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At least 1,585 records · Page 88

Determination of the technological growth parameters in the InAs-GaAs system for the MOCVD synthesis of “Multimodal” InAs QDs

The specific features of growth in the InAs-GaAs system by the metal-organic chemical vapor deposition method are studied. The dependences of the In content of the InxGa{sub 1−x}As solid solution and of the InAs growth rate on the molar flow of In in a wide temperature range (480–700°C) are determined. The growth processes of InAs quantum dots (QDs) on GaAs with different surface misorientations are examined. The conditions are found in which InAs QDs are formed with a small number of defects and at a high density on a GaAs “sublayer” grown at a high rate. An epitaxial technique is developed for the synthesis of InAs QDs with multimodal size distribution and an extended photoluminescence spectrum, which can be effectively used in designing solar cells with QDs in the active region.

36 MATERIALS SCIENCE↗

Household Energy Burden in Lawrence, Massachusetts [Slides]

The City of Lawrence consists of 18 census tracts, of those, 9 census tracts have an average energy burden (the percent of income spent on energy bills) of 6% or greater. The Lawrence Stakeholders Coalition's (LSC) main goal is to "Reduce energy burden and create well-paying local jobs and businesses by increasing the distribution and use of sustainable technologies such as heat pumps, community and rooftop solar, and weatherization." As part of that goal, the LSC is interested in understanding Lawrence's pathway to electrification, specifically through the building sector. This technical assistance aims to assist the LSC's electrification and energy burden reduction planning by: 1) Identifying the most energy-burdened households by owner-occupied and renter-occupied housing status; 2) Identifying and quantifying the characteristics of the most energy-burdened housing units by housing type, age, and heating fuel type; 3) Identifying the tenure and housing types of the most energy-burdened and prevalent households for subsequent ResStock analysis of cost-effective efficiency upgrades.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Retrieval Analysis of the Emission Spectrum of WASP-12b: Sensitivity of Outcomes to Prior Assumptions and Implications for Formation History

We analyze the emission spectrum of the hot Jupiter WASP-12b using our HELIOS-R retrieval code and HELIOS-K opacity calculator. When interpreting Hubble and Spitzer data, the retrieval outcomes are found to be prior-dominated. When the prior distributions of the molecular abundances are assumed to be log-uniform, the volume mixing ratio of HCN is found to be implausibly high. A VULCAN chemical kinetics model of WASP-12b suggests that chemical equilibrium is a reasonable assumption even when atmospheric mixing is implausibly rigorous. Guided by (exo)planet formation theory, we set Gaussian priors on the elemental abundances of carbon, oxygen, and nitrogen with the Gaussian peaks being centered on the measured C/H, O/H, and N/H values of the star. By enforcing chemical equilibrium, we find substellar O/H and stellar to slightly superstellar C/H for the dayside atmosphere of WASP-12b. The superstellar carbon-to-oxygen ratio is just above unity, regardless of whether clouds are included in the retrieval analysis, consistent with Madhusudhan et al. Furthermore, whether a temperature inversion exists in the atmosphere depends on one’s assumption for the Gaussian width of the priors. Our retrieved posterior distributions are consistent with the formation of WASP-12b in a solar-composition protoplanetary disk, beyond the water iceline, via gravitational instability or pebble accretion (without core erosion) and migration inward to its present orbital location via a disk-free mechanism, and are inconsistent with both in situ formation and core accretion with disk migration, as predicted by Madhusudhan et al. We predict that the interpretation of James Webb Space Telescope WASP-12b data will not be prior-dominated.

79 ASTRONOMY AND ASTROPHYSICS↗

Was There a Negative Vacuum Energy in Your Past?

We introduce a novel model for the origin of the observable universe in which a flat universe with a positive vacuum energy is proceeded by a flat universe with a negative vacuum energy. A negative vacuum energy is consistent with a supersymmetric ground state similar to that predicted by superstring theories. A positive vacuum energy could emerge as a result of the gravitational collapse of the negative vacuum energy universe when the matter temperature reaches a characteristic value where supersymmetry is strongly broken. In principle this allows one to derive all the features of our expanding universe from a single parameter: the magnitude of the pre-big bang negative vacuum energy density. In this paper, a simple model for the big bang is introduced which allows us to use the present day entropy density, and temperature fluctuations of the CMB, together with the present day density of dark matter, to predict the magnitude of the negative vacuum energy. This model for the big bang also makes a dramatic prediction: dark matter consists of compact objects with masses on the order of 104 solar masses. Remarkably this is consistent with numerical simulations for how the primordial fluctuations in the density of dark matter give rise to the observed inhomogeneous distribution of matter in our universe. Our model for the big bang also allows for the production of some compact objects with masses greater than 104 solar masses which are consistent with observations of massive compact objects at the center of the earliest galaxies.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Improving the Power Outage Resilience of Buildings with Solar PV through the Use of Battery Systems and EV Energy Storage

Buildings with solar photovoltaic (PV) generation and a stationary battery energy storage system (BESS) may self-sustain an uninterrupted full-level electricity supply during power outages. The duration of off-grid operation is dependent on the time of the power fault and the capabilities of the home energy management system (HEMS). In this paper, building resilience is quantified by analyzing the self-sustainment duration for all possible power outages throughout an entire year. An evaluation method is proposed and exercised on a reference house in California climate zone 9 for which the detailed electricity usage is simulated using the EnergyPlus software. The influence of factors such as energy use behavioral patterns, energy storage capacity from the BESS, and an electric vehicle (EV) battery on the building resilience is evaluated. Varying combinations of energy storage and controllable loads are studied for optimally improved resilience based on user preferences. It is shown that for the target home and region with a solar PV system of 7.2 kW, a BESS with a capacity of 11 kWh, and an EV with a battery of 80 kWh permanently connected to the home, off-grid self-sustained full operation is guaranteed for at least 72 h.

14 SOLAR ENERGY↗

A POLYTROPIC MODEL FOR SPACE AND LABORATORY PLASMAS DESCRIBED BY BI-MAXWELLIAN ELECTRON DISTRIBUTIONS

Non-local electron energy probability functions (EEPFs) are shown to have an important effect on the thermodynamic behavior of plasmas in the context of solar wind and laboratory plasmas. A conservation relation is held for electron enthalpy and plasma potential during the electron transport. For an adiabatic system governed by non-local electron dynamics, the correlation between electron temperature and density can be approximated by a polytropic relation, with different indexes demonstrated using three cases of bi-Maxwellian EEPFs. This scenario differs from a local thermodynamic equilibrium having a single polytropic index of 5/3 for adiabaticity.

79 ASTRONOMY AND ASTROPHYSICS↗

CORONAL MAGNETOGRAPHY OF A SIMULATED SOLAR ACTIVE REGION FROM MICROWAVE IMAGING SPECTROPOLARIMETRY

We have simulated the Expanded Owens Valley Solar Array (EOVSA) radio images generated at multiple frequencies from a model solar active region, embedded in a realistic solar disk model, and explored the resulting data cube for different spectral analysis schemes to evaluate the potential for realizing one of EOVSA’s most important scientific goals—coronal magnetography. In this paper, we focus on modeling the gyroresonance and free–free emission from an on-disk solar active region model with realistic complexities in electron density, temperature and magnetic field distribution. We compare the magnetic field parameters extrapolated from the image data cube along each line of sight after folding through the EOVSA instrumental profile with the original (unfolded) parameters used in the model. We find that even the most easily automated, image-based analysis approach (Level-0) provides reasonable quantitative results, although they are affected by systematic effects due to finite sampling in the Fourier (UV) plane. Finally, we note the potential for errors due to misidentified harmonics of the gyrofrequency, and discuss the prospects for applying a more sophisticated spectrally based analysis scheme (Level-1) to resolve the issue in cases where improved UV coverage and spatial resolution are available.

79 ASTRONOMY AND ASTROPHYSICS↗

Wavelet-based Characterization of Small-scale Solar Emission Features at Low Radio Frequencies

Low radio frequency solar observations using the Murchison Widefield Array have recently revealed the presence of numerous weak short-lived narrowband emission features, even during moderately quiet solar conditions. These nonthermal features occur at rates of many thousands per hour in the 30.72 MHz observing bandwidth, and hence necessarily require an automated approach for their detection and characterization. Here, we employ continuous wavelet transform using a mother Ricker wavelet for feature detection from the dynamic spectrum. We establish the efficacy of this approach and present the first statistically robust characterization of the properties of these features. In particular, we examine distributions of their peak flux densities, spectral spans, temporal spans, and peak frequencies. We can reliably detect features weaker than 1 SFU, making them, to the best of our knowledge, the weakest bursts reported in literature. The distribution of their peak flux densities follows a power law with an index of −2.23 in the 12–155 SFU range, implying that they can provide an energetically significant contribution to coronal and chromospheric heating. These features typically last for 1–2 s and possess bandwidths of about 4–5 MHz. Their occurrence rate remains fairly flat in the 140–210 MHz frequency range. At the time resolution of the data, they appear as stationary bursts, exhibiting no perceptible frequency drift. These features also appear to ride on a broadband background continuum, hinting at the likelihood of them being weak type-I bursts.

79 ASTRONOMY AND ASTROPHYSICS↗

SOLAR OPACITY CALCULATIONS USING THE SUPER-TRANSITION-ARRAY METHOD

A new opacity model has been developed based on the Super-Transition-Array (STA) method for the calculation of monochromatic opacities of plasmas in local thermodynamic equilibrium. The atomic code, named STAR (STA-Revised), is described and used to calculate spectral opacities for a solar model implementing the recent AGSS09 composition. Calculations are carried out throughout the solar radiative zone. The relative contributions of different chemical elements and atomic processes to the total Rosseland mean opacity are analyzed in detail. Monochromatic opacities and charge-state distributions are compared with the widely used Opacity Project (OP) code, for several elements near the radiation–convection interface. STAR Rosseland opacities for the solar mixture show a very good agreement with OP and the OPAL opacity code throughout the radiation zone. Finally, an explicit STA calculation was performed of the full AGSS09 photospheric mixture, including all heavy metals. It was shown that, due to their extremely low abundance, and despite being very good photon absorbers, the heavy elements do not affect the Rosseland opacity.

79 ASTRONOMY AND ASTROPHYSICS↗

Hierarchical Flexibility Offering Strategy for Integrated Hybrid Resources in Real-time Energy Markets

This paper proposes a hierarchical model for determining the energy flexibility offering strategy of integrated hybrid resources (IHRs) in power distribution systems to participate in real-time energy markets. The proposed model utilizes the scalability, fast response time, and uncertainty observation of deep reinforcement learning (DRL) to overcome the scalability issue of operating numerous flexible resources and deliverability of energy flexibility to the real-time markets in the presence of the network constraints. To that end, the power distribution system is divided into multiple IHRs, where different types of flexible loads, energy storage systems, and solar plants with controllable inverters are operated through local IHR controllers, trained by deep deterministic policy gradient (DDPG) algorithm. Active power request and reactive power capacity of IHRs are then transmitted to a central flexibility controller, where a quadratic optimization model ensures the deliverability of the energy flexibility to the real-time energy market by satisfying the distribution network constraints. The proposed model is implemented on the 123-bus test power distribution system, demonstrating the capability of DRL-based hierarchical model for scalable operation of IHRs in order to offer deliverable energy flexibility to the real-time energy market.

Majidi, Majid↗

Utility-Scale Solar: Empirical Trends in Project Technology, Cost, Performance, and PPA Pricing in the United States – 2018 Edition

The utility-scale solar sector has led the overall U.S. solar market in terms of installed capacity since 2012. In 2017, the utility-scale sector accounted for nearly 60% of all new solar capacity, and is expected to maintain its market-leading position for at least another six years. Two-thirds of all states, representing all regions of the country, are now home to one or more utility-scale solar projects. This report—the sixth in an ongoing annual series—provides in-depth data-driven analysis of the utility-scale solar project fleet in the United States. Drawing on empirical project-level data from a wide range of sources, this report analyzes technology trends, installed project prices, operating costs, capacity factors, power purchase agreement ("PPA") prices, the levelized cost of solar energy (LCOE), and the market value of solar. Given its current preeminence in the market, utility-scale PV also dominates much of this report, though data from CPV and CSP projects are also presented where appropriate. Highlights from this year's edition include: -Installation and Technology Trends: The use of solar trackers dominated 2017 installations with nearly 80% of all new capacity. In a reflection of the ongoing geographic expansion of the market beyond California and the high-insolation Southwest, the median insolation level at newly built project sites declined again in 2017. While new fixed-tilt projects are now seen predominantly in less-sunny regions, tracking projects are increasingly pushing into these same regions. The median inverter loading ratio grew to 1.32 in 2017, allowing the inverters to operate closer to full capacity for a greater percentage of the day. -Installed Prices: Median installed PV project prices have steadily fallen by two-thirds since the 2007-2009 period, to $2.0/WAC (or $1.6/WDC) for projects completed in 2017. The lowest 20th percentile of projects within our 2017 sample were priced at or below $1.8/WAC, with the lowest-priced projects around $0.9/WAC. Overall price dispersion across the entire sample has decreased steadily every year since 2013; similarly, price variation across regions decreased in 2017. -Operation and Maintenance ("O&M") Costs: PV O&M costs were in the neighborhood of $16/kWAC-year, or $8/MWh, in 2017. These numbers include only those costs incurred to directly operate and maintain the generating plant. -Capacity Factors: The cumulative net AC capacity factors of individual projects vary widely, from 14.3% to 35.2%, with a sample median of 26.3%. This project-level variation is based on a number of factors, including the strength of the solar resource at the project site, whether the array is mounted at a fixed tilt or on a tracking mechanism, the inverter loading ratio, degradation, and curtailment. Changes in at least the first three of these factors drove mean capacity factors higher from 2010-vintage to 2013-vintage projects, where they've remained fairly steady among more-recent project vintages as an ongoing increase in the prevalence of tracking has been offset by a build-out of lower resource sites. -PPA Prices and LCOE: Driven by lower installed project prices and improving capacity factors, levelized PPA prices for utility-scale PV have fallen dramatically over time, by $20-$30/MWh per year on average from 2006 through 2012, with a smaller price decline of ~$10/MWh per year evident from 2013 through 2016. Most recent PPAs in our sample—including many outside of California and the Southwest—are priced at or below $40/MWh levelized (in real 2017 dollars), with a few priced as aggressively as ~$20/MWh. The median LCOE among operational PV projects in our sample has followed PPA prices lower, suggesting a relatively competitive market for PPAs. -Solar's Wholesale Energy Market Value: Falling PPA prices have been offset to some degree by a decline in the wholesale energy market value of solar within higher-penetration markets like California, where solar earned just 79% of the average price across all hours within CAISO's real-time wholesale energy market in 2017 (down from 125% back in 2012). In other markets with less solar penetration, however, solar's hourly generation profile still earns more than the average wholesale price (e.g., 127% in ERCOT, 112% in PJM). -Solar+Storage: Adding battery storage is one way to at least partially restore the value of solar, and three recent PV+storage PPAs in Nevada (each using 4-hour batteries sized at 25% of PV nameplate capacity) suggest that the incremental PPA price adder for storage has fallen to ~$5/MWh, down from ~$15/MWh just a year ago for a similarly configured project. As PV plus battery storage becomes more cost-effective, a number of developers are regularly offering it as a viable upgrade to standalone PV. At the end of 2017, there were at least 188.5 GW of utility-scale solar power capacity within the interconnection queues across the nation. The 2017 growth within these queues is widely distributed across all regions of the country, but is most pronounced in the up-and-coming Midwest region, which accounts for 27% of the 99.2 GW of new queue capacity. The widening geographic distribution is as clear of a sign as any that the utility-scale market is maturing and expanding outside of its traditional high-insolation comfort zones.

14 SOLAR ENERGY↗

Coordinated Modeling of Electric Grid and Natural Gas Network Operations

Presentation based upon full report of a Colorado case study and coordination framework, which is available at https://www.nrel.gov/docs/fy20osti/77096.pdf. JISEA analysts Brian Sergi, Omar Guerra, and Bri-Mathias Hodge will present on recent JISEA work on coordination between the natural gas and electricity sectors. Power and gas are becoming increasingly interdependent but weren't designed to function together. How does greater coordination impact system operations with different levels of solar and wind penetrations? This free JISEA presentation will take place in a Webinar on Tuesday, May 11, 2021 at 12 p.m.: Learn how greater coordination between the natural gas and electricity sectors impacts system operations with different levels of solar and wind penetrations. Presentation information includes: Historical and projected data for natural gas consumption and power generation in the United States as demonstrated by 2014 East Coast Polar Vortex, 2021 Texas Winter Storm Uri. Showing coupling points, FERC identified need for better coordination, different levels of coordination (decision making and optimization control), coordination framework. Case study on Colorado Front Range, ramping requirements and gas nominations, real-time dispatch (June and December scenarios), results of analysis of impacts of coordination on unserved load. Total real-time gas offtakes by node, impacts on unserved gas, effect on CO2 emissions. Discussions on clusions drawn from Colorado Case study expanded co-simulation via HELICS, objectives of the HELICS+ natural gas use case, modeling of hydrogen blending, techno economic assessment of blending, and blending impacts on energy content and pressure.

analysis↗

Excited-State Charge Distribution of a Donor–π–Acceptor Zn Porphyrin Probed by N K-Edge Transient Absorption Spectroscopy

Zinc porphyrin solar cell dyes with donor-π–acceptor architectures combine light absorber (π), electron-donor, and electron-acceptor moieties inside a single molecule with atomic precision. The donor-π–acceptor design promotes the separation of charge carriers following optical excitation. Here, we probe the excited-state electronic structure within such molecules by combining time-resolved X-ray absorption spectroscopy at the N K-edge with first-principles time-dependent density functional theory (TD-DFT) calculations. Furthermore, customized Zn porphyrins with strong-donor triphenylamine groups or weak-donor tri-tert-butylbenzene groups were synthesized. Energetically well-separated N K-edge absorption features simultaneously probe the excited-state electronic structure from the perspectives of the macrocycle and triphenylamine N atoms. New absorption transitions between the macrocycle N atoms and the excited-state HOMO vacancy are observed, and the triphenylamine associated absorption feature blue-shifts, consistent with partial oxidation of the donor groups in the excited state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Large-Scale Adoption of Self Synchronized Universal Droop Controller-Based Inverters to Enable Ancillary Services for Different Modes of Distribution System Operations

This poster presents the results of using the self-synchronized universal droop controller to enable solar power to provide ancillary services so that the use of solar power can be increased. A 300-node system using the IEEE 123 bus test feeder are modeled on a real time power system simulator with the results presented.

Arce, Laura↗

Insulation Coordination Design for Grid-Connected Solid-State Transformers

The deployment of solid-state transformers (SSTs) in medium-voltage (MV) distribution systems is facing various challenges, especially the challenge of insulation coordination design against grid-originated lightning impulses. In this article, two challenges in existing insulation coordination designs for grid-connected SSTs are identified. One challenge is the mismatch between metal-oxide varistor (MOV) protective levels and SST insulation strength, the other challenge is the incompatibility of standard impulse test on SST protective structures. To address the MOV selection challenge, a novel lightning protection scheme is designed to protect a single-stage SST where the semiconductor modules are directly exposed to external lightning impulses. Here, the in-lab lightning impulse tests are performed to verify the overvoltage attenuation performance of the prototyped lightning protection scheme. To address the impulse test challenge, the surge withstand capability of the protected SST is comprehensively evaluated with a complete set of insulation coordination design procedures beyond the basic insulation level (BIL) test. After these two challenges are addressed, a discussion is presented on substituting conventional transformers with the protected SSTs into insulation-coordinated distribution systems to facilitate the field deployment of SSTs.

solid-state transformer (SST)↗

DETECTION OF THE YORP EFFECT FOR SMALL ASTEROIDS IN THE KARIN CLUSTER

The Karin cluster is a young asteroid family thought to have formed only ≃5.75 Myr ago. The young age can be demonstrated by numerically integrating the orbits of Karin cluster members backward in time and showing the convergence of the perihelion and nodal longitudes (as well as other orbital elements). Previous work has pointed out that the convergence is not ideal if the backward integration only accounts for the gravitational perturbations from the solar system planets. It improves when the thermal radiation force known as the Yarkovsky effect is accounted for. This argument can be used to estimate the spin obliquities of the Karin cluster members. Here we take advantage of the fast growing membership of the Karin cluster and show that the obliquity distribution of diameter D≃1--2 km Karin asteroids is bimodal, as expected if the YORP effect acted to move obliquities toward extreme values (0° or 180°). The measured magnitude of the effect is consistent with the standard YORP model. The surface thermal conductivity is inferred to be 0.07–0.2 W m{sup −1} K{sup −1} (thermal inertia ≃300--500 J m{sup −2} K{sup −1} s{sup −1/2}). We find that the strength of the YORP effect is roughly ≃0.7 of the nominal strength obtained for a collection of random Gaussian spheroids. These results are consistent with a surface composed of rough, rocky regolith. The obliquity values predicted here for 480 members of the Karin cluster can be validated by the light-curve inversion method.

79 ASTRONOMY AND ASTROPHYSICS↗

Kink Waves in Non-isothermal Stratified Solar Waveguides: Effect of the External Magnetic Field

We study the effect of an external magnetic field on the properties of kink waves, propagating along a thin non-isothermal stratified and diverging magnetic flux tube. A wave equation, governing the propagation of kink waves under the adopted model is derived. It is shown that the vertical gradient of temperature introduces a spatially local cut-off frequency ω {sub c}. The vertical distribution of the cut-off frequency is calculated for the reference VAL-C model of the solar atmosphere and for different values of a ratio of external to internal magnetic fields. The results show that the cut-off frequency is negative below the temperature minimum due to the negative temperature gradient. In the chromosphere the cut-off frequency at a given height is smaller for a stronger external magnetic field. For the appropriate range of a ratio B{sub e} / B{sub i} ≈ 0–0.8, the cutoff lies in the range ω{sub c} ≈ 0.003–0.010 s{sup −1} (periods 600 < P{sub c} < 2000 s). The estimate of the cut-off frequency in the transition region is provided as well. In the propagating wave regime, the effective wave energy flux in the non-isothermal diverging flux tubes is the same as in the straight and homogeneous cylindrical waveguides. The obtained wave equation in the limit β = 0 is used to study the kink oscillations of non-isothermal coronal loops. It is found that the gradient of temperature along the coronal loops reduces the frequency ratio of the first overtone to the fundamental mode, i.e., ω{sub 2}/ ω{sub 1} < 2. This reduction grows for a larger ratio of temperature at the loop top to the temperature at the footpoints. Moreover, the effect of reduction is most pronounced for the steeper temperature profiles.

79 ASTRONOMY AND ASTROPHYSICS↗

Association of Supergranule Mean Scales with Solar Cycle Strengths and Total Solar Irradiance

We analyze the long-term behavior of the supergranule scale parameter, in active regions (ARs) and quiet regions (QRs), using the Kodaikanal digitized data archive. This database provides century-long daily full disk observations of the Sun in Ca ii K wavelengths. In this paper, we study the distributions of the supergranular scales, over the whole data duration, which show identical shape in these two regimes. We found that the AR mean scale values are always higher than that of the QR for every solar cycle. The mean scale values are highly correlated with the sunspot number cycle amplitude and also with total solar irradiance (TSI) variations. Such a correlation establishes the cycle-wise mean scale as a potential calibrator for the historical data reconstructions. We also see an upward trend in the mean scales, as has already been reported in TSI. This may provide new input for climate forcing models. These results also give us insight into the different evolutionary scenarios of the supergranules in the presence of strong (AR) and weak (QR) magnetic fields.

79 ASTRONOMY AND ASTROPHYSICS↗