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At least 163 records · Page 9

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NASA NTRS1973

Optical properties of carbonaceous chondrites and their relationship to asteroids

Results of diffuse reflectance measurements of nine samples of carbonaceous chondrites (one C1, three C2, four C3, and one C4) and one iron meteorite, Odessa. Measurements were also made of mineral mixtures in an attempt to understand the cause of some features of the meteorite reflectances. The C1 and C2 carbonaceous chondrites have reflectances low enough to match the anomalously low albedos of some asteroids. Some asteroids have spectral reflectances similar to carbonaceous chondrites, whereas others with flat or F-type curves appear to match simulated mineral mixtures with slightly greater amounts of the carbonaceous component than those found in the meteorites. This observation suggests either that surface physical processes such as melting may be enhancing the optical effect of opaque carbonaceous material on some asteroid surfaces and/or that these asteroids contain even more carbonaceous material than the C1 meteorites.

Johnson, T. V.↗

NASA NTRS1983

Exospheric cleaning of the Earth Radiation Budget solar radiometer during solar maximum

Anomalous behavior of the Earth Sensor Assemblies (ESA) had been observed on the Defense Meteorological Satellite Program (DMSP) 5D/1 satellites and the Tiros-N satellite. The present investigation is concerned with the reasons for the observed phenomena. Degradation of the Earth Radiation Budget (ERB) solar channels and the Solar Backscatter Ultraviolet and Total Ozone Mapping Spectrometer (SBUV/TOMS) diffuser plate is attributed to transmission or reflection loss originating from the growth of an organic film by photolytic polymerization. Simultaneous degradation of the ESA interference filter coated lenses facing the flight direction and the recovery of the ERB solar channels on Nimbus 6 and 7 is caused by a reaction with the increase in the exospheric atmospheric density caused by solar maximum.

Predmore, R. E.↗

NASA NTRS2017

Anticipated Electrical Environment at Phobos: Nominal and Solar Storm Conditions

A passing coronal mass ejection (CME) will manifest a different response at an airless body compared to a magnetized planet. Specifically,because the regolith-rich surfaces of airless bodies are directly exposed to the variations in the plasma flow, the surfaces are found to undergo anomalous surface charging during the passing of CME fast plasma events. In this study, we model the surface charging expected at Phobos for nominal solar wind conditions and also those associated with disturbed solar wind conditions during the passage of a CME similar to that observed by MAVEN at Mars in early March 2015. We use an ambipolar diffusion model to examine the development of the trailing wake void in the plasma flow behind Phobos and the formation of mini-wakes within obstruction regions like Stickney Crater. We also consider the roving of an astronaut in Stickney Crater for Phobos positioned near 10 hours Local Time relative to Mars. We examine the plasma dissipation of the collected astronaut charge from contact electrification with the regolith.

Phobos; Surface chargin↗

NASA NTRS1974

Radiation pressure and air drag effects on the orbit of the balloon satellite 1963 30D

Computed orbits of the balloon satellite 1963 30D are given every 2 days over an interval of 456 days near the beginning of the satellite's lifetime and an interval of 824 days near the end of its lifetime. The effects of radiation pressure on the satellite are examined in some detail. It is found that the variations in all the elements can be represented by use of a single parameter to specify the effect of diffuse reflection from the satellite's surface, and that this parameter remains constant, or nearly so, during the entire 7-year lifetime. Success in obtaining a consistent representation of the radiation-pressure effects is ascribed to the inclusion of the effects of terrestrial radiation pressure, using a model for the earth's albedo that includes seasonal and latitudinal variations. Anomalous effects in the orbital acceleration, as well as in the other elements, are represented quite well by including a small force at right angle to the solar direction and by allowing this to rotate about the solar direction. This implies that the satellite is aspherical, that it is rotating, and that the axis of rotation precesses.

Slowey, J. W.↗

DOE OSTI2026

Super-Resolved Single-Molecule Tracking Studies of Rhodamine B Accumulation on Fresh and Aged Polyethylene Terephthalate

It is well-known that toxic organic micropollutants (OMs) accumulate on the surfaces of microplastics. However, much remains to be learned about the exact molecular level mechanisms of OM accumulation and how these evolve as the plastics age. In this work, super-resolved single-molecule tracking (SMT) is used for the first time to investigate the accumulation of Rhodamine B (RhB) dye on fresh and artificially aged polyethylene terephthalate (PET) surfaces. PET thin films serve as models for microplastics, while RhB serves as a proxy for the OMs they accumulate. Artificial aging of the films is accomplished by exposing them in a UV-ozone chamber. Water contact angle, spectroscopic ellipsometry, and carbonyl index measurements reveal a gradual decrease in film hydrophobicity, thickness, and carbonyl content with age. Atomic force microscopy (AFM) data reveal an increase in surface roughness and confirm that the films remain largely intact and continuous across the aging times explored. In SMT experiments, wide-field fluorescence videos acquired from the water/PET interface under 7.5 pM RhB reveal both mobile and immobile dye molecules. Measurements of the frame-to-frame displacements of the dye show that diffusion occurs by a desorption-mediated mechanism and that the diffusion rate varies with PET film age. The surface density of mobile dye molecules decreases with increasing PET age, while the population of immobile molecules becomes relatively larger, suggesting an age-dependent transformation of the mechanism(s) by which the dye is accumulated. SMT data reveal that both mobile and immobile molecules repeatedly adsorb over the same surface sites, consistent with the emergence of nanoscale PET surface heterogeneity also revealed by AFM. Estimates of the adsorption coefficients are obtained using a nearest-neighbor analysis, giving values from 9.9 × 10 5 to 2.1 × 10 6 M –1 for immobile molecules and from 1.8 × 10 5 to 2.5 × 10 5 M –1 for mobile molecules on fresh and 5 min aged PET, respectively. Here, anomalous age-dependent variations in the velocity of molecular motion on the PET surface and in the population of immobile molecules are shown to correlate with changes in the strength of RhB adsorption.

Adsorption↗

DOE OSTI2026

Signatures of Thermoreversible Associations in X-ray and Neutron Scattering from Dilute Polyzwitterion Solutions

In aqueous solutions of polyzwitterions (PZs), an interplay between dipole–dipole interactions and hydration of zwitterionic groups can lead to thermoreversible associations, which have been difficult to detect in experiments. Here, in this study, we investigated dilute aqueous solutions of poly(1-(3-sulphonatopropyl)-2-vinylpyridinium) (P2VPPS) using small-angle X-ray and neutron scattering (SAXS and SANS) to probe the structure and neutron spin-echo (NSE) spectroscopy to probe dynamics. The SAXS and SANS data show that the correlation length increases with an increase in the concentration of P2VPPS for three different molecular weights. The addition of 0.1 M NaCl to one of the solutions led to almost no dependence of the correlation length on the concentration. Such a concentration dependence of the correlation length suggests the formation of clusters driven by thermoreversible associations in the solutions. The NSE measurements show that the solutions with a larger correlation length display slower relaxation, reflecting the reduced mobility of larger clusters. These results should be considered as signatures of thermoreversible associations in the solutions of P2VPPS. To establish a quantitative link between local structure (clusters) and dynamics in dilute solutions of P2VPPS, we combined a thermoreversible gelation theory for the structure of PZ solutions (Li, S.-F.; Muthukumar, M. Theory of Thermoreversible Gelation and Anomalous Concentration Fluctuations in Polyzwitterion Solutions. J. Chem. Phys. 2024, 161, 024903) with a model for the dynamics of the clusters (generalized Zimm model), developed in this work. Using such a theoretical framework, we have predicted the distribution of clusters in the solutions probed with SANS and SAXS. With the distributions, the generalized Zimm model has been used to extract the diffusion constant of the clusters and their characteristic size from the NSE data, where the latter agrees with the values estimated from the SAXS/SANS data. These findings confirm the presence of thermoreversible associations and establish a quantitative link between local structure (clusters) and dynamics in dilute solutions of P2VPPS. Furthermore, with growing interest in technological applications, this work can provide useful insights into the structural and dynamical properties of other PZ solutions.

field theory↗

NASA NTRS1979

Grain carriers of isotopic anomalies

The dynamics of grain motion through gas are examined in terms of the injection of isotopically anomalous (compared to solar abundances) material into the early solar nebula. Calculations indicate that the injected grains cannot penetrate to the center of any of a range of reasonable configurations, suggesting the formation of an edge region enriched in injected material. Furthermore, the dynamical behavior of grains in turbulent flows indicates that pockets of grains can have some resistance to turbulent diffusion. The constraints developed here are used to delineate a set of consistent, injected-grain models for the origin of the isotopic anomalies in meteorite inclusions.

Margolis, S. H.↗

NASA NTRS1993

Burn rates of TiH2/KClO4/Viton and output testing of NASA SKD26100098-301 pressure cartridges

The burn rates of the pyrotechnic TiH2/KClO4/Viton with a mass ratio of 30/65/5 have been measured as a function of pressure in nitrogen up to 312 MPa(45 Kpsi). The burn rates were fit to R = a pn, with a = 2.055 cm/sec/MPan and n = 0.472 between 0.15 MPa (22 psi) and 21.6 MPa (3.13 Kpsi) and a = 4.38 cm/sec/MPan and n = 0.266 between 70 MPa (10.15 Kpsi) and 312 MPa (45.25 Kpsi). The decrease in slope at the higher pressures is attributed to a diffusion limited reaction. No acoustically driven flame instabilities or large conductive-to-convective burn transitions were observed. Solid reaction products were analyzed by x-ray diffraction and scanning electron microscopy (SEM). X-ray diffraction detected only TiO2 and KC1. SEM showed that the particle size of the reaction products increased as the nitrogen pressure increased. There were no anomalous characteristics of the burn of this pyrotechnic that could be interpreted as a cause of the o-ring blow-by problem in the forward shear bolt assembly. Three NASA SKD26100098-301 pressure cartridges were fired into a fixed volume vessel that was sealed with an O-ring. A maximum pressure of 181.7 MPa(26,350 psi) was reached in around 100 ,mu sec for two shots fired into a volume of 16.3 cm3(0.996 in3). A maximum pressure of 33,460 psi was reached for one shot fired into a volume of 9.55 cm3(0.583 in3). The O-ring burned through on one shot in the larger volume and leaked on the other two thereby simulating the effects of an O-ring leak. The results imply that the piston in the shear bolt assembly would receive a large impulse even if there was a leak in an O-ring seal.

Holy, John A.↗

NASA NTRS1971

Nuclear processes associated with peculiar A-type stars.

A discussion is given of the various roles that nuclear reactions may play in production of anomalous abundances of elements in peculiar A stars. The effects which may be expected to occur both in the surface nuclear reactions and in some possible internal reactions that can occur in advanced stages of stellar evolution are considered. It is suggested that various features of peculiar A stars may require simultaneous operation of two or more of the processes of surface diffusion, surface nuclear reactions, and internal nuclear reactions.

Cameron, A. G. W.↗

NASA NTRS1973

Evaluation of ERTS data for certain oceanographic uses

The author has identified the following significant results. A significant result was reported 13 July on anomalous dark patches observed in certain ERTS-1 images. This sunglint related feature is possible whenever the solar elevation is greater than 55 deg and the surface waters are calm. It is observed in all MSS bands. Although the bright specular point is nearly 300 nm from nadir no bright specular returns are possible with a 0930 local time descending path-only diffuse glitter, that may reach reflectance levels of 1-2% under wind speeds of 5-10 m/sec and solar elevations greater than 60 deg.

Strong, A. E.↗

NASA NTRS1982

Ion distribution effects of turbulence on a kinetic auroral arc model

An inverted-V auroral arc structure plasma-kinetic model is extended to phenomenologically include the effects of electrostatic turbulence, with k-parallel/k-perpendicular being much less than unity. It is shown that, unless plasma sheet ions are very much more energetic than the electrons, anomalous resistivity is not a large contributor to parallel electrostatic potential drops, since the support of the observed potential drop requires a greater dissipation of energy than can be provided by the plasma sheet. Wave turbulence can, however, be present, with the ion cyclotron turbulence levels suggested by the ion resonance broadening saturation mechanism of Dum and Dupree (1970) being comparable to those observed on auroral field lines. The diffusion coefficient and net growth rate are much smaller than estimates based solely on local plasma properties.

Cornwall, J. M.↗

NASA NTRS1972

Development of a theory of the spectral reflectance of minerals, part 3

Significant refinements were made in the theory of the diffuse reflectance of particulate media. The theory predicts the opposite trends of reflectance with particle size in regions of the spectrum in which the particles are semi-transparent and those in which they are opaque. Enhanced absorption caused by wave-optical effects of small surface asperities and edges was used to improve the theory. The same mechanism remedies the theory to account for the data in spectral regions of anomalous dispersion.

Aronson, J. R.↗

NASA NTRS2012

Multi-Scale Modeling of Magnetospheric Dynamics

Magnetic reconnection is a key element in many phenomena in space plasma, e.g. Coronal mass Ejections, Magnetosphere substorms. One of the major challenges in modeling the dynamics of large-scale systems involving magnetic reconnection is to quantifY the interaction between global evolution of the magnetosphere and microphysical kinetic processes in diffusion regions near reconnection sites. Recent advances in small-scale kinetic modeling of magnetic reconnection significantly improved our understanding of physical mechanisms controlling the dissipation in the vicinity of the reconnection site in collisionless plasma. However the progress in studies of small-scale geometries was not very helpful for large scale simulations. Global magnetosphere simulations usually include non-ideal processes in terms of numerical dissipation and/or ad hoc anomalous resistivity. Comparative studies of magnetic reconnection in small scale geometries demonstrated that MHD simulations that included non-ideal processes in terms of a resistive term 11 J did not produce fast reconnection rates observed in kinetic simulations. In collisionless magnetospheric plasma, the primary mechanism controlling the dissipation in the vicinity of the reconnection site is nongyrotropic pressure effects with spatial scales comparable with the particle Larmor radius. We utilize the global MHD code BATSRUS and replace ad hoc parameters such as "critical current density" and "anomalous resistivity" with a physically motivated model of dissipation. The primary mechanism controlling the dissipation in the vicinity of the reconnection site in incorporated into MHD description in terms of non-gyrotropic corrections to the induction equation. We will demonstrate that kinetic nongyrotropic effects can significantly alter the global magnetosphere evolution. Our approach allowed for the first time to model loading/unloading cycle in response to steady southward IMF driving. The role of solar wind parameters and ionospheric conductance on the dynamics of the loading/unloading cycle will be discussed.

Kuznetsova, M. M.↗

NASA NTRS1981

Ultraviolet extinction curves derived from IUE data

Data from the International Ultraviolet Explorer (IUE) have been used to derive extinction curves for several stars chosen because of unusual diffuse band strength or location within dense clouds. Both the strength and position of the 2200 A extinction maximum were assessed, as well as the level of extinction in the far-ultraviolet. A variety of combinations of these features were found, ranging from near or complete absence of a 2200 A bump (HD 29647), to low far-ultraviolet extinction (Rho Oph), to unusually steep, far-ultraviolet extinction (HD 169454). Anomalous extinction apparently shows up frequently in stars associated with nebulosity or dense clouds. The apparent independence of 2200 A and far-ultraviolet extinction supports earlier suggestions that these two features are created by distinct populations of grains.

Seab, C. G.↗

NASA NTRS1982

Ground based studies for the space processing of lead-tin-telluride

This paper summarizes the results of a series of studies dealing with crystal growth from the melt and in particular, the growth of the narrow bandgap semiconductor PbSnTe by the Bridgman technique. Theoretical calculations have shown that for low Prandtl number fluids such as semiconductors, convection has no effect on the temperature field in the melt but has a significant effect on the compositional field. They also show that convective flow will exist in a Bridgman growth system on earth, even in the 'thermally stable' configuration. Measurements of the specific heat have been made up to temperatures of 722 C. The thermal diffusivity has been measured up to 1010 C which includes values for the melt. The interdiffusion coefficients for PbTe and SnTe in the melt have been determined. A technique has been developed and tested which provides a vacuum tight quartz ampoule with electrical feedthroughs for interface demarcation studies during the Bridgman growth. Analysis of crystals grown has indicated that the PbSnTe system is solutally unstable and the distribution of SnTe in the crystal, after an anomalous first to freeze region, follows that predicted by Pfann for convection controlled growth. Studies of the amount of supercooling in PbSnTe indicate that this may explain an anomalous composition distribution in the first to freeze region of an unseeded growth.

Crouch, R. K.↗

NASA NTRS1994

Study of cosmic-ray H and He isotopes at 23 AU

We have measured the spectra of H and He isotopes during the 1987 solar minimum with the cosmic-ray detector system (CRS) on the Voyager 2 spacecraft. By carrying out the measurement near solar minimum and at large heliospheric distances, the effects of solar modulations were reduced. In particular, the adiabatic energy losses were smaller, and these results from 23 AU over the solar minimum period of cycle 21 represent observations at energies not accessible from previous measurements near 1 AU. The modulated spectra with the diffusion coefficient constant k(sub 0) = 3.15 x 10(exp 22) sq cm/s (which corresponds to a solar modulation parameter of 360 MV at 23 AU and 500 MV at 1 AU) agree well with both our data at 23 AU and the previous solar minimum measurements at 1 AU. The measured H-1 and H-2 spectra are both consistent with the calculated spectra, using standard Galactic and heliospheric propagation models without invoking an anomalous hydrogen component. With the fixed modulation parameter of 360 MV, the mean pathlengths, source spectra, and cross sections were varied to study the effects of different input parameters on the spectra and relative abundances. At this stage of our work, we have not found any strong evidence from the low-energy H-2 and He-3 data that H-1 and He-4 should have a different propagation history, or different types of source spectra from the heavier cosmic-ray nuclei.

Seo, E. S.↗

NASA NTRS1981

Annealing and anomalous high-energy electron irradiation effects in low-cost silicon N+P solar cells

Silicon solar cells of N(+)P type were subjected to 1 MeV electron irradiation (up to 10 to the 16th electrons/sq cm) and then annealed at 450 C for 20 min or annealed with no electron irradiation. Electron irradiation resulted in a degradation of longer wavelength cell response, but produced a marked enhancement of response at shorter wavelengths with a peak change of 40% at 0.44 microns. Subsequent thermal anneal at 450 C reduced the long-wavelength degradation, but enhancement at shorter wavelengths persisted. Excitation at the shorter wavelengths was in the N(+)-diffused layer and in the junction region of the cell. Anneal of unirradiated cells produced shorter-wavelength enhancement with a similar peaking at 0.44 microns, but with a relative change of only 20%. More enhancement was produced in the longer wavelength region (up to 0.8 microns). These effects in the different cell regions are explained by a decrease in the interstitial oxygen-impurity complexes (deep recombination levels) and the formation of substantial oxygen-silicon vacancy centers (donors).

Garlick, G. F. J.↗

NASA NTRS1972

Anomalous FIM images of tungsten.

Observation of unusual field-ion images consisting of bright bands of variable width parallel to the 111 (in carets) zones in tungsten at 78 K. Typical conditions for the effect are: pulse width from 1 to 50 microsec and pulse height adjusted so that five to ten pulses are required to remove one (110) plane. The influence of a number of accessible variables was studied and the results lead to a two-mechanism model for field evaporation involving (1) a slow process requiring helium promotion and (2) unpromoted evaporation when the local helium supply is depleted at high rates. The model implies that helium diffusion is rate-limiting in the promotion mechanism and leads to a migration energy of about 0.15 eV during field evaporation. There is a measurable difference in end form in the limits of high- and low-field evaporation rates. High rates are nearly isotropic and yield a more hemispherical end form.

Hren, J. J.↗