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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,585 records · Page 88

Hydrogen generation via ammonia decomposition on highly efficient and stable Ru-free catalysts: approaching complete conversion at 450 °C

We report Hydrogen (H 2 ) is a prospective zero-carbon and high-energy-density fuel alternative to fossil fuels for generating power and clean energy. Ammonia (NH 3 ) is a promising H 2 (17.7%) carrier, which can easily overcome the challenges associated with H 2 storage and transportation. Thermocatalytic ammonia decomposition reaction (ADR) is an effective way to produce clean H 2 but it relies on the use of expensive and rare ruthenium (Ru)-based catalysts at elevated temperatures (>500 °C), hence is not sustainable and economically feasible. Herein, we report a synergistic strategy to design a heterostructured Ru-free catalyst, consisting of CoNi alloy nanoparticles well-dispersed on a MgO–CeO 2 –SrO mixed oxide support with potassium promotion. The resulting K–CoNi alloy –MgO–CeO 2 –SrO catalyst presents 97.7% and 87.5% NH 3 conversion efficiency at 450 °C at gas hourly space velocities (GHSVs) of 6000- and 12 000-mL h -1 g cat -1 , respectively. At 500 °C, the H 2 production rate (57.75 mmol g cat -1 min -1 ) becomes comparable to that of most of the reported Ru-based catalysts. The catalyst stability has been successfully demonstrated in both a fixed-bed reactor under high pressure (120 h at 5.0 bar) and a membrane reactor prototype (600 h at 1.5 bar) at 500 °C. High-temperature in situ XPS analysis, temperature-programmed desorption/reduction, and density functional theory calculations have been carried out to elucidate the possible active sites and performance enhancement mechanisms. This work highlights the importance of constructing optimal interfaces between active metal nanoparticles and oxide support for boosting the NH 3 to H 2 conversion efficiency and long-term stability.

25 ENERGY STORAGE↗

Increasing CO2 Conversion Efficiency with Optical Thermal Management in Concentrated Solar Reactors: New Dual-Stage Solar Reactor Design for Reduction of CO2 to Fuels

The proposed project will result in a new dual-stage solar chemical reactor designed to convert carbon dioxide (CO2) to value-added chemicals. Using sunlight as the main power source, a sustainable process will be developed that closes the loop on our industrial carbon cycle in an energy efficient and environmentally friendly manner. The hybrid photochemical and photothermal reactor design will vastly increase utilization of the solar spectrum and increase CO2 conversion efficiencies over Dimensional Energy’s current state-of-the-art.

10 SYNTHETIC FUELS↗

A Co-Simulation Framework for Steady-State Analyses of Multiple Droop-based MTdc Grids in Continental-Scale Systems

The growing scale and complexity of planning continental hybrid ac and multi-terminal dc (MTdc) systems require scalable steady-state modeling and analysis approaches not currently available in commercial tools. This paper presents a comprehensive multi-fidelity model-conversion framework that enables the efficient transition of MTdc grid models from production cost modeling (PCM) and approximated ac power flow to detailed ac–MTdc power flow for large-scale planning studies. The core of this framework is a scalable co-simulation approach that, for the first time, enables power flow analysis in continental-scale ac–MTdc systems. It seamlessly couples commercial ac solvers with a detailed MTdc grid model that incorporates droop-based control and current-limiting strategies of multiple meshed MTdc grids. Leveraging this capability, an evaluation framework to systematically assess and compare different MTdc power redispatch strategies under ac and dc contingencies is introduced. The proposed framework and algorithm are evaluated using a combined Western and Eastern Interconnection system with 11 MTdc grids of various sizes, showing a coherent transition from PCM to detailed ac–MTdc power flow and improved system performance in voltage regulation and line overload mitigation following typical contingencies.

Nguyen, Quan H.↗

Cavity electro-optics in thin-film lithium niobate for efficient microwave-to-optical transduction

Linking superconducting quantum devices to optical fibers via microwave-optical quantum transducers may enable large-scale quantum networks. For this application, transducers based on the Pockels electro-optic (EO) effect are promising for their direct conversion mechanism, high bandwidth, and potential for low-noise operation. However, previously demonstrated EO transducers require large optical pump power to overcome weak EO coupling and reach high efficiency. Here, we create an EO transducer in thin-film lithium niobate, a platform that provides low optical loss and strong EO coupling. We demonstrate on-chip transduction efficiencies of up to and of optical pump power. The transduction efficiency can be improved by further reducing the microwave resonator’s piezoelectric coupling to acoustic modes, increasing the optical resonator quality factor to previously demonstrated levels, and changing the electrode geometry for enhanced EO coupling. We expect that with further development, EO transducers in thin-film lithium niobate can achieve near-unity efficiency with low optical pump power.

Holzgrafe, Jeffrey (ORCID:0000000160121451)↗

Development of a polysilicon process based on chemical vapor deposition, phase 1 and phase 2

High-purity polycrystalline silicon was produced in an experimental, intermediate and advanced CVD reactor. Data from the intermediate and advanced reactors confirmed earlier results obtained in the experimental reactor. Solar cells were fabricated by Westinghouse Electric and Applied Solar Research Corporation which met or exceeded baseline cell efficiencies. Feedstocks containing trichlorosilane or silicon tetrachloride are not viable as etch promoters to reduce silicon deposition on bell jars. Neither are they capable of meeting program goals for the 1000 MT/yr plant. Post-run CH1 etch was found to be a reasonably effective method of reducing silicon deposition on bell jars. Using dichlorosilane as feedstock met the low-cost solar array deposition goal (2.0 gh-1-cm-1), however, conversion efficiency was approximately 10% lower than the targeted value of 40 mole percent (32 to 36% achieved), and power consumption was approximately 20 kWh/kg over target at the reactor.

Plahutnik, F.↗

Dc-To-Dc Converter Uses Reverse Conduction Of MOSFET's

In modified high-power, phase-controlled, full-bridge, pulse-width-modulated dc-to-dc converters, switching devices power metal oxide/semiconductor field-effect transistors (MOSFET's). Decreases dissipation of power during switching by eliminating approximately 0.7-V forward voltage drop in anti-parallel diodes. Energy-conversion efficiency increased.

Gruber, Robert P.↗

Update on Extended Operation of Stirling Convertors in Thermal Vacuum at NASA Glenn Research Center

The U.S. Department of Energy (DOE), Lockheed Martin Space Systems (LMSS), Infinia Corporation, and NASA Glenn Research Center (GRC) have been developing a Stirling Radioisotope Generator (SRG) for use as a power system on space science missions. This generator would make use of Stirling cycle energy conversion to achieve higher efficiency than currently used alternatives. A test has been initiated at GRC to demonstrate functionality of Stirling conversion in a thermal vacuum environment over an extended period of time. The test article resembles the configuration of the SRG, but was designed without the requirement of low mass. Throughout the 8700 cumulative hours of operation, modifications to the supporting hardware were required to attain the desired operating conditions. These modifications, the status of testing, and the data recorded will be discussed in this paper.

Oriti, Salvatore M.↗

Dynamic Radioisotope Power Systems

NASA's dynamic power convertor development in support of high-efficiency RPS is progressing as planned, and shows promise. Ongoing research utilizing existing hardware supports viability of dynamic power conversion for Radioisotope Power Systems.

Oriti, Salvatore↗

A High-Power Broadband Terahertz Source Enabled by Three-Dimensional Light Confinement in a Plasmonic Nanocavity

The scope and potential uses of time-domain terahertz imaging and spectroscopy are mainly limited by the low optical-to-terahertz conversion efficiency of photoconductive terahertz sources. State-of-theart photoconductive sources utilize short-carrier-lifetime semiconductors to recombine carriers that cannot contribute to efficient terahertz generation and cause additional thermal dissipation. Here, we present a novel photoconductive terahertz source that offers a significantly higher efficiency compared with terahertz sources fabricated on short-carrier-lifetime substrates. The key innovative feature of this source is the tight three-dimensional confinement of the optical pump beam around the terahertz nanoantennas that are used as radiating elements. This is achieved by means of a nanocavity formed by plasmonic structures and a distributed Bragg reflector. Consequently, almost all of the photo-generated carriers can be routed to the terahertz nanoantennas within a sub-picosecond time-scale. This results in a very strong, ultrafast current that drives the nanoantennas to produce broadband terahertz radiation. We experimentally demonstrate that this terahertz source can generate 4 mW pulsed terahertz radiation under an optical pump power of 720 mW over the 0.1–4 THz frequency range. This is the highest reported power level for terahertz radiation from a photoconductive terahertz source, representing more than an order of magnitude of enhancement in the optical-to-terahertz conversion efficiency compared with state-of-the-art photoconductive terahertz sources fabricated on shortcarrier- lifetime substrates.

42 ENGINEERING↗

1.1 eV GaInAs Cell Development for Dual-Use Solar and 1070 nm Laser Power Converters

Dual-use photovoltaic cells can receive solar and laser power simultaneously to generate current, an application relevant to space and terrestrial industries. This study investigates two concepts of solar cells optimized for dual-use 1070 nm laser and solar power conversion, a single-junction and triple-junction cell. The cell designs are based upon the 3- junction inverted metamorphic solar cell, previously shown highly efficient for solar conversion. Because it is closely bandgap-tuned for a 1070 nm laser, the 1 eV bottom junction is incorporated into each of the two designs, making its development key to the success of both concepts. However, each design requires some modification for efficient dual use. The single-junction device requires optimization to reduce short wavelength absorption of the broad solar spectrum. In both devices, the graded buffer layers in the GaInAs cell affect the cell's performance by reducing threading dislocations in the active junction. However, the buffer in the three-junction device also acts as a lateral transport layer and so affects the fill factor depending on its sheet resistance. By varying the buffer thickness, we demonstrate a direct relationship between buffer thickness and sheet resistance reduction, while considering implications to open-circuit voltages. We also performed resistance modeling to determine the optimal grid spacing and thickness of the grid fingers to minimize losses due to sheet resistance and grid shading. Efficiency data for a one junction GaInAs cell demonstrates a laser conversion efficiency of 38% at 1070 nm wavelength without an anti-reflection coating.

dual-use↗

The heat transfer coefficient associated with a moving packed bed of silica particles flowing through parallel plates

Concentrating Solar Power (CSP) with thermal energy storage has the potential to be a renewable energy technology with long duration, inexpensive energy storage. Higher temperature operation increases the conversion efficiency and reduces the cost of energy storage. Several emerging CSP designs utilize particles as the solar receiver due to their high temperature stability and low cost. In some designs, the particles are also used as the thermal energy storage (TES) media. In either configuration, an energy transfer is required between the hot particles and the working fluid in the power cycle in a Particle-to-Fluid Heat Exchanger (PtFHX). Understanding the heat transfer between a moving packed bed and a stationary surface is critical to the successful design of a PtFHX. In this paper, a test facility is described in which a moving packed bed of silica sand with particle size 100–600 μm is introduced into the channel formed by two parallel plates, one of which is heated. The effective static thermal conductivity of the particles used for the test are separately measured over the entire range of test temperatures. The inlet and outlet bulk temperatures of the particle flow are measured as are the surface temperatures at several axial locations along the centerline of the plate. The result is the measurement of heat transfer coefficient as a function of temperature for several velocities. The uncertainty of the measurements is presented and the results are compared to model results found in the literature.

14 SOLAR ENERGY↗

On-orbit performance of the 12 GHz, 200 watt transmitter experiment package for CTS

Performance characteristics from on-orbit tests of the Transmitter Experiment Package (TEP) for the Communications Technology Satellite (CTS) are presented. The TEP consists of a Power Processing System (PPS), an Output Stage Tube (OST), and a Variable Conductance Heat Pipe System (VCHPS), all of which are described. The OST is a coupled-cavity traveling-wave tube with a multistage depressed collector and a stepped velocity-tapered slow-wave structure for efficiency enhancement. It has an RF output power of 240 W and an overall efficiency of 51.5% at a center band frequency of 12.080 GHz. The PPS provides the required operating voltages, regulation, control, and protection for the OST. It has a measured dc-dc conversion efficiency of 86.5% to 88.5%. The VCHPS consists of a fin radiator and three dual-artery stainless steel heat pipes using methanol and a mixture of inert gases. Test results presented include efficiencies, RF output power, frequency response, and performance with single and multiple (two) carriers frequency-modulated by video signals.

Alexovich, R. E.↗

Integrated Large-Scale Data Management Platform for Photovoltaic Power Conversion Equipment (PCE) Reliability Data

To meet the demand for accuracy and real-time capability of PV system degradation evaluation, massive volume data is needed to run high-fidelity and high-efficiency simulations and perform advanced data analysis. However, PV farm operators have a series of difficulties with PV inverter data, such as data collection from multiple channels, massive data storage, data management and massive data analysis. To address these challenges, we developed an integrated data management platform capable of data acquisition, processing, storage, query, and performing big data analysis utilizing AI algorithms. The platform can also achieve data correctness verification and provide an effective distributed data management solution to retrieve massive data and establish a connection to distributed computational frameworks.

data management platform↗

Efficiency of Synchrotron Radiation from Rotation-powered Pulsars

Synchrotron radiation is widely considered to be the origin of the pulsed non-thermal emissions from rotation-powered pulsars in optical and X-ray bands. In this paper, we study the synchrotron radiation emitted by the created electron and positron pairs in the pulsar magnetosphere to constrain the energy conversion efficiency from the Poynting flux to the particle energy flux. We model two pair creation processes, two-photon collision, which efficiently works in young γ -ray pulsars (≲10{sup 6} year), and magnetic pair creation, which is the dominant process to supply pairs in old pulsars (≳10{sup 6} year). Using the analytical model, we derive the maximum synchrotron luminosity as a function of the energy conversion efficiency. From the comparison with observations, we find that the energy conversion efficiency to the accelerated particles should be an order of unity in the magnetosphere, even though we make a number of the optimistic assumptions to enlarge the synchrotron luminosity. In order to explain the luminosity of the non-thermal X-ray/optical emission from pulsars with low spin-down luminosity L {sub sd} ≲ 10{sup 34} erg s{sup −1}, non-dipole magnetic field components should be dominant at the emission region. For the γ -ray pulsars with L {sub sd} ≲ 10{sup 35} erg s{sup −1}, observed γ -ray to X-ray and optical flux ratios are much higher than the flux ratio between curvature and the synchrotron radiations. We discuss some possibilities such as the coexistence of multiple accelerators in the magnetosphere as suggested from the recent numerical simulation results. The obtained maximum luminosity would be useful to select observational targets in X-ray and optical bands.

79 ASTRONOMY AND ASTROPHYSICS↗

Solar power satellite system definition study. Part 1 and part 2, volume 2: Technical summary

Practical designs for power transmission were developed to meet requirements and constraints. Microwave link error was analyzed to confirm attainability of acceptable link efficiency. Silicon photovoltaic was determined to be the best overall choice for energy conversion, with a potassium Rankine cycle as the backup choice. Space transportation operations provide low cost because of traffic level, and the payload volume is the launch vehicle design driver. The power cost is 4 to 5 /kwh, which will be competitive with fossil fuel sources by the year 2000.

Source record↗

An Efficient Single Frequency Ho:YLF Laser for IPDA Lidar Applications

A highly efficient, versatile, single frequency 2-micron pulsed laser can be used in a pulsed Differential Absorption Lidar (DIAL) / Integrated Path Differential Absorption (IPDA) instrument to make precise, high-resolution measurements to investigate sources and sinks of CO2. For a direct detection IPDA lidar, the desired 2 m Ho:YLF laser should generate 30-40 mJ pulses at the repetition rate of 100 to 200 Hz, with short pulse length (<100 ns) and better than 2% wall plug efficiency. A Tm fiber laser in-band pumped Ho:YLF laser has been developed to meet this technical challenge. This Ho:YLF laser is designed in a four mirror ring resonator with bow tie configuration, which helps to obtain high beam quality. It is end-pumped by a 40 W linearly polarized Tm fiber laser at 1.94μm. The resonator length is 1.10 meters with output coupler reflectivity at 45%. The laser crystal size is 3 x 3 x 60 mm (w, h, l) with a doping concentration of 0.5% Holmium. The laser beam and pump beam are mode-matched in the active medium. Thus, the pump and laser beams have the same confocal parameters. Mode-matching is also helpful for operating the laser in a single transverse mode. The laser beam waist is slightly less than 0.5 mm at the center of the laser crystal. Based on quasi-four level modeling, pump absorption and saturation depend on laser intensity. Laser amplification and saturation also depend on the pump intensity in the crystal. The laser is injection seeded to obtain the single frequency required by an IPDA lidar measurement. The seed beam is entered into the resonator through an output coupler. The laser is mounted on a water cooled optical bench for stable and reliable operation. The size of the optical bench is 22.16 x 9.20 x 1.25 inches. It is stiffened so that the laser can be operated in any orientation of the optical bench. This packaged Ho:YLF laser is designed for either mobile trailer or airborne platform operation. The engineering prototype Ho:YLF laser has been fully characterized to demonstrate laser performance. Figure 1 shows the laser output power as a function of pump power at different pulse repetition rates from 100 Hz to 333 Hz. The threshold of the laser is less than 14 W. The slope efficiencies are 28%, 40%, 41% and 43% for pulse repetition rates of 100, 200, 250 and 333 Hz, respectively. Maximum power increases with the pulse repetition rate. Output power of 4.2 W, 6 W, 6.7 W, and 7.7 W is achieved for pulse repetition rates of 100, 200, 250 and 333Hz, respectively. This represents the optical conversion efficiency of 16.7%, 22.4%, 23.7%, and 26.5% at these various pulse repletion rates. It is the most efficient and compact Ho:YLF laser demonstrated in the high pulse energy (>20mJ) and moderate pulse repetition rate (100's Hz) operation range. As shown in Figure 1, the maximum pulse energy at 100 Hz is 42 mJ. This is limited due to optical damage. The laser stability is characterized and found to be very stable. A relative pulse energy standard deviation of 2% was measured. The beam quality of the Ho:YLF was measured by a Spiricon infrared laser beam camera. Figure 2 shows the beam profile image of the laser. Both the X-profile of the beam (horizontal direction) and the Y-profile of the beam (vertical direction) are well fitted by a Gaussian profile. The qualitative beam quality measurement shows excellent beam quality in both axis. The M-square value for the laser beam is measured at 1.06 and 1.09 for the x and y axis respectively.-

Yu, J.↗

Processing and Preparation of Advanced Stirling Convertors for Extended Operation at NASA Glenn Research Center

The U.S. Department of Energy (DOE), Lockheed Martin Space Company (LMSC), Sunpower Inc., and NASA Glenn Research Center (GRC) have been developing an Advanced Stirling Radioisotope Generator (ASRG) for use as a power system on space science missions. This generator will make use of the free-piston Stirling convertors to achieve higher conversion efficiency than currently available alternatives. NASA GRC is supporting the development of the ASRG by providing extended operation of several Sunpower Inc. Advanced Stirling Convertors (ASCs). In the past year and a half, eight ASCs have operated in continuous, unattended mode in both air and thermal vacuum environments. Hardware, software, and procedures were developed to prepare each convertor for extended operation with intended durations on the order of tens of thousands of hours. Steps taken to prepare a convertor for long-term operation included geometry measurements, thermocouple instrumentation, evaluation of working fluid purity, evacuation with bakeout, and high purity charge. Actions were also taken to ensure the reliability of support systems, such as data acquisition and automated shutdown checkouts. Once a convertor completed these steps, it underwent short-term testing to gather baseline performance data before initiating extended operation. These tests included insulation thermal loss characterization, low-temperature checkout, and full-temperature and power demonstration. This paper discusses the facilities developed to support continuous, unattended operation, and the processing results of the eight ASCs currently on test.

Oriti, Salvatore M.↗