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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,567 records · Page 87
All sourcesNASA NTRSDOE OSTI
DOE OSTI2019

Domain decomposition and multiscale mortar mixed finite element methods for linear elasticity with weak stress symmetry

Two non-overlapping domain decomposition methods are presented for the mixed finite element formulation of linear elasticity with weakly enforced stress symmetry. The methods utilize either displacement or normal stress Lagrange multiplier to impose interface continuity of normal stress or displacement, respectively. By eliminating the interior subdomain variables, the global problem is reduced to an interface problem, which is then solved by an iterative procedure. The condition number of the resulting algebraic interface problem is analyzed for both methods. A multiscale mortar mixed finite element method for the problem of interest on non-matching multiblock grids is also studied. It uses a coarse scale mortar finite element space on the non-matching interfaces to approximate the trace of the displacement and impose weakly the continuity of normal stress. A priori error analysis is performed. It is shown that, with appropriate choice of the mortar space, optimal convergence on the fine scale is obtained for the stress, displacement, and rotation, as well as some superconvergence for the displacement. Computational results are presented in confirmation of the theory of all proposed methods.

Mathematics↗
DOE OSTI2018

Attachment between heterotrophic bacteria and microalgae influences symbiotic microscale interactions

The surface and surroundings of microalgal cells (phycosphere) are critical interaction zones but have been difficult to functionally interrogate due to methodological limitations. In this study, we examined effects of phycosphere-associated bacteria for two biofuel-relevant microalgal species ( Phaeodactylum tricornutum and Nannochloropsis salina ) using stable isotope tracing and high spatial resolution mass spectrometry imaging (NanoSIMS) to quantify elemental exchanges at the single-cell level. Each algal species responded differently to bacterial attachment. In P. tricornutum , a high percentage of cells had attached bacteria (92%–98%, up to eight bacteria per alga) and fixed 64% more carbon with attached bacteria compared to axenic cells. In contrast, N. salina cells were less commonly associated with bacteria (42%–63%), harboured fewer bacteria per alga, and fixed 10% more carbon without attached bacteria compared to axenic cells. Additionally, an uncultivated bacterium related to Haliscomenobacter sp. was identified as an effective mutualist; it increased carbon fixation when attached to P. tricornutum and incorporated 71% more algal-fixed carbon relative to other bacteria. Our results illustrate how phylogenetic identity and physical location of bacteria and algae facilitate diverse metabolic responses. Phycosphere-mediated, mutualistic chemical exchanges between autotrophs and heterotrophs may be a fruitful means to increase microalgal productivity for applied engineering efforts.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Data measured on water collected from eastern Mojave Desert, California

In March of 2000 field collection of water from the Eastern Mojave Desert resulted in the measurement of stable isotope, radiocarbon, tritium, and limited dissolved noble gases. This work was follow-on to previous studies on similar systems in southern Nevada associated with the Nevada Test Site (Davisson et al., 1999; Rose and Davisson, 2003). The data for groundwater from wells and springs was never formally published and is therefore tabulated in Table 1 in order to be recorded in public record. In addition 4 years of remote precipitation data was collected for stable isotopes and is included in Table 2. These studies, along with many parallel and subsequent ones using isotopes and elemental concentrations, are all related to the general research area of tracing sources and quantifying transport times of natural and man-made materials in the environment. This type of research has direct relevance in characterizing environmental contamination, understanding resource development and protection, designing early detection in WMD related terrorism, and application in forensics analysis.

07 ISOTOPE AND RADIATION SOURCES↗
NASA NTRS1979

Detecting transition in agricultural systems

Remote sensing of agricultural phenomena has been largely concentrated on analysis of agriculture at the field level. Concern has been to identify crop status, crop condition, and crop distribution, all of which are spatially analyzed on a field-by-field basis. A more general level of abstraction is the agricultural system, or the complex of crops and other land cover that differentiate various agricultural economies. The paper reports on a methodology to assist in the analysis of the landscape elements of agricultural systems with Landsat digital data. The methodology involves tracing periods of photosynthetic activity for a fixed area. Change from one agricultural system to another is detected through shifts in the intensity and periodicity of photosynthetic activity as recorded in the radiometric return to Landsat. The Landsat-derived radiometric indicator of photosynthetic activity appears to provide the ability to differentiate agricultural systems from each other as well as from conterminous natural vegetation.

Neary, P. J.↗
NASA NTRS1991

Catalytic oxidation for treatment of ECLSS and PMMS waste streams

It is shown that catalytic oxidation is an effective technique for the removal of trace organic contaminants in a multifiltration potable processor's effluent. Essential elements of this technology are devices that deliver oxygen to the influent, and remove gaseous reaction byproducts from the effluent, via hollow-tube, gas-permeable membranes. Iodine, which poisons existing catalysis, is removed by a small deiodination bed prior to catalytic reactor entrance. The catalyst used is a mixture of Pt and Ru deposited on carbon, operating at 125-160 C and 39-90 psi pressures.

Akse, James R.↗
NASA NTRS2000

Ion Transmission to the Focal Plane of the Chandra X-Ray Observatory

The severe degradation in spectrometric performance observed by the AXAF CCD Imaging Spectrometer (ACIS) instrument on-board the Chandra X-ray Observatory (CXO) was associated with a sharp increase in charge transfer inefficiency combined with relatively constant dark current. It was also observed that damage occurred only during passage through the earth's radiation belts, and only when ACIS remained in the focal plane during the passage. Subsequent measurements and analyses support the conjecture that the damaging radiation entered through the Observatory's High-Resolution Mirror Assembly (HRMA) aperture. A mechanism whereby low energy magnetospheric protons and/or heavier ions are scattered through the HRMA and reach the focal plane with just enough energy to stop in the CCD's charge transfer region currently provides a reasonably consistent explanation of all observed phenomena. In this paper, we will describe analyses which support this conclusion. Simulations using standard ion transmission codes were used to generate a bi-directional response function (BDRF) for the mirror surfaces and transmission through the various path elements. The BDRF was convolved with the geometry via ray-trace. Damage estimates using measured proton fluence and ground measurements of ACIS- type CCD damage vs. proton energy will be presented and compared with observed on- orbit damage.

Kolodziejczak, J. J.↗
NASA NTRS2000

Mars surface gas chromatograph mass spectrometer

A Mars surface lander Gas Chromatograph Mass Spectrometer (GCMS) is described to measure the chemical composition of abundant and trace volatile species and isotope ratios for noble gases and other elements. These measurements are relevant to the study of atmospheric evolution and past climatic conditions. A Micromission plan is under study where a surface package including a miniaturized GCMS would be delivered to the surface by a solar heated hot air balloon based system. The balloon system would be deployed about 8 km above the surface of Mars, wherein it would rapidly fill with Martian atmosphere and be heated quickly by the sun. The combined buoyancy and parachuting effects of the solar balloon result in a surface package impact of about 5 m/sec. After delivery of the package to the surface, the balloon would ascend to about 4 km altitude, with imaging and magnetometry data being taken for the remainder of the daylight hours as the balloon is blown with the Martian winds. Total atmospheric entry mass of this mission is estimated to be approximately 50 kg, and it can fit as an Ariane 5 piggyback payload.

Mahaffy, P.↗
DOE OSTI2024

Understanding Trace Iron and Chromium Incorporation During Gibbsite Crystallization and Effects on Mineral Dissolution

Incorporation of pollutants, e.g., heavy metals, or critical elements, e.g., lithium, as impurities in mineral phases can significantly affect their mobility or sequestration in the environment. Even when present at low concentrations, impurities can alter the solubility and reactivity of the host mineral. Here, in this study, we investigate the incorporation of trace amounts of iron (Fe 3+ ) and chromium (Cr 3+ ) during the crystal growth of the aluminum (Al 3+ ) hydroxide, gibbsite, a major component of bauxite ores, an important soil mineral, and a dominant mineral phase in stored radioactive wastes. Using a comprehensive suite of analytical techniques, we show that both Cr 3+ and Fe 3+ can be incorporated into the gibbsite lattice during coprecipitation by replacing Al 3+ in octahedral sites. These small amounts are consistent with limited to no structural isomorphism shared between Al 3+ and Cr 3+ /Fe 3+ hydroxide precipitates, nor room temperature miscibility of their isostructural M 2 O 3 oxide forms, in contrast with oxyhydroxide forms where Al 3+ and Fe 3+ share similar structural topologies. Despite the limited uptake of Cr 3+ /Fe 3+ , we show that these impurities have significant implications for gibbsite dissolution behavior. The limited uptake of Cr 3+ /Fe 3+ (e.g. 0.43% Cr 3+ and 0.4% Fe 3+ ), we show that these impurities have significant implications for gibbsite dissolution behavior and subsequent reactivity in complex environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2002

Advances in space radiation shielding codes

Early space radiation shield code development relied on Monte Carlo methods and made important contributions to the space program. Monte Carlo methods have resorted to restricted one-dimensional problems leading to imperfect representation of appropriate boundary conditions. Even so, intensive computational requirements resulted and shield evaluation was made near the end of the design process. Resolving shielding issues usually had a negative impact on the design. Improved spacecraft shield design requires early entry of radiation constraints into the design process to maximize performance and minimize costs. As a result, we have been investigating high-speed computational procedures to allow shield analysis from the preliminary concept to the final design. For the last few decades, we have pursued deterministic solutions of the Boltzmann equation allowing field mapping within the International Space Station (ISS) in tens of minutes using standard Finite Element Method (FEM) geometry common to engineering design methods. A single ray trace in such geometry requires 14 milliseconds and limits application of Monte Carlo methods to such engineering models. A potential means of improving the Monte Carlo efficiency in coupling to spacecraft geometry is given.

manned↗
NASA NTRS1996

Development of Software to Model AXAF-I Image Quality

This draft final report describes the work performed under the delivery order number 145 from May 1995 through August 1996. The scope of work included a number of software development tasks for the performance modeling of AXAF-I. A number of new capabilities and functions have been added to the GT software, which is the command mode version of the GRAZTRACE software, originally developed by MSFC. A structural data interface has been developed for the EAL (old SPAR) finite element analysis FEA program, which is being used by MSFC Structural Analysis group for the analysis of AXAF-I. This interface utility can read the structural deformation file from the EAL and other finite element analysis programs such as NASTRAN and COSMOS/M, and convert the data to a suitable format that can be used for the deformation ray-tracing to predict the image quality for a distorted mirror. There is a provision in this utility to expand the data from finite element models assuming 180 degrees symmetry. This utility has been used to predict image characteristics for the AXAF-I HRMA, when subjected to gravity effects in the horizontal x-ray ground test configuration. The development of the metrology data processing interface software has also been completed. It can read the HDOS FITS format surface map files, manipulate and filter the metrology data, and produce a deformation file, which can be used by GT for ray tracing for the mirror surface figure errors. This utility has been used to determine the optimum alignment (axial spacing and clocking) for the four pairs of AXAF-I mirrors. Based on this optimized alignment, the geometric images and effective focal lengths for the as built mirrors were predicted to cross check the results obtained by Kodak.

Ahmad, Anees↗
DOE OSTI2025

Detection and quantification of trace technetium in the presence of molybdenum using laser-induced breakdown spectroscopy

Technetium (Tc) is a very important element that is encountered in many aspects, from its presence in radioactive waste and its potential environmental impact to its use as a medical radioisotope. Its detection and quantification in liquid samples is traditionally cumbersome, involving detailed sample preparation and analysis by mass spectrometry or scintillation. This article demonstrates the first comprehensive emission spectral analysis of Tc from a liquid sample by immobilization in a polymer and analysis by laser-induced breakdown spectroscopy (LIBS). A survey of LIBS spectra was completed to identify the strongest analytical lines for quantification of trace Tc in the presence of Mo. The quantification of Tc in a Mo-containing matrix was selected because Tc radioisotopes are the daughter products of Mo isotope decay. The first reported calibration curves by LIBS are provided with limits of detection and quantification down to 0.710 µg mL −1 and 1.39 µg mL −1 , respectively. Ultimately, this study demonstrated the feasibility of trace Tc quantification using LIBS and will serve as a reference for future research related to monitoring this radioactive species.

Andrews, Hunter B. [Oak Ridge National Laboratory ↗
NASA NTRS2021

The Origins Space Telescope: Baseline Mission Concept

The Origins Space Telescope will trace the history of our origins from the time dust and heavy elements permanently altered the cosmic landscape to present-day life. How did galaxies evolve from the earliest galactic systems to those found in the Universe today? How do habitable planets form? How common are life-bearing worlds? To answer these alluring questions, Origins will operate atmid- and far-infrared (IR) wavelengths and offer powerful spectroscopic instruments and sensitivity three orders of magnitude better than that of the Herschel Space Observatory, the largest telescope flown in space to date. We describe the baseline concept for Origins recommended to the 2020 US Decadal Survey in Astronomy and Astrophysics. The baseline design includes a 5.9-m diameter telescope cryocooled to 4.5 K and equipped with three scientific instruments. A mid-infrared instrument (Mid-Infrared Spectrometer and Camera Transit spectrometer) will measure the spectra of transiting exoplanets in the 2.8 to 20 μm wavelength range and offer unprecedented spectrophotometric precision, enabling definitive exoplanet biosignature detections. The far-IR imager polarimeter will be able to survey thousands of square degrees with broadband imaging at 50 and 250 μm. The Origins Survey Spectrometer will cover wavelengths from 25 to 588 μm, making wide-area and deep spectroscopic surveys with spectral resolving power R ∼ 300, and pointed observations at R ∼ 40;000 and 300,000 with selectable instrument modes. Origins was designed to minimize complexity. The architecture is similar to that of the Spitzer Space Telescope and requires very few deployments after launch, while the cryothermal system design leverages James Webb Space Telescope technology and experience. A combination of current-state-of-the-art cryocoolers and next-generation detector technology will enable Origins’ natural background-limited sensitivity.

David Leisawitz↗
NASA NTRS1985

Space station trace contaminant control

Different systems for the control of space station trace contaminants are outlined. The issues discussed include: spacecabin contaminant sources, technology base, contaminant control system elements and configuration, approach to contaminant control, contaminant load model definition, spacecraft maximum allowable concentrations, charcoal bed sizing and performance characteristics, catalytic oxidizer sizing and performance characteristics, special sorbent bed sizing, animal and plant research payload problems, and emergency upset contaminant removal. It is concluded that the trace contaminant control technology base is firm, the necessary hardware tools are available, and the previous design philosophy is still applicable. Some concerns are the need as opposed to danger of the catalytic oxidizer, contaminants with very low allowable concentrations, and the impact of relaxing materials requirements.

Olcutt, T.↗
DOE OSTI2019

Heavy Metal Atmospheric Deposition Study in Moscow Region, Russia

The air quality in north-eastern part of Moscow region was evaluated by trace metals atmospheric deposition using moss Pleurozium schreberi as bioindicator. Thirty six elements were determined in analyzed samples by Neutron activation analysis and Atomic absorption spectrometry. Principal component analysis was used to identify and characterize different pollution sources. Maps showing the geographical distribution of the factor scores were built using ArcGis software. Median values of the elements studied were compared with data obtained for other regions in Russia. The present survey showed that industrial activity, thermal power plants and transport still have the largest anthropogenic impact on air pollution in studied region.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Structural properties of a bone-ceramic composite as a promising material in spinal surgery

The paper describes the results of in vitro tests of composite bone-ceramic implants and procedures for modifying implant surfaces to enhance osteogenesis. Analysis of CBCI ESs demonstrated that they have a porous structure with the mean longitudinal pore size of 70 µm and the mean transverse pore size of 46 µm; surface pores are open, while inner pores are closed. Elemental analysis of the CBCI surface demonstrates that CBCIs are composed of aluminum and zirconium oxides and contain HA inclusions. Profilometry of the CBCI ES surface revealed the following deviations: the maximum deviation of the profile in the sample center is 15 µm and 16 µm on the periphery, while the arithmetical mean and mean square deviations of the profile are 2.65 and 3.4 µm, respectively. In addition, CBCI biodegradation products were pre-examined; a 0.9% NaCl solution was used as a comparison group. Potentially toxic and tissue accumulated elements, such as cadmium, cobalt, mercury, and lead, are present only in trace amounts and have no statistically significant differences with the comparison group, which precludes their potential toxic effects on the macroorganism. Ceramic-based CBCI may be effective and useful in medicine for restoration of the anatomic integrity and functions of the bone tissue.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Improving the Representation of Soluble Iron in Climate Models

Mineral dust produced in the arid and semi-arid regions of the world is the dominant source of iron (Fe) in atmospheric aerosol inputs to the open ocean. The bioavailable Fe fraction of atmospheric dust is thought to regulate and occasionally limit the primary productivity in large oceanic regions, which influences the CO2 uptake from the atmosphere affecting the Earth’s climate. Because Fe bioavailability cannot be directly measured, it is assumed that the dissolved Fe or highly reactive Fe in the dust is bioavailable. The fraction of soluble Fe in dust is mainly controlled by: (1) the mineral composition of the soils and the emitted dust from the source areas; (2) the atmospheric processing that converts the Fe in Fe-bearing minerals into highly soluble forms of Fe. The project has mainly focused on constraining the mineral composition of dust aerosols (1), a previously neglected, yet a key issue to constrain the deposition of soluble iron. Deriving aerosol mineral composition requires global knowledge of the soil mineral content, which is available from poorly constrained global atlases. In addition, the mineral content of the emitted aerosol differs from that of the parent soil. Measurements of soil mineral fractions are based upon wet sedimentation (or ’wet sieving’) techniques that disturb the soil sample, breaking aggregates that are found in the original, undispersed soil that is subject to wind erosion. Wet sieving alters the soil size distribution, replacing aggregates that are potentially mobilized as aerosols with a collection of smaller particles. A major challenge is to derive the size-distributed mineral fractions of the emitted dust based upon their fractions measured from wet-sieved soils. Finally, representations of dust mineral composition need to account for mixtures of minerals. Examination of individual particles shows that iron, an element that is central to many climate processes, is often found as trace impurities of iron oxide attached to aggregates of other minerals. This is another challenge that has been tackled by the project. The project has produced a major step forward on our understanding of the key processes needed to predict the mineral composition of dust aerosols by connecting theory, modeling and observations. The project has produced novel semi-empirical and theoretical methods to estimate the emitted size distribution and mineral composition of dust aerosols. These methods account for soil aggregates that are potentially emitted from the original undisturbed soil but are destroyed during wet sieving. The methods construct the emitted size distribution of individual minerals building upon brittle fragmentation theory, reconstructions of wet-sieved soil mineral size distributions, and/or characteristic mineral size distributions estimated from observations at times of high concentration. Based on an unprecedented evaluation with a new global compilation of observations produced with the project support, we showed that the new methods remedy some key deficiencies compared to the previous state-of-the-art. This includes the correct representation of Fe-bearing phyllosilicates at silt sizes, where they are abundant according to observations. In addition, the quartz fraction of silt particles is in better agreement with measured values. In addition, we represent an additional class of iron oxide aerosol that is a small impurity embedded within other minerals, allowing it to travel farther than in its pure crystalline state. We assume that these impurities are least frequent in soils rich in iron oxides (as a result of the assumed effect of weathering that creates pure iron oxide crystals). The mineral composition of dust is also important to other interaction with climate - through shortwave absorption and radiative forcing, nucleation of cloud droplets and ice crystals, and the heterogeneous formation of sulfates and nitrates - and to its impacts upon human health. Despite the importance of mineral composition, models have typically assumed that soil dust aerosols have globally uniform composition. The results of this project will allow an improved estimation of the dust effects upon climate and health.

54 ENVIRONMENTAL SCIENCES↗