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At least 1,585 records · Page 88

Vibroacoustic Process Monitoring of 5-Stage Centrifugal Contactors

Vibroacoustic monitoring was investigated to aid in informing process operators with parameters regarding aqueous separation techniques. These techniques have a wide range of applications including nuclear fuel reprocessing. A small-scale solvent extraction system was set up with five magnetic drive contactors and two piston pumps to collect realistic operation. Vibration sensors were placed on three of the contactors and both pumps, and a microphone was placed near the system. Contactor rotational speed and pump flow rate were varied with known values to compare against measured vibroacoustic signatures. Spectral analysis allowed for the determination of contactor rotational speed and the ratio of organic to aqueous flow rate, an important parameter for ensuring optimal extraction. Vibration metrics such as kurtosis and crest factor provided additional details regarding individual rotational speeds and have potential in examination of faults for predictive maintenance. Overall, results indicate the capability of vibroacoustic monitoring to improve operator awareness and process outcomes.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Impact experimentation and the microgravity environment: An overview

Impact is an ubiguitous physical process in the solar system. It occurs on all solid bodies and operates over a spectrum of scales. Understanding impact phenomena is therefore paramount in constraining and underpinning a large number of research efforts into fundamental problems in planetary geology. Gravity is an important parameter in impact processes. The advantages of microgravity experimentation are discussed.

Grieve, Richard A. F.↗

An overview of surface radiance and biology studies in FIFE

The use of satellite data to study and to understand energy and mass exchanges between the land surface and the atmosphere requires information about various biological processes and how various reflected or emitted spectral radiances are influenced by or manifested in these processes. To obtain such information, studies were conducted by the First ISLSCP Field Experiment (FIFE) surface radiances and biology (SRB) group using surface, near-surface, helicopter, and aircraft measurements. The two primary objectives of this group were to relate radiative fluxes to biophysical parameters and physiological processes and to assess how various management treatments affect important biological processes. This overview paper summarizes the results obtained by various SRB teams working in nine different areas: (1) measurements of bidirectional reflectance and estimation of hemispherical albedo; (2) evaluation of spatial and seasonal variability reflectance and vegetation indices; (3) determination of surface and radiational factors and their effects on vegetation indices and photosynthetically active radiation relationships; (4) use of surface temperatures to estimate sensible heat flux; (5) controls over photosynthesis and respiration at small scales; (6) soil surface CO2 fluxes and grassland carbon budget; (7) landscape variations in controls over gas exchange and energy partitioning; (8) radiometric response of prairie to management and topography; and (9) determination of nitrogen gas exchanges in a tallgrass prairie.

Blad, B. L.↗

Combustion and Flammability Characteristics of Solids at Microgravity in very Small Velocity Flows

Fires still remain as one of the most important safety risks in manned spacecraft. This problem will become even more important in long endurance non orbital flights in which maintenance will be non existing or very difficult. The basic process of a fire is the combustion of a solid at microgravity conditions in O2/N2 mixtures. Although a large number of research programs have been carried out on this problem, especially on flame spreading, several aspects of these processes are not yet well understood. It may be mentioned, for example, the temperature and characteristic of low emissivity flames in the visual range that take place in some conditions at microgravity; and there exists a lack of knowledge on the influence of key parameters, such as convective flow velocities of the order of magnitude of typical oxygen diffusion velocities. The "Departamento de Motopropulsion y Termofluidodinamica" of the "Universidad Politecnica de Madrid, Escuela Tecnica Superior de Ingenieros Aeronauticos" is conducting a research program on the combustion of solids at reduced gravity conditions within O2/N2 mixtures. The material utilized has been polymethylmethacrylate (PMMA) in the form of rectangular slabs and hollow cylinders. The main parameters of the process have been small convective flow velocities (including velocity angle with the direction of the spreading flame) and oxygen concentration. Some results have also been obtained on the influence of material thickness and gas pressure.

Sanchez-Tarifa, C.↗

Process-informed adsorbent design guidelines for direct air capture

Direct air capture using solid adsorbents is a proven technology critical to reducing our net greenhouse gas emissions to zero and beyond. Currently, academic research into the technology mainly focuses on the development of new adsorbents. However, there is a discord between the adsorbent design and process performance. Many materials scientists focus on maximising metrics such as the CO 2 capacity of their adsorbent. Here, we combine detailed process modelling, machine learning, and extensive global sensitivity analysis, which entails varying all of the model parameters together, on a direct air capture process to show that the dry CO 2 adsorption capacity does not influence process performance for an amine-functionalised adsorbent operating in a temperature vacuum swing adsorption (TVSA) process, while it is important in a steam-assisted TVSA (S-TVSA) process. In fact, adsorption kinetics, density, and thermal conductivity are all critical attributes to obtaining a low energy penalty and reduced costs. The analysis also highlights the importance of heat transfer, directing process engineers to (alternative) adsorber designs that maximise this. By an in-depth evaluation of how process performance indicators are affected by materials properties and process operating parameters, this work provides guidance to both material scientists and process engineers towards the design of a “unicorn adsorbent” and intensified DAC processes. This will improve the performance of solid adsorbent direct air capture and help drive down the costs of this vital technology to avert the worst impacts of climate change.

42 ENGINEERING↗

IFSAR Simulation Using the Shooting and Bouncing Ray Technique

Interferometric Synthetic Aperture Radar (IFSAR) is a technique that allows an automated way to carry out terrain mapping. IFSAR is carried out by first generating a SAR image pair from two antennas that are spatially separated. The phase difference between the SAR image pair is proportional to the topography. After registering the SAR images, the difference in phase in each pixel is extracted to generate an interferogram. Since the phase can only be measured within 2pi radians, phase unwrapping is carried out to extract the absolute phase for each pixel that will be proportional to the local height. While IFSAR algorithm is typically applied to measurement data, it is useful to develop an IFSAR simulator to develop a better understanding of the IFSAR technique. The IFSAR simulator can be used in choosing system parameters, experimenting with processing procedures and mission planning. In this paper we will present an IFSAR simulation methodology to simulate the interferogram based on the shooting and bouncing ray (SBR) technique. SBR is a standard ray-tracing technique used to simulate scattering from large, complex targets. SBR is carried out by shooting rays at the target or scene. At the exit point of each ray, a ray-tube integration is done to find its contribution to the total field. A fast algorithm has been developed for the SBR for simulating SAR images of complex targets. In the IFSAR simulation, we build upon the fast SAR simulation technique. Given the antenna pair configuration, radar system parameters and the geometrical description of the scene, we first simulate two SAR images from each antenna. After post processing the two SAR images, we generate an interferogram. Phase unwrapping is then performed on the interferogram to arrive at the desired terrain map. We will present results from the SBR-based IFSAR simulator. The results will include terrain map reconstruction of urban environments. The reconstruction will be compared to the ground truth to examine the fidelity of the simulation. We will also investigate the effect of multi-bounce scattering in urban environments on phase unwrapping and reconstruction.

Houshmand, Bijan↗

A Bayesian Approach for Statistical–Physical Bulk Parameterization of Rain Microphysics. Part II: Idealized Markov Chain Monte Carlo Experiments

Observationally informed development of a new framework for bulk rain microphysics, the Bayesian Observationally Constrained Statistical–Physical Scheme (BOSS; described in Part I of this study), is demonstrated. This scheme’s development is motivated by large uncertainties in cloud and weather simulations associated with approximations and assumptions in existing microphysics schemes. Here, a proof-of-concept study is introduced using a Markov chain Monte Carlo sampling algorithm with BOSS to probabilistically estimate microphysical process rates and parameters directly from a set of synthetically generated rain observations. The framework utilized is an idealized steady-state one-dimensional column rainshaft model with specified column-top rain properties and a fixed thermodynamical profile. Different configurations of BOSS—flexibility being a key feature of this approach—are constrained via synthetic observations generated from a traditional three-moment bulk microphysics scheme. The ability to retrieve correct parameter values when the true parameter values are known is illustrated. For cases when there is no set of true parameter values, the accuracy of configurations of BOSS that have different levels of complexity is compared. It is found that addition of the sixth moment as a prognostic variable improves prediction of the third moment (proportional to bulk rain mass) and rain rate. In contrast, increasing process rate formulation complexity by adding more power terms has little benefit—a result that is explained using further-idealized experiments. BOSS rainshaft simulations are shown to well estimate the true process rates from constraint by bulk rain observations, with the further benefit of rigorously quantified uncertainty of these estimates.

58 GEOSCIENCES↗

Mycosynthesis of Zinc Oxide Nanoparticles Exhibits Fungal Species Dependent Morphological Preference

Filamentous fungi can synthesize a variety of nanoparticles (NPs), a process referred to as mycosynthesis that requires little energy input, do not require the use of harsh chemicals, occurs at near neutral pH, and do not produce toxic byproducts. While NP synthesis involves reactions between metal ions and exudates produced by the fungi, the chemical and biochemical parameters underlying this process remain poorly understood. Here, the role of fungal species and precursor salt on the mycosynthesis of zinc oxide (ZnO) NPs is investigated. This data demonstrates that all five fungal species tested are able to produce ZnO structures that can be morphologically classified into i) well-defined NPs, ii) coalesced/dissolving NPs, and iii) micron-sized square plates. Further, species-dependent preferences for these morphologies are observed, suggesting potential differences in the profile or concentration of the biochemical constituents in their individual exudates. This data also demonstrates that mycosynthesis of ZnO NPs is independent of the anion species, with nitrate, sulfate, and chloride showing no effect on NP production. Finally, these results enhance the understanding of factors controlling the mycosynthesis of ceramic NPs, supporting future studies that can enable control over the physical and chemical properties of NPs formed through this “green” synthesis method.

59 BASIC BIOLOGICAL SCIENCES↗

ParFlow Sand Tank: A tool for groundwater exploration

The ParFlow Sand Tank model is an open source application designed to allow users to interactively simulate and visualize groundwater movement through the subsurface. The app is designed for both research and education; teaching hydrogeology concepts and making it easy explore and run sophisticated groundwater simulations. Our goal is to support increased accessibility and usability of research grade hydrology tools for research and teaching. The Sand Tank application simulates groundwater and surface water fluxes as well as contaminant transport in real time using the integrated physical hydrology model ParFlow (Kollet & Maxwell, 2006; Maxwell & Miller, 2005; Osei-Kuffuor et al., 2014) and the particle tracking code EcoSlim (Maxwell et al., 2019). ParFlow is a numerical hydrology model that simulates spatially distributed groundwater and surface water flow. It is a well established research tool with more than 90 publications documenting its development use to advance our understanding of groundwater dynamics and groundwater surface water interactions from the hillslope to the continental scale e.g. (Condon et al., 2020; Condon & Maxwell, 2019; Maxwell & Condon, 2016). It is designed for efficient parallel computation and has been run on many platforms spanning from laptops to supercomputers. However, one of the challenges of ParFlow is that it requires significant training and hydrologic expertise to develop simulations. The Sand Tank application makes this model accessible to anyone for education and exploration. Our application uses ParFlow for its simulation backend and ParaView for the data loading and processing. The communication infrastructure relies on the ParaViewWeb framework. We use model templates deployed in Docker images to setup the Sand Tank framework. Users can build the application locally or interact with it through our web deployment. When interacting with a template users can interactively change model parameters like subsurface processes or pump/inject water into the subsurface and watch the system respond to their changes in real time as the simulation runs. Additionally, our template setup will allow more advanced users to build custom templates of increasing complexity for both research and educational purposes.

54 ENVIRONMENTAL SCIENCES↗

Microsimulation model calibration using incremental mixture approximate Bayesian computation

Microsimulation models (MSMs) are used to inform policy by predicting population-level outcomes under different scenarios. MSMs simulate individual-level event histories that mark the disease process (such as the development of cancer) and the effect of policy actions (such as screening) on these events. MSMs often have many unknown parameters; calibration is the process of searching the parameter space to select parameters that result in accurate MSM prediction of a wide range of targets. We develop Incremental Mixture Approximate Bayesian Computation (IMABC) for MSM calibration which results in a simulated sample from the posterior distribution of model parameters given calibration targets. IMABC begins with a rejection-based ABC step, drawing a sample of points from the prior distribution of model parameters and accepting points that result in simulated targets that are near observed targets. Next, the sample is iteratively updated by drawing additional points from a mixture of multivariate normal distributions and accepting points that result in accurate predictions. Posterior estimates are obtained by weighting the final set of accepted points to account for the adaptive sampling scheme. We demonstrate IMABC by calibrating CRC-SPIN 2.0, an updated version of a MSM for colorectal cancer (CRC) that has been used to inform national CRC screening guidelines.

97 MATHEMATICS AND COMPUTING↗

Advanced multilateration theory, software development, and data processing: The MICRODOT system

The process of geometric parameter estimation to accuracies of one centimeter, i.e., multilateration, is defined and applications are listed. A brief functional explanation of the theory is presented. Next, various multilateration systems are described in order of increasing system complexity. Expected systems accuracy is discussed from a general point of view and a summary of the errors is listed. An outline of the design of a software processing system for multilateration, called MICRODOT, is presented next. The links of this software, which can be used for multilateration data simulations or operational data reduction, are examined on an individual basis. Functional flow diagrams are presented to aid in understanding the software capability. MICRODOT capability is described with respect to vehicle configurations, interstation coordinate reduction, geophysical parameter estimation, and orbit determination. Numerical results obtained from MICRODOT via data simulations are displayed both for hypothetical and real world vehicle/station configurations such as used in the GEOS-3 Project. These simulations show the inherent power of the multilateration procedure.

Escobal, P. R.↗

Hydrogen Production by Steam Oxidation of Reduced CaFe 2 O 4 during Chemical Looping Coal Gasification: Equilibrium and Kinetic Analysis

CaFe 2 O 4 reduced during chemical looping coal gasification can be oxidized with steam for production of hydrogen. The conversion and equilibrium data of the oxidation of reduced CaFe 2 O 4 with steam were analyzed using steam concentrations of 10–25 vol % with a balance of helium and the temperature range of 1023–1123 K. Experimental data were evaluated to characterize H 2 production rates and oxidation isotherms. The film diffusion was the controlling step for the oxygen uptake process, and its parameters were determined on the basis of the uptake rate model. The steady-state oxygen uptake data were also evaluated with Langmuir, Temkin, Freundlich, and Dubinin–Radushkevich isotherms. The Langmuir isotherm model correlated the oxidation isotherms best, and the peak uptake capacity decreased with increasing temperatures, which suggests an exothermic process. In conclusion, the negative Gibbs free energy values (–Δ G °) implied the spontaneous nature of the uptake process at 1023–1123 K.

01 COAL, LIGNITE, AND PEAT↗

Apollo 17 photographic processing control document

The control parameters are defined which are to be used by the Photographic Technology Division for the processing of all films flown on Apollo Mission J-3. The procedures necessary for establishment of processing control are given along with information for denoting and solving any problem areas or conflicts which may occur prior to the mission.

Weinstein, M. S.↗

Statistical analysis of spatial distribution of pores in metal additive manufacturing

We report mechanical properties of additively manufactured parts are sensitive to the presence of pores form during the manufacturing process. The impact of pores on the mechanical performance has been investigated extensively with respect to different parameters, such as pore volume fraction, shape, and size. However, statistical investigations focusing on the relationships between the spatial distribution of pores and process parameters; and consequently, the performance of the manufactured parts are scattered and limited. Also, these sparse investigations usually suffer from an ambiguous definition of terminologies. For instance, the required criteria to consider a point pattern as complete spatial randomness (CSR) are generally not clarified. Moreover, no numerical formalism is yet developed to show how much the observed spatial results are statistically significant. To address these shortcomings, the statistical definition of CSR in a point pattern and the procedure to quantitatively determine the deviation of a pattern from CSR were discussed. The explained statistical approach was used to investigate the effect of scanning speed parameter on the spatial distribution of gas pores in laser powder bed fusion manufactured stainless steel parts. Furthermore, and to highlight the impact of the spatial distribution of pores on mechanical properties, fatigue performances of parts with clustered and randomly distributed pores were simulated by finite element analysis. It is shown that by reducing the scanning speed, the spatial distribution of gas pores deviated more from CSR, and correspondingly fatigue performance deteriorated.

36 MATERIALS SCIENCE↗

Cocrystallization of Uranyl and Plutonyl Nitrate Hexahydrates

In the system UO{sub 2}(NO{sub 3}){sub 2}–PuO{sub 2}(NO{sub 3}){sub 2}–HNO{sub 3}–H{sub 2}O with the ratio Pu/(U + Pu) = 0.3–0.5 and stabilization of the pair U(VI)–Pu(VI), the crystallization of (U, Pu)O{sub 2}(NO{sub 3}){sub 2}·6H{sub 2}O occurs in accordance with the metric of the phase diagram of the system UO{sub 2}(NO{sub 3}){sub 2}–HNO{sub 3}–H{sub 2}O with coefficient of cocrystallization of plutonium 0.804 ± 0.028. This condition holds in the sector of the working lines of the crystallization process that correspond to the minimum content of uranium in the mother solution. The degree of enrichment of the mother solution is determined by the crystallization temperature, i.e., the mass fraction of the mother solution in the total mass of the system. The constancy of the coefficient of cocrystallization with the technologically important parameters of the process makes it possible to use the metric of the solubility diagram of the system UO{sub 2}(NO{sub 3}){sub 2}–HNO{sub 3}–H{sub 2}O to calculate the crystallization of (U, Pu)O{sub 2}(NO{sub 3}){sub 2}·6H{sub 2}O with the crystalline phase with the required composition being obtained.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Amine Functionalized Electrospun Cellulose Nanofibers for Fluoride Adsorption from Drinking Water

In this study, we synthesized amine functionalized cellulose nanofiber based adsorbent for effective removal of dissolved fluoride ions from groundwater samples. Cellulose acetate was electrospun into nanofibers followed by deacetylation to yield cellulose nanofibers which were then treated with ethylenediamine to prepare amine functionalized cellulose fabric to be used as an adsorbent. As- synthesized adsorbent was first characterized by scanning electron microscopy and Fourier transform infrared spectroscopy for physiochemical characteristics. Fluoride adsorption studies were then carried out under batch mode to study the influence of various parameters on adsorption process. Amine functionalized cellulose nanofibrous mat was found to be effective with high adsorption efficiency for removal of fluoride ions from aqueous solution, even at low fluoride concentrations (< 5 mg L{sup −1}). Adsorption mechanism of fluoride onto prepared cellulose nanofibers based adsorbent was explained from the studies of isotherms, kinetic and thermodynamic parameters. Field studies conducted using this amine functionalized cellulose nanofibrous mat revealed the suitability and effectiveness of adsorbent for fluoride removal from contaminated groundwater.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Rapid Airplane Parametric Input Design (RAPID)

RAPID is a methodology and software system to define a class of airplane configurations and directly evaluate surface grids, volume grids, and grid sensitivity on and about the configurations. A distinguishing characteristic which separates RAPID from other airplane surface modellers is that the output grids and grid sensitivity are directly applicable in CFD analysis. A small set of design parameters and grid control parameters govern the process which is incorporated into interactive software for 'real time' visual analysis and into batch software for the application of optimization technology. The computed surface grids and volume grids are suitable for a wide range of Computational Fluid Dynamics (CFD) simulation. The general airplane configuration has wing, fuselage, horizontal tail, and vertical tail components. The double-delta wing and tail components are manifested by solving a fourth order partial differential equation (PDE) subject to Dirichlet and Neumann boundary conditions. The design parameters are incorporated into the boundary conditions and therefore govern the shapes of the surfaces. The PDE solution yields a smooth transition between boundaries. Surface grids suitable for CFD calculation are created by establishing an H-type topology about the configuration and incorporating grid spacing functions in the PDE equation for the lifting components and the fuselage definition equations. User specified grid parameters govern the location and degree of grid concentration. A two-block volume grid about a configuration is calculated using the Control Point Form (CPF) technique. The interactive software, which runs on Silicon Graphics IRIS workstations, allows design parameters to be continuously varied and the resulting surface grid to be observed in real time. The batch software computes both the surface and volume grids and also computes the sensitivity of the output grid with respect to the input design parameters by applying the precompiler tool ADIFOR to the grid generation program. The output of ADIFOR is a new source code containing the old code plus expressions for derivatives of specified dependent variables (grid coordinates) with respect to specified independent variables (design parameters). The RAPID methodology and software provide a means of rapidly defining numerical prototypes, grids, and grid sensitivity of a class of airplane configurations. This technology and software is highly useful for CFD research for preliminary design and optimization processes.

Smith, Robert E.↗

Distributed optimal power flow processes for unbalanced radial distribution networks

Node controllers and power distribution networks in accordance with embodiments of the invention enable distributed power control on an unbalanced network. One embodiment includes a node controller including a distributed power control application; a plurality of node operating parameters describing the operating parameter of a node in an unbalanced network; wherein the processor is configured by the distributed power control application to: send node operating parameters to nodes in the set of at least one node; receive operating parameters from the nodes in the set of at least one node; calculate a plurality of updated node operating parameters using an iterative process to determine updated node operating parameters using the node operating parameters that describe the operating parameters of the node, and the operating parameters of the set of at least one node, where each iteration in the iterative process involves evaluation of a subproblem; and adjust node operating parameters.

24 POWER TRANSMISSION AND DISTRIBUTION↗