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At least 1,585 records · Page 88

A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics

Several techniques were used to study pretreated Ti 6-4 surfaces including scanning electron microscopy (SEM), electron spectroscopy of chemical analysis (ESCA), and, reflectance visible spectroscopy. Each pretreatment type gave a characteristic surface morphology as seen by SEM. Elemental analysis of the Ti 6-4 surfaces was done using ESCA. Trace residual contaminants from particular chemical pretreatments were identified readily. Results indicate that reflectance visible spectroscopy using indicator dyes placed on Ti 6-4 surfaces appears to be a feasible approach to establish surface acidity. Differences in surface acidity were observed using bromthymol blue on Ti 6-4 surfaces pretreated by two different methods.

Beck, B.↗

Spectroscopic characterization of titanium 6-4 surfaces after chemical pretreatments

Several techniques have been used to study pretreated Ti 6-4 surfaces including scanning electron microscopy (SEM), electron spectroscopy of chemical analysis (ESCA), and, reflectance visibile spectroscopy. Each pretreatment type gives a characteristic surface morphology as seen by SEM. Elemental analysis of the Ti 6-4 surfaces was done using ESCA. Trace residual contaminants from particular chemical pretreatments are identified readily. Reflectance visible spectroscopy using indicator dyes placed on Ti 6-4 surfaces appears to be a feasible approach to establish surface acidity. Differences in surface acidity have been observed using bromthymol blue on Ti 6-4 surfaces pretreated by two different methods.

Chen, W.↗

Linearized ray-trace analysis

A new, coordinate-free version of the exact ray-trace equations for optical systems consisting of conic reflecting, refracting and reference surfaces is presented. These equations are differentiated to obtain closed-form optical sensitivity dyadics. For computation, the sensitivities are evaluated in a single global coordinate frame and combined in linearized ray-trace matrix difference equations that propagate the rays and the sensitivities from element to element. One purpose of this analysis is to create optical models that can be directly integrated with models of the instrument structure and control systems for dynamic simulation.

Redding, David C.↗

Hybrid techniques for complex aerospace electromagnetics problems

Important aerospace electromagnetics problems include the evaluation of antenna performance on aircraft and the prediction and control of the aircraft's electromagnetic signature. Due to the ever increasing complexity and expense of aircraft design, aerospace engineers have become increasingly dependent on computer solutions. Traditionally, computational electromagnetics (CEM) has relied primarily on four disparate techniques: the method of moments (MoM), the finite-difference time-domain (FDTD) technique, the finite element method (FEM), and high frequency asymptotic techniques (HFAT) such as ray tracing. Each of these techniques has distinct advantages and disadvantages, and no single technique is capable of accurately solving all problems of interest on computers that are available now or will be available in the foreseeable future. As a result, new approaches that overcome the deficiencies of traditional techniques are beginning to attract a great deal of interest in the CEM community. Among these new approaches are hybrid methods which combine two or more of these techniques into a coherent model. During the ASEE Summer Faculty Fellowship Program a hybrid FEM/MoM computer code was developed and applied to a geometry containing features found on many modern aircraft.

Aberle, Jim↗

Computational Simulation of Damage Progression of Composite Thin Shells Subjected to Mechanical Loads

Defect-free and defected composite thin shells with ply orientation (90/0/+/-75) made of graphite/epoxy are simulated for damage progression and fracture due to internal pressure and axial loading. The thin shells have a cylindrical geometry with one end fixed and the other free. The applied load consists of an internal pressure in conjunction with an axial load at the free end, the cure temperature was 177 C (350 F) and the operational temperature was 21 C (70 F). The residual stresses due to the processing are taken into account. Shells with defect and without defects were examined by using CODSTRAN an integrated computer code that couples composite mechanics, finite element and account for all possible failure modes inherent in composites. CODSTRAN traces damage initiation, growth, accumulation, damage propagation and the final fracture of the structure. The results show that damage initiation started with matrix failure while damage/fracture progression occurred due to additional matrix failure and fiber fracture. The burst pressure of the (90/0/+/- 75) defected shell was 0.092% of that of the free defect. Finally the results of the damage progression of the (90/0/+/- 75), defective composite shell was compared with the (90/0/+/- theta, where theta = 45 and 60, layup configurations. It was shown that the examined laminate (90/0/+/- 75) has the least damage tolerant of the two compared defective shells with the (90/0/+/- theta), theta = 45 and 60 laminates.

Gotsis, P. K.↗

The Origins Space Telescope: Mission Concept Overview

The Origins Space Telescope (OST) will trace the history of our origins from the time dust and heavy elements permanently altered the cosmic landscape to present-day life. How did the universe evolve in response to its changing ingredients? How common are life-bearing planets? To accomplish its scientific objectives, OST will operate at mid- and far-infrared wavelengths and offer superlative sensitivity and new spectroscopic capabilities. The OST study team will present a scientifically compelling, executable mission concept to the 2020 Decadal Survey in Astrophysics. To understand the concept solution space, our team studied two alternative mission concepts. We report on the study approach and describe both of these concepts, give the rationale for major design decisions, and briefly describe the mission-enabling technology.

Leisawitz, D.↗

The Origins Space Telescope

The Origins Space Telescope will trace the history of our origins from the time dust and heavy elements permanently altered the cosmic landscape to present-day life. How did galaxies evolve from the earliest galactic systems to those found in the universe today? How do habitable planets form? How common are life-bearing worlds? To answer these alluring questions, Origins will operate at mid- and far-infrared wavelengths and offer powerful spectroscopic instruments and sensitivity three orders of magnitude better than that of Herschel, the largest telescope flown in space to date. After a 3 ½ year study, the Origins Science and Technology Definition Team will recommend to the Decadal Survey a concept for Origins with a 5.9-m diameter telescope cryo cooled to 4.5 K and equipped with three scientific instruments. A mid-infrared instrument (MISC-T) will measure the spectra of transiting exoplanets in the 2.8 – 20 μm wavelength range and offer unprecedented sensitivity, enabling definitive biosignature detections. The Far-IR Imager Polarimeter (FIP) will be able to survey thousands of square degrees with broadband imaging at 50 and 250 μm. The Origins Survey Spectrometer (OSS) will cover wavelengths from 25 – 588 μm, make wide-area and deep spectroscopic surveys with spectral resolving power R ~ 300, and pointed observations at R ~ 40,000 and 300,000 with selectable instrument modes. Origins was designed to minimize complexity. The telescope has a Spitzer-like architecture and requires very few deployments after launch. The cryo-thermal system design leverages JWST technology and experience. A combination of current-state-of-the-art cryocoolers and next-generation detector technology will enable Origins’ natural background limited sensitivity.

Leisawitz, D.↗

The Origins Space Telescope: Trades and Decisions Leading to the Baseline Mission Concept

The Origins Space Telescope will trace the history of our origins from the time dust and heavy elements permanently altered the cosmic landscape to present-day life. How did galaxies evolve from the earliest galactic systems to those found in the universe today? How do habitable planets form? How common are life-bearing worlds? We describe how Origins was designed to answer these alluring questions. We discuss the key decisions taken by the Origins mission concept study team, the rationale for those choices, and how they led through an exploratory design process to the Origins baseline mission concept. To understand the concept solution space, we studied two distinct mission concepts and descoped the second concept, aiming to maximize science per dollar and hit a self-imposed cost target. We report on the study approach and describe the concept evolution. The resulting baseline design includes a 5.9-m diameter telescope cryocooled to 4.5 K and equipped with three scientific instruments. The chosen architecture is similar to that of the Spitzer Space Telescope and requires very few deployments after launch. The cryo-thermal system design leverages JamesWebb Space Telescope technology and experience.

Infrared↗

Origins Space Telescope: From First Light to Life

The Origins Space Telescope ( Origins ) is one of four science and technology definition studies selected by National Aeronautics and Space Administration (NASA) in preparation of the 2020 Astronomy and Astrophysics Decadal survey in the US. Origins will trace the history of our origins from the time dust and heavy elements permanently altered the cosmic landscape to present-day life. It is designed to answer three major science questions: How do galaxies form stars, make metals, and grow their central supermassive black holes from reionization? How do the conditions for habitability develop during the process of planet formation? Do planets orbiting M-dwarf stars support life? Origins operates at mid- to far-infrared wavelengths from ~ 2.8 to 588 μm, is more than 1000 times more sensitive than prior far-IR missions due to its cold (~ 4.5 K) aperture and state-of-the-art instruments.

Spaceborne astrophysics↗

PRIMA: The PRobe Far-Infrared Mission for Astrophysics

PRIMA is a far-infrared observatory concept being developed to address timely and fundamental questions about the growths of galaxies and solar systems and their constituents. It will observe the build-up of heavy elements, dust, stars, and black holes in galaxies and their interrelationships, and trace the masses and water contents of protoplanetary disks to probe the growths of solar systems. The majority of observing time will be devoted to Guest Observer programs to enable the astrophysics community to identify and plan the most critical observations, with focused PI programs to address key science with rapid releases of data to inform community planning. PRIMA will have spectral, hyperspectral imaging, and polarimetric capabilities, enabled now for the first time by extraordinary progress in kinetic inductance detector (KID) array technology over the last two decades. The 2.0-meter telescope will be cooled to < 5 K to take maximum advantage of the KID sensitivities. For observations of atomic fine-structure lines, molecular lines, and solid-state emission and absorption bands, R = 200 spectral coverage will range from approximately 25 µm to 200 µm, with a high-resolution mode across the entire band that will have a spectral resolving power of a few thousand at 100 µm. R ~ 10 moderate-resolution (hyperspectral) imaging will range from 25 to 80 µm for rest-frame, mid- and far-infrared spectral energy distribution measurements to probe dust grain composition and disambiguate star formation and active galactic nuclei in galaxies. Polarimetric observations of large areas of Galactic molecular clouds and the Magellanic Clouds from 80 to ~200 µm will bridge between the large-scale polarimetry of the interstellar medium from cosmic microwave background observatories and protostellar disk-scale interferometric observations to probe magnetic fields at the critical scales at which clouds collapse to form stars. An overview of PRIMA’s basic design and capabilities will be presented. Other posters in this session describe PRIMA science, technology, and instrumentation in greater depth.

Jason Glenn↗

In situ liquid SIMS analysis of uranium oxide

Trace analysis of nuclear materials in solid particles collected in the environment or particles in liquid slurry generated in nuclear material manufacturing processes can pinpoint elemental, organic, and isotopic signatures of nuclear fuel cycle activities and processes. Such information can support nuclear safeguards programs by increasing our ability to detect undeclared nuclear materials, routine activities for safeguarding at declared facilities, and illicit activities. However, trace radioactive material analysis in liquids and slurries is challenging using bulk approaches. For example, one drawback of sensitive analysis such as inductively coupled plasma mass spectrometry (ICP-MS) is that sample is consumed or destroyed as a result of the technical approach. We developed a vacuum compatible microfluidic interface to enable surface analysis of liquids and liquid-solid interactions using time-of-flight secondary ion mass spectrometry (ToF-SIMS). In this work, we illustrate initial results of liquid standards containing uranium using in situ liquid SIMS. Specifically a series of diluted uranium standards used for ICPMS analysis were studied and the limit of detection was estimated. Since the liquid SIMS analysis is almost nondestructive, the same sample can be analyzed by other more destructive approaches afterwards or saved for future references. Consequently, multimodal analysis is possible. Our results demonstrate that in situ liquid SIMS can be used as a new approach to analyze radioactive materials in liquid and slurry forms of relevance to the IAEA safeguards missions.

In situ liquid ToF-SIMS, uranium, limit of detecti↗

Quantitative imaging of trace B in Si and SiO{sub 2} using ToF-SIMS

Changes in the oxidation state of an element can result in significant changes in the ionization efficiency and hence signal intensity during secondary ion mass spectrometry (SIMS) analysis; this is referred to as the SIMS matrix effect [Secondary Ion Mass Spectrometry: A Practical Handbook for Depth Profiling and Bulk Impurity Analysis, edited by R. G. Wilson, F. A. Stevie, and C. W. Magee (Wiley, New York, 1990)]. The SIMS matrix effect complicates quantitative analysis. Quantification of SIMS data requires the determination of relative sensitivity factors (RSFs), which can be used to convert the as measured intensity into concentration units [Secondary Ion Mass Spectrometry: A Practical Handbook for Depth Profiling and Bulk Impurity Analysis, edited by R. G. Wilson, F. A. Stevie, and C. W. Magee (Wiley, New York, 1990)]. In this manuscript, the authors report both: RSFs which were determined for quantification of B in Si and SiO{sub 2} matrices using a dual beam time of flight secondary ion mass spectrometry (ToF-SIMS) instrument and the protocol they are using to provide quantitative ToF-SIMS images and line scan traces. The authors also compare RSF values that were determined using oxygen and Ar ion beams for erosion, discuss the problems that can be encountered when bulk calibration samples are used to determine RSFs, and remind the reader that errors in molecular details of the matrix (density, volume, etc.) that are used to convert from atoms/cm{sup 3} to other concentration units will propagate into errors in the determined concentrations.

42 ENGINEERING↗

Measurement of Total, Elemental, and Methyl Mercury in Hanford Tank Waste: Technology Transfer from PNNL to Hanford 222-S Laboratory

This report describes the chemical separations used to measure the amount and chemical form of mercury in Hanford tank waste and provides the technical basis and recommendations for transferring and implementing this new ultra-trace mercury analytical technique at Hanford’s 222-S Laboratory. In the Hanford tank waste, mercury can exist as either elemental, inorganic, or organic mercury species. Of key interest is understanding the quantification and speciation of total (elemental + inorganic + organic), elemental, and organic (assumed to be only methyl mercury) mercury. The tanks may also have other organic mercury species, but their direct measurement is outside the scope of this report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Program Instrumentation and Trace Analysis

Several attempts have been made recently to apply techniques such as model checking and theorem proving to the analysis of programs. This shall be seen as a current trend to analyze real software systems instead of just their designs. This includes our own effort to develop a model checker for Java, the Java PathFinder 1, one of the very first of its kind in 1998. However, model checking cannot handle very large programs without some kind of abstraction of the program. This paper describes a complementary scalable technique to handle such large programs. Our interest is turned on the observation part of the equation: How much information can be extracted about a program from observing a single execution trace? It is our intention to develop a technology that can be applied automatically and to large full-size applications, with minimal modification to the code. We present a tool, Java PathExplorer (JPaX), for exploring execution traces of Java programs. The tool prioritizes scalability for completeness, and is directed towards detecting errors in programs, not to prove correctness. One core element in JPaX is an instrumentation package that allows to instrument Java byte code files to log various events when executed. The instrumentation is driven by a user provided script that specifies what information to log. Examples of instructions that such a script can contain are: 'report name and arguments of all called methods defined in class C, together with a timestamp'; 'report all updates to all variables'; and 'report all acquisitions and releases of locks'. In more complex instructions one can specify that certain expressions should be evaluated and even that certain code should be executed under various conditions. The instrumentation package can hence be seen as implementing Aspect Oriented Programming for Java in the sense that one can add functionality to a Java program without explicitly changing the code of the original program, but one rather writes an aspect and compiles it into the original program using the instrumentation. Another core element of JPaX is an observation package that supports the analysis of the generated event stream. Two kinds of analysis are currently supported. In temporal analysis the execution trace is evaluated against formulae written in temporal logic. We have implemented a temporal logic evaluator on finite traces using the Maude rewriting system from SRI International, USA. Temporal logic is defined in Maude by giving its syntax as a signature and its semantics as rewrite equations. The resulting semantics is extremely efficient and can handle event streams of hundreds of millions events in few minutes. Furthermore, the implementation is very succinct. The second form of even stream analysis supported is error pattern analysis where an execution trace is analyzed using various error detection algorithms that can identify error-prone programming practices that may potentially lead to errors in some different executions. Two such algorithms focusing on concurrency errors have been implemented in JPaX, one for deadlocks and the other for data races. It is important to note, that a deadlock or data race potential does not need to occur in order for its potential to be detected with these algorithms. This is what makes them very scalable in practice. The data race algorithm implemented is the Eraser algorithm from Compaq, however adopted to Java. The tool is currently being applied to a code base for controlling a spacecraft by the developers of that software in order to evaluate its applicability.

Havelund, Klaus↗

Recovery of Rare Earths, Precious Metals and Other Critical Materials from Geothermal Waters with Advanced Sorbent Structures

The work evaluates, develops and demonstrates flexible, scalable mineral extraction technology for geothermal brines based upon solid phase sorbent materials with a specific focus upon rare earth elements (REEs). The selected organic and inorganic sorbent materials demonstrated high performance for collection of trace REEs, precious and valuable metals. The nanostructured materials typically performed better than commercially available sorbents. Data contains organic and inorganic sorbent removal efficiency, Sharkey Hot Springs (Idaho) water chemsitry analysis, and rare earth removal efficiency from select sorbents.

15 GEOTHERMAL ENERGY↗

Optimization of a phase-space beam position and size monitor for low-emittance light sources

The recently developed vertical phase-space beam position and size monitor (ps-BPM) system has proven to be able to measure the electron-source position, angle, size and divergence simultaneously in the vertical plane at a single location of a beamline. The optimization of the ps-BPM system is performed by ray-tracing simulation to maximize the instrument sensitivity and resolution. The contribution of each element is studied, including the monochromator, the K -edge filter, the detector and the source-to-detector distance. An optimized system is proposed for diffraction-limited storage rings, such as the Advanced Photon Source Upgrade project. The simulation results show that the ps-BPM system can precisely monitor the source position and angle at high speed. Precise measurements of the source size and divergence will require adequate resolution with relatively longer integration time.

47 OTHER INSTRUMENTATION↗

Thermal distortion analysis of the space station solar dynamic concentrator

A method was developed to evaluate the thermal distortion of the Space Station Solar Dynamic Concentrator and the effects of thermal distortion on concentrator optical performance. The analytical method includes generating temperature distributions with TRASYS and SINDA models, interfacing the SINDA results with the SINDA-NASTRAN Interface Program (SNIP), calculating thermal distortion with a NASTRAN/PATRAN finite element model, and providing flux distribution maps within the receiver with the ray tracing OFFSET program. Temperature distributions, thermally induced slope errors, and flux distribution maps within the receiver are discussed. Results during a typical orbit indicate that temperatures of the hexagonal panels and triangular facets range between -18 and 99 C (-1 to 210 F), facet rotations are less than 0.2 mrad, and a change in facet radius due to thermal flattening is less than 5 percent. The predicted power loss with thermal distortion effects was less than 0.3 percent. The thermal distortion of the Solar Dynamic concentrator has negligible effect on the flux distribution within the receiver cavity.

Trudell, Jeffrey J.↗

Thermal distortion analysis of the Space Station solar dynamic concentrator

A method was developed to evaluate the thermal distortion of the Space Station Solar Dynamic Concentrator and the effects of thermal distortion on concentrator optical performance. The analytical method includes generating temperature distributions with TRASYS and SINDA models, interfacing the SINDA results with the SINDA-NASTRAN Interface Program (SNIP), calculating thermal distortion with a NASTRAN/PATRAN finite element model, and providing flux distribution maps within the receiver with the ray tracing OFFSET program. Temperature distributions, thermally induced slope errors, and flux distribution maps within the receiver are discussed. Results during a typical orbit indicate that temperatures of the hexagonal panels and triangular facets range between -18 and 99 C (-1 to 210 F), facet rotations are less than 0.2 mrad, and a change in facet radius due to thermal flattening is less than 5 percent. The predicted power loss with thermal distortion effects was less than 0.3 percent. The thermal distortion of the Solar Dynamic concentrator has negligible effect on the flux distribution within the receiver cavity.

Trudell, Jeffery J.↗