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NASA NTRS1994

Symmetry breaking in O4(+): An application of the Brueckner coupled-cluster method

A recent calculation of the antisymmetric stretch frequency for the rectangular structure of quartet O4(+) using the singles and doubles quadratic configuration interaction method with a perturbational estimate of connected triple excitations (QCISD(T)) method gave a value of 3710 cm(exp -1). This anomalous frequency is shown to be a consequence of symmetry breaking effects, which occur even though the QCISD(T) solution derived from a delocalized SCF reference function lies energetically well below the two localized (symmetry-broken) solutions at the equilibrium geometry. The symmetry breaking is almost eliminated at the CCSD level of theory, but the small remaining symmetry breaking effects are magnified at the CCSD(T) level of theory so that the antisymmetric stretch frequency is still significantly in error. The use of the Brueckner coupled cluster method, however, leads to a symmetrical solution which is free of symmetry breaking effects, with an antisymmetric stretch frequency of 1322 cm(exp -1), in good agreement with our earlier calculations using the complete active space self consistent field/complete active space state interaction (CASSCF/CASSI) method.

Barnes, Leslie A.↗

NASA NTRSDate not supplied

Distribution and Sources of Tropospheric Aerosols Over the Western North Atlantic During ACTIVATE (February-March 2020)

The Aerosol Cloud meTeorology Interactions oVer the western ATlantic Experiment (ACTIVATE) is a five-year (2019-2023) NASA Earth-Venture Suborbital-3 (EVS-3) mission to robustly characterize aerosol-cloud-meteorology interactions during February-June, with a focus on marine boundary layer clouds. This characterization requires understanding of aerosol composition, distribution, transport pathways, and sources. Here we use the GEOS-Chem chemical transport model driven by the MERRA-2 reanalysis to simulate tropospheric carbon monoxide (CO) and aerosols over the western North Atlantic Ocean (WNAO) during the first field deployment of ACTIVATE (February-March 2020). CO is used as a tracer to diagnose transport pathways for continental pollution outflow to the WNAO. The aerosol simulation represents all major aerosols including sulfate-nitrate-ammonium (SNA), mineral dust, sea salt, black and organic carbon aerosols. Model-simulated mixing ratios of SNA and organic carbon are compared with aircraft observations. We show that intensive aerosol mass measurements in the lower troposphere over the North American outflow region during ACTIVATE provide strong constraints on model aerosol wet scavenging. Comparisons of model aerosol extinctions with the airborne High Spectral Resolution Lidar-2 (HSRL-2) measurements indicate that the model generally captures continental outflow of aerosols and enhanced extinctions associated with sea salt. Simulated aerosol optical depths (AODs) and extinction vertical profiles are also compared with satellite retrievals from MODIS/Aqua and CALIOP/CALIPSO, respectively. CALIOP sometimes observes enhanced aerosol extinction at altitudes between ~1.5km and ~2.0km south of 32°N. The model reproduces this enhancement and attributes it to coarse-mode sea salt associated with high relative humidity. The relative contributions of continental and oceanic sources to the aerosol loading, AOD, and their distributions over the study domain will also be discussed.

aerosols↗

NASA NTRS2002

Laboratory for Atmospheres: Philosophy, Organization, Major Activities, and 2001 Highlights

How can we improve our ability to predict the weather? How is the Earth's climate changing? What can the atmospheres of other planets teach us about our own? The Laboratory for Atmospheres is helping to answer these and other scientific questions. The Laboratory conducts a broad theoretical and experimental research program studying all aspects of the atmospheres of the Earth and other planets, including their structural, dynamical, radiative, and chemical properties. Vigorous research is central to NASA's exploration of the frontiers of knowledge. NASA scientists play a key role in conceiving new space missions, providing mission requirements., and carrying out research to explore the behavior of planetary systems, including, notably, the Earth's. Our Laboratory's scientists also supply outside scientists with technical assistance and scientific data to further investigations not immediately addressed by NASA itself. The Laboratory for Atmospheres is a vital participant in NASA's research program. The Laboratory is part of the Earth Sciences Directorate based at NASA's Goddard Space Flight Center in Greenbelt, Maryland. The Directorate itself comprises the Global Change Data Center; the Earth and Space Data Computing Division; three laboratories: the Laboratory for Atmospheres, the Laboratory for Terrestrial Physics, and the Laboratory for Hydrospheric Processes; and the Goddard Institute for Space Studies (GISS) in New York, New York. In this report, you will find a statement of our philosophy and a description of our role in NASA's mission. You'll also find a broad description of our research and a summary of our scientists' major accomplishments in 2001. The report also presents useful information on human resources, scientific interactions, and outreach activities with the outside community. For your convenience, we have published a version of this report on the Internet. Our Web site includes links to additional information about the Laboratory's Offices and Branches. You can find us on the World Wide Web at http://atmospheres.gsfc.nasa.gov.

Hoegy, Walter R.↗

NASA NTRS2001

Interaction between vestibulosympathetic and skeletal muscle reflexes on sympathetic activity in humans

Evidence from animals indicates that skeletal muscle afferents activate the vestibular nuclei and that both vestibular and skeletal muscle afferents have inputs to the ventrolateral medulla. The purpose of the present study was to investigate the interaction between the vestibulosympathetic and skeletal muscle reflexes on muscle sympathetic nerve activity (MSNA) and arterial pressure in humans. MSNA, arterial pressure, and heart rate were measured in 17 healthy subjects in the prone position during three experimental trials. The three trials were 2 min of 1) head-down rotation (HDR) to engage the vestibulosympathetic reflex, 2) isometric handgrip (IHG) at 30% maximal voluntary contraction to activate skeletal muscle afferents, and 3) HDR and IHG performed simultaneously. The order of the three trials was randomized. HDR and IHG performed alone increased total MSNA by 46 +/- 16 and 77 +/- 24 units, respectively (P < 0.01). During the HDR plus IHG trial, MSNA increased 142 +/- 38 units (P < 0.01). This increase was not significantly different from the sum of the individual trials (130 +/- 41 units). This finding was also observed with mean arterial pressure (sum = 21 +/- 2 mmHg and HDR + IHG = 22 +/- 2 mmHg). These findings suggest that there is an additive interaction for MSNA and arterial pressure when the vestibulosympathetic and skeletal muscle reflexes are engaged simultaneously in humans. Therefore, no central modulation exists between these two reflexes with regard to MSNA output in humans.

NASA Discipline Neuroscience↗

NASA NTRS1972

Orbital operations study. Executive summary

A summary of the analyses of the orbital operations study is presented. Objectives, scope of study, and technical documentation format are discussed. A summary of the mission analyses including generic mission models, element pair interactions, and interfacing activities are presented. The analyses associated with each interfacing activity are also summarized. Significant implications derived during the course of the study on the EOS orbiter, space tug, RAM, and MSS are indicated.

Hogan, L. R.↗

NASA NTRS1972

Earthquake epicenters and fault intersections in central and southern California

The author has identifed the following significant results. ERTS-1 imagery provided evidence for the existence of short transverse fault segments lodged between faults of the San Andreas system in the Coast Ranges, California. They indicate that an early episode of transverse shear has affected the Coast Ranges prior to the establishment of the present San Andreas fault. The fault has been offset by transverse faults of the Transverse Ranges. It appears feasible to identify from ERTS-1 imagery geomorphic criteria of recent fault movements. Plots of historic earthquakes in the Coast Ranges and western Transverse Ranges show clusters in areas where structures are complicated by interaction of tow active fault systems. A fault lineament apparently not previously mapped was identified in the Uinta Mountains, Utah. Part of the lineament show evidence of recent faulting which corresponds to a moderate earthquake cluster.

Abdel-Gawad, M.↗

NASA NTRS1973

Automatic vehicle location system

An automatic vehicle detection system is disclosed, in which each vehicle whose location is to be detected carries active means which interact with passive elements at each location to be identified. The passive elements comprise a plurality of passive loops arranged in a sequence along the travel direction. Each of the loops is tuned to a chosen frequency so that the sequence of the frequencies defines the location code. As the vehicle traverses the sequence of the loops as it passes over each loop, signals only at the frequency of the loop being passed over are coupled from a vehicle transmitter to a vehicle receiver. The frequencies of the received signals in the receiver produce outputs which together represent a code of the traversed location. The code location is defined by a painted pattern which reflects light to a vehicle carried detector whose output is used to derive the code defined by the pattern.

Hansen, G. R., Jr.↗

NASA NTRS1976

Proton aurora on Io

The Jovian satellite Io should exhibit substantial auroral activity due to interactions of the satellite's atmosphere with Jovian magnetospheric particles. Plasma sheaths that may form around the satellite will cause substantial proton aurorae on the Jupiter-facing hemisphere and electron aurorae on the outward-facing hemisphere. A sample calculation indicates that Doppler-shifted radiation from high-velocity hydrogen atoms (proton aurora) will be observable from a spacecraft in the vicinity of Jupiter. Emission near Lyman-alpha may be present at a level as much as 100 times that of the solar background reflected from Io's surface.

Pilcher, C. B.↗

NASA NTRS1976

Inflight Rotor Stability Monitor

An inflight rotor stability monitor developed at Sikorsky Aircraft to support stability testing of new rotorcraft is described. The monitor has as its core a damping estimation algorithm which embodies spectral analysis techniques. The interactive system is activated and controlled from a cathode ray tube (CRT) and operates on-line in a flight test telemetry environment. Accurate estimates of the level of damping of critical system modes are generated within one minute of the completion of a prescribed test maneuver. The stability monitor was used successfully to support various Sikorsky research and development flight programs including the UTTAS, CH-53E, S-67 Fan-in-Fin, and ABC.

Kuczynski, W. A.↗

NASA NTRS1976

Proton aurora on Io

The Jovian satellite Io should exhibit substantial auroral activity due to interactions of the satellite's atmosphere with Jovian magnetospheric particles. Plasma sheaths that may form around the satellite will cause substantial proton aurora on the Jupiter-facing hemisphere and electron aurora on the outward-facing hemisphere. A sample calculation indicates that Doppler-shifted radiation from high-velocity hydrogen atoms (proton aurora) will be observable from a spacecraft in the vicinity of Jupiter. Emission near Lyman-alpha may be present at a level as much as 100 times that of the solar background reflected from Io's surface.

Pilcher, C. B.↗

NASA NTRS1977

Assess 2: Spacelab simulation. Executive summary

An Airborne Science/Spacelab Experiments System Simulation (ASSESS II) mission, was conducted with the CV-990 airborne laboratory in May 1977. The project studied the full range of Spacelab-type activities including management interactions, experiment selection and funding, hardware development, payload integration and checkout, mission specialist and payload specialist selection and training, mission control center payload operations control center arrangements and interactions, real time interaction during flight between principal investigators and the flight crew, and retrieval of scientific flight data. ESA established an integration and coordination center for the ESA portion of the payload as planned for Spacelab. A strongly realistic Spacelab mission was conducted on the CV-990 aircraft. U.S. and ESA scientific experiments were integrated into a payload and flown over a 10 day period, with the payload flight crew fully-confined to represent a Spacelab mission. Specific conclusions for Spacelab planning are presented along with a brief explanation of each.

Source record↗

NASA NTRS1983

The future of the U.S. aviation system

The growth of the aviation system of the U.S. over the last twenty years is described. Long-term and short-term causes of air travel are analyzed, showing the interaction of economic activity, airline yields and quality of service. Future trends in general aviation, aircraft technology, and telecommunications are described. Potential future scenarios for the airline industry are presented.

Ausrotas, R. A.↗

NASA NTRS1983

A mechanistic model of Eulerian, Lagrangian mean, and Lagrangian ozone transport by steady planetary waves

Ozone transport is calculated for steady, dissipative planetary waves using the Eulerian, Lagrangian mean, and residual circulation. A Lagrangian model of parcel dynamics is used to interpret planetary wave-photochemistry interaction. In chemically active regions the mean field ozone changes are found to be significant only where there are large gradients in chemical sources and sinks along parcel trajectories. The largest changes in the mean field are found in the lower stratosphere and are due to the Lagrangian mean advection. When the Lagrangian mean advection is approximated by the residual circulation, errors in the transport velocities as large as 30 pct may occur.

Rood, R. B.↗

NASA NTRS1984

Research Review, 1983

The Global Modeling and Simulation Branch (GMSB) of the Laboratory for Atmospheric Sciences (GLAS) is engaged in general circulation modeling studies related to global atmospheric and oceanographic research. The research activities discussed are organized into two disciplines: Global Weather/Observing Systems and Climate/Ocean-Air Interactions. The Global Weather activities are grouped in four areas: (1) Analysis and Forecast Studies, (2) Satellite Observing Systems, (3) Analysis and Model Development, (4) Atmospheric Dynamics and Diagnostic Studies. The GLAS Analysis/Forecast/Retrieval System was applied to both FGGE and post FGGE periods. The resulting analyses have already been used in a large number of theoretical studies of atmospheric dynamics, forecast impact studies and development of new or improved algorithms for the utilization of satellite data. Ocean studies have focused on the analysis of long-term global sea surface temperature data, for use in the study of the response of the atmosphere to sea surface temperature anomalies. Climate research has concentrated on the simulation of global cloudiness, and on the sensitivities of the climate to sea surface temperature and ground wetness anomalies.

Source record↗

NASA NTRS1984

Defect interactions in GaAs single crystals

The two-sublattice structural configuration of GaAs and deviations from stoichiometry render the generation and interaction of electrically active point defects (and point defect complexes) critically important for device applications and very complex. Of the defect-induced energy levels, those lying deep into the energy band are very effective lifetime ""killers". The level 0.82 eV below the condition band, commonly referred to as EL2, is a major deep level, particularly in melt-grown GaAs. This level is associated with an antisite defect complex (AsGa - VAS). Possible mechanisms of its formation and its annihilation were further developed.

Gatos, H. C.↗

NASA NTRS1983

Radio emission from AM Herculis - The quiescent component and an outburst

The VLA has been used to search for radio emission from the AM Her-type binaries VV Pup, EF Eri, PG 1550 + 191, CW 1103 + 354, and AN UMa, at 4.9 GHz. A remarkable 10-min outburst was detected from AM Her at 4.9 GHz, which was about 20 times more intense than the quiescent emission and was essentially 100 percent circularly polarized. It is suggested that the quiescent emission of AM Her can be accounted for by 500-keV electrons trapped in the magnetosphere of the white dwarf, provided that the electron energy spectrum is quite hard and that the spectral hardness or number density of energetic electrons increases with radius, while the outburst is probably due to an electron-cyclotron maser operating near the surface of the red dwarf companion. The implied existence of a 1000-gauss localized magnetic field and a corona on the red dwarf has consequences for mass transfer, field line interactions, and variable activity.

Dulk, G. A.↗

NASA NTRS1985

Gas deficiency in cluster galaxies - A comparison of nine clusters

The available 21 cm line data in the literature for galaxies in nine clusters is combined with new high-sensitivity observations of 51 galaxies in five of the nine clusters in order to test for discriminating circumstances between those clusters which show H I deficiency among their spiral population and those which do not. An H I deficiency for the complete cluster sample is derived employing a comparison sample of galaxies chosen from the Catalog of Isolated Galaxies. The deficiency and its radial dependence is summarized for each cluster and a composite. A comparison of the environments in different clusters leads to the conclusion that the occurrence of H I deficiency is correlated with the presence of a hot X-ray intracluster medium, and that an ongoing interaction process is active through the cores of X-ray clusters.

Giovanelli, R.↗

NASA NTRS1985

Calculated electric dipole moment of NiH X2Delta

A calculated dipole moment of 2.39 D at R sub e = 2.79 a sub 0 is reported, obtained from complete active space SCF/configuration interaction calculations plus one natural orbital iteration. The calculation is in good agreement with the experimental value of 2.4 + or - 0.1 D measured for the lowest vibrational level. In agreement with Gray et al. (1985), it is found that the dipole moment is strongly correlated with the 3d electron population; the good agreement with experiment thus provides verification of the mixed state model of NiH. It is concluded that the electric dipole moment of NiH is a sensitive test of the quality of the NiH wave function.

Walch, S.↗