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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Nonstoichiometric Salt Intercalation as a Means to Stabilize Alkali Doping of 2D Materials

Although doping with alkali atoms is a powerful technique for introducing charge carriers into physical systems, the resulting charge-transfer systems are generally not air stable. Here, in this paper, we describe computationally a strategy towards increasing the stability of alkali-doped materials that employs stoichiometrically unbalanced salt crystals with excess cations (which could be deposited during, e.g., in situ gating) to achieve doping levels similar to those attained by pure alkali metal doping. The crystalline interior of the salt crystal acts as a template to stabilize the excess dopant atoms against oxidation and deintercalation, which otherwise would be highly favorable. We characterize this doping method for graphene, NbSe 2 , and Bi 2 Se 3 and its effect on direct-to-indirect band gap transitions, 2D superconductivity, and thermoelectric performance. Salt intercalation should be generally applicable to systems which can accommodate this “ionic crystal” doping (and particularly favorable when geometrical packing constraints favor nonstoichiometry).

2-dimensional systems↗
DOE OSTI2024

Competing Intermolecular and Molecule–Surface Interactions: Dipole–Dipole-Driven Patterns in Mixed Carborane Self-Assembled Monolayers

Carboranedithiol isomers adsorbing with opposite orientations of their dipoles on surfaces are self-assembled together to form mixed monolayers where both lateral dipole–dipole and lateral thiol–thiolate (S–H···S) interactions provide enhanced stability over single-component monolayers. Here, we demonstrate the first instance of the ability to map individual isomers in a mixed monolayer using the model system carboranedithiols on Au{111}. The addition of methyl groups to one isomer provides both an enhanced dipole moment and extra apparent height for differentiation via scanning tunneling microscopy (STM). Associated computational investigations rationalize favorable interactions of mixed pairs and the associated stability changes that arise from these interactions. Both STM images and Monte Carlo simulations yield similarly structured mixed monolayers, where approximately 10% of the molecules have reversed dipole moment orientations but no direct chemical attachment to the surface, leading to homogeneous monolayers with no apparent phase separation. Deprotonating the thiols by depositing the molecules under basic conditions eliminates the lateral S–H···S interactions while accentuating the dipole–dipole forces. The molecular system investigated is composed of isomeric molecules with opposite orientations of dipoles and identical surface packing, which enables the mapping of individual molecules within the mixed monolayers and enables analyses of the contributions of the relatively weak lateral interactions to the overall stability of the assemblies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Enhanced hindrance from phenyl outer side chains on nonfullerene acceptor enables unprecedented simultaneous enhancement in organic solar cell performances with 16.7% efficiency

Inner side-chain engineering on Y6 has been a proven successful in improving short-circuit current density (JSC) through fine-tuning aggregated structures of acceptors. However, it fails in tuning the lowest unoccupied molecular orbital level (LUMO) and open-circuit voltage (V OC ). In this paper, we turn to focus on engineering the outer side chains on the flanking thienothiophene units with 4-hexylphenyl (PhC6) and 6-phenylhexyl (C6Ph) chains. Use of PhC6 enhances the steric effect between the attached phenyl and the ending group, which in combination with the additional conjugation effect provided by the linking phenyl leads to upshifted energy levels and increased V OC as a result. Again, substitution with the bulkier PhC6 unprecedentedly improves film-morphology with reduced paracrystalline disorder and long period and increased root-mean-square composition variations as well, leading to increased electron and hole mobilities and suppressed monomolecular recombination with J SC and fill-factor (FF) simultaneously enhanced. The PM6:BTP-PhC6-based devices yield a higher efficiency value of 16.7% than the PM6:BTP-C6Ph-based one (15.5%). Furthermore, this study shows a conceptual advance in materials design towards reducing the conflict between V OC and J SC in binary blended organic solar cells, which can be achieved by introducing bulkier chains to twist the backbone and simultaneously enhance the packing order.

14 SOLAR ENERGY↗
DOE OSTI2022

CO2 Hydrogenation to Hydrocarbons over Fe/BZY Catalysts

This manuscript reports a CO2 hydrogenation process in a catalytic laboratory-scale packed-bed reactor using an Fe/BZY15 (BaZr0.8Y0.15O3-d) catalyst to form hydrocarbons (e.g., CH4, C2+) at elevated pressure of 30 bar and temperatures in the range 270 = T = 375 degrees C. The effects of temperature, feed composition (i.e., CO2/H2 ratio, and residence time (i.e., Weight Hourly Space Velocity (WHSV) are studied to understand the relationship between CO2 conversion and carbon selectivity. Catalyst characterization elucidates the relationships between the catalyst structure, surface adsorbates, and reaction pathways. Thermodynamic analyses guide the experimental conditions and assist interpreting results. While the feed composition and temperature influence the product distribution, the results suggest that the higher-carbon (C2+) selectivity and yield depend strongly on residence time. The results suggest that the CO2 hydrogenation reaction pathway is similar to Fischer-Tropsch (FT) synthesis. The reaction begins with CO2 activation to form CO, followed by chain-growth reactions similar to the FT process. The CO2 activation depends on the redox activity of the catalyst. However, the carbon chain growth depends primarily on the residence time. as is the case for the FT synthesis, high residence time (on the orders of hours) is required to achieve high C2+ yield. For such high residence times, catalyst-fouling carbon deposition can be problematic. The coke-resistant BZY15 catalyst support contributes to the catalytic activity and enables a coke-free operation for more than 100 h time-on-stream.

bi-functional catalyst↗
DOE OSTI2017

Robust metal-ceramic coaxial cable sensors for distributed temperature monitoring in fossil energy power systems

The project aims to develop a new type of low cost, robust metal-ceramic coaxial cable (MCCC) Fabry-Pérot interferometer (FPI) sensor and demonstrate the capability of cascading a series of FPI sensing points in a single MCCC for real-time distributed monitoring of temperature up to 1000°C. The technical accomplishments of this project include: (i) development of metal and ceramic materials for fabricating the MCCC suitable for use in high temperature (up to 1000oC) fossil fuel, (ii) design, construction and test of single point MCCC-FPI sensors for high temperature measurement at deviation within ±2.7%, (iv) demonstration of the MCCC-FPI sensors for real-time distributed temperature measurement with desired sensitivity, spatial resolution, stability, and response speed that are important to practical applications, and (v) development of a novel MCCC-FPI sensor platform for measuring high frequency dielectric constants for solids and liquids as function of temperature. Single point MCCC-FPI sensors are fabricated based on the FPI parameters, including the relationship between reflector width and reflectance as well as the inter-reflector distance for a FPI, estimated by model calculations. MCCC-FPI sensors have been made using insulators of packed ceramic powders, ceramic tubes, and air or inert gases; outer conductors of various metal tubes; inner conductors of wires of the same metal materials as the tubes used; and reflectors of dense ceramic discs, casted ceramic discs and air gaps. The insulator, conductor and reflector materials are investigated for their thermal, chemical, and structural stabilities under temperatures up to 1000°C in simulated coal-derived syngas. Based on the experimental findings, alumina tube and discs, and stainless steel tube and wire are selected for reflector, insulator and outer and inner conductors, respectively. Air or inert gases are found to be useful for reflectors (in the form of narrow groves) or insulators (in the form of empty chamber cavity between ceramic discs) in construction of MCCC-FPI sensors. Single point MCCC-FPI sensors have been fabricated using stainless steel as conductors, dense α-alumina tubes as dielectric insulators, and two air gaps in the insulator as reflectors. The MCCC-FPI sensor with air gap reflectors has been demonstrated for measuring temperature between 200 and 500°C using microwave as sensing signal in a frequency range of 2 – 8 GHz. The temperature measurement is achieved by monitoring the frequency shift (Δƒ) of a selected resonant peak of the microwave interferogram reflected from the pair of air gap reflectors. The MCCC-FPI sensor exhibited excellent linear temperature-dependence for Δƒ, good accuracy (deviation ±2.7%), and reasonable response speed (<180 s for stabilization). Thermal drifting of the sensing signal was also rather minimal for the MCCC-FPI sensors after operating for more than one week at around 500oC. MCCC-FPI sensors with each containing 2 or 3 pairs of reflectors (i.e. 2 or 3 FPIs in a single cable) have been fabricated and demonstrated for distributed temperature measurement between 250 and 550°C in a microwave frequency range of 3-6 GHz. The measurement is achieved by monitoring the frequency shift of a selected resonant peak of the reflected microwave interferogram, which is obtained by the join-time-domain signal processing method. The results demonstrate that the FPI sensing points in both the three-point and two-point MCCC sensors can measure distributed high temperature with good reproducibility and consistency in multiple runs of measurement tests. The sensor signal displays excellent linear dependence between temperature and the corresponding frequency shift. The 2-point and 3-point MCCC-FPI sensors also exhibit fast response to environmental temperature changes. A three-point MCCC-FPI sensor has been further examined for temperature measurement up to 1000°C for multiple heating-cooling cycles and the results prove that the sensor is suitable for distributed temperature measurement up to 1000°C. MCCC-FPI sensors with more than 4 FPIs point in a single line are made in two structures: the first uses alumina tube as insulation and air gaps as reflectors; and the second uses air chamber as insulation and complete circular alumina discs (2 mm-thick) as reflectors. MCCC-FPIs in neither of the two structures are able to exceed four FPIs in a cable because the reflections from the FPIs are too strong for the microwave to transmit through >4 FPIs over a long distance. Specially shaped alumina discs made by removing parts of the circular discs are found to decrease the microwave reflectance because of reduced reflection areas. However, the smallest reflectance (in terms of percentage of the incident signal) obtained in this work is as high as 7.5%, which is still too large to construct more than 10 FPIs in a single MCCC. Nevertheless, the feasibility of the proposed multipoint MCCC-FPI has been demonstrated using air insulation and 2 mm-thick low-ε r Teflon discs as reflectors on a 2 m-long cable containing 10 FPIs (with reflectance <5% on each FPI). These results indicate that the contrast of dielectric constant between the insulation and reflector has a more significant impact on the reflectance. Thus, future research efforts should also be directed to developing ceramic materials (dense or porous) with low dielectric constant values which, when used as insulation or reflector, can realize large numbers of FPIs in a single cable over a long distance. To assist the development of high temperature dielectric materials, a novel MCCC-FPI sensor platform is developed and successfully demonstrated for measuring high frequency dielectric constants for fluids, packed dielectric solids, and ceramic tube materials and determining ε r dependencies on temperature and chemical composition, etc..

36 MATERIALS SCIENCE↗
DOE OSTI2012

Template-directed preparation of two-layer porous NiO film via hydrothermal synthesis for lithium ion batteries

Graphical abstract: A two-layer porous NiO film is prepared via hydrothermal synthesis method based on monolayer polystyrene sphere template and shows noticeable Li battery performance with good cycle life and high capacity. Highlights: ► Two-layer porous NiO film is prepared via monolayer polystyrene spheres template. ► NiO film with high capacity as anode material for lithium ion batteries. ► Two-layer porous structure is favorable for fast lithium ion and electron transfer. -- Abstract: A two-layer porous NiO film is prepared by hydrothermal synthesis method through self-assembled monolayer polystyrene spheres template. The substructure of the NiO film is composed of ordered close-packed hollow-sphere array and the superstructure is made up of randomly NiO nanoflakes. The electrochemical properties are measured by galvanostatic charge/discharge tests and cyclic voltammetric analysis (CV). As anode material for lithium ion batteries, the two-layer porous NiO film exhibits high initial coulombic efficiency of 75%, high reversible capacity and rather good cycling performance. The discharge capacity of the two-layer porous NiO film is 501 mAh g{sup −1} at 0.5 C after 50 cycles. The two-layer porous architecture is responsible for the enhancement of electrochemical properties.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Molecular Structure of Aromatic Reverse Osmosis Polyamide Barrier Layers

The molecular structures of polyamide barrier layers in reverse osmosis membranes, made by interfacial polymerization of m -phenylenediamine and trimesoyl chloride under different reaction and post-treatment conditions, were characterized by grazing incidence wide-angle X-ray scattering (GIWAXS). Thus, the molecular backbone packing is consistent with two different aromatic molecular packing motifs (parallel and perpendicular) with preferential surface-induced orientation. The results imply that the perpendicular, T-shaped, packing motif (5 Å spacing) might be associated with optimal membrane permeance, compared with the parallel packings (3.5–4.0 Å spacings).

36 MATERIALS SCIENCE↗
DOE OSTI2024

Enriched Molecular-Level View of Saline Wetland Soil Carbon by Sensitivity-Enhanced Solid-State NMR

Soil organic matter (SOM) plays a major role in mitigating greenhouse gas emission and regulating earth’s climate, carbon cycle, and biodiversity. Wetland soils account for one-third of all SOM; however, globally, coastal wetland soils are eroding faster due to increasing sea-level rise. Our understanding of carbon sequestration dynamics in wetlands lags behind that of upland soils. Here, we employ solid-state nuclear magnetic resonance (ssNMR) to investigate the molecular-level structure of biopolymers in wetland soils spanning 11 centuries. High-resolution multidimensional spectra, enabled by dynamic nuclear polarization (DNP), demonstrate enduring preservation of molecular structures within herbaceous plant cores, notably condensing aromatic motifs and carbohydrates, even over a millennium, with the preserved cores constituting a decreasing minority among molecules from decomposition and repolymerization with depth and age. Such preserved cores occur alongside molecules from the decomposition of loosely packed parent biopolymers. These findings emphasize the relative vulnerability of coastal wetland SOM when exposed to oxygenated water due to geological and anthropogenic changes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

The nuclear physics of neutron stars

We explore the unique and fascinating structure of neutron stars. Although neutron stars are of interest in many areas of Physics, our aim is to provide an intellectual bridge between Nuclear Physics and Astrophysics. We argue against the naive perception of a neutron star as a uniform assembly of neutrons packed to enormous densities. Rather, by focusing on the many exotic phases that are speculated to exist in a neutron star, we show how the reality is different and far more interesting.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2014

Solid-to-fluid – like DNA transition in viruses facilitates infection

Releasing the packaged viral DNA into the host cell is an essential process to initiate viral infection. In many double-stranded DNA bacterial viruses and herpesviruses, the tightly packaged genome is hexagonally ordered and stressed in the protein shell, called the capsid. DNA condensed in this state inside viral capsids has been shown to be trapped in a glassy state, with restricted molecular motion in vitro. This limited intracapsid DNA mobility is caused by the sliding friction between closely packaged DNA strands, as a result of the repulsive interactions between the negative charges on the DNA helices. It had been unclear how this rigid crystalline structure of the viral genome rapidly ejects from the capsid, reaching rates of 60,000 bp/s. Through a combination of single- molecule and bulk techniques, we determined how the structure and energy of the encapsidated DNA in phage λ regulates the mobility required for its ejection. Our data show that packaged λ -DNA undergoes a solid-to-fluid – like disordering transition as a function of temperature, resultin g locally in less densely packed DNA, reducing DNA – DNA repulsions. This p rocess leads to a sig- nificant increase in genome mobility or fluidity, which facilitates genome release at temperatures close to that of viral infection (37 °C), suggesting a remarkab le physical adaptation of bac- terial viruses to the environment of Escherichia coli cells in a human host.

AFM↗
DOE OSTI2020

Uncovering dark multichromophoric states in Peridinin–Chlorophyll–Protein

It has long been recognized that visible light harvesting in Peridinin–Chlorophyll–Protein is driven by the interplay between the bright (S 2 ) and dark (S 1 ) states of peridinin (carotenoid), along with the lowest-lying bright (Q y ) and dark (Q x ) states of chlorophyll-a. Here, we analyse a chromophore cluster in the crystal structure of Peridinin–Chlorophyll–Protein, in particular, a peridinin–peridinin and a peridinin–chlorophyll-a dimer, and present quantum chemical evidence for excited states that exist beyond the confines of single peridinin and chlorophyll chromophores. These dark multichromophoric states, emanating from the intermolecular packing native to Peridinin–Chlorophyll–Protein, include a correlated triplet pair comprising neighbouring peridinin excitations and a charge-transfer interaction between peridinin and the adjacent chlorophyll-a. Lastly, we surmise that such dark multichromophoric states may explain two spectral mysteries in light-harvesting pigments: the sub-200-fs singlet fission observed in carotenoid aggregates, and the sub-200-fs chlorophyll-a hole generation in Peridinin–Chlorophyll–Protein.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2016

Preliminary irradiation effect on corrosion resistance of zirconium alloys - 2016-0067

In order to improve the composition and structure of zirconium alloys, it is important to know how changes in their structure-phase state under irradiation affect various properties, including corrosion. In this work, autoclave corrosion tests were carried out on fuel cladding samples made of zirconium-niobium and zirconium-niobium-tin-iron alloy systems. All samples were preliminarily irradiated in a BOR-60 nuclear reactor at a fluence of 2 X10{sup 26} m{sup -2} (E>0.1 MeV). The autoclave tests of irradiated and unirradiated samples were performed at 350 deg. C for 240 days in distilled water containing 10 ppm lithium and 1,600 ppm boron. The irradiation of all alloys resulted in a significant change in their initial structure-phase state. The content of niobium in b-niobium-phase precipitates was reduced from 80 % to - 90 % to 50 % to - 60 %. Iron atoms from the Laves-phase particles were diffused into a matrix, and their lattice transformed from hexagonal close-packed to body-centered cubic. An average size of the transformed second-phase precipitates in the irradiated alloys increased relatively to an average size of the initial precipitates. Elongated radiation-induced precipitates (RIPs) with an average length up to 7 nm were formed in all alloys under irradiation. In comparison with the unirradiated state, irradiation reduced the corrosion of zirconium-niobium alloys, and this effect became more apparent with increased niobium content in the alloy. For zirconium-niobium-tin-iron alloys, irradiation led to more severe corrosion, mostly because of increasing tin content. Niobium content increased up to 2.37 %, and iron content decreased up to 0.18 % in the alloys, contributing to higher corrosion resistance. An interconnection between the niobium/(tin + iron) alloying parameter, quantity of nanometric precipitates formed therein under irradiation, and their corrosion performance has been suggested. (authors)

36 MATERIALS SCIENCE↗
NASA NTRS1977

Protection of cooled blades of complex internal structure

The problem of general protection of cooled blades of complex internal structure was solved by a method called SF technique which makes possible the protection of both external and internal surfaces, as well as those of the orifices of cooling air, whatever their diameter. The SF method is most often applied in the case of pack process, at controlled or high activity; it can be of use on previously uncoated parts, but also on pieces already coated by a thermochemical, chemical or PVD method. The respective thickness of external and internal coatings may be precisely predetermined, no parasitic particle being liable to remain inside the parts after application of the protecting treatment. Results obtained to date by application of this method are illustrated by the presentation and examination of a various selection of advanced turbo engines.

Glamiche, P.↗
NASA NTRS1980

Low-thrust vehicle concept studies

Part of NASA's orbit transfer vehicle propulsion program is devoted to the development of analytical tools to define propulsion system performance, weight, size, and other parameters, and to develop packing concepts for LSS mission propulsion and payload systems. Packing studies discussed relate to shuttle cargo bay constraints; low thrust engine profile and performance; large space frame concept and weight; low thrust vehicles stowed in shuttle, LSS payload capability, and weight distribution. Further study is needed to determine interactions among propulsion system, payload structures, and shuttle. Low thrust-to-weight ratios are desirable to maximize payload weights and deployed areas.

Smolak, G. R.↗
DOE OSTI2016

Neutronics analysis of fuel-in-fiber concept

One of the consequences of Fukushima was the increase in interest in development of safer, more accident tolerant fuels and claddings. Accident tolerant fuels (ATF) are defined by the Nuclear Regulatory Committee (NRC) as fuels that, in comparison with the standard UO{sub 2}- Zircaloy system, can tolerate loss of active cooling in the core for a considerably longer time period while maintaining or improving the fuel performance during normal operations. One of the ideas being considered is tri-isotropic (TRISO) fuel particles. TRISO fuel pebbles consist of several layers - the outermost being graphite. TRISO pebbles are considered to be accident tolerant, because of their ability to retain fission products at high temperatures. One of the ideas implementing TRISO pebbles is Fully Ceramic Microencapsulated fuel where the pellet is comprised of TRISO pebbles in a matrix. TRISO particles though have a low maximum packing fraction when put in the spherical or cylindrical configuration with the current fabrication techniques (hot and cold press). This leads to considerable increase in enrichment to maintain cycle length for today's Light Water Reactors (LWR). The Fuel-in-Fiber concept, developed by FreeForm-Fiber (FFF), has the advantages of TRISO particles while utilizing a novel additive direct manufacturing technique for rapid fabrication. Fuel-in-Fiber are small fibers made of layers just like TRISO particles but because of their cylindrical nature, they can be packed with a tighter packing fraction than the TRISO particles. The fibers are woven within a SiC matrix and used to replace a typical pellet in a fuel pin. This means that they can easily be placed into LWR's without having to change the assembly or core structures. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Microscopic theory of onset of decaging and bond-breaking activated dynamics in ultradense fluids with strong short-range attractions

We theoretically study thermally activated “in cage” elementary dynamical processes that precede full structural relaxation in ultra-dense particle liquids interacting via strong short range attractive forces. The analysis is based on a microscopic theory formulated at the particle trajectory level built on the dynamic free energy concept and an explicit treatment of how attractive forces control the formation and lifetime of physical bonds. Mean time scales for bond breaking, the early stage of cage escape, and non-Fickian displacement by a fixed amount are analyzed in the repulsive glass, bonded repulsive (attractive) glass, fluid, and dense gel regimes. The theory predicts a strong length-scale-dependent growth of these time scales with attractive force strength at fixed packing fraction, a much weaker slowing down with density at fixed attraction strength, and a strong decoupling of the shorter bond breaking time with the other two time scales that are controlled mainly by perturbed steric caging. All results are in good accord with simulations, and additional testable predictions are made. In conclusion, the classic statistical mechanical projection approximation of replacing all bare attractive and repulsive forces with a single effective force determined by pair structure incurs major errors for describing processes associated with thermally activated escape from transiently localized states.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Origins of low-symmetry phases in asymmetric diblock copolymer melts

Cooling disordered compositionally asymmetric diblock copolymers leads to the formation of nearly spherical particles, each containing hundreds of molecules, which crystallize upon cooling below the order–disorder transition temperature (T ODT ). Self-consistent field theory (SCFT) reveals that dispersity in the block degrees of polymerization stabilizes various Frank–Kasper phases, including the C14 and C15 Laves phases, which have been accessed experimentally in low-molar-mass poly(isoprene)-b-poly(lactide) (PI-PLA) diblock copolymers using thermal processing strategies. Heating and cooling a specimen containing 15% PLA above and below the TODT from the body-centered cubic (BCC) or C14 states regenerates the same crystalline order established at lower temperatures. This memory effect is also demonstrated with a specimen containing 20% PLA, which recrystallizes to either C15 or hexagonally ordered cylinders (HEX C ) upon heating and cooling. The process-path–dependent formation of crystalline order shapes the number of particles per unit volume, n/V, which is retained in the highly structured disordered liquid as revealed by small-angle X-ray scattering (SAXS) experiments. We hypothesize that symmetry breaking during crystallization is governed by the particle number density imprinted in the liquid during ordering at lower temperature, and this metastable liquid is kinetically constrained from equilibrating due to prohibitively large free energy barriers for micelle fusion and fission. Ordering at fixed n/V is enabled by facile chain exchange, which redistributes mass as required to meet the multiple particle sizes and packing associated with specific low-symmetry Frank–Kasper phases. Lastly, this discovery exposes universal concepts related to order and disorder in self-assembled soft materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

A lyotropic liquid crystal-templated nanofiltration membrane with thermo- and pH-responsive 3D transport pathway

We produce controlled nanostructured membranes from cross-linking of self-assembled diacrylated poloxamers. At sufficiently high concentrations, poloxamers form lyotropic liquid crystals (LLCs), such as lamellar (L α ), cubic packing of spherical micelles, and hexagonal packing of rod-like micelles in water (H 1 ). We use the H 1 phase as a template to produce orderly packed nanofibrous membranes. The obtained membrane has a continuous 3D transport pathway and can alter its nanofiltration (NF) properties in response to changes in temperature and pH. The formulation includes Pluronic P84-diacrylate (P84DA), a thermoresponsive component that acts as both macromer and structure-directing amphiphile. P84DA facilitates changes in membrane pore size with temperature due to its thermoresponsiveness when it is in contact with water. Furthermore, the precursor contains acrylic acid (AAc) as the charged component, which upon copolymerization with P84DA, not only enables ion separation through Donnan exclusion but also imparts pH-responsive behavior for the separation of ionic species. The membrane performance is studied and compared with a commercial NF membrane (NF270). We show that the synthesized NF membrane has separation properties adjustable with temperature and pH with exceptional resistance to fouling by various solutes due to its highly hydrophilic surface. Furthermore, the membrane shows an outstanding sulfate over chloride ion selectivity, which is a requirement for salt fractionation applications. Deducted from separate experiments, the ideal chloride/sulfate selectivity for magnesium cation is about 2.38 at low ionic strengths. This study is done on a model system to show the capability of incorporating pH-responsiveness in LLC templated membranes, in which the pH-responsive range can be designed by changing the charged groups of comonomer in the formulation.

36 MATERIALS SCIENCE↗