Enhanced magnetism-generated ferroelectricity in highly frustrated Fe-doped Ho{sub 2}Ti{sub 2}O{sub 7}
We present careful experiments on the ferroelectric (FE), dielectric, and magnetic behaviors of Ho{sub 2−x}Fe{sub x}Ti{sub 2}O{sub 7} with Fe{sup 3+} substitution for Ho{sup 3+}. A remarkable enhancement of polarization up to 235 μC/m{sup 2} is obtained at a low level x = 0.08, accompanied with the FE transition up to ∼80 K. The ac susceptibility under magnetic fields shows an expected saturated maximum in the real part χ′, along with an unexpected frequency-dependent peak in the imaginary part χ″, indicating unusual slow spin relaxation. The coupled correlated spin domains through dipolar interaction are argued to give rise to nonzero electric-dipole via Dzyaloshinskii-Moriya interaction.