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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,567 records · Page 87
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Continuous microstructure evolution of ball rolled TWIP Ti15Mo alloy and its effect on phase precipitation behavior

Highlights: • Gradient microstructure was induced by ball rolling method in a Ti15Mo alloy. • Twin density increased and then decreased as increasing distance from surface. • Ultrafine (α + β) duplex structure was formed in the heavily deformed region. • α-phase in plate was precipitated in twined region in slightly deformed region. • Strengthening by formation of sub/nano-grains was notable than that by twins. - Abstract: A β-type Ti15Mo alloy with {332}<113> twinning-induced plasticity (TWIP) effect was utilized to investigate the continuous microstructure evolution of β-matrix by ball rolling method. Precipitation behavior of α-phase and strengthening mechanism were examined in regions with different strain. Amounts of intersected twins were present in the slightly deformed region of β-matrix, and their area fraction decreased with an increase of distance from rolled surface. The β-matrix close to surface was heavily deformed to result in the formation of abundant subgrains and nanograins, which was caused by cooperative occurrence of twinning refinement, intragranular dislocation activities and subgrain rotation. Mechanical twins provided the preferential nucleation sites for plate-like α-phase with strong variant selection. Equiaxed α-phase preferentially nucleated at the boundaries of subgrains and nanograins with weak variant selection to form the ultrafine (α + β) duplex structure. Due to the formation of subgrains and nanograins as well as the strain hardening, strengthening became more significant than that by twinning refinement solely. Similarly, the ultrafine (α + β) duplex structure exhibited a better strengthening effect than that by precipitation of plate-like α-phase. The diversities of deformation microstructure combined with different precipitation behaviors of α-phase are desirable for controlling the mechanical properties of β-type TWIP titanium alloys.

36 MATERIALS SCIENCE↗
DOE OSTI2019

The effect of phosphorus on the formation of grain boundary laves phase in high-refractory content Ni-based superalloys

The effect of phosphorous on the microstructure of a powder-processed, high Nb-content, Ni-based superalloy was studied and compared to a P-free variant. The P-doped sample had a lower incipient melting temperature, forming a (Ni, Co, Cr, P) 2 (Nb, Mo) laves phase along the grain boundaries. Transmission electron microscopy and atom probe tomography were used to identify the crystal structure, assess phase compositions, and determine any elemental segregation to phase boundaries. The results revealed strong partitioning of P to the laves phase and a slight Mo gradient towards the γ' phrase. Finally, a simplified laves phase was successfully modeled via density functional theory calculations.

Antonov, Stoichko↗
DOE OSTI2018

Measurements of ion velocity separation and ionization in multi-species plasma shocks

The ion velocity structure of a strong collisional shock front in a plasma with multiple ion species is directly probed in laser-driven shock-tube experiments. Thomson scattering of a 263.25 nm probe beam is used to diagnose ion composition, temperature, and flow velocity in strong shocks (M ~ 6) propagating through low-density (ρ ~ 0.1 mg/cc) plasmas composed of mixtures of hydrogen (98%) and neon (2%). Within the preheat region of the shock front, two velocity populations of ions are observed, a characteristic feature of strong plasma shocks. The ionization state of the Ne is observed to change within the shock front, demonstrating an ionization-timescale effect on the shock front structure. In conclusion, the forward-streaming proton feature is shown to be unexpectedly cool compared to predictions from ion Fokker-Planck simulations; the neon ionization gradient is evaluated as a possible cause.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Including the vacuum energy in stellarator coil design

Being three-dimensional, stellarators have the advantage that plasma currents are not essential for creating rotational-transform; however, the external current-carrying coils in stellarators can have strong geometrical shaping, which can complicate the construction. Reducing the inter-coil electromagnetic forces acting on strongly shaped 3D coils and the stress on the support structure while preserving the favorable properties of the magnetic field is a design challenge. In this work, we recognize that the inter-coil forces are the gradient of the vacuum magnetic energy. We introduce an objective functional built on the usual quadratic flux on a prescribed target surface together with a weighed penalty on the vacuum energy. The Euler–Lagrange equation for stationary states is derived, and numerical illustrations are computed using a modern stellarator optimization framework. A study of the effect of the energy functional on the inter-coil forces is conducted and the energy is shown to be a promising quantity in producing coils with low forces.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Lamellar fluctuations melt ferroelectricity.

We consider a standard Ginzburg-Landau model of a ferroelectric whose electrical polarization is coupled to gradients of elastic strain. At the harmonic level, such flexoelectric interaction is known to hybridize acoustic and optic phonon modes and lead to phases with modulated lattice structures that precede the state with spontaneously broken inversion symmetry. Here, we use the self-consistent phonon approximation to calculate the effects of thermal and quantum polarization fluctuations on the bare hybridized modes to show that such long-range modulated order is unstable at all temperatures. We discuss the implications for the nearly ferroelectric SrTiO3 and KTaO3, and we propose that these systems are melted versions of an underlying modulated state that is dominated by nonzero momentum thermal fluctuations except at the very lowest temperatures.

Guzman-Verri, G. G.↗
NASA NTRS1971

Dynamic upper atmospheric force model on stabilized vehicles for a high-precision trajectory computer program

The upper atmosphere model draws heavily on the behavior of the earth's upper atmosphere which exhibits cyclic as well as irregular variations in density profile, temperature, pressure, and composition in unison with solar activities as deduced from the more recent land-based and satellite observations. The lift and drag model is designed specifically for inertially stabilized vehicles of the Mariner class, with possible extension to gravity gradient stabilized vehicles of the GEOS class. The model considers operation in the free molecular flow regimes with large Knudsen numbers. The vehicle is considered a composite structure with basic components having well-defined shapes, each with its own surface characteristics in terms of temperature, reflectivity, and accommodation of free stream molecules. The model takes into account both the calculation of precise aerodynamic force coefficients in terms of expansion of modified Bessel functions in speed ratios and angle of attack, and approximate force coefficients when the speed ratios approach infinity. Other considerations include specular and diffused reflectivity, shielding, and shadow effects.

Khatib, A. R.↗
NASA NTRS1983

Combustion in a turbulent mixing layer formed at a rearward-facing step

A premixed propane/air flame was stabilized in a turbulent mixing layer formed at a rearward-facing step. The mean and rms averages of the turbulent velocity flowfield were determined by laser velocimetry for both reacting (phi = 0.57) and nonreacting flows (Re = 15,000-37,000 based on step height). The reacting-flow was visualized by high-speed schlieren photography. Large-scale structures dominate the reacting mixing layer. The growth of the large-scale structures was tied to the propagation of the flame. The linear growth rate of the reacting mixing layer defined by the mean velocity profiles was unchanged by combustion but the virtual origin moves downstream. The reacting mixing layer boundaries based on the mean velocity profiles were shifted toward the recirculation zone and reattachment lengths were shortened by 30 percent. The edge of the flame controlled by the large-scale structure development propagated faster into the incoming reactants than the boundary of the mixing layer given by the mean velocity flowfield. Thus, the region of high velocity gradient did not coincide with the region of high reaction and heat transfer.

Pitz, R. W.↗
NASA NTRS1983

Three-dimensional baroclinic instability of a Hadley cell for small Richardson number

For the case of a baroclinic flow whose Richardson number, Ri, is of order unity, a three-dimensional linear stability analysis is conducted on the basis of a model for a thin, horizontal, rotating fluid layer which is subjected to horizontal and vertical temperature gradients. The Hadley cell basic state and stability analysis are both based on the Navier-Stokes and energy equations, and perturbations possessing zonal, meridional, and vertical structures are considered. An attempt is made to extend the previous theoretical work on three-dimensional baroclinic instability for small Ri to a more realistic model involving the Prandtl and Ekman numbers, as well as to finite growth rates and a wider range of the zonal wavenumber. In general, it is found that the symmetric modes of maximum growth are not purely symmetric, but have a weak zonal structure.

Antar, B. N.↗
NASA NTRS1992

The determination of a one year mean sea surface height track from Geosat altimeter data and ocean variability implications

Results are presented for determinations of mean sea surface along a reference Geosat altimeter tracking, using Geosat data from the first year of the exact repeat mission (ERM) and improved orbits. The results were used to study the time variability of the ocean surface, and a map was constructed of the major current structure. The data included 21 complete and one incomplete ERMs, with the sea surface heights being referenced to the single reference track through the application of geoid gradient corrections. This Geosat surface can be used as a reference surface to which other altimeter data could be incorporated; the data could then be used for the recovery of geoid undulations and gravity anomalies in the ocean areas.

Wang, Yan M.↗
NASA NTRS1997

The Volume Grid Manipulator (VGM): A Grid Reusability Tool

This document is a manual describing how to use the Volume Grid Manipulation (VGM) software. The code is specifically designed to alter or manipulate existing surface and volume structured grids to improve grid quality through the reduction of grid line skewness, removal of negative volumes, and adaption of surface and volume grids to flow field gradients. The software uses a command language to perform all manipulations thereby offering the capability of executing multiple manipulations on a single grid during an execution of the code. The command language can be input to the VGM code by a UNIX style redirected file, or interactively while the code is executing. The manual consists of 14 sections. The first is an introduction to grid manipulation; where it is most applicable and where the strengths of such software can be utilized. The next two sections describe the memory management and the manipulation command language. The following 8 sections describe simple and complex manipulations that can be used in conjunction with one another to smooth, adapt, and reuse existing grids for various computations. These are accompanied by a tutorial section that describes how to use the commands and manipulations to solve actual grid generation problems. The last two sections are a command reference guide and trouble shooting sections to aid in the use of the code as well as describe problems associated with generated scripts for manipulation control.

Alter, Stephen J.↗
NASA NTRS2009

Oxygen Ion Heat Rate within Alfvenic Turbulence in the Cusp

The role that the cleft/cusp has in ionosphere-magnetosphere coupling makes it a dynamic and important region. It is directly exposed to the solar wind, making it possible for the entry of electromagnetic energy and precipitating electrons and ions from dayside reconnection and other dayside events. It is also a significant source of ionospheric plasma, contributing largely to the mass loading of the magnetosphere with large fluxes of outflowing ions. Crossing the cusp/cleft near 5100 km, the Polar instruments observe the common correlation of downward Poynting flux, ion energization, soft electron precipitation, broadband extremely low-frequency (BB-ELF) emissions, and density depletions. The dominant power in the BB-ELF emissions is now identified to be from spatially broad, low frequency Alfv nic structures. For a cusp crossing, we determine using the Electric Field Investigation (EFI), that the electric and magnetic field fluctuations are Alfv nic and the electric field gradients satisfy the inequality for stochastic acceleration. With all the Polar 1996 horizontal crossings of the cusp, we determine the O+ heating rate using the Thermal Ion Dynamics Experiment (TIDE) and Plasma Wave Investigation (PWI). We then compare this heating rate to other heating rates assuming the electric field gradient criteria exceeds the limit for stochastic acceleration for the remaining crossings. The comparison suggests that a stochastic acceleration mechanism is operational and the heating is controlled by the transverse spatial scale of the Alfvenic waves.

Coffey, Victoria N.↗
NASA NTRSDate not supplied

Validation of Shadowgraph Spectral Analysis using an SLS Block 2 Wind-Tunnel Model

A flow quantification method has previously been developed that uses high-speed shadowgraph images to extract frequency content of a transonic flow field around a wind-tunnel model. In this method, a classical spectral analysis is performed on a set of shadowgraph image pixels to identify their intensity fluctuation frequencies. The spatial change of the image intensity is related to the second derivative of the density gradient. Examining the change of the density gradient as a function of time can be used to understand the flow field pressure fluctuations. Pressure measurements collected during a Booster Obsolescence Life Extension Forward Attachment Structure Trade Study Test are used to calibrate the shadowgraph-based measurements. The test was performed at the NASA Ames Research Center Unitary Plan Wind Tunnel 11- by 11-foot test section and investigated aerodynamic environment downstream of various booster forward attachment hardware geometries of the Space Launch System Block 2 Cargo configuration. Time-correlated shadowgraph video and model surface pressure measurements were acquired during the test and served as an ideal opportunity to calibrate and validate the shadowgraph image intensity method.

Shadowgraph↗
DOE OSTI2019

Investigation on Electronic Structures and Magnetic Properties of (Mn, Ga) Co-doped SnO{sub 2}

The electronic structures and magnetic properties of (Mn, Ga) co-doped SnO{sub 2} are studied by the first-principles calculations in full-potential linearized augmented plane wave formalism within generalized gradient approximations. We found that the doped system favors the ferromagnetic state and room-temperature ferromagnetism can be expected in it. The origin of ferromagnetism can be attributed to p-d exchange interactions as Mn-O-Mn. Ga acts as acceptor in (Mn, Ga) co-doped SnO{sub 2} host and can donate one hole, increasing the carrier concentration and thus leading to a more stable ferromagnetic state. These results suggest a recipe obtaining promising dilute magnetic semiconductor by doping nonmagnetic elements in SnO{sub 2} matrix.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Mapping strain and structural heterogeneities around bubbles in amorphous ionically conductive Bi 2 O 3

While amorphous materials are often approximated to have a statistically homogeneous atomic structure, they frequently exhibit localized structural heterogeneity that challenges simplified models. This study uses 4D scanning transmission electron microscopy to investigate the strain and structural modifications around gas bubbles in amorphous Bi 2 O 3 induced by argon irradiation. We present a method for determining strain fields surrounding bubbles that can be used to measure the internal pressure of the gas. Compressive strain is observed around the cavities, with higher-order crystalline symmetries emerging near the cavity interfaces, suggesting paracrystalline ordering as a result of bubble coarsening. This ordering, along with a compressive strain gradient, indicates that gas bubbles induce significant localized changes in atomic packing. By analyzing strain fields with maximum compressive strains of 3%, we estimate a lower bound on the internal pressure of the bubbles at 2.5 GPa. These findings provide insight into the complex structural behavior of amorphous materials under stress, particularly in systems with gas inclusions, and offer new methods for probing the local atomic structure in disordered materials. Although considering structural heterogeneity in amorphous systems is non-trivial, these features have crucial impacts on material functionalities, such as mechanical strength, ionic conductivity, and electronic mobility.

36 MATERIALS SCIENCE↗
NASA NTRS1999

A Generalized Wall Function

The asymptotic solutions, described by Tennekes and Lumley (1972), for surface flows in a channel, pipe or boundary layer at large Reynolds numbers are revisited. These solutions can be extended to more complex flows such as the flows with various pressure gradients, zero wall stress and rough surfaces, etc. In computational fluid dynamics (CFD), these solutions can be used as the boundary conditions to bridge the near-wall region of turbulent flows so that there is no need to have the fine grids near the wall unless the near-wall flow structures are required to resolve. These solutions are referred to as the wall functions. Furthermore, a generalized and unified law of the wall which is valid for whole surface layer (including viscous sublayer, buffer layer and inertial sublayer) is analytically constructed. The generalized law of the wall shows that the effect of both adverse and favorable pressure gradients on the surface flow is very significant. Such as unified wall function will be useful not only in deriving analytic expressions for surface flow properties but also bringing a great convenience for CFD methods to place accurate boundary conditions at any location away from the wall. The extended wall functions introduced in this paper can be used for complex flows with acceleration, deceleration, separation, recirculation and rough surfaces.

Shih, Tsan-Hsing↗
DOE OSTI2023

ORNL_AISD_NiPt

This dataset describes the nickel-platinum (NiPt) solid solution binary alloy, where the two constituent elements nickel (Ni) and platinum (Pt) are randomly placed on the face centered cubic (FCC) crystal structure, with the lattice constant of 3.840 angstroms. The dataset comprises data for three different sizes of the crystal structure: 256 atoms, 864 atoms, and 2,048 atoms, each of which contains 1900 configurations. For each size of the crystal structure, the data set was generated for concentrations ranging from 0at% of Pt to 100at% of Pt in the NiPt binary system, with increasing the concentration of Pt in the system every 5at%. For each one of the chemical compositions, 100 random configurations were generated, each with a different random seed. Each of the output files contains the mass, type, atomic coordinates, energy per atom, and forces in x, y, and z directions respectively. For each atomic configuration, the output was collected every 150 steps during the minimization stage and every 1000 steps during the replica exchange stage. Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) [1], which is a molecular dynamics code, was used to generate data for NiPt alloy. The simulation used the interatomic potential for NiPt binary system MEAM_LAMMPS_KimSeolJi_2017_PtNi__MO_020840179467_001 [3] from the OpenKIM library (Open Knowledgebase of Interatomic Models) [2]. This potential was developed based on the second nearest-neighbor modified embedded-atom method (2NN MEAM). The simulation process begins with the generation of the random NiPt structure and follows with the short minimization and replica exchange simulation. The minimization procedure adjusts atomic coordinates and performs energy minimization, which typically leads to a local potential energy minimum. The method used for the minimization was the conjugate gradient algorithm. A short replica exchange (parallel tempering) simulation involves four replicas (ensembles) of a system and follows the minimization stage. Multiple snapshots of the configuration were collected during the minimization and replica exchange stages. NiPt alloy is interesting due to its magnetic and charge transfer properties [4]. The data is provided in three compressed zipped folders: atoms256.zip, atoms864.zip, atoms2048.zip Each zipped folder contains the data that describes crystals of size 256 atoms, 864 atoms, and 2,048 atoms respectively. Each one of the three zipped folders contains the data structured in the following way: -Ni_ground_state.cfg --> atomic configuration for the pure nickel -Pt_ground_state.cfg --> atomic configuration for the pure platinum -Pt#_filtered --> folders containing atomic configurations for #at% concentration of platinum. The folder contains 100 atomic configurations, each saved in a subfolder. Each subfolder named config* is associated with a specific atomic configuration. Each of these subfolders contains files with .cfg format, corresponding to outputs for each atomic configuration The total number of atomic configurations contained in atoms256.zip is 65,046. The total number of atomic configurations contained in atoms864.zip is 63,936. The total number of atomic configurations contained in atoms2048.zip is 61,997. The total number of atomic configurations spanned by the entire dataset is 190,979. References [1] https://www.lammps.org/ [2] https://openkim.org/ [3] https://openkim.org/id/MEAM_LAMMPS_KimSeolJi_2017_PtNi__MO_020840179467_001 [4] El-Gendy, Ahmed A. and Hampel, Silke and Büccchner, Bernd and Klingeler, Rüdiger, Tuneable magnetic properties of carbon-shielded NiPt-nanoalloys, RSC Adv., volume 6, issue 57, pages 52427-52433, 2016, The Royal Society of Chemistry, doi:10.1039/C6RA05910D

36 MATERIALS SCIENCE↗
NASA NTRS2007

Bulk Crystal Growth of Piezoelectric PMN-PT Crystals Using Gradient Freeze Technique for Improved SHM Sensors

There has been a growing interest in recent years in lead based perovskite ferroelectric and relaxor ferroelectric solid solutions because of their excellent dielectric, piezoelectric and electrostrictive properties that make them very attractive for various sensing, actuating and structural health monitoring (SHM) applications. We are interested in the development of highly sensitive and efficient PMN-PT sensors based on large single crystals for the structural health monitoring of composite materials that may be used in future spacecrafts. Highly sensitive sensors are needed for detection of defects in these materials because they often tend to fail by distributed and interacting damage modes and much of the damage occurs beneath the top surface of the laminate and not detectable by visual inspection. Research is being carried out for various combinations of solid solutions for PMN-PT piezoelectric materials and bigger size crystals are being sought for improved sensor applications. Single crystals of this material are of interest for sensor applications because of their high piezoelectric coefficient (d33 greater than 1700 pC/N) and electromechanical coefficients (k33 greater than 0.90). For comparison, the commonly used piezoelectric ceramic lead zirconate titanate (PZT) has a d33 of about 600 pC/N and electromechanical coefficients k33 of about 0.75. At the present time, these piezoelectric relaxor crystals are grown by high temperature flux growth method and the size of these crystals are rather small (~3x4x5 mm(exp 3). In the present paper, we have attempted to grow bulk single crystals of PMN-PT in a 2 inch diameter platinum crucible and successfully grown a large size crystal of 67%PMN-33%PT using the vertical gradient freeze technique with no flux. Piezoelectric properties of the grown crystals are investigated. PMN-PT plates show excellent piezoelectric properties. Samples were poled under an applied electric field of 5 kV/cm. Dielectric properties at a frequency of 1 kHz are examined. The grown PMN-PT crystals show typical relaxor dielectric properties. Additionally, the thermal properties of the sample are tested. The results are in good agreement with those found in the literature and some are reported for the first time.

Aggarwal, Mohan D.↗