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Far-IR/Submillimeter Interferometry Missions in NASA's Roadmap: SPIRIT and SPECS

Information vital to the attainment of the major scientific objectives of NASA's Origins and Structure and Evolution of the Universe themes is uniquely available in the far-IR and submillimeter (FIR/SMM). NASA is studying concepts and investing in technologies for FIR/SMM observatories that could fly in the period 2010 - 2025 and provide enormous increases in measurement capabilities to extend the legacy of the next-generation missions SIRTF and Herschel. Future FIR/SMM space observatories will have the sensitivity needed to reach back in time to the formation epoch of the first luminous objects, the angular resolution needed to image proto-planetary systems and distinguish the emissions of individual galaxies, and the spectral resolution needed to probe the physical conditions and measure the flows of interstellar gas in young galaxies, nascent stars, and the dust-enshrouded nuclei of galaxies that harbor massive black holes. NASA's roadmap includes the JWST-class Single Aperture Far-IR (SAFIR) telescope and 1 km maximum-baseline FIR/SMM interferometer. This talk will focus on the niche for FIR/SMM interferometry and describe two missions: SPECS, the Submillimeter Probe of the Evolution of Cosmic Structure, and the pathfinder mission SPIRIT, the Space Infrared interferometric Telescope. I will give the scientific motivation for these missions, describe mission concepts and telescope measurement capabilities, and compare these capabilities with those of the next-generation IR telescopes, and with the complementary JWST and ALMA.

Leisawitz, David T.↗

Heterodyne Receiver Requirements for the Single Aperture Far-Infrared (SAFIR) Observatory

In the next few years, work will commence in earnest on the development of technology for the next generation large cryogenic far-infrared telescope: the Single Aperture Far- Infrared (SAFIR) Observatory. SAFIR's science goals are driven by the fact that youngest stages of almost all phenomena in the universe are shrouded in absorption by cool dust, resulting in the energy being emitted primarily in the far-infrared. The earliest stages of star formation, when gas and dust clouds are collapsing and planets forming, can only be observed in the far-infrared. Spectral diagnostics in the far-infrared are typically quite narrow (approx. 1 km/s) and require high sensitivity to detect them. SAFIR is a 10 m-class telescope designed for cryogenic operation at L2, removing all sources of thermal emission from the telescope and atmosphere. Despite its limited collecting area and angular resolution as compared to the ALMA interferometer, its potential for covering the entire far-infrared band cannot be matched by any ground-based or airborne observatory. This places a new challenge on heterodyne receivers: broad frequency coverage. The ideal mixer would be able to detect frequencies over several octaves (e.g., 0.6 THz - 12 THz) with near quantum-limited performance at all frequencies. In contrast to ground-based observatories, it may not be necessary to strive for high instantaneous bandwidth, as direct detection spectroscopy is preferable for bandwidths of Delta v/ v greater than or equal to 10(exp -4) (e.g., 1 GHz at 10 THz). We consider likely directions for technology development for heterodyne receivers for SAFIR.

Benford, Dominic J.↗

Prebiotic Soup-Revisiting the Miller Experiment

'Isn't life wonderful?' sang Alma Cogan and Les Howard in their almost forgotten 1953 hit. That same year, Stanley L. Miller raised the hopes of understanding the origin of life when on 15 May, Science published his paper on the synthesis of amino acids under conditions that simulated primitive Earth's atmosphere. Miller had applied an electric discharge to a mixture of CH4, NH3, H2O, and H2 - believed at the time to be the atmospheric composition of early Earth. Surprisingly, the products were not a random mixture of organic molecules, but rather a relatively small number of biochemically significant compounds such as amino acids, hydroxy acids, and urea. With the publication of these dramatic results, the modem era in the study of the origin of life began.

Bada, Jeffrey L.↗

Charting the Winds that Change the Universe, II The Single Aperture Far Infrared Observatory (SAFIR)

The Single Aperture Far Infrared Observatory (SAFIR) will study the birth and evolution of stars and planetary systems so young that they are invisible to optical and near-infrared telescopes such as NGST. Not only does the far-infrared radiation penetrate the obscuring dust clouds that surround these systems, but the protoplanetary disks also emit much of their radiation in the far infrared. Furthermore, the dust reprocesses much of the optical emission from the newly forming stars into this wavelength band. Similarly, the obscured central regions of galaxies, which harbor massive black holes and huge bursts of star formation, can be seen and analyzed in the far infrared. SAFIR will have the sensitivity to see the first dusty galaxies in the universe. For studies of both star-forming regions in our galaxy and dusty galaxies at high redshifts, SAFIR will be essential in tying together information that NGST will obtain on these systems at shorter wavelengths and that ALMA will obtain at longer wavelengths.

Leisawitz, David↗

The Submillimeter Probe of the Evolution of Cosmic Structure (SPECS)

The NASA roadmap mission SPECS is conceived as an imaging and spectral interferometer that will have the sensitivity needed to reach back in time to the formation epoch of the first luminous objects, the angular resolution needed to image proto-planetary systems and galaxies at high redshift, and the spectral resolution needed to probe the physical conditions and measure the flows of interstellar gas in young galaxies, nascent stars, and the dust-enshrouded nuclei of galaxies that harbor massive black holes. With a 1 km maximum baseline and the capability to sample the u-v plane completely, SPECS will produce images with angular resolution 20 (lambda / 100 microns) mas over the wavelength range 40 less than lambda less than 800 microns. In this talk I will give the scientific motivation for SPECS, describe mission concepts and telescope measurement capabilities, and compare these capabilities with those of the next-generation IR telescopes, and with the complementary JWST and ALMA.

Leisawitz, David↗

NASA's Far-IR/Submillimeter Roadmap Missions SAFIR and SPECS

The far-IR is rich with information about star, disk and planet formation because protostars emit predominantly in this spectral range, and the radiation can escape from the inherently dusty stellar birth sites. Spectral lines contain particularly valuable information about the cooling, collapse, and chemistry of molecular cloud cores and protostars. However, the interpretation of line intensities and profiles is model-dependent; ultimately, high angular resolution is needed to break model degeneracy and definitively characterize the source. Processes occurring on scales smaller than 10,000 AU (72 arcsec at 140 pc, where the nearest protostellar objects are found) likely affect the stellar initial mass function and determine the product of cloud collapse (Binary star or planetary system? How many planets, and what kind will they be?) The next-generation far-IR observatories SIRTF, SOFIA, and Herschel will revolutionize star formation studies and leave the community yearning for telescopes that operate in this spectral region but provide many orders of magnitude better angular resolution. NASA's space science roadmap includes the JWST-scale Single Aperture Far-IR (SAFIR) telescope and the 1 km maximum baseline far-IR interferometer, SPECS (the Submillimeter Probe of the Evolution of Cosmic Structure). I will give the scientific motivation for these missions, describe mission concepts and telescope measurement capabilities, and compare these capabilities with those of the next-generation IR telescopes and with the complementary JWST and ALMA. I will also describe the Space Infrared Interferometric Telescope (SPIRIT), a science and technology pathfinder for SPECS, which could be ready to launch in about a decade. At 100 microns, SAFIR will provide 2.5 arcsec resolution (10 times better than SIRTF), SPIRIT will provide 0.25 arcsec resolution, and SPECS will provide 10 milli-arcsec resolution, which is comparable to that of the Hubble Space Telescope.

Leisawitz, David↗

The Wide-Field Imaging Interferometry Testbed: Progress and Plans

We describe the technique of wide field mosaic imaging for optical/IR interferometers and present early experimental results from a laboratory instrument designed to validate, experiment with, and refine the technique. A conventional single-detector stellar interferometer operating with narrow bandwidth at center wavelength lambda is limited in its field of view to the primary beam of the individual telescope apertures, or approx. lambda/D(sub tel) radians, where is the telescope diameter. Such a field is too small for many applications; often one wishes to image extended sources. We are developing and testing a technique analogous to the mosaic method employed in millimeter and radio astronomy, but applicable to optical/IR Michelson interferometers, in which beam combination is done in the pupil plane. An N(sub pix) x N(sub pix) detector array placed in the image plane of the interferometer is used to record simultaneously the fringe patterns from many contiguous telescope fields, effectively multiplying the field size by N(sub pix)/2, where the factor 2 allows for Nyquist sampling. This mosaic imaging technique will be especially valuable for far IR and submillimeter interferometric space observatories such as the Space Infrared Interferometric Telescope (SPIRIT) and the Submillimeter Probe of the Evolution of Cosmic Structure (SPECS). SPIRIT and SPECS will be designed to provide sensitive, high angular resolution observations of fields several arcminutes in diameter, and views of the universe complementary to those provided by HST, NGST, and ALMA.

Rinehart, S. A.↗

WaFIRS, a Waveguide Far-IR Spectrometer: Enabling Space-Borne Spectroscopy of High-z Galaxies in the Far-IR and Submm

The discovery of galaxies beyond z approximately equal to 1 which emit the bulk of their luminosity at long wavelengths has demonstrated the need for high sensitivity, broadband spectroscopy in the far-IR/submm/mm bands. Because many of these sources are not detectable in the optical, long wavelength spectroscopy is key to measuring their redshifts and ISM conditions. The continuum source list will increase in the next decade with new ground-based instruments (SCUBA2, Bolocam, MAMBO) and the surveys of HSO and SIRTF. Yet the planned spectroscopic capabilities lag behind, primarily due to the difficulty in scaling existing IR spectrograph designs to longer wavelengths. To overcome these limitations, we are developing WaFIRS, a novel concept for long-wavelength spectroscopy which utilizes a parallel-plate waveguide and a curved diffraction grating. WaFIRS provides the large (approximately 60%) instantaneous bandwidth and high throughput of a conventional grating system, but offers a dramatic reduction in volume and mass. WaFIRS requires no space overheads for extra optical elements beyond the diffraction grating itself, and is two-dimensional because the propagation is confined between two parallel plates. Thus several modules could be stacked to multiplex either spatially or in different frequency bands. The size and mass savings provide opportunities for spectroscopy from space-borne observatories which would be impractical with conventional spectrographs. With background-limited detectors and a cooled 3.5 telescope, the line sensitivity would be better than that of ALMA, with instantaneous broad-band coverage. We have built and tested a WaFIRS prototype for 1-1.6 mm, and are currently constructing Z-Spec, a 100 mK model to be used as a ground-based lambda/DELTAlambda approximately equal to 350 submillimeter galaxy redshift machine.

Bradford, C. M.↗

The Case for Space-Borne Far-Infrared Line Surveys

The combination of sensitive direct detectors and a cooled aperture promises orders of magnitude improvement in the sensitivity and survey time for far-infrared and submillimeter spectroscopy compared to existing or planned capabilities. Continuing advances in direct detector technology enable spectroscopy that approaches the background limit available only from space at these wavelengths. Because the spectral confusion limit is significantly lower than the more familiar spatial confusion limit encountered in imaging applications, spectroscopy can be carried out to comparable depth with a significantly smaller aperture. We are developing a novel waveguide-coupled grating spectrometer that disperses radiation into a wide instantaneous bandwidth with moderate resolution (R ~ 1000) in a compact 2-dimensional format. A line survey instrument coupled to a modest cooled single aperture provides an attractive scientific application for spectroscopy with direct detectors. Using a suite of waveguide spectrometers, we can obtain complete coverage over the entire far-infrared and sub-millimeter. This concept requires no moving parts to modulate the optical signal. Such an instrument would be able to conduct a far-infrared line survey 10 6 times faster than planned capabilities, assuming existing detector technology. However, if historical improvements in bolometer sensitivity continue, so that photon-limited sensitivity is obtained, the integration time can be further reduced by 2 to 4 orders of magnitude, depending on wavelength. The line flux sensitivity would be comparable to ALMA, but at shorter wavelengths and with the continuous coverage needed to extract line fluxes for sources at unknown redshifts. For example, this capability would break the current spectroscopic bottleneck in the study of far-infrared galaxies, the recently discovered, rapidly evolving objects abundant at cosmological distances.

Bock, J. J.↗

Far-Infrared and Submillimeter Spectroscopy of Low to Moderate Redshift Normal and Active Galaxies

Broadband surveys with planned observatories such as SIRTF, ASTRO-F, NGST, Herschel, SMA, and ALMA will provide large samples of dust-enshrouded galaxies undergoing varying proportions of star formation and accretion onto supermassive black holes. Recent evidence suggests that the mass of supermassive central black holes are proportional to central velocity dispersions of their host galaxy bulges, but it is not yet known how these properties are evolutionarily connected. To trace the evolution of these components during the important luminous, dusty merger episodes as a function of redshift, sensitive mid- to far-infrared spectroscopic diagnostic observations from space will be necessary. The high sensitivity and spatial resolution of a large aperture, natural background limited far-infrared/submillimeter telescope such as SAFAIR will allow detection and identification of the far-infrared/submillimeter components of galaxies and of a multitude of rest-frame mid- to far-infrared recombination, fine-structure, and molecular lines toward dusty galactic nuclei. The line diagnostics beginning to be developed from ISO work will help determine important parameters such as the intrinsic spectral energy distribution, ionization parameters, metallicities, densities, extinction to the embedded energy sources, and ultimately the star-formation and accretion rates in these galaxies. Ultimately, the higher spatial resolution provided by a cold, far-infrared submillimeter interferometer is needed to view the distribution of structure in galaxies in order to unravel the as yet untold story of the evolution of galaxies over the lifetime of the Universe.

Fischer, Jacqueline↗

Charting the Winds that Change the Universe, II: The Single Aperture Far Infrared Observatory (SAFIR)

SAFIR will study the birth and evolution of stars and planetary systems so young that they are invisible to optical and near-infrared telescopes such as NGST. Not only does the far-infrared radiation penetrate the obscuring dust clouds that surround these systems, but the protoplanetary disks also emit much of their radiation in the far infrared. Furthermore, the dust reprocesses much of the optical emission from the newly forming stars into this wavelength band. Similarly, the obscured central regions of galaxies, which harbor massive black holes and huge bursts of star formation, can be seen and analyzed in the far infrared. SAFIR will have the sensitivity to see the first dusty galaxies in the universe. For studies of both star-forming regions in our galaxy and dusty galaxies at high redshifts, SAFIR will be essential in tying together information that NGST will obtain on these systems at shorter wavelengths and that ALMA will obtain at longer wavelengths.

Rieke, G. H.↗

BLAST: The Balloon-Borne Large Aperture Submillimeter Telescope

BLAST is the Balloon-borne Large-Aperture Sub-millimeter Telescope. It will fly from a Long Duration Balloon (LDB) platform from Antarctica. The telescope design incorporates a 2 m primary mirror with large-format bolometer arrays operating at 250, 350 and 500 microns. By providing the first sensitive large-area (10 sq. deg.) sub-mm surveys at these wavelengths, BLAST will address some of the most important galactic and cosmological questions regarding the formation and evolution of stars, galaxies and clusters. Galactic and extragalactic BLAST surveys will: (1) identify large numbers of high-redshift galaxies; (2) measure photometric redshifts, rest-frame FIR luminosities and star formation rates thereby constraining the evolutionary history of the galaxies that produce the FIR and sub-mm background; (3) measure cold pre-stellar sources associated with the earliest stages of star and planet formation; (4) make high-resolution maps of diffuse galactic emission over a wide range of galactic latitudes. In addition to achieving the above scientific goals, the exciting legacy of the BLAST LDB experiment will be a catalogue of 3000-5000 extragalactic sub-mm sources and a 100 sq. deg. sub-mm galactic plane survey. Multi-frequency follow-up observations from SIRTF, ASTRO-F, and Herschel, together with spectroscopic observations and sub-arcsecond imaging from ALMA are essential to understand the physical nature of the BLAST sources.

Devlin, Mark↗

NASA's Far-Infrared/Submillimeter Roadmap Missions

Information vital to the attainment of the major scientific objectives of NASA s Origins and Structure and Evolution of the Universe themes is uniquely available in the far-IR and submillimeter (FIR/SMM). NASA is studying concepts and investing in technologies for FIF/SMM telescopes that could fly in the decade 201 0 - 2020 and provide enormous increases in measurement capabilities to extend the legacy of the next-generation missions SlRTF and Herschel. Future FIR/SMM space observatories will have the sensitivity needed to reach back in time to the formation epoch of the first luminous objects, the angular resolution needed to image proto-planetary systems and distinguish the emissions of individual galaxies, and the spectral resolution needed to probe the physical conditions and measure the flows of interstellar gas in young galaxies, nascent stars, and the dust-enshrouded nuclei of galaxies that harbor massive black holes. NASA s infrared roadmap includes the JWST-class Single Aperture Far-IR (SAFIR) telescope and FIR/SMM interferometers. The talk will give the scientific motivation for these missions, describe mission concepts and telescope measurement capabilities, and compare these capabilities with those of the next-generation IR telescopes and with the complementary JWST and ALMA.

Leisawitz, David↗

NASA's Far-Infrared/Submillimeter Roadmap Missions

Information vital to the attainment of the major scientific objectives of NASA's Origins and Structure and Evolution of the Universe themes is uniquely available in the far-IR and submillimeter (FIR/SMM). NASA is studying concepts and investing in technologies for FIR/SMM telescopes that could fly in the decade 2010 - 2020 and provide enormous increases in measurement capabilities to extend the legacy of the next-generation missions SIRTF and Herschel. Future FIR/SMM space observatories will have the sensitivity needed to reach back in time to the formation epoch of the first luminous objects, the angular resolution needed to image proto-planetary systems and distinguish the emissions of individual galaxies, and the spectral resolution needed to probe the physical conditions and measure the flows of interstellar gas in young galaxies, nascent stars, and the dust-enshrouded nuclei of galaxies that harbor massive black holes. NASA's infrared roadmap includes the JWST-class Single Aperture Far-IR (SAFIR) telescope and FIR/SMM interferometers. The talk will give the scientific motivation for these missions, describe mission concepts and telescope measurement capabilities, and compare these capabilities with those of the next-generation IR telescopes and with the complementary JWST and ALMA.

Leisawitz, David↗

Prebiotic Soup: Revisiting the Miller Experiment

Isn't life wonderful? sang Alma Cogan and Les Howard in their almost forgotten 1953 hit. That same year, Stanley L. Miller raised the hopes of understanding the origin of life when on 15 May, Science published his paper on the synthesis of amino acids under conditions that simulated primitive Earth's atmosphere. Miller had applied an electric discharge to a mixture of CH4, NH3, H2O, and H2 - believed at the time to be the atmospheric composition of early Earth. Surprisingly, the products were not a random mixture of organic molecules. but rather a relatively small number of biochemically significant compounds such as amino acids, hydroxy acids, and urea. With the publication of these dramatic results, the modern era in the study of the origin of life began.

Bada, Jeffrey L.↗

Influence of Coronal Abundance Variations

The PI of this project was Jeff Scargle of NASA/Ames. Co-I's were Alma Connors of Eureka Scientific/Wellesley, and myself. Part of the work was subcontracted to Eureka Scientific via SAO, with Vinay Kashyap as PI. This project was originally assigned grant number NCC2-1206, and was later changed to NCC2-1350 for administrative reasons. The goal of the project was to obtain, derive, and develop statistical and data analysis tools that would be of use in the analyses of high-resolution, high-sensitivity data that are becoming available with new instruments. This is envisioned as a cross-disciplinary effort with a number of "collaborators" including some at SA0 (Aneta Siemiginowska, Peter Freeman) and at the Harvard Statistics department (David van Dyk, Rostislav Protassov, Xiao-li Meng, Epaminondas Sourlas, et al). We have developed a new tool to reliably measure the metallicities of thermal plasma. It is unfeasible to obtain high-resolution grating spectra for most stars, and one must make the best possible determination based on lower-resolution, CCD-type spectra. It has been noticed that most analyses of such spectra have resulted in measured metallicities that were significantly lower than when compared with analyses of high- resolution grating data where available (see, e.g., Brickhouse et al., 2000, ApJ 530,387). Such results have led to the proposal of the existence of so-called Metal Abundance Deficient, or "MAD" stars (e.g., Drake, J.J., 1996, Cool Stars 9, ASP Conf.Ser. 109, 203). We however find that much of these analyses may be systematically underestimating the metallicities, and using a newly developed method to correctly treat the low-counts regime at the high-energy tail of the stellar spectra (van Dyk et al. 2001, ApJ 548,224), have found that the metallicities of these stars are generally comparable to their photospheric values. The results were reported at the AAS (Sourlas, Yu, van Dyk, Kashyap, and Drake, 2000, BAAS 196, v32, #54.02), and at the conference on Statistical Challenges in Modem Astronomy (Sourlas, van Dyk, Kashyap, Drake, and Pease, 2003, SCMA 111, Eds. E.D.Feigelson, G.J.Babu, New York:Springer, p489-490). We also described the limitations of one of the most egregiously misused and misapplied statistical tests in astrophysical literature, the F-test for verifying model components (Protassov, van Dyk, Connors, Kashyap, and Siemiginowska, 2002, ApJ, 571,545). Indeed, a search through the ApJ archives turned up 170 papers in the 5 previous years that used the F-test explicitly in some form or the other, and with the vast majority of them not using it correctly! Indeed, looking at just 4 issues of the ApJ in 2001, we found 13 instances of its use, of which nine were demonstrably incorrect. Clearly, it is difficult to understate the importance of this issue. We also worked on speeding up Bayes Blocks and Sparse Bayes Blocks algorithms to make them more tractable for large searches. We also supported staistics students and postdocs in both explicit physics- model-based (spectra with tens of thousands of atomic lines) and "model-free" -- i.e. non-parametric or semi-parametric -- algorithms. Work on using more of the latter is just beginning; while using multi-scale methods for Poisson imaging has come to hition. In fact, "An Image Restoration Technique with Error Estimates", by D. Esch, A. Connors, M. Karovska, and D. van Dyk, was published by ApJ (Esch et a1.2004, ApJ, 610, 1213). The code has been delivered to M. Karovska for CXC; and is available for beta-testing upon request. The other large project we worked on was on the self-consistent modeling of logN-logs curves in the Poisson limit. logN-logs curves are a fundamental tool in the study of source populations, luminosity functions, and cosmological parameters. However, their determination is hampered by statistical effects such as the Eddington bias, incompleteness due to detection efficiency, faint source flux fluctuations, etc. We have develed a new and powerful method using the full Poisson machinery that allows us to model the logN-logs distribution of X-ray sources in a self-consistent manner. Because we properly account for all the above statistical effects, our modeling is valid over the full range of the data, and not just for strong sources, as is normally done. Using a Bayesian approach and modeling the fluxes with known functional forms such as simple or broken power-laws, and conditioning the expected photon counts on the fluxes, the background contamination, effective area, detector vignetting, and detection probability, we can delve deeply into the low counts regime and extend the usefulness of medium sensitivity surveys such as ChAMP by orders of magnitude. The built-in flexibility of the algorithm also allows a simultaneous analysis of multiple datasets. We have applied this analysis to a set a Chandra observations (Sourlas, Kashyap, Zezas, van Dyk, 2004, HEAD #8, #16.32)

Scargle, Jeffrey D.↗

Thermal design trades for SAFIR architecture concepts

SAFIR is a IO-meter, 4 K space telescope optimized for wavelengths between 20 microns and 1 mm. The combination of aperture diameter and telescope temperature will provide a raw sensitivity improvement of more than a factor of 1000 over presently-planned missions. The sensitivity will be comparable to that of the JWST and ALMA, but at the critical far-IR wavelengths where much of the universe's radiative energy has emerged since the origin of stars and galaxies. We examine several of the critical technologies for SAFIR which enable the large cold aperture, and present results of studies examining the telescope optics and the spacecraft thermal architecture. Both the method by which the aperture is filled, and the overall optical design for the telescope can impact the potential scientific return of SAFIR. Thermal architecture that goes far beyond the sunshades developed for the James Webb Space Telescope will be necessary to achieve the desired sensitivity of SAFIR. By combining active and passive cooling at critical points within the observatory, a significant reduction of the required level of active cooling can be obtained.

infrared telescopes↗

The Gaseous Disks of Young Stellar Objects

Disks represent a crucial stage in the formation of stars and planets. They are novel astrophysical systems with attributes intermediate between the interstellar medium and stars. Their physical properties are inhomogeneous and are affected by hard stellar radiation and by dynamical evolution. Observing disk structure is difficult because of the small sizes, ranging from as little as 0.05 AU at the inner edge to 100-1000 AU at large radial distances. Nonetheless, substantial progress has been made by observing the radiation emitted by the dust from near infrared to mm wavelengths, i.e., the spectral energy distribution of an unresolved disk. Many fewer results are available for the gas, which is the main mass component of disks over much of their lifetime. The inner disk gas of young stellar objects (henceforth YSOs) have been studied using the near infrared rovibrational transitions of CO and a few other molecules, while the outer regions have been explored with the mm and sub-mm lines of CO and other species. Further progress can be expected in understanding the physical properties of disks from observations with sub-mm arrays like SMA, CARMA and ALMA, with mid infrared measurements using Spitzer, and near infrared spectroscopy with large ground-based telescopes. Intense efforts are also being made to model the observations using complex thermal-chemical models. After a brief review of the existing observations and modeling results, some of the weaknesses of the models will be discussed, including the absence of good laboratory and theoretical calculations for essential microscopic processes.

Glassgold, A. E.↗