-2a tumor cells. Probably, the differences in the proliferation activity of normal and tumor cells in contact with the synthesized nanostructures are due to a change in the pH of the cell microenvironment.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Scanning SQUID study of ferromagnetism and superconductivity in infinite-layer nickelates

Infinite-layer nickelates R 1-x Sr x NiO 2 (R = La, Pr, Nd) are a class of superconductors with structural similarities to cuprates. Although long-range antiferromagnetic order has not been observed for these materials, magnetic effects such as antiferromagnetic spin fluctuations and spin-glass behavior have been reported. Different experiments have drawn different conclusions about whether the pairing symmetry is s or d wave. In this paper, we applied a scanning superconducting quantum interference device (SQUID) to probe the magnetic behavior of film samples of three infinite-layer nickelates (La 0.85 Sr 0.15 NiO 2 , Pr 0.8 Sr 0.2 NiO 2 , and Nd 0.775 Sr 0.225 NiO 2 ) grown on SrTiO 3 (STO), each with a nominal thickness of 20 unit cells. In all three films, we observed a ferromagnetic background. We also measured the magnetic susceptibility above the superconducting critical temperature in Pr 0.8 Sr 0.2 NiO 2 and La 0.85 Sr 0.15 NiO 2 and identified a non-Curie-Weiss dynamic susceptibility. Both magnetic features are likely due to NiO x nanoparticles. We investigated superconductivity in Pr 0.8 Sr 0.2 NiO 2 and Nd 0.775 Sr 0.225 NiO 2 , which exhibited inhomogeneous diamagnetic screening. The superfluid density inferred from the diamagnetic susceptibility in relatively homogeneous regions shows T-linear behavior in both samples. Finally, we observed superconducting vortices in Nd 0.775 Sr 0.225 NiO 2 . We determined a Pearl length of 330 µm for Nd 0.775 Sr 0.225 NiO 2 at 300 mK, both from the strength of the diamagnetism and from the size and shape of the vortices. These results highlight the importance of considering NiO x particles when interpreting experimental results for these films.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Some scattering problems of interstellar grains

Consideration of the general effects of size, shape, chemical composition, index of refraction, temperature, and other physical parameters of small particles upon their scattering properties. A determination of the relative importance of these effects to interstellar dust interpretations is attempted with the ultimate aim of a full definition of interstellar grain optics.

Greenberg, J. M.↗

Critique of fluid theory of magnetospheric phenomena

It is pointed out that the fluid theory has been successful in magnetospheric problems (such as the shape of the magnetopause) which involve basic considerations such as the conservation of particles, of momentum, and of energy, but that it is inadequate for other problems (such as the energization of auroral particles). Difficulties arise from the fact that it is not always possible to specify 'a volume of plasma' because particles do not remain as neighbors. Misuse of the fluid theory has led to a number of fallacies, such as the idea that the causal order of physical events in cosmic electrodynamics is the reverse of that in the familiar laboratory electrodynamics. This mistaken idea comes from a confusion of a mathematical sequence of calculations with the causal order. A plea is made for a common sense approach to magnetospheric and auroral problems wherein the fluid theory is used whenever it can, but where it is not expected to be adequate for all occasions.

Heikkila, W. J.↗

Cosmic ray composition measurements and high energy ionization spectrometers

Element abundances of cosmic rays Li through Si with energy above 0.8 GeV/amu were measured on a balloon borne instrument containing a total absorption ionization spectrometer. Statistical techniques were used to analyze the five measurements of each particle to determine its charge and energy. The technique allows a determination of systematic errors to be made. Corrections for Landau fluctuations, spark chamber inefficiency, and background particles were included. Comparison with other published results is made. Differences in the shape of the spectrum determined from measurements of different workers indicate that the absolute intensity is still known to only plus or minus 15% between 2 and 10 GV/c rigidity.

Arens, J. F.↗

Characteristics of magnetospheric radio noise spectra

Magnetospheric radio noise spectra (30 kHz to 10 MHz) taken by IMP-6 and RAE-2 exhibit time-varying characteristics which are related to spacecraft position and magnetospheric processes. In the mid-frequency range (100-1,000 kHz) intense noise peaks rise by a factor of 100 or more above background; 80% of the peak frequencies are within the band 125 kHz to 600 kHz, and the peak occurs most often (18% of the time) at 280 kHz. This intense mid-frequency noise has been detected at radial distances from 1.3 Re to 60 Re on all sides of the Earth during magnetically quiet as well as disturbed periods. Maximum occurrence of the mid-frequency noise is in the evening to midnight hours where splash-type energetic particle precipitation takes place. ""Magnetospheric lightning'' can be invoked to explain the spectral shape of the observed spectra.

Herman, J. R.↗

Apollo 17 ropy glasses

Ropy glasses are a major soil component in the Apollo 17 gray soils 74240 and 74260. These particles form a distinct morphological type characterized by a wide range of dynamic shapes with a diagnostic sorted and welded fine-grained debris coating. Apollo 17 ropy glasses show abundant evidence for shock. Shocked lithic and mineral inclusions, lack of any igneous textures, and lechatelierite, all indicate an impact origin. A striking similarity is observed between the lunar ropy glasses and the glass impact bombs (Flaedle) of the Ries Crater in Germany. A highland basaltic composition was observed for the Apollo 17 ropy glasses in contrast to the KREEP composition of ropy glasses from the Apollo 12 and Apollo 14 landing sites. Other workers have presented convincing evidence that ejecta from Tycho reached the Taurus-Littrow Valley, and these ropy glasses may represent Tycho ejecta. However, the close stratigraphic association of the ropy glasses with the greater than 3.5 b.y. old orange glass suggests the ropy glasses may be too old to be Tycho ejecta, which should be only about 100 m.y. old. If this is the case, the ropy glasses represent impact glasses from a very old impact in an unknown highlands source area.

Fruland, R. M.↗

The effect of coronal transport of energetic solar particles

A single active center was the origin of several solar flares observed in September, 1977. The longitude of the flares ranged from approximately 115 deg E to approximately 117 deg W. During this period Helios 1, Helios 2, Voyager 1 and Voyager 2 were extended over a range of approximately 120 deg in longitude, thus providing an opportunity to study the coronal transport of energetic solar flare particles. The result of a detailed study of the relative intensity and spectral shape of approximately 2-200 MeV protons and alphas at several solar longitudes has enabled the imposition of some criteria on models of coronal transport.

Conlon, T. F.↗

The energy spectra of solar flare electrons

A survey of 50 electron energy spectra from .1 to 100 MeV originating from solar flares was made by the combination of data from two spectrometers onboard the International Sun Earth Explorer-3 spacecraft. The observed spectral shapes of flare events can be divided into two classes through the criteria of fit to an acceleration model. This standard two step acceleration model, which fits the spectral shape of the first class of flares, involves an impulsive step that accelerates particles up to 100 keV and a second step that further accelerates these particles up to 100 MeV by a single shock. This fit fails for the second class of flares that can be characterized as having excessively hard spectra above 1 MeV relative to the predictions of the model. Correlations with soft X-ray and meter radio observations imply that the acceleration of the high energy particles in the second class of flares is dominated by the impulsive phase of the flares.

Evenson, P. A.↗

Twinning of dodecanedicarboxylic acid

Twinning of 1,10-dodecanedicarboxyl acid (DDA) was observed in 0.1 mm thick films with a polarizing microscope. Twins originated from polycrystalline regions which tended to nucleate on twin faces, and terminated by intersection gone another. Twinning increased dramatically with addition of organic compounds with a similar molecular size and shape. Increasing the freezing rate, increasing the temperature gradient, and addition of silica particles increased twinning. It is proposed that twins nucleate with polycrystals and sometimes anneal out before they become observable. The impurities may enhance twinning either by lowering the twin energy or by adsorbing on growing faces.

Sen, R.↗

Effect of conductivity and concentration on the sample stream in the transverse axis of a continuous flow electrophoresis chamber

The resolution of continuous flow electrophoresis systems is generally measured by the spread of the sample bands in the direction of the electrophoretic migration. This paper evaluates the cross section of the sample bands in the plane perpendicular to the flow and shows that the spread in the direction perpendicular to the migration increased significantly with the applied electric field. Concentrated samples of monodisperse latex particles and vinyltoluene T-butylstyrene particles in sample buffers of different electrical conductivities were used to map the shape of the sample bands relative to the zero electric field case. As the electric field was applied, the sample band spread from an initial diameter of only one-third the chamber thickness until it approached the chamber walls where electroosmosis significantly reduced the resolution of separation. It can be shown, however, that it is possible to minimize these distortions by careful sample preparation and experiment design.

Miller, Teresa Y.↗

Optical Analysis of Impact Features in Aerogel From the Orbital Debris Collection Experiment on the MIR Station

The Mir Environmental Effects Package (MEEP) was deployed on the Mir station and retrieved after 18 months in space. The payload included the orbital debris collector (ODC), designed and built at the Johnson Space Center to capture and return analyzable residues of the man-made and natural particulate environment in low-Earth orbit for a detailed assessment of its compositional makeup and potential origins. The ODC exposed 2 identical trays, with highly porous, low-density SiO2 aerogel as the basic collector medium, pointed in opposite directions. The aerogel was expected to gently decelerate and capture hypervelocity particles, as opposed to other media that resulted in melting or vaporization of many impactors. Even cursory examination of the returned ODC collectors revealed a surprising variety of impact features. The compositional analyses using scanning electron "miccroscope-energy-dispersive X-ray spectroscopy concentrated on a survey-type inventory of diverse particle types and associated impact features. Detections, in the form of carrot-shaped tracks and shallow pits, included metallic Al, stainless steel, soldering compounds, human waste, and paint flakes. Many pits contained no detectable impactor residue (it was assumed to have vaporized), but most of the tracks contained analyzable residue. The study showed that aerogel would be useful for future low-velocity impact analysis.

Hoerz, Friedrich↗

High-Resolution Mapping of Lunar Crustal Magnetic Fields: Correlations with Albedo Markings of the Reiner Gamma Class

During the last eight months of the Lunar Prospector mission (December 1999-July 1999), the spacecraft was placed in a relatively low-altitude (15-30-km perapsis), near-polar orbit that allowed high-resolution mapping of crustal magnetic fields. We report here initial studies of the correlation of locally strong magnetic anomalies with unusual, swirl-like albedo markings of the Reiner Gamma class. Based on this correlation, which is known from earlier studies of Apollo subsatellite magnetometer data, it has been proposed that the swirls represent regions whose higher albedos have been preserved via deflection of the solar-wind ion bombardment by strong crustal fields. This model in turn depends on the hypothesis that solar-wind implanted H is at least one component of the process that optically matures exposed silicate surfaces in the inner solar system . Specifically, it is hypothesized that implanted H acts as an effective reducing agent to enhance the rate of production of nanophase metallic Fe particles from preexisting silicates during micrometeoroid impacts. According to the model, the curvilinear shapes of these albedo markings are caused, at least in part, by the geometry of ion deflections in a magnetic field. The improved resolution and coverage of the Prospector data allow more detailed mapping of the fields, especially on the lunar farside. This permits a more quantitative test of whether all albedo markings of this class are associated with strong local magnetic fields.Only if the latter condition is met can the solar-wind deflection hypothesis he valid. The basic procedure for mapping crustal magnetic fields using Lunar Prospector magnetometer data follows that developed for analysis of Apollo subsatellite magnetometer data. The specific mapping steps are (1) selection of mission time intervals suitable for mapping crustal fields; these are limited essentially either to times when the Moon is in a lobe of the geomagnetic tail or to times when the Moon is in the solar wind but the spacecraft is in the lunar wake; the data are transformed to a radial, east, and north coordinate system with measurements given as a function of spacecraft latitude, longitude, and altitude; (2) visual editing of individual orbit segments selected for minimal external field disturbances; (3) minimization of remaining low-frequency external fields for individual orbit data segments by quadratic detrending; and (4) two-dimensional filtering of individual orbit segments to produce a vector field map along the slightly curved surface defined by the spacecraft altitude; maps of the three field components (radial, east, and north), the field magnitude, and the spacecraft altitude are constructed. For data obtained at low to middle latitudes, the horizontal resolution of the field maps is limited by the orbit-track separation (about 30 km at the equator). Maps of the field magnitude have been constructed within limited selenographic regions based mainly on data acquired in March, April, and May of 1999. This was a time period when the orbit plane was nearly aligned with the Sun-Moon line so that field mapping was possible at times when the Moon was in the solar wind as well as when the Moon was in the geomagnetic tail. Most of the coverage is across the lunar farside. However, a shows an example of a field map produced from solar-wind wake data for a region including Reiner Gamm on western Oceanus Procellarum (location: 58.5W, 7.5N). The contour interval is 3 nT and the mean spacecraft altitude is 18 km to within the accuracy allowed by the resolution of the map (30 km or about 1 deg.); strong magnetic anomalies correlate closely with swirl locations. Individual orbit profiles (whose resolution along the orbit track is comparable to the spacecraft altitude of 18 km) also demonstrate a good correlation of field magnitude with surface albedo. In order to investigate the correlation of magnetic fields with the location of swirl features, we have reexamined available lunar imagery (Lunar Orbiter, Apollo, and Clementine) to identify and map swirl locations within regions where swirls have previously been mapped. In these images, swirls were distinguished from other high-albedo features such as crater rays by their curvilinear shapes and increased visibility in forward-scattered light. Digital maps of swirls identified by all available imagery were then superposed on maps of the field magnitude at the spacecraft altitude. Based upon analysis of these composite magnetic/geologic maps, we draw the preliminary conclusion that swirl features are associated with magnetic anomalies revealed by Lunar Prospector. Detailed maps of these swirl features are currently being constructed for the magnetically strong regions antipodal to the Imbrium, Serenitatis, and Crisium Basins. Additional information contained in the original,

Hood, L. L.↗