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At least 163 records · Page 9

Effects of nonmethane hydrocarbons in the atmosphere

An investigation was conducted to determine whether nonmethane hydrocarbons (NMHC) are abundant enough to have a significant impact upon the ambient photochemistry. The vertical distribution of C2H6, C2H2, C3H8, C4H10, and C5H12 in the altitude range from 0 to 40 km was calculated in this connection. A one-dimensional steady state model with coupled photochemistry and vertical transport was employed in the investigation. The calculations imply that measurable quantities of relatively unreactive NMHC, especially C2H6 and C2H2, may be present in the upper troposphere and stratosphere. The results indicate, however, that NMHC are not likely to have a large impact on the background photochemistry of the troposphere, although local effects near source regions are probable. The findings support the current practice of many modelers who neglect NMHC in their calculations.

Chameides, W. L.↗

Stability of the Io plasma torus/atmosphere interaction

The stability of the Io plasma torus-atmosphere interaction is examined. A simple plasma deflection model describes how transients in the plasma flux and the content of the atmosphere affect the ionospheric conductance, limiting the plasma bombardment and, hence, the supply of atmospheric species to the torus. The supply of the torus is seen to be determined by the thermal structure of the plasma, namely, the amount of low energy plasma producing atmospheric erosion vs. that which produces ionization, so that the torus supply rate is not simply proportional to the torus ion density.

Johnson, R. E.↗

Atmospheric, climatic and environmental research

Research conducted during the past year in the climate and atmospheric modeling programs was focused on the development of appropriate atmospheric and upper ocean models, and preliminary applications of these models. Prinicpal models are a one-dimensional radiative-convection model, a three-dimensional global climate model, and an upper ocean model. Principal application is the study of the impact of CO2, aerosols and the solar constant on climate. Also the performance of the International Satellite Cloud Climatology Project cloud detection algorithm was evaluated, concentrating initially on its application to geosynchronous data, with an eventual switch of the developed methodologies to data from polar orbiting satellites. In the process, a number of improvements were made, in particular: an improved technique for tracking small scale day to day variability in clear sky continental temperatures; a number of techniques for the statistical assessment of cloud detection uncertainties due to cloud types which are spatially and temporally invariant; and a method used to detect those cloudy regions which have long term spatial and temporal stability.

Broecker, W. S.↗

Survey and Modeling of Windblown Ejecta Deposits on Venus

Venus' thick atmosphere rotates in the same direction as the solid body, but ∼60 times faster. This atmospheric superrotation has produced dozens of windblown ejecta deposits (“parabolas”) on the surface of Venus. The formation and modification of parabolas is an interplay between impacts, aeolian modification, and atmospheric dynamics. We conducted a survey to explore the nature of these sedimentary surface features. First, we observe trends in parabolas' morphology that shed light on how they are deposited and gradated. Changes in the size and radar albedo of parabolas are likely linked to the height and density (respectively) of ejecta plumes at time of formation. Next, we discovered that parabolas show orientations inconsistent with present atmospheric dynamics. This discrepancy may record a change in these dynamics or geologically recent true polar wander at a rate of ∼1° Myr −1 , which is similar to that observed on Earth over the past century. These results highlight how overlapping observations at different radar wavelengths provide important insights into the history and character of geologic processes on Venus. Overall, atmospheric superrotation has probably persisted for at least the age of Venus' surface.

Venus↗

Heterogeneous photocatalytic oxidation of atmospheric trace contaminants

Research was conducted on: (1) design and construction of a continuous flow photoreactor to study oxidation of trace atmospheric contaminants; (2) kinetics of acetone oxidation including adsorption equilibrium, variation of oxidatiin rate with acetone concentration and water, and variation of rate and apparent quantum yield with light intensity, and (3) kinetics of butanol oxidation, including rate variations; and (4) kinetics of catalyst deactivation including deactivation rate, influence of dark conditions, and photocatalytic regeneration in alcohol-free air.

Ollis, David F.↗

Observations of surface energy fluxes and meteorology in the seasonally snow-covered high-elevation East River watershed during SPLASH, 2021–2023

Abstract. From autumn 2021 through summer 2023, scientists from the National Oceanic and Atmospheric Administration (NOAA) and partners conducted the Study of Precipitation, the Lower Atmosphere, and Surface for Hydrometeorology (SPLASH) campaign in the East River watershed of Colorado. One objective of SPLASH was to observe the transfer of energy between the atmosphere and the surface, which was done at several locations. Two remote sites were chosen that did not have access to power utilities. These were along the valley floor near the East River in the vicinity of the unincorporated town of Gothic, Colorado. Energy balance measurements were made at these locations using autonomous, single-level flux towers referred to as atmospheric surface flux stations (ASFSs). The ASFSs were deployed on 28 September 2021 at the Kettle Ponds Annex site and on 12 October 2021 at the Avery Picnic site and operated until 19 July and 21 June 2023, respectively. Measurements included basic meteorology; upward and downward longwave and shortwave radiative fluxes and subsurface conductive flux, each at 1 min resolution; 3-D winds from a sonic anemometer and H2O/CO2 from an open-path gas analyzer, both at 20 Hz from which sensible, latent heat, and CO2 fluxes were derived; and profiles of soil properties in the upper 0.5 m (both sites) and temperature profiles through the snow (at Avery Picnic), each reported between 10 min and 6 h. The system uptime was 97 % (Kettle Ponds) and 90 % (Avery Picnic), and collectively 1184 d of data was obtained between the stations. The purpose of this article is to document the ASFS deployment at SPLASH, to document the data acquisition and post-processing of measurements, and to serve as a guide for interested users of the data sets, which are archived at Zenodo (https://doi.org/10.5281/zenodo.10313363, Cox et al., 2023b; https://doi.org/10.5281/zenodo.10327409, Cox et al., 2023c; https://doi.org/10.5281/zenodo.10313894, Cox et al., 2023d; https://doi.org/10.5281/zenodo.10307825, Cox et al., 2023e; https://doi.org/10.5281/zenodo.10310520, Cox et al., 2023f) with the Creative Commons Attribution 4.0 International license.

Cox, Christopher J. (ORCID:0000000322037173)↗

Microgravity nucleation and particle coagulation experiments support

A hollow sphere model is developed to predict the range of supersaturation ratio values for refractory metal vapors in a proposed experimental nucleation apparatus. Since the experiments are to be carried out in a microgravity environment, the model neglects the effects of convection and assumes that the only transfer of vapors through an inert gas atmosphere is by conduction and molecular diffusion. A consistent set of physical properties data is assembled for the various candidate metals and inert ambient gases expected to be used in the nucleation experiments. Transient partial pressure profiles are computed for the diffusing refractory species for two possible temperature distributions. The supersaturation ratio values from both candidate temperature profiles are compared with previously obtained experimetnal data on a silver-hydrogen system. The model is used to simulate the diffusion of magnesium vapor through argon and other inert gas atmospheres over ranges of initial and boundary conditions. These results identify different combinations of design and operating parameters which are liekly to produce supersaturation ratio values high enough to induce homogeneous nucleation in the apparatus being designed for the microgravity nucleation experiments.

Lilleleht, L. U.↗

Workshop on Oxygen in the Terrestrial Planets

This volume contains abstracts that have been accepted for presentation at the Workshop on Oxygen in the Terrestrial Planets, July 20-23,2004, Santa Fe, New Mexico. The contents include: 1) Experimental Constraints on Oxygen and Other Light Element Partitioning During Planetary Core Formation; 2) In Situ Determination of Fe(3+)/SigmaFe of Spinels by Electron Microprobe: An Evaluation of the Flank Method; 3) The Effect of Oxygen Fugacity on Large-Strain Deformation and Recrystallization of Olivine; 4) Plagioclase-Liquid Trace Element Oxygen Barometry and Oxygen Behaviour in Closed and Open System Magmatic Processes; 5) Core Formation in the Earth: Constraints from Ni and Co; 6) Oxygen Isotopic Compositions of the Terrestrial Planets; 7) The Effect of Oxygen Fugacity on Electrical Conduction of Olivine and Implications for Earth s Mantle; 8) Redox Chemical Diffusion in Silicate Melts: The Impact of the Semiconductor Condition; 9) Ultra-High Temperature Effects in Earth s Magma Ocean: Pt and W Partitioning; 10) Terrestrial Oxygen and Hydrogen Isotope Variations: Primordial Values, Systematics, Subsolidus Effects, Planetary Comparisons, and the Role of Water; 11) Redox State of the Moon s Interior; 12) How did the Terrestrial Planets Acquire Their Water?; 13) Molecular Oxygen Mixing Ratio and Its Seasonal Variability in the Martian Atmosphere; 14) Exchange Between the Atmosphere and the Regolith of Mars: Discussion of Oxygen and Sulfur Isotope Evidence; 15) Oxygen and Hydrogen Isotope Systematics of Atmospheric Water Vapor and Meteoric Waters: Evidence from North Texas; 16) Implications of Isotopic and Redox Heterogeneities in Silicate Reservoirs on Mars; 17) Oxygen Isotopic Variation of the Terrestrial Planets; 18) Redox Exchanges in Hydrous Magma; 19) Hydrothermal Systems on Terrestrial Planets: Lessons from Earth; 20) Oxygen in Martian Meteorites: A Review of Results from Mineral Equilibria Oxybarometers; 21) Non-Linear Fractionation of Oxygen Isotopes Implanted in Lunar Metal Grains: Solar, Lunar or Terrestrial Origin? 22) Isotopic Zoning in the Inner Solar System; 23) Redox Conditions on Small Bodies; 24) Determining the Oxygen Fugacity of Lunar Pyroclastic Glasses Using Vanadium Valence - An Update; 25) Mantle Redox Evolution and the Rise of Atmospheric O2; 26) Variation of Kd for Fe-Mg Exchange Between Olivine and Melt for Compositions Ranging from Alkaline Basalt to Rhyolite; 27) Determining the Partial Pressure of Oxygen (PO,) in Solutions on Mars; 28) The Influence of Oxygen Environment on Kinetic Properties of Silicate Rocks and Minerals; 29) Redox Evolution of Magmatic Systems; 30) The Constancy of Upper Mantlefo, Through Time Inferred from V/Sc Ratios in Basalts: Implications for the Rise in Atmospheric 0 2; 31) Nitrogen Solubility in Basaltic Melt. Effects of Oxygen Fugacity, Melt Composition and Gas Speciation; 32) Oxygen Isotope Anomalies in the Atmospheres of Earth and Mars; 33) The Effect of Oxygen Fugacity on Interdiffusion of Iron and Magnesium in Magnesiowiistite 34) The Calibration of the Pyroxene Eu-Oxybarometer for the Martian Meteorites; 35) The Europium Oxybarometer: Power and Pitfalls; 36) Oxygen Fugacity of the Martian Mantle from PigeoniteMelt Partitioning of Samarium, Europium and Gadolinium; 37) Oxidation-Reduction Processes on the Moon: Experimental Verification of Graphite Oxidation in the Apollo 17 Orange Glasses; 38) Oxygen and Core Formation in the Earth; 39) Geologic Record of the Atmospheric Sulfur Chemistry Before the Oxygenation of the Early Earth s Atmosphere; 40) Comparative Planetary Mineralogy: V/(CrCAl) Systematics in Chromite as an Indicator of Relative Oxygen Fugacity; 41) How Well do Sulfur Isotopes Constrain Oxygen Abundance in the Ancient Atmospheres? 42) Experimental Constraints on the Oxygen Isotope (O-18/ O-16) Fractionation in the Ice vapor and Adsorbant vapor Systems of CO2 at Conditions Relevant to the Surface of Mars; 43) Micro-XANES Measurements on Experimental Spinels andhe Oxidation State of Vanadium in Spinel-Melt Pairs; 44) Testing the Magma Ocean Hypothesis Using Metal-Silicate Partitioning of Te, Se and S; 45) Solubility of Oxygen in Liquid Iron at High Pressure and Consequences for the Early Differentiation of Earth and Mars Metallic Liquid Segregation in Planetesimals; 46) Oxygen Fugacity of Lunar Basalts and the Lunar Mantle. Range of fo2 and the Effectiveness of Oxybarometers; 47) Thermodynamic Study of Dissociation Processes of Molecular Oxygen in Vapor over Oxide Compounds; 48) Oxygen Profile of a Thermo-Haliophilic Community in the Badwater Salt Flat; 49) Oxygen Barometry Using Synchrotron MicroXANES of Vanadium; 50) Mass-Independent Isotopic Fractionation of Sulfur from Sulfides in the Huronian Supergroup, Canada; 51) Mass Independent Isotopes and Applications to Planetary Atmospheres; 52) Electrical Conductivity, Oxygen Fugacity, and Mantle Materials; 53) Crustal Evolution and Maturation on Earth: Oxygen Isotope Evidence; 54) The Oxygen Isotope Composition of the Moon: Implications for Planet Formation; 55) Oxygen Isotope Composition of Eucrites and Implications for the Formation of Crust on the HED Parent Body; and 56) The Role of Water in Determining the Oxygen Isotopic Composition of Planets.

Source record↗

Spectral Irradiance Measurements of Simulated Lightning in Planetary Atmospheres

Optical emissions from lightning provide information to estimate the altitude, latitude and longitude of lightning storms, the energy of the discharges, and the production of important trace species such as HCN and C2H2. Knowledge of the spectra of planetary lightning is needed to deduce the total energy dissipated by lightning (and thereby, the production of trace gases) and to help design experiments to detect and track lightning storms. Measurements of the spectral irradiance from approximately 380 to 820 nm are reported for laboratory simulations of lightning in the atmospheres of Venus, Jupiter, and Titan. In our laboratory, laser-induced plasmas (LIP) are used to simulate lightning discharges. This technique avoids contamination of the spectra by elect-ode material and maintains a safe environment while allowing the use of flammable gases, such as hydrogen and methane, found in outer planet atmospheres. The observations were made at I and 5 bars pressure for Venus and Jupiter and at 1 bar for the Titan mixture. At a pressure of one bar, our results show prominent lines from H(sub alpha), H(sub beta), H(sub gamma), and H(sub delta) lines of the Balmer Series of atomic hydrogen, a single line from Helium at 588 nm and strong continuum radiation. At pressures of 5 bars, the H(sub alpha) and H(sub beta) lines are wider, the H(sub gamma), and H(sub delta) lines merge into the continuum because of pressure broadening, and the helium line at 588 nm is no longer visible. The observed spectra of simulated lightning in the venusian atmosphere at 1 and 5 bars shows that the OI multiplet at 777.7 nm dominates the spectra, but weak features due to atomic carbon and singly excited and singly ionized oxygen atoms are also visible. Although lightning has not yet been observed on Titan, it conceivable that some form of lightning discharge could be occurring. Therefore experiments on a Titan atmosphere mixture were conducted. The most prominent features seen in the simulated spectra are the H(sub alpha) at 656 nm. from the dissociation of the methane and two strong features at 740 and 820 nm from singly excited nitrogen atoms. Most of the features between 400 and 656 nm are due to ionized nitrogen atoms. A broad, highly structured feature centered near 389 nm is molecular band radiation from CN molecules formed in the cooling plasma of atomic nitrogen, carbon, and hydrogen. It is observed in the lightning simulations of both the venusian and Titan atmospheres, For Venus, Jupiter, and Titan, narrow spectral features that are ideal for detecting lightning in the presence of sunlight are present in the spectra. These features could allow lightning to be detected and tracked by Earth-based instruments.

Borucki, W. J.↗

A Liquefier for Mars Surface Propellant Production

NASA's planned Mars exploration missions will require that cryogenic propellants be manufactured on the surface. The present scenario calls for oxygen and methane gases to he produced using the carbon dioxide atmosphere plus seed hydrogen brought from Earth. Gases will require liquefaction for both storage on the Martian surface and for use in the ascent vehicle. The planned liquefaction rates range from 12.6 g/hr of oxygen for the 2003 robotic mission to 2500 g/hr for the later human missions. This paper presents the results of a nitrogen liquefaction demonstration using a commercially available cryocooler. The experiment was set up to liquefy nitrogen gas instead of oxygen to limit laboratory safety concerns. A nitrogen gas condensor, attached to the cooler's cold tip, was sized to liquefy up to 42 gN2/hr at the intended storage pressure (0.2 MPa). The experiment was conducted inside an atmospheric, air-filled, refrigerated chamber simulating the average Martian daytime temperature (240 K). In this demonstration a liquefaction rate of 9.1 gN2/hr was realized, which is equivalent to 13 gO2/hr.

Salerno, Lou J.↗

Selection of fluorescence lidar operating parameters for SNR maximization

Fluorescence lidar when applicable offers one of the most sensitive methods for measuring the concentration of trace constituents of the atmosphere. In the conduct of a fluorescence lidar experiment, a number of parameters which can be used to optimize the SNR can be controlled. In this paper the optimum division of laser pulses centered on and off the fluorescence excitation wavelength is calculated as a function of the ratio of the fluorescence signal strength to the strength of fluorescence from interfering species. For strong interference signals the time should be divided equally on and off the line. For strong fluorescence signals the time on line is proportional to the square root of the on-line off-line signal ratio. The optimization of the integration time for varying values of signal-to-background and signal-to-interference ratios, atmospheric attenuation, laser energy variations, background measurement time, and on-line off-line time division is also considered.

Heaps, W. S.↗

Verification by Viking landers of earlier radio occultation measurements of surface atmospheric pressure on Mars

The landing of Viking 1 in Chryse Planitia on July 20, 1976 provided the first opportunity to obtain measurements of atmospheric pressure directly from the surface of Mars. A computation was conducted to predict the atmospheric pressure at the landing site before the landing itself. The relative altitude between occultation points and the Viking 1 site was obtained with the aid of earth-based planetary radar data taken in 1967. The data cover Martian latitudes from 19 deg N to 24 deg N. The investigation indicates that the radio occultation results from Mariner 9 closely correspond to the actual surface pressure on Mars.

Kliore, A. J.↗

The heating of a thermally conducting stratified medium. II - A simple plane model of an atmosphere

Exact solutions of the following theoretical problem are presented: A plane atmosphere is in hydrostatic equilibrium with a uniform gravity. The ideal gas law is assumed. Heat is generated everywhere at a rate proportional to the local density. The atmosphere is maintained in a steady state through cooling by thermal conduction and radiation. This problem is reducible to quadratures for a thermal conductivity which is an arbitrary, but prescribed, function of the temperature, and for a radiative loss which is expressible as the product of the density and an arbitrary, but prescribed, function of the pressure. The analysis is carried out for the case of power law thermal conductivity, and a radiative loss proportional to the square of the density and to the first power of the temperature. The radiative cooling function adopted here has the basic mathematical form for an optically thin medium. The solutions reproduce the macroscopic ordering of a hot 'corona' separated from a 'photosphere' by a layer of temperature minimum. The analytic solutions allow direct illustration of the interplay between steady energy transport and the requirements of hydrostatic equilibrium.

Lerche, I.↗

Large Eddy Simulation of Aircraft Wake Vortices in a Homogeneous Atmospheric Turbulence: Vortex Decay and Descent

The effects of ambient turbulence on decay and descent of aircraft wake vortices are studied using a validated, three-dimensional: large-eddy simulation model. Numerical simulations are performed in order to isolate the effect of ambient turbulence on the wake vortex decay rate within a neutrally-stratified atmosphere. Simulations are conducted for a range of turbulence intensities, by injecting wake vortex pairs into an approximately homogeneous and isotropic turbulence field. The decay rate of the vortex circulation increases clearly with increasing ambient turbulence level, which is consistent with field observations. Based on the results from the numerical simulations, simple decay models are proposed as functions of dimensionless ambient turbulence intensity (eta) and dimensionless time (T) for the circulation averaged over a range of radial distances. With good agreement with the numerical results, a Gaussian type of vortex decay model is proposed for weak turbulence: while an exponential type of Tortex decay model can be applied for strong turbulence. A relationship for the vortex descent based on above vortex decay model is also proposed. Although the proposed models are based on simulations assuming neutral stratification, the model predictions are compared to Lidar vortex measurements observed during stable, neutral, and unstable atmospheric conditions. In the neutral and unstable atmosphere, the model predictions appear to be in reasonable agreement with the observational data, while in the stably-stratified atmosphere, they largely underestimate the observed circulation decay with consistent overestimation of the observed vortex descent. The underestimation of vortex decay during stably-stratified conditions suggests that stratification has an important influence on vortex decay when ambient levels of turbulence are weak.

Han, Jongil↗

Investigations of Mechanisms Associated with Nucleate Boiling Under Microgravity Conditions

In this work a building block type of approach is used so that a basic understanding of the processes that contribute to nucleate boiling heat fluxes under microgravity conditions can be developed. This understanding will lead to development of a mechanistic model for nucleate boiling heat transfer which could eventually be used as a design tool in space applications. Task Description Task 1: Fabrication of the Experimental Setup. Under this task, the test section and liquid holding and viewing chambers will be fabricated. Artificial cylinder cavities will be formed on silicon wafers. A single cavity and two or four cavities, with a prescribed spacing and size, will be formed. The desired nucleation wall superheat will be used to determine the size of the mouth of the cavities. Task 2: Experiments. The basic experiments for flow and temperature field around single and multiple (2 or 4 separated or merged bubbles growing on downward facing or inclined surfaces) will be carried out under normal gravity conditions. The experiments will be conducted at one atmosphere pressure, but liquid subcooling will be varied from 0 to 30C. Water and PF-5050 will be used as test liquids. Task 3: Analytical/Numerical Models. In this task, transient temperature and flow field in vapor and liquid will be determined during growth of a single bubble. Analysis will include the evolution of the vapor-liquid interface and development of microlayer underneath the bubbles. For merged bubbles, detailed calculations of flow and temperature field will be carried out for transient shapes of vapor stems supporting a large bubble and the corresponding evaporation rate. Flow and temperature field for a bubble sliding along a heated wall will also be determined. Microgravity conditions will be simulated and a framework of a numerical tool for prediction of nucleate boiling heat fluxes under microgravity conditions will be developed. Task 4: Experiments in a KC-135. To understand bubble growth and detachment behavior of single or large merged bubbles, boiling experiments will be conducted under low gravity (10-2 g) conditions of the aircraft. In these experiments, 'designed' surfaces will be used. Visual observations and heat transfer data will be taken, but holography will not be used. The apparatus used for laboratory experiments will also be employed for experiments in the aircraft. Task 5: Experiments in the Space Shuttle. Effort will be devoted for defining a boiling experiment to be conducted on a 'designed' surface. The experiment will provide microgravity data on bubble growth and departure. These data are needed for development of a credible model for nucleate boiling heat fluxes under microgravity conditions. The heat transfer data will also be obtained and will be used to validate the models.

Dhir, Vijay K.↗

Chemical Imaging of Atmospheric Biomass Burning Particles from North American Wildfires

The effects of biomass burning aerosols (BBA) on radiative forcing and cloud formation depend on chemical composition and the internal structures of individual particles within smoke plumes. To improve our understanding of the chemical and physical properties of BBA emitted at different times of the day and their evolution during atmospheric aging, we conducted a study as a part of the Fire Influence on Regional to Global Environments and Air Quality field campaign. Particle samples were collected onboard a research aircraft from smoke plumes from a wildfire in eastern Oregon during late afternoon and nighttime flights on August 28, 2019. A time-resolved aerosol collector was used to collect samples on substrates for offline spectromicroscopic imaging to investigate the single-particle characteristics of BBA particles. Approximately 20,400 individual particles from 10 selected samples were analyzed using computer-controlled scanning electron microscopy coupled with energy-dispersive X-ray microanalysis, revealing their elemental composition, morphology, and viscosity. Elemental microanalysis indicated that aged potassium is likely found in the form of K 2 SO 4 , KNO 3 , and possible K-organic salts. Further chemical speciation and carbon bonding mapping within individual particles were conducted using synchrotron-based scanning transmission X-ray microscopy (STXM) coupled with near edge X-ray absorption fine structure (NEXAFS) spectroscopy. Real-time, water-soluble light absorption measurements were acquired using a particle-into-liquid sampler instrument coupled to a liquid waveguide capillary cell and total organic analyzer. In the late afternoon samples, 65% of the total particle number population consisted entirely of organic components, compared to 46% in the nighttime particles. These differences were attributed to discrepancies in composition at the time of emission and to the daytime condensation and accumulation of photochemically formed secondary organic material on existing BBA particles, a process that halts at night. Microscopy images indicated that particle viscosity was lower in the nighttime particles (<10 1 Pa·s), likely due to increased relative humidity and a higher contribution from hygroscopic inorganic components. The chemical heterogeneity of individual particles was quantified using STXM-derived mixing state parameters. The nature of carbon bonding within individual particles was inferred from the extent of carbon sp 2 hybridization derived from NEXAFS spectra. Average percentages of sp 2 hybridization range between 40% and 60%, with no noticeable differences between late afternoon and nighttime flights. These findings were compared with the online optical properties of both late afternoon and nighttime smoke plumes, providing valuable insights into the complex relationship between chemical composition and optical properties of BBA particles at different times of the day.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Shrub Expansion Simulations at Trail Valley Creek Tundra site using E3SM Land Model (ELM) Arctic-focused Version

The warming of the Arctic is causing substantial compositional, structural, and functional changes in tundra vegetation including shrub and densification in parts of the Arctic. Assessing the impact of these changes in vegetation composition on the Arctic’s carbon and energy budgets is important to constrain projected local and global surface-atmosphere exchanges. We conduct a sensitivity analysis of the projected surface energy fluxes, soil carbon pools, and carbon dioxide fluxes (net ecosystem exchange, gross primary production, and ecosystem respiration) between present day and 2100 to different shrub expansion rates and air temperature increases under future emission scenarios (intermediate – RCP4.5, and high – RCP8.5) using the Arctic-focused version of the Energy Exascale Earth System Model (E3SM) Land Model (ELM). We focus on Trail Valley Creek (TVC), a mineral upland tundra site located in the western Canadian Arctic, which is experiencing tall shrub densification and expansion. In this study, we run TVC under two different warming scenarios RCP4.5 and RCP 8.5 and simulate different shrubification rates projected until year 2100. In this repository, we include all the forcing, input, parameters, and output data corresponding to all the simulations performed. flmd.csv includes a detailed description of the datasets files.

54 ENVIRONMENTAL SCIENCES↗