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Radio emission from a plasmoid that expands in a nonspherically symmetric manner is analyzed. The properties of this model are compared with the results of Andrews et al. (1978) and Epstein et al. (1982) concerning the values of beta derived for standard (delayed) radio sources. Mechanisms that might produce plasmoids that expand progressively in length while retaining substantially constant cross-sections are briefly discussed.
An evaluation is made of the prospects for SETI applications of multichannel spectroscopy, assuming narrowband RF beacon transmission, with a mHz resolution that matches interstellar medium properties. Receiver Doppler corrections must furnish substantial interference rejection. Results are presented from an Arecibo antenna search of 250 sunlike stars at 1.4 and 2.8 GHz. A meridian transit search of the northern sky is also in progress with the Harvard-Smithsonian 26-m antenna.
The first systems of molecules having the properties of the living state presumably self-assembled from a mixture of organic compounds available on the prebiotic Earth. To carry out the polymer synthesis characteristic of all forms of life, such systems would require one or more sources of energy to activate monomers to be incorporated into polymers. Possible sources of energy for this process include heat, light energy, chemical energy, and ionic potentials across membranes. These energy sources are explored here, with a particular focus on mechanisms by which self-assembled molecular aggregates could capture the energy and use it to form chemical bonds in polymers. Based on available evidence, a reasonable conjecture is that membranous vesicles were present on the prebiotic Earth and that systems of replicating and catalytic macromolecules could become encapsulated in the vesicles. In the laboratory, this can be modeled by encapsulated polymerases prepared as liposomes. By an appropriate choice of lipids, the permeability properties of the liposomes can be adjusted so that ionic substrates permeate at a sufficient rate to provide a source of monomers for the enzymes, with the result that nucleic acids accumulate in the vesicles. Despite this progress, there is still no clear mechanism by which the free energy of light, ion gradients, or redox potential can be coupled to polymer bond formation in a protocellular structure.
Ground-based measurements of particle size and fall speed distributions using a Particle Size and Velocity (PARSIVEL) disdrometer are compa red among samples obtained in mixed precipitation (rain and wet snow) and rain in the Oregon Cascade Mountains and in dry snow in the Rock y Mountains of Colorado. Coexisting rain and snow particles are distinguished using a classification method based on their size and fall sp eed properties. The bimodal distribution of the particles' joint fall speed-size characteristics at air temperatures from 0.5 to 0 C suggests that wet-snow particles quickly make a transition to rain once mel ting has progressed sufficiently. As air temperatures increase to 1.5 C, the reduction in the number of very large aggregates with a diame ter > 10 mm coincides with the appearance of rain particles larger than 6 mm. In this setting. very large raindrops appear to be the result of aggregates melting with minimal breakup rather than formation by c oalescence. In contrast to dry snow and rain, the fall speed for wet snow has a much weaker correlation between increasing size and increasing fall speed. Wet snow has a larger standard deviation of fall spee d (120%-230% relative to dry snow) for a given particle size. The ave rage fall speed for observed wet-snow particles with a diameter great er than or equal to 2.4 mm is 2 m/s with a standard deviation of 0.8 m/s. The large standard deviation is likely related to the coexistence of particles of similar physical size with different percentages of melting. These results suggest that different particle sizes are not required for aggregation since wet-snow particles of the same size can have different fall speeds. Given the large standard deviation of fa ll speeds in wet snow, the collision efficiency for wet snow is likely larger than that of dry snow. For particle sizes between 1 and 10 mm in diameter within mixed precipitation, rain constituted I % of the particles by volume within the isothermal layer at 0 C and 4% of the particles by volume for the region just below the isothermal layer where air temperatures rise from 0" to 0.5"C. As air temperatures increa sed above 0.5 C, the relative proportions of rain versus snow particl es shift dramatically and raindrops become dominant. The value of 0.5 C for the sharp transition in volume fraction from snow to rain is sl ightly lower than the range from 1 .l to 1.7 C often used in hydrolog ical models.
The Materials Technology Program supports the Vehicle Technologies Office’s (VTO’s) mission to help consumers and businesses reduce their transportation energy costs while meeting or exceeding vehicle performance expectations. The propulsion materials research portfolio seeks to develop higher performance materials that can withstand increasingly extreme environments and address the future properties needed for a variety of high-efficiency powertrain types, sizes, fueling concepts, and combustion modes. The lightweight materials research portfolio enables improvements in fuel economy by providing properties that are equal to or better than traditional materials at a lower weight. Because it takes less energy to accelerate a lighter object, replacing cast-iron and traditional steel components with lightweight materials such as advanced high-strength steels, magnesium (Mg) alloys, aluminum (Al) alloys, and fiber-reinforced polymer composites can directly reduce a vehicle’s fuel consumption. By 2025, Materials Technology research activities seek to enable a 25% weight reduction of the glider for light-duty (LD) vehicles including body, chassis, and interior as compared to a 2015 baseline at no more than a $5/lb-saved increase in cost.
The NASA funding allowed Clark Atlanta University (CAU) to establish a High Performance Polymers And Ceramics (HiPPAC) Research Center. The HiPPAC Center is consolidating and expanding the existing polymer and ceramic research capabilities at CAU through the development of interdepartmental and interinstitutional research in: (1) polymer synthesis; (2) polymer characterization and properties; (3) polymer processing; (4) polymer-based ceramic synthesis; and (5) ceramic characterization and properties. This Center has developed strong interactions between scientists and materials scientists of CAU and their counterparts from sister institutions in the Atlanta University Center (AUC) and the Georgia Institute of Technology. As a component of the center, we have started to develop strong collaborations with scientists from other universities and the HBCU's, national and federal agency laboratories, and the private sector during this first year. During this first year we have refined the focus of the research in the HiPPAC Center to three areas with seven working groups that will start programmatic activities on January 1, 1993, as follows: (1) nonlinear optical properties of chitosan derivatives; (2) polymeric electronic materials; (3) nondestructive characterization and prediction of polyimide performance; (4) solution processing of high-performance materials; (5) processable polyimides for composite applications; (6) sol-gel based ceramic materials processing; and (7) synthetic based processing of pre-ceramic polymers.
A study on the effects of lateral air entrainment on an upward spreading flame has been conducted. The fuel is a flat PMMA plate of constant length and thickness but variable width. Video images and surface temperatures have allowed establishing the progression of the pyrolyis front and on the flame stand-off distance. These measurements have been incorporated into a theoretical formulation to establish characteristic mass transfer numbers ("B" numbers). The mass transfer number is deemed as a material related parameter that could be used to assess the potential of a material to sustain co-current flame spread. The experimental results show that the theoretical formulation fails to describe heat exchange between the flame and the surface. The discrepancies seem to be associated to lateral air entrainment that lifts the flame off the surface and leads to an over estimation of the local mass transfer number. Particle Image Velocimetry (PIV) measurements are in the process of being acquired. These measurements are intended to provide insight on the effect of air entrainment on the flame stand-off distance. A brief description of the methodology to be followed is presented here.
Young's modulus, bulk density, fracture strength, and fracture toughness of alpha silicon carbide manufactured by extrusion and by isopressing were measured at room and elevated temperature in order to determine material feasibility as augers for the Tile Overlay Repair attachment. The measured properties of extruded and isopressed materials differ significantly, with the extruded material exhibiting marked strength anisotropy and lower density. The measurements were made between July and September 2006 at Glenn Research Center (GRC), in order to obtain design data for use in structural and thermal mathematical models.
Highlights: • AZO and IAZO (303–473 K) films were grown by RF magnetron sputtering technique. • Ar ion-beam converts its kinetic energy as diffusion energy to the deposited atoms. • Structural evolution relies on diffusion energy imparted to the deposited atoms. • Surface texture densify under the aid of ion-beam and substrate temperature. - Abstract: In this study, pronounced effects of ion-beam-assistance and substrate temperature were revealed by exploring the physical properties of Al-doped ZnO thin films deposited by the RF magnetron sputtering technique. Herein, two measurable parameters, ion-beam discharge current (0.1 A) and substrate temperature (303–473 K) were adopted to regulate the structural changes in Al-doped ZnO films. Specifically, progressive structural changes were achieved based on the addition of Ar ion-beam during the film growth. From XRD analysis, we observed significant structural changes that provided an improvement in the film growth towards c-axis (002) plane. In addition, FESEM and AFM analyses demonstrated excellent surface features with the assisted Ar ion-beam. As a result of this process, we effectively modulated the binding energy of Zn 2p level. Finally, the structural investigation accurately demonstrated that the dependence of assisted ion-beam and substrate temperature linearly related to the superior visible transmittance and reduced band gap.
This is a presentation on the Evolution of Permeability and Strength Recovery of Shear Fractures Under Hydrothermal Conditions project by the U.S. Geological Survey, presented by Dr. David Lockner. The project's objective was to determine how thermal, hydraulic, mechanical, and chemical processes affect the sustainability of fracture networks in geothermal reservoirs and provide strategies for improved EGS techniques that maximize thermal coupling and increase reservoir longevity. This presentation was featured in the Utah FORGE R&D Annual Workshop on September 8, 2023. The workshop provided a valuable opportunity to explore the progress made in each of the 17 Research and Development projects funded under Solicitation 2020-1 which aim to enhance our understanding of the crucial factors influencing the development of Enhanced Geothermal Systems (EGS) reservoirs and resources.
In spite of the simple body-centered-cubic crystal structure, the elements of group V, vanadium, niobium and tantalum, show strong interactions between the electronic properties and lattice dynamics. Further, these interactions can be tuned by external parameters, such as pressure and temperature. We used inelastic x-ray scattering to probe the phonon dispersion of single-crystalline vanadium as a function of pressure to 45 GPa. Our measurements show an anomalous high-pressure behavior of the transverse acoustic mode along the (100) direction and a softening of the elastic modulus C44 that triggers a rhombohedral lattice distortion occurring between 34 and 39 GPa. Lastly, our results provide the missing experimental confirmation of the theoretically predicted shear instability arising from the progressive intra-band nesting of the Fermi surface with increasing pressure, a scenario common to all transition metals of group V.
The Materials Technology subprogram supports the Vehicle Technologies Office’s (VTO’s) mission to accelerate the deployment of clean energy technology toward achieving net-zero emissions in the transportation sector. The Propulsion Materials research portfolio seeks to develop higher performance materials that can withstand increasingly extreme environments and address the future properties needed for a variety of high-efficiency powertrain types, sizes, fueling concepts, and combustion modes. The Lightweight Materials research portfolio enables improvements in fuel economy by providing properties that are equal to or better than traditional materials at a lower weight. Because it takes less energy to accelerate a lighter object, replacing cast-iron (Fe) and traditional steel components with lightweight materials—such as advanced high-strength steels (AHSS), magnesium (Mg) alloys, aluminum (Al) alloys, and fiber-reinforced polymer composites—can directly reduce a vehicle’s fuel consumption. By 2025, the Materials Technology research activities seek to enable a 25% weight reduction of the glider for light-duty (LD) vehicles including body, chassis, and interior as compared to a 2015 baseline at no more than a $5/lb-saved increase in cost.
Highlights: • Mg{sup 2+}-Ge{sup 4+} ion pairs can partially substitute the Al{sup 3+} ions of YAG successfully. With the substitution, the garnet crystal structure remains unchanged. • With increasing Mg{sup 2+}-Ge{sup 4+} ions concentrations, the emission spectra show a progressive red-shift, from 528 to 552 nm (about 24 nm). • In white LEDs, with increasing Mg{sup 2+}-Ge{sup 4+} ions concentrations, the CCT decreased gradually from 6798 to 3261 K and the CRI increased from 76.5 to 89.3. - Abstract: Mg{sup 2+}-Ge{sup 4+} ions substituted YAG: Ce{sup 3+} phosphors (Y{sub 3}Al{sub 5-2x}Mg{sub x}Ge{sub x}O{sub 12}: Ce{sup 3+}) were prepared by high temperature solid state reaction method. X-ray diffraction (XRD), Scanning election microscope (SEM), Photoluminescence (PL) spectra and so on were used to characterize the samples. The effects of Mg{sup 2+}-Ge{sup 4+} concentrations on the morphology, structure, luminescence properties, fluorescence lifetime and white LED performance of YAG: Ce{sup 3+} phosphors were studied in detail. The results indicate that Mg{sup 2+}-Ge{sup 4+} ion pairs can partially substitute the Al{sup 3+} ions of YAG successfully. With the substitution, the garnet crystal structure remains unchanged. However the emission spectra show a progressive red-shift, from 528 to 552 nm (about 24 nm). The lifetime decreased rapidly from 84 to 26 ns. In particular, the correlated color temperature (CCT) decreases gradually from 6798 to 3261 K and the color rendering index (CRI) increases from 76.5 to 89.3 with the increasing of the incorporation content of Mg{sup 2+}-Ge{sup 4+} ion pairs.
The U.S. Department of Energy's (DOE) Waste Treatment and Immobilization Plant (WTP) Pretreatment (PT) Facility has a number of first-of-a-kind technical challenges that have required additional expert analysis and testing activities to resolve. In 2006 an External Flowsheet Review Team identified 28 technical vulnerabilities with the plant design or future operability. Over a period of three months starting in September 2012, a number of top scientists and engineers conducted a review of the major technical issues associated with the design and operability of the WTP. These experts also provided independent advice on some of the broader challenges associated with completing the Hanford tank waste mission - highlighting the linkage between the physical and chemical properties of the tank waste and the PT Facility technical issues. In 2012 and early 2013 DOE's Office of River Protection (ORP) directed the WTP contractor to suspend production work on the Pretreatment Facility until the outstanding technical issues could be resolved and the nuclear safety basis could be updated and brought into alignment with any updates to the facility design and/or process flowsheet. Specific plans for resolving each the technical issues have been developed and significant progress has been made over the past year in identifying solution sets for each of the issues. The eight remaining technical issues (referred to as T1 to T8) are as follows: (T1) Hydrogen Gas Release from Vessel Solids; (T2) Potential Criticality in Pretreatment Facility Vessels; (T3) Hydrogen in Piping and Ancillary Vessels; (T4) Pulse-Jet Mixing and Control; (T5) Erosion and Localized Corrosion in WTP Vessels and Piping; (T6) Design Redundancy in Black Cells/In-Service Inspection; (T7) Black Cell Vessel Structural Integrity; (T8) Facility Ventilation. This paper provides a synopsis of the progress that has been made on resolving the Pretreatment technical issues over the past year, and how resolution of the issues will enable DOE to make an informed decision to resume design and production engineering for the Pretreatment Facility. (authors)
Vertically aligned nanocomposite thin films with ordered two phases, grown epitaxially on substrates, have attracted tremendous interest in the past decade. These unique nanostructured composite thin films with large vertical interfacial area, controllable vertical lattice strain, and defects provide an intriguing playground, allowing for the manipulation of a variety of functional properties of the materials via the interplay among strain, defect, and interface. This field has evolved from basic growth and characterization to functionality tuning as well as potential applications in energy conversion and information technology. Lastly, the remarkable progress achieved in vertically aligned nanocomposite thin films from a perspective of tuning functionalities through control of strain, defect, and interface is summarized.
To facilitate and accelerate the process of introducing, evaluating and adopting of new material systems, it is important to develop/establish comprehensive and effective procedures of characterization, modeling and failure prediction of structural laminates based on the properties of the constituent materials, e. g., fibers, matrix, and the single ply or lamina. A new failure theory, the Northwestern (NU-Daniel) theory, has been proposed for predicting lamina yielding and failure under multi-axial states of stress including strain rate effects. It is primarily applicable to matrix-dominated interfiber/interlaminar failures. It is based on micromechanical failure mechanisms but is expressed in terms of easily measured macroscopic lamina stiffness and strength properties. It is presented in the form of a master failure envelope incorporating strain rate effects. The theory was further adapted and extended to the prediction of in situ first ply yielding and failure (FPY and FPF) and progressive failure of multi-directional laminates under static and dynamic loadings. The significance of this theory is that it allows for rapid screening of new composite materials without very extensive testing and offers easily implemented design tools.
Thermal spray deposited WC-CoCr coatings are extensively used for surface protection of wear prone components in a variety of applications. Although the primary purpose of the coating is wear and corrosion protection, many of the coated components are structural systems (aero landing gear, hydraulic cylinders, drive shafts etc.) and as such experience cyclic loading during service and are potentially prone to fatigue failure. It is of interest to ensure that the coating and the application process does not deleteriously affect the fatigue strength of the parent structural metal. It has long been appreciated that the relative fatigue life of a thermal sprayed component can be affected by the residual stresses arising from coating deposition. The magnitude of these stresses can be managed by torch processing parameters and can also be influenced by deposition effects, particularly the deposition temperature. In this study, the effect of both torch operating parameters (particle states) and deposition conditions (notably substrate temperature) were investigated through rotating bending fatigue studies. The results indicate a strong influence of process parameters on relative fatigue life, including credit or debit to the substrate's fatigue life measured via rotating bend beam studies. Damage progression within the substrate was further explored by stripping the coating off part way through fatigue testing, revealing a delay in the onset of substrate damage with more fatigue resistant coatings but no benefit with coatings with inadequate properties. Finally, the results indicate that compressive residual stress and adequate load bearing capability of the coating (both controlled by torch and deposition parameters) delay onset of substrate damage, enabling fatigue credit of the coated component.
Tin halide perovskites and perovskite-related materials have emerged as promising lead-free hybrid materials for various optoelectronic applications. While remarkable progress has been achieved in the development of organic tin halide hybrids with diverse structures and controlled dimensionalities at the molecular level, some controversial results that have been reported recently need to be addressed. For instance, different photophysical properties have been reported for two-dimensional (2D) (PEA) 2 SnBr 4 (PEA = phenylethylammonium) by several groups with distinct emission peaks at around 468 and 550 nm. Here we report our efforts in the synthesis of phenylethylammonium tin bromide hybrids with zero-dimensional (0D) and 2D structures, and characterizations of their structural and photophysical properties. 0D [(PEA) 4 SnBr 6 ][(PEA)Br] 2 [CCl 2 H 2 ] 2 was found to exhibit strong yellow emission peak at 566 nm with a photoluminescence quantum efficiency (PLQE) of ~90%, while 2D (PEA) 2 SnBr 4 had weak emission peak at 470 nm with a PLQE of <0.1%. Interestingly, 0D [(PEA) 4 SnBr 6 ][(PEA)Br] 2 [CCl 2 H 2 ] 2 can be converted into 2D (PEA) 2 SnBr 4 upon drying, which would return to 0D [(PEA) 4 SnBr 6 ][(PEA)Br] 2 [CCl 2 H 2 ] 2 upon addition of dichloromethane. Powder X-ray diffraction results confirmed the reversible transformation between 0D and 2D structures. Density functional theory calculations showed that excitons in 0D [(PEA) 4 SnBr 6 ][(PEA)Br] 2 [CCl 2 H 2 ] 2 are highly localized, resulting in a strongly Stokes shifted broadband emission, while delocalized electronic states in 2D (PEA) 2 SnBr 4 result in weaker exciton binding, a higher exciton mobility, and a higher nonradiative decay.