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Stitching methods at the European Synchrotron Radiation Facility (ESRF)

X-ray mirror quality has continuously improved over the past 20 years and manufacturers are now able to provide long mirrors with slope errors below 0.2 μrad. Nevertheless, these mirrors are mounted on holders or even mechanical benders to adjust their curvature and their intrinsic quality must be preserved from any parasitic deformation such as twist. The most direct method of detecting these deformations is to measure the 3D topography of the optical surface. At the ESRF metrology laboratory, three different stitching systems are under development based on Fizeau sub-aperture measurements. The first one consists of measuring long flat mirrors, the second based on the relative angle determinable stitching interferometry (RADSI) method developed at SPring-8 is aimed primarily at the measurement of short mirrors with strong curvature down to a few meters, and the last, also based on the RADSI method, is dedicated to characterize longer mirrors with intermediate curvature. For each method we will describe the measurement setup and discuss first results obtained. Micro-stitching interferometry is also currently used at the ESRF metrology laboratory. The technique is suitable for measuring deeply curved aspherical profiles and will be illustrated with results from a Kirkpatrick-Baez mirror system for nano-focusing.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

NEAR-INFRARED IMAGING OF A z = 6.42 QUASAR HOST GALAXY WITH THE HUBBLE SPACE TELESCOPE WIDE FIELD CAMERA 3

We report on deep near-infrared F125W (J) and F160W (H) Hubble Space Telescope Wide Field Camera 3 images of the z = 6.42 quasar J1148+5251 to attempt to detect rest-frame near-ultraviolet emission from the host galaxy. These observations included contemporaneous observations of a nearby star of similar near-infrared colors to measure temporal variations in the telescope and instrument point-spread function (PSF). We subtract the quasar point source using both this direct PSF and a model PSF. Using direct subtraction, we measure an upper limit for the quasar host galaxy of m{sub J} > 22.8 and m{sub H} > 23.0 AB mag (2 {sigma}). After subtracting our best model PSF, we measure a limiting surface brightness from 0.''3 to 0.''5 radius of {mu}{sub J} > 23.5 and {mu}{sub H} > 23.7 AB mag arcsec{sup -2} (2 {sigma}). We test the ability of the model subtraction method to recover the host galaxy flux by simulating host galaxies with varying integrated magnitude, effective radius, and Sersic index, and conducting the same analysis. These models indicate that the surface brightness limit ({mu}{sub J} > 23.5 AB mag arcsec{sup -2}) corresponds to an integrated upper limit of m{sub J} > 22-23 AB mag, consistent with the direct subtraction method. Combined with existing far-infrared observations, this gives an infrared excess log (IRX) > 1.0 and corresponding ultraviolet spectral slope {beta} > -1.2 {+-} 0.2. These values match those of most local luminous infrared galaxies, but are redder than those of almost all local star-forming galaxies and z {approx_equal} 6 Lyman break galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

Generalized scaling relationships on transition metals: Influence of adsorbate-coadsorbate interactions

Linear scaling relations of adsorbate energies across a range of catalytic surfaces have emerged as a central interpretive paradigm in heterogeneous catalysis. They are, however, typically developed for low adsorbate coverages which are not always representative of realistic heterogeneous catalytic environments. Herein, we present generalized linear scaling relations on transition metals that explicitly consider adsorbate-coadsorbate interactions at variable coverages. The slopes of these scaling relations do not follow the simple bond counting principles that govern scaling on transition metals at lower coverages. In this work, the deviations from bond counting are explained using a pairwise interaction model wherein the interaction parameter determines the slope of the scaling relationship on a given metal at variable coadsorbate coverages, and the slope across different metals at fixed coadsorbate coverage is approximated by adding a coverage-dependent correction to the standard bond counting contribution. The analysis provides a compact explanation for coverage-dependent deviations from bond counting in scaling relationships and suggests a useful strategy for incorporation of coverage effects into catalytic trends studies.

36 MATERIALS SCIENCE↗

Quasi-Lagrangian measurements of density surface fluctuations and power spectra in the stratosphere

Pressure and temperature data from eight superpressure balloon flights at 26 km in the southern hemisphere stratosphere are analyzed. The balloons, which float on a constant density surface, travel steadily westward during summer and eastward during winter, as expected from local climatology. Two types of fluctuations are observed: neutral buoyancy oscillations (NBO) of around 4 min, and 0.1- to 1-hour oscillations that are characterized as small-amplitude density surface fluctuations. Lapse rates and densities are calculated and found to agree well with the expected values. Examples of wave damping and simultaneous fluctuation at two nearby balloons are presented. Spectral analysis is performed clearly showing the NBO and that the majority of the power is in the mesoscale range. Spectral slopes of power versus frequency are measured to be on the average -2.18 + or - 0.24 for pressure and -1.72 + or - 0.24 for temperature. These slopes are compared to the predictions of turbulence theories and the theory of a universal gravity wave spectrum.

Quinn, Elizabeth P.↗

A Scalable Framework for Post Fire Debris Flow Hazard Assessment Using Satellite Precipitation Data

Wildfire is a global phenomenon that has dramatic effects on erosion and flood potential. On steep slopes, burned areas are more likely to experience significant overland flow during heavy rainfall leading to post fire debris flows (PFDFs). Previous work establishes methods for PFDF hazard assessment, often relying on regional-scale parameterizations with in-situ rainfall measurements to categorize hazard as a function of meteorological and surface properties. We present a globally scalable approach to extend the benefit these models provide to new areas. Our new model relies on publicly available satellite-based inputs with a global extent to provide first order hazard assessments of recently burned areas. Our results show it is possible to identify the conditions relevant for PFDF-initiation processes across a variety of physiographic settings. Improvements to satellite borne rainfall intensity data and increased availability of PFDF occurrence data worldwide are expected to enhance model skill and applicability further.

Wildfire↗

Hanford Technology Development (Tank Farms) - 12509

The mission of the Department of Energy's Office of River Protection (ORP) is to safely retrieve and treat the 56 million gallons of Hanford's tank waste and close the Tank Farms to protect the Columbia River. The millions of gallons of tank waste are a byproduct of decades of plutonium production. After irradiated fuel rods were taken from the nuclear reactors to the processing facilities at Hanford they were exposed to a series of chemicals designed to dissolve away the rod, which enabled workers to retrieve the plutonium. Once those chemicals were exposed to the fuel rods they became radioactive and extremely hot. They also couldn't be used in this process more than once. Because the chemicals are caustic and extremely hazardous to humans and the environment, underground storage tanks were built to hold these chemicals until a more permanent solution could be found. One key part of the ongoing work at Hanford is retrieving waste from the single-shell tanks, some of which have leaked in the past, and transferring that waste to the double-shell tanks - none of which have ever leaked. The 56 million gallons of radioactive tank waste is stored in 177 underground tanks, 149 of which are single-shell tanks built between 1943 and 1964. The tanks sit approximately 250 feet above the water table. Hanford's single-shell tanks are decades past their 20-year design life. In the past, up to 67 of the single-shell tanks are known or suspected to have leaked as much as one million gallons of waste to the surrounding soil. Starting in the late 1950's, waste leaks from dozens of the single-shell tanks were detected or suspected. Most of the waste is in the soil around the tanks, but some of this waste is thought to have reached groundwater. The Vadose Zone Project was established to understand the radioactive and chemical contamination in the soil beneath the tanks as the result of leaks and discharges from past plutonium-production operations. The vadose zone is the area of soil between the ground surface and the water table 200-to-300 feet below. The project tracks and monitors contamination in the soil. Technologies are being developed and deployed to detect and monitor contaminants. Interim surface barriers, which are barriers put over the single-shell tanks, prevent rain and snow from soaking into the ground and spreading contamination. The impermeable barrier placed over T Farm, which was the site of the largest tank waste leak in Hanford's history, is 60,000 square feet and sloped to drain moisture outside the tank farm. The barrier over TY Farm is constructed of asphalt and drains moisture to a nearby evaporation basin. Our discussion of technology will address the incredible challenge of removing waste from Hanford's single-shell tanks. Under the terms of the Tri-Party Agreement, ORP is required to remove 99 percent of the tank waste, or until the limits of technology have been reached. All pumpable liquids have been removed from the single-shell tanks, and work now focuses on removing the non-pumpable liquids. Waste retrieval was completed from the first single-shell tank in late 2003. Since then, another six single-shell tanks have been retrieved to regulatory standards. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Cable Car Transfer System for the Cigeo Access Ramps - An Original Approach - 17035

Andra is currently implementing the detailed engineering phase of the step-wise design of Cigeo (the French HLW and IL-LLW Deep Geological Repository). Various technical issues are at stake, including the definition and development of a key component: a funicular ('cable-car') system dedicated to the transfer (down the access ramp and leading to the underground infrastructures) of the shielding casks housing the waste disposal containers (packages). The present paper starts with a brief description of the Cigeo architecture (i.e. the surface utilities, the service and nuclear ramps, the various shafts and finally the underground facilities). A focus is then made on the 'nuclear ramp' dedicated to the transfer of the waste containers lodged inside the casks (those latter weighing some 100 to 130 metric tons each) and its main geometrical characteristics (slope, length, diameter, structure). Then a discussion follows to detail the rationale having led to the choice of a somehow 'sophisticated' funicular transfer system, at the expense of what could be called 'more conventional' and more straightforward transport solutions (like a transfer system by trucks or by rack and pinion trains). A systematic comparison is finally made between the various solutions, explaining and rating the pros and cons of each concept, via a multi-criteria analysis. This technical choice (and the related justification approach) was submitted to an Experts review at the end of the Preliminary Design phase of Cigeo and comforted by their strong support before the design freeze of this solution was integrated in Cigeo. The following part of the paper is then focused on a description of the main technical components and the mechanical performance of the cable-car system, its current state of design and the set of qualification tests (of key safety components) to be implemented before its effective construction. This article concludes with a timeline of the qualification tests and developments to come. The positive outcomes of this future technical test campaign will also pave the way for the future instruction of the Cigeo licensing file, scheduled as of mid-2018. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Design for high-power, single-lobe, grating-surface-emitting quantum cascade lasers enabled by plasmon-enhanced absorption of antisymmetric modes

Resonant coupling of the transverse-magnetic polarized (guided) optical mode of a quantum-cascade laser (QCL) to the antisymmetric surface-plasmon modes of 2nd-order distributed-feedback (DFB) metal/semiconductor gratings results in strong antisymmetric-mode absorption. In turn, lasing in the symmetric mode, that is, surface emission in a single-lobe far-field beam pattern, is strongly favored over controllable ranges in grating duty cycle and tooth height. By using core-region characteristics of a published 4.6 μm-emitting QCL, grating-coupled surface-emitting (SE) QCLs are analyzed and optimized for highly efficient single-lobe operation. For infinite-length devices, it is found that when the antisymmetric mode is resonantly absorbed, the symmetric mode has negligible absorption loss (∼0.1 cm{sup −1}) while still being efficiently outcoupled, through the substrate, by the DFB grating. For finite-length devices, 2nd-order distributed Bragg reflector (DBR) gratings are used on both sides of the DFB grating to prevent uncontrolled reflections from cleaved facets. Equations for the threshold-current density and the differential quantum efficiency of SE DFB/DBR QCLs are derived. For 7 mm-long, 8.0 μm-wide, 4.6 μm-emitting devices, with an Ag/InP grating of ∼39% duty cycle, and ∼0.22 μm tooth height, threshold currents as low as 0.45 A are projected. Based on experimentally obtained internal efficiency values from high-performance QCLs, slope efficiencies as high as 3.4 W/A are projected; thus, offering a solution for watt-range, single-lobe CW operation from SE, mid-infrared QCLs.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Ertel potential vorticity versus Bernoulli streamfunction in earth's extratropical atmosphere: Q vs. B

We investigate the correlation of Ertel potential vorticity, Q, with Bernoulli streamfunction, B,on potential-temperature surfaces, θ, in Earth’s atmosphere poleward of ± 30° latitude. For input, we use the 1979–2010 CMAM30-SD specified-dynamics data set. We fit the model Q=Q 0 exp [-λ 0 (B-B0)] separately in the midlatitude [30°, 60°) and polar [60°, 90°] regions, and nondimensionalize the slope parameter as $\hat{λ}_0\equiv$ ($\overline{NH}$) 2 λ 0 In the troposphere, the peak of $\hat{λ}_0$ is approximately 2-3 in winter and 3–4 in summer in both regions. In the stratosphere during winter, both $\hat{λ}_0$| midlat and $\hat{λ}_0$| polar hover around unity. In spring and fall, $\hat{λ}_0$| polar continues to hover near unity, but $\hat{λ}_0$| midlat rises by a factor of two, with its maximum located at θ ~ 700 to 900 K. In summer, the polar value drops to $\hat{λ}_0$| polar << 1, while the midlatitude value swings negative to $\hat{λ}_0$| midlat ~ 22 to 23. In the mesosphere, $\hat{λ}_0$ exhibits incessant fluctuations with values that usually fall within the range 0 to 1. The results support the paradigm $\hat{λ}_0$ << 1for dynamically active regions primarily in the vicinity of θ ~ 3000–4000 K (~62–72 km) in the mesosphere, whereas except in summer, we get the simple result that the monthly climate-averaged profile, $\langle$ $\hat{λ}_0$ $\rangle$, in the polar regions is nearly unity across the entire stratosphere. In conclusion, during extended recoveries following SSWs, the midlatitude vertical profile develops a peak near 2000 K that descends over the course of a few weeks, alongside the descent of the elevated stratopause in the polar region.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Floodplain Wetland Channel Planform, Cross-Sectional Morphology, and Sediment Characteristics Along an Estuarine to Tidal River Gradient

The formation of wetland channel networks on coastal river floodplains is affected by spatial transitions in tidal-fluvial processes. This study evaluated sedimentation patterns in tidal marshes on the 147-km tidal Columbia River and its 87-km estuary and characterized the cross-sectional geometry and planform morphometry of tidal wetlands along the estuarine to riverine gradient. Tidal marshes were predominantly depositional (median 0.7 cm yr-1, primarily silt), consistent with late-Holocene rates. Marsh sediment accretion rate increased with annual maximum 7-day average daily maximum water depth. Elevation was negatively correlated with accretion rate in the tidal river and positively correlated with total organic carbon (TOC%) in the tidal river and estuary. TOC% was greater in the estuary and, like percent fines, greater farther from the main-channel Columbia River. For four single-channel and six channel-network planforms of tidal marsh, shrub-dominated, and forested wetlands: (1) Spatial patterns of cross-sectional morphology conformed to typical coastal wetland morphology in estuarine reaches up to the tidal river. (2) Reach-based and common slope linear models for channel perimeter on wetland area were predictive in the estuary (R2 > 0.81) and differed between island (n = 144) and mainland (n = 164) wetlands. No planform linear models were predictive for the entire study area or the tidal river. No models for channel outlets were acceptable. (3) Channel perimeter, surface area, and outlets were all highly variable within and among estuarine–riverine reaches. Analyses of sediment, cross-section, and planform support the use of a “natural network paradigm” for wetland-restoration design on tidal river floodplains.

channel morphology↗

An Analysis of Terrestrial and Aquatic Environmental Controls of Riverine Dissolved Organic Carbon in the Conterminous United States

Riverine carbon cycling is an important, but insufficiently investigated component of the global carbon cycle. Analyses of environmental controls on riverine carbon cycling are critical for improved understanding of mechanisms regulating carbon processing and storage along the terrestrial-aquatic continuum. Here, we compile and analyze riverine dissolved organic carbon (DOC) concentration data from 1402 United States Geological Survey (USGS) gauge stations to examine the spatial variability and environmental controls of DOC concentrations in the United States (U.S.) surface waters. DOC concentrations exhibit high spatial variability, with an average of 6.42 ± 6.47 mg C/ L (Mean ± Standard Deviation). In general, high DOC concentrations occur in the Upper Mississippi River basin and the Southeastern U.S., while low concentrations are mainly distributed in the Western U.S. Single-factor analysis indicates that slope of drainage areas, wetlands, forests, percentage of first-order streams, and instream nutrients (such as nitrogen and phosphorus) pronouncedly influence DOC concentrations, but the explanatory power of each bivariate model is lower than 35%. Analyses based on the general multi-linear regression models suggest DOC concentrations are jointly impacted by multiple factors. Soil properties mainly show positive correlations with DOC concentrations; forest and shrub lands have positive correlations with DOC concentrations, but urban area and croplands demonstrate negative impacts; total instream phosphorus and dam density correlate positively with DOC concentrations. Notably, the relative importance of these environmental controls varies substantially across major U.S. water resource regions. In addition, DOC concentrations and environmental controls also show significant variability from small streams to large rivers, which may be caused by changing carbon sources and removal rates by river orders. In sum, our results reveal that general multi-linear regression analysis of twenty one terrestrial and aquatic environmental factors can partially explain (56%) the DOC concentration variation. In conclusion, this study highlights the complexity of the interactions among these environmental factors in determining DOC concentrations, thus calls for processes-based, non-linear methodologies to constrain uncertainties in riverine DOC cycling.

54 ENVIRONMENTAL SCIENCES↗

Excess junction current of silicon solar cells

The current-voltage characteristics of n(plus)-p silicon solar cells with 0.1, 1.0, 2.0, and 10 ohm-cm p-type base materials have been examined in detail. In addition to the usual I-V measurements, we have studied the temperature dependence of the slope of the I-V curve at the origin by the lock-in technique. The excess junction current coefficient (Iq) deduced from the slope at the origin depends on the square root of the intrinsic carrier concentration. The Iq obtained from the I-V curve fitting over the entire forward bias region at various temperatures shows the same temperature dependence. This result, in addition to the presence of an aging effect, suggest that the surface channel effect is the dominant cause of the excess junction current.

Wang, E. Y.↗

Analyses of processing variables in propellant burn rate and modulus. I - Mixing times

The effect of the final mixing time on quality of smokeless AP/HTPB propellant with bimodal AP was examined. Identical ingredients were mixed for various intervals, cast in a circular tube, then fired in a static test. Mechanical properties were measured and initial moduli were calculated from the initial slope of the S-N curves. A theoretical model was developed using the data to quantitatively configure a quality control procedure. A minimum time for mixing fine and coarse AP particles was identified and was approximated to within a factor of two or three using a viscous dispersion time and the surface areas of the particles. The model could be improved by considering settling time and particle size distribution effects.

Ramohalli, K.↗

MOLA-derived Roughness Data Used to Predict Surface Scattering for Mars Subsurface Radar Sounding

The Mars Express orbiter, to be launched by the European Space Agency in 2003, will carry a low-frequency radar sounding instrument, MARSIS (Mars Advanced Radar for Subsurface and Ionospheric Sounding). The primary goal of MARSIS is to map the distribution of water, both solid and (if present) liquid, in the upper several km of the martian crust. Detecting discontinuities in the crust, such as an ice-water transition, presents many challenges for a Mars orbital radar sounder. One challenge that must be overcome is the presence of radar scattering (echoes) from the surface of Mars, expected to be detected by the sounder antennas at the same time as any echoes aris-ing from subsurface interfaces. As the transmitted spherical wavefront spreads within the crust of Mars,. it also interacts with surface topography at off-nadir positions, creating a "clutter" signal that can mask the subsurface echoes. The MARSIS instrument will utilize Doppler filtering to limit the off-nadir clutter in the along-track direction, and a nadir-null secondary antenna to identify strong off-nadir clutter from the cross-track direction. To evaluate the effects of off-nadir surface clutter and the capability of these schemes to reduce the clutter, it is necessary to predict the range of scattering behavior that may be expected from martian surface topography. In this paper, we utilize Mars Orbital Laser Altimeter (MOLA) data from the current Mars Global Surveyor mission to characterize the topographic roughness of a variety of martian terrain types, at scales relevant to the MARSIS clutter problem. Segments of MOLA altimetry profiles are reduced to the topographic parameters rms slope and fractal dimension, which then are used as inputs to a near-nadir radar scattering model to predict the strength of the clutter signal. Additional information is contained in the original extended abstract.

Plaut, J. J.↗

Ceiling Fires Studied to Simulate Low-Gravity Fires

A unique new way to study low-gravity flames in normal gravity has been developed. To study flame structure and extinction characteristics in low-stretch environments, a normal gravity low-stretch diffusion flame was generated using a cylindrical PMMA sample of varying large radii, as shown in the photograph. These experiments have demonstrated that low-gravity flame characteristics can be generated in normal gravity through the proper use of scaling. On the basis of this work, it is feasible to apply this concept toward the development of an Earth-bound method of evaluating material flammability in various gravitational environments from normal gravity to microgravity, including the effects of partial gravity low-stretch rates such as those found on the Moon (1/6g) or Mars (1/3g). During these experiments, the surface regression rates for PMMA were measured for the first time over the full range of flammability in air, from blowoff at high stretch, to quenching at low stretch, as plotted in the graph. The solid line drawn through the central portion of the data (3<a<100 sec-1) has a slope of unity, which indicates regression is proportional to stretch. The figure coordinates assume that the values of stretch are equivalent, whether derived from forced stretch or from buoyant stretch. The excellent correlation of the regression-rate data over the two-order-of-magnitude variation of stretch shows the reasonableness of this assumption.

Olson, Sandra L.↗

Bulk Insolation Models as Predictors for Locations for High Lunar Hydrogen Concentrations

In this study we consider the bulk effects of surface illumination on topography (insolation) and the possible thermodynamic effects on the Moon's hydrogen budget. Insolation is important as one of the dominant loss processes governing distributions of hydrogen volatiles on the Earth, Mars and most recently Mercury. We evaluated three types of high latitude > 65 deg., illumination models that were derived from the Lunar Observing Laser Altimetry (LOLA) digital elevation models (DEM)'s. These models reflect varying accounts of solar flux interactions with the Moon's near-surface. We correlate these models with orbital collimated epithermal neutron measurements made by the Lunar Exploration Neutron Detector (LEND). LEND's measurements derive the Moon's spatial distributions of hydrogen concentration. To perform this analysis we transformed the topographic model into an insolation model described by two variables as each pixels 1) slope and 2) slope angular orientation with respect to the pole. We then decomposed the illumination models and epithermal maps as a function of the insolation model and correlate the datasets.

Hydrogen Concentrations↗

Ridge belt-related scarps and troughs: Compressional crustal bending on Venus

Cytherean ridge arcs resulted in crustal shortening in places with either the strongest compression or weakest surface layers. Arcuate scarps on or close to the edge of the ridge arcs were compressional fronts formed by overthrust over or subduction of adjacent lowland. These ridge arcs became wider due to the propagation of new ridge formation close to previous one(s). As this process repeated itself with time, the crust became thicker and the foreland was bent either due to the excess load, overthrust or subduction event. The Salme Dorsa arc measures 100 km in width and 600 km in length. It consists of a horseshoe-like set of ridges and grooves on a gently sloping lowland. The westward arcuate ridge belt indicates lateral compressional stresses and crustal deformation from SE against the southern Ishtar Terra foreland plain. The trough on the western side of the ridge belt and tensional grabens close to the crest of the bulge to the west of the trough are due to the crustal bending and indicate effects of the load and thrust. Compression and relative movement from southeast against and over the foreland planitia have resulted in ridge belt, trough and bulge formation. The load- and/or stress-induced bending of the uppermost crust allows some estimations of the uppermost elastic lithosphere thickness. Repeated folding and thrust faulting of surface layers due to compression are indicated by four more ridge belts located close to Salme Dorsa. The northeasternmost one has short ridges located in troughs. The west-opening arcuate ridge belt interlocks with the Salme Dorsa horseshoe.

Raitala, J.↗

THE RELATION BETWEEN MID-PLANE PRESSURE AND MOLECULAR HYDROGEN IN GALAXIES: ENVIRONMENTAL DEPENDENCE

Molecular hydrogen (H{sub 2}) is the primary component of the reservoirs of cold, dense gas that fuel star formation in our Galaxy. While the H{sub 2} abundance is ultimately regulated by physical processes operating on small scales in the interstellar medium (ISM), observations have revealed a tight correlation between the ratio of molecular to atomic hydrogen in nearby spiral galaxies and the pressure in the mid-plane of their disks. This empirical relation has been used to predict H{sub 2} abundances in galaxies with potentially very different ISM conditions, such as metal-deficient galaxies at high redshifts. Here, we test the validity of this approach by studying the dependence of the pressure-H{sub 2} relation on environmental parameters of the ISM. To this end, we follow the formation and destruction of H{sub 2} explicitly in a suite of hydrodynamical simulations of galaxies with different ISM parameters. We find that a pressure-H{sub 2} relation arises naturally in our simulations for a variety of dust-to-gas ratios or strengths of the interstellar radiation field in the ISM. Fixing the dust-to-gas ratio and the UV radiation field to values measured in the solar neighborhood results in fair agreement with the relation observed in nearby galaxies with roughly solar metallicity. However, the parameters (slope and normalization) of the pressure-H{sub 2} relation vary in a systematical way with ISM properties. A particularly strong trend is the decrease of the normalization of the relation with a lowering of the dust-to-gas ratio of the ISM. We show how this trend and other properties of the pressure-H{sub 2} relation arise from the atomic-to-molecular phase transition in the ISM caused by a combination of H{sub 2} formation, destruction, and shielding mechanisms.

79 ASTRONOMY AND ASTROPHYSICS↗