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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,585 records · Page 88

The importance of considering sub-grid cloud variability when using satellite observations to evaluate the cloud and precipitation simulations in climate models

Abstract. Satellite cloud observations have become an indispensable tool for evaluating general circulation models (GCMs). To facilitate the satellite and GCM comparisons, the CFMIP (Cloud Feedback Model Inter-comparison Project) Observation Simulator Package (COSP) has been developed and is now increasingly used in GCM evaluations. Real-world clouds and precipitation can have significant sub-grid variations, which, however, are often ignored or oversimplified in the COSP simulation. In this study, we use COSP cloud simulations from the Super-Parameterized Community Atmosphere Model (SPCAM5) and satellite observations from the Moderate Resolution Imaging Spectroradiometer (MODIS) and CloudSat to demonstrate the importance of considering the sub-grid variability of cloud and precipitation when using the COSP to evaluate GCM simulations. We carry out two sensitivity tests: SPCAM5 COSP and SPCAM5-Homogeneous COSP. In the SPCAM5 COSP run, the sub-grid cloud and precipitation properties from the embedded cloud-resolving model (CRM) of SPCAM5 are used to drive the COSP simulation, while in the SPCAM5-Homogeneous COSP run only grid-mean cloud and precipitation properties (i.e., no sub-grid variations) are given to the COSP. We find that the warm rain signatures in the SPCAM5 COSP run agree with the MODIS and CloudSat observations quite well. In contrast, the SPCAM5-Homogeneous COSP run which ignores the sub-grid cloud variations substantially overestimates the radar reflectivity and probability of precipitation compared to the satellite observations, as well as the results from the SPCAM5 COSP run. The significant differences between the two COSP runs demonstrate that it is important to take into account the sub-grid variations of cloud and precipitation when using COSP to evaluate the GCM to avoid confusing and misleading results.

54 ENVIRONMENTAL SCIENCES↗

Time Series Analysis in the Search for Other Worlds Through Transit Photometry

The Kepler Mission launched in June 2009 to commence NASA's first mission to search for potentially habitable, Earth-size planets orbiting Sun-like stars. Kepler discovered explanets via the transit method: searching for minute (100 ppm) drops in brightness lasting 1 - 13 hours corresponding to occasions where the planet crosses the face of its host star from Kepler's point of view. The exquisite precision required to carry out the Kepler mission (20 ppm in 6.5 hours) pushed astronomical time series analysis to the limits, and motivated the development of novel algorithmic approaches. Transit signatures of rocky planets are often dwarfed by the intrinsic stellar variability, which is not white noise, and often is non-stationary, and by instrumental systematic effects, which can include transients and electronic artifacts. Surmounting this challenging regime of weak, temporally compact, periodic signals in observation noise with strong systematics and other sources of variability motivated the development of 1) an overcomplete, non-decimated, wavelet-based matched filter to jointly estimate the properties of the non-stationary, non-white observation noise process, and 2) a multi-scale, maximum a posteriori (msMAP) approach to identifying and removing instrumental systematic effects. After over nine years of observations, the Kepler spacecraft finally ran out of fuel in November 2018, ending its data collection activities. Over 2300 planets were discovered by Kepler in its primary mission, and over 355 have been discovered by K2, the repurposed mission that followed Kepler's primary mission after the loss of a second reaction wheel in May 2013. We have ported the Kepler science pipeline for the Transiting Exoplanet Survey Satellite (TESS) Mission, which began science observations in July 2019, and report initial results and performance of the modified science pipeline.The Kepler and TESS Missions are supported by NASA's Science Mission Directorate.

transit surveys↗

Detecting Hail from Space: Using a Multi-Frequency Passive-Microwave Retrieval to Analyze the Global Climatology and Diurnal Cycle of Severe Hail

Severe hail poses myriad threats to society, causing extensive damage to infrastructure and agriculture. As hail is severe, relatively infrequent, and highly localized, it is difficult to measure in-situ and if left unresolved in models and precipitation retrievals, hail can cause large errors and uncertainties. The difficulty in measuring hail in situ and the inconsistency of surface-based hail reporting drive the motivation to use spaceborne remote-sensing platforms to retrieve hail and construct climatologies in a globally uniform way. We leverage the scattering signatures of severe hail in spaceborne passive-microwave datasets paired with surface hail reports to construct a multi-frequency hail retrieval using Tropical Rainfall Measuring Mission (TRMM) microwave imager (TMI) data. Using coincident Global Precipitation Measurement (GPM) Ku-band precipitation radar, we assessed this retrieval and several others in the literature for their effectiveness and regional variability. We use this retrieval to construct global passive-microwave climatologies of severe hail using the TRMM, GPM, Advanced Microwave Scanning Radiometer for EOS (AMSR-E), and Advanced Microwave Scanning Radiometer 2 (AMSR2) sensors and extend into the pre-TRMM era to the Special Sensor Microwave Imager/Sounder (SSMI/(S)) data. We also leverage the sensors in inclined orbits to assess the diurnal variability of severe hail globally and the effect the diurnal cycle has on the detection of hail by sensors in sun-synchronous orbit. The goal is to construct a robust, multi-decade multi-satellite climatology of hail. As part of the NASA Disasters Applied Sciences program, we assess these climatologies against other satellite severe weather datasets and use these climatologies in collaboration with stakeholders and end-users to help them assess risk, and improve the prediction, preparation, and response to severe storms around the world.

Sarah D Bang↗

MPACT FY2011 Advanced Time-Correlated Measurement Research at INL

Simulations and experiments have been carried out to investigate advanced time-correlated measurement methods for characterizing and assaying nuclear material for safeguarding the nuclear fuel cycle. These activities are part of a project studying advanced instrumentation techniques in support of the U.S. Department of Energy's Fuel Cycle Research and Development program and its Materials Protection, Accounting, and Control Technologies (MPACT) program. For fiscal year 2011 work focused on examining the practical experimental aspects of using a time-tagged, associated-particle electronic neutron generator for interrogating low-enrichment uranium in combination with steady-state interrogation using a moderated 241Am-Li neutron source. Simulation work for the project involved the use of the MCNP-PoliMi Monte Carlo simulation tool to determine the relative strength and the time-of-flight energy spectra of different sample materials under irradiation. Work also took place to develop a post-processor parser code to extract comparable data from the MCNP5&6 codes. Experiments took place using a commercial deuterium-tritium associated-particle electronic neutron generator to irradiate a number of uranium-bearing material samples. Time-correlated measurements of neutron and photon signatures of these measurements were made using five liquid scintillator detectors in a novel array, using high-speed waveform digitizers for data collection. This report summarizes the experiments that took place in FY2011, presents preliminary analyses that have been carried out to date for a subpart of these experiments, and describes future activities planned in this area. The report also describes support Idaho National Laboratory gave to Oak Ridge National Laboratory in 2011 to facilitate 2-dimensional imagery of mixed-oxide fuel pins for safeguards applications as a part of the MPACT program.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Signatures of the unique microstructure of additively manufactured steel observed via diffraction

A series of measurements were designed to gain confidence in the interpretation of the peak breadth in diffraction patterns collected from additively manufactured material, which has a novel microstructure in comparison to the well understood microstructure of wrought materials. Stainless steels made with two additive manufacturing techniques were compared to wrought material. Similar patterns observed in the scattering vector dependence for additively manufactured and deformed wrought materials suggested that the broadening in both materials was related to dislocations. Finally, this was confirmed by heat-treatment, during which both materials exhibited recovery due to the annealing of dislocations at the same temperature.

304L stainless-steel↗

Battery aging mode identification across NMC compositions and designs using machine learning

A comprehensive understanding of lithium-ion battery (LiB) lifespan is the key to designing durable batteries and optimizing use protocols. Although battery lifetime prediction methods are flourishing, diagnosis of the root causes of aging and degradation have not yet been well developed nor studied for a broad mixture of designs and use cases. Here, we create a machine-learning (ML)-based framework that distinguishes aging modes using multiple electrochemical signatures recorded cycle-by-cycle. The predominant aging behaviors include a combination of loss of active materials in cathode (LAMPE) and a loss of Li inventory (LLI) in Li plating or solid electrolyte interphase (SEI) formation, manifested from 44 batteries representing two cathode chemistries, two electrode loadings, and five charging rates. Here, the aging mode classification accuracy is 86% using features within the first 50 cycles and increases to 88% beyond 225 cycles. The same features can quantify the percentage of end-of-life LAMPE with only 4.3% of error.

25 ENERGY STORAGE↗

Mapping canopy defoliation by herbivorous insects at the individual tree level using bi-temporal airborne imaging spectroscopy and LiDAR measurements

Defoliation by herbivorous insects is a widespread forest disturbance driver, affecting global forest health and ecosystem dynamics. Additionally, compared with time- and labor-intensive field surveys, remote sensing provides the only realistic approach to mapping canopy defoliation by herbivorous insects over large spatial and temporal scales. However, the spectral and structural signatures of defoliation by insects at the individual tree level have not been well studied. Additionally, the predictive power of spectral and structural metrics for mapping canopy defoliation has seldom been compared. These critical knowledge gaps prevent us from consistently detecting and mapping canopy defoliation by herbivorous insects across multiple scales. During the peak of a gypsy moth outbreak in Long Island, New York in summer 2016, we leveraged bi-temporal airborne imaging spectroscopy (IS, i.e., hyperspectral imaging) and LiDAR measurements at 1m spatial resolution to explore the spectral and structural signatures of canopy defoliation in a mixed oak-pine forest. We determined that red edge and near-infrared spectral regions within the IS data were most sensitive to crown-scale defoliation severity. LiDAR measurements including B70 (i.e., 70th bincentile height), intensity skewness, and kurtosis were effectively able to detect structural changes caused by herbivorous insects. In addition to canopy leaf loss, increased exposure of understory and non-photosynthetic materials contributed to the detected spectral and structural signatures. Comparing the ability of individual sensors to map canopy defoliation, the LiDAR-only Ordinary Least-Square (OLS) model performed better than the IS-only model (Adj. R-squared = 0.77, RMSE = 15.37% vs. Adj. R- squared = 0.63, RMSE = 19.11%). The IS+LiDAR model improved on performance of the individual sensors (Adj. R-squared = 0.81, RMSE = 14.46%). Our study improves our understanding of spectral and structural signatures of defoliation by herbivorous insects and presents a novel approach for mapping insect defoliation at the individual tree level. Furthermore, with the current and next generation of spaceborne sensors (e.g., WorldView-3, Landsat, Sentinel-2, HyspIRI, and GEDI), higher accuracy and frequent monitoring of insect defoliation may become more feasible across a range of spatial scales, which are critical for ecological research and management of forest resources including the economic consequences of forest insect infestations (e.g., reduced growth and increased mortality), as well as for informing and testing of carbon cycle models.

54 ENVIRONMENTAL SCIENCES↗

Size-Dependent Lattice Symmetry Breaking Determines the Exciton Fine Structure of Perovskite Nanocrystals

The order of bright and dark excitonic states in lead-halide perovskite nanocrystals is debated. It has been proposed that the Rashba effect, driven by lattice-induced symmetry breaking, causes a bright excitonic ground state. Direct measurements of excitonic spectra, however, show the signatures of a dark ground state, bringing the role of the Rashba effect into question. We use an atomistic theory to model the exciton fine structure of perovskite nanocrystals, accounting for realistic lattice distortions. We calculate optical gaps and excitonic features that compare favorably with experimental works. The exciton fine structure splittings show a nonmonotonic size dependence due to a structural transition between cubic and orthorhombic phases. Additionally, the excitonic ground state is found to be dark with spin triplet character, exhibiting a small Rashba coupling. Here we additionally explore the effects of nanocrystal shape on the fine structure, clarifying observations on polydisperse nanocrystals.

36 MATERIALS SCIENCE↗

First Observations of Gigantic Jets from Geostationary Orbit

In this work, we present the first observations of gigantic jets (GJs) by the Geostationary Lightning Mapper (GLM) on board the Geostationary Operational Environmental Satellite-R series. Fourteen GJs produced by Tropical Storm Harvey on 19 August 2017 were observed by both GLM and a ground-based low-light-level camera system. The majority of the GJs produced distinguishable signatures in the GLM data, which include long continuous emissions, large peak flash optical energies, and small lateral propagation distances in comparison with other flashes observed by GLM. For two GJs with the best ground-based images, each have a single pixel that contains the largest optical energy throughout the duration of the GJ and also coincides with the azimuth of the GJ from the video images. The optical energy of the pixel increases as the GJ propagates upward, reaches its peak when the GJ connects to the ionosphere, and then fades away.

54 ENVIRONMENTAL SCIENCES↗

Allelic variation contributes to bacterial host specificity

Understanding the molecular parameters that regulate cross-species transmission and host adaptation of potential pathogens is crucial to control emerging infectious disease. Although microbial pathotype diversity is conventionally associated with gene gain or loss, the role of pathoadaptive nonsynonymous single-nucleotide polymorphisms (nsSNPs) has not been systematically evaluated. Here, our genome-wide analysis of core genes within Salmonella enterica serovar Typhimurium genomes reveals a high degree of allelic variation in surface-exposed molecules, including adhesins that promote host colonization. Subsequent multinomial logistic regression, MultiPhen and Random Forest analyses of known/suspected adhesins from 580 independent Typhimurium isolates identifies distinct host-specific nsSNP signatures. Moreover, population and functional analyses of host-associated nsSNPs for FimH, the type 1 fimbrial adhesin, highlights the role of key allelic residues in host-specific adherence in vitro. In conclusion, together, our data provide the first concrete evidence that functional differences between allelic variants of bacterial proteins likely contribute to pathoadaption to diverse hosts.

60 APPLIED LIFE SCIENCES↗

Absence of 3$a_0$ charge density wave order in the infinite-layer nickelate NdNiO 2

A hallmark of many unconventional superconductors is the presence of many-body interactions that give rise to broken-symmetry states intertwined with superconductivity. Recent resonant soft X-ray scattering experiments report commensurate 3a0 charge density wave order in infinite-layer nickelates, which has important implications regarding the universal interplay between charge order and superconductivity in both cuprates and nickelates. Here we present X-ray scattering and spectroscopy measurements on a series of NdNiO 2+x samples, which reveal that the signatures of charge density wave order are absent in fully reduced, single-phase NdNiO 2 . The 3a 0 superlattice peak instead originates from a partially reduced impurity phase where excess apical oxygens form ordered rows with three-unit-cell periodicity. The absence of any observable charge density wave order in NdNiO 2 highlights a crucial difference between the phase diagrams of cuprate and nickelate superconductors.

36 MATERIALS SCIENCE↗

Directional ballistic transport in the two-dimensional metal PdCoO2

Abstract In an idealized infinite crystal, the material properties are constrained by the symmetries of the unit cell. The point-group symmetry is broken by the sample shape of any finite crystal, but this is commonly unobservable in macroscopic metals. To sense the shape-induced symmetry lowering in such metals, long-lived bulk states originating from an anisotropic Fermi surface are needed. Here we show how a strongly facetted Fermi surface and the long quasiparticle mean free path present in microstructures of PdCoO 2 yield an in-plane resistivity anisotropy that is forbidden by symmetry on an infinite hexagonal lattice. We fabricate bar-shaped transport devices narrower than the mean free path from single crystals using focused ion beam milling, such that the ballistic charge carriers at low temperatures frequently collide with both of the side walls that define the channel. Two symmetry-forbidden transport signatures appear: the in-plane resistivity anisotropy exceeds a factor of 2, and a transverse voltage appears in zero magnetic field. Using ballistic Monte Carlo simulations and a numerical solution of the Boltzmann equation, we identify the orientation of the narrow channel as the source of symmetry breaking.

36 MATERIALS SCIENCE↗

Electron magnetic reconnection without ion coupling in Earth’s turbulent magnetosheath

Magnetic reconnection in current sheets is a magnetic-to-particle energy conversion process that is fundamental to many space and laboratory plasma systems. In the standard model of reconnection, this process occurs in a minuscule electron-scale diffusion region. On larger scales, ions couple to the newly reconnected magnetic-field lines and are ejected away from the diffusion region in the form of bi-directional ion jets at the ion Alfvén speed. Much of the energy conversion occurs in spatially extended ion exhausts downstream of the diffusion region. In turbulent plasmas, which contain a large number of small-scale current sheets, reconnection has long been suggested to have a major role in the dissipation of turbulent energy at kinetic scales. However, evidence for reconnection plasma jetting in small-scale turbulent plasmas has so far been lacking. Here we report observations made in Earth’s turbulent magnetosheath region (downstream of the bow shock) of an electron-scale current sheet in which diverging bi-directional super-ion-Alfvénic electron jets, parallel electric fields and enhanced magnetic-to-particle energy conversion were detected. Contrary to the standard model of reconnection, the thin reconnecting current sheet was not embedded in a wider ion-scale current layer and no ion jets were detected. Observations of this and other similar, but unidirectional, electron jet events without signatures of ion reconnection reveal a form of reconnection that can drive turbulent energy transfer and dissipation in electron-scale current sheets without ion coupling.

79 ASTRONOMY AND ASTROPHYSICS↗

Field Angle Tuned Metamagnetism and Lifschitz Transitions in UPt 3

Strongly correlated electronic systems can harbor a rich variety of quantum spin states. Understanding and controlling such spin states in quantum materials is of great current interest. Focusing on the simple binary system UPt 3 with ultrasound (US) as a probe we identify clear signatures in field sweeps demarkating new high field spin phases. Magnetostriction (MS) measurements performed up to 65 T also show signatures at the same fields confirming these phase transitions. At the very lowest temperatures (<200 mK) we also observe magneto-acoustic quantum oscillations which for θ = 90° (B||c-axis) and vicinity abruptly become very strong in the 24.8–30 T range. High resolution magnetization measurements for this same angle reveal a continuous variation of the magnetization implying the subtle nature of the implied transitions. With B rotated away from the c-axis, the US signatures occur at nearly the same field. These transitions merge with the separate sequence of the well known metamagnetic transition which commences at 20 T for θ = 0° but moves to higher fields as 1/cosθ. This merge, suggesting a tricritical behavior, occurs at θ ≈ 51° from the ab-plane. This is an unique off-symmetry angle where the length change along the c-axis is precisely zero due to the anisotropic nature of MS in UPt 3 for all magnetic field values.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Zhang-Rice physics and anomalous copper states in A-site ordered perovskites

In low dimensional cuprates several interesting phenomena, including high Tc superconductivity, are deeply connected to electron correlations on Cu and the presence of the Zhang-Rice (ZR) singlet state. Here, we report on direct spectroscopic observation of the ZR state responsible for the low-energy physical properties in two isostructural A-site ordered cuprate perovskites, CaCu3Co4O12 and CaCu3Cr4O12 as revealed by resonant soft x-ray absorption spectroscopy on the Cu L3,2- and O K-edges. These measurements reveal the signature of Cu in the high-energy 31 (3d8 ), the typical 21 (3d9 ), as well as features of the ZR singlet state (i.e., 3d9 L, L denotes an oxygen hole). First principles GGA 1 U calculations affirm that the B-site cation controls the degree of Cu-O hybridization and, thus, the Cu valency. These findings introduce another avenue for the study and manipulation of cuprates, bypassing the complexities inherent to conventional chemical doping (i.e. disorder) that hinder the relevant physics.

ELECTRONIC STRUCTURE↗

Direct measurement of hot-carrier generation in a semiconductor barrier heterostructure: Identification of the dominant mechanism for thermal droop

Energy measurements of electrons emitted from a semiconductor can reveal internal physical processes hitherto elusive. Signatures of hot-electron processes in heterostructures have been observed from cesiated, light-emitting, and p-i-n diodes. In p-i-n devices with AlGaN barriers, a high-energy peak was measured and ascribed to a trap-assisted Auger recombination process. Furthermore, temperature dependent measurements of light-emitting diodes with AlGaN electron blocking layers also show such hot carriers when electrons thermally reach these barriers, identifying carrier escape as the mechanism of thermal droop and demonstrating the efficacy of such barriers to partially mitigate thermal droop.

36 MATERIALS SCIENCE↗

Coexistence of tunable Weyl points and topological nodal lines in ternary transition-metal telluride TaIrT e 4

Here we report a combined theoretical and experimental study on TaIrTe 4 , a potential candidate for a minimal model of type-II Weyl semimetals. Unexpectedly, an intriguing node structure with 12 Weyl points and a pair of nodal lines protected by mirror symmetry was found by first-principles calculations. Some signatures of the complex electronic structure, such as topologically nontrivial band crossings and topologically trivial Fermi arcs, are cross-validated by angle-resolved photoemission spectroscopy. Through external strain, the number of Weyl points can be reduced to a theoretical minimum of four, and the appearance of the nodal lines can be switched between different mirror planes in momentum space. The coexistence of switchable Weyl points and nodal lines establishes transition-metal chalcogenides as a unique test ground for topological state characterization and engineering.

36 MATERIALS SCIENCE↗

Visualizing broken symmetry and topological defects in a quantum Hall ferromagnet

The interaction between electrons in graphene under high magnetic fields drives the formation of a rich set of quantum Hall ferromagnetic (QHFM) phases with broken spin or valley symmetry. Visualizing atomic-scale electronic wave functions with scanning tunneling spectroscopy (STS), we resolved microscopic signatures of valley ordering in QHFM phases and spectral features of fractional quantum Hall phases of graphene. At charge neutrality, we observed a field-tuned continuous quantum phase transition from a valley-polarized state to an intervalley coherent state, with a Kekulé distortion of its electronic density. Mapping the valley texture extracted from STS measurements of the Kekulé phase, we could visualize valley skyrmion excitations localized near charged defects. Our techniques can be applied to examine valley-ordered phases and their topological excitations in a wide range of materials.

valley symmetry↗