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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
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NASA NTRS1988

Temporal and spatial distribution of stratospheric trace gases over Antarctica in August and September, 1987

There have been a large number of suggestions made concerning the origin of the Antarctic 'ozone hole' since its discovery; these changes include stratospheric chemistry, or changes in the solar input, or combinations of these effects. Supporting or refuting these theories requires a wide variety of data for comparison with the predictions. In Aug. and Sept., 1987, a field observation expedition was made over Antarctica from a base in Punta Arenas, Chile. Two aircraft, an ER-2 with in-situ instruments flew at altitudes up to 18 km measuring ozone, water, ClO, BrO, NO sub x, particles, and meteorological parameters in the ozone layer. A DC-8 flew at altitudes of 10 to 12 km, below the ozone layer, using remote sensing instruments for measuring composition and aerosol content of the ozone layer, as well as in-situ instruments for measuring composition at aircraft altitudes. The obsevation of a number of chemical species and their correlation with each other and with meteorological parameters gives a useful set of data for comparison with various theories.

Coffey, M. T.↗
NASA NTRS1988

A feasibility study of methods for stopping the depletion of ozone over Antarctica

Ways of stopping the ozone depletion in the ozone hole over Antarctica were studied. The basic objectives were: (1) to define and understand the phenomenon of the ozone hole; (2) to determine possible methods of stopping the ozone depletion; (3) to identify unknowns about the hole and possible solutions. Two basic ways of attacking the problem were identified. First is replenishment of ozone as it is being depleted. Second is elimination of ozone destroying agents from the atmosphere. The second method is a more permanent form of the solution. Elimination and replenishment methods are discussed in detail.

Source record↗
NASA NTRS1988

Volcanic ash layers in blue ice fields (Beardmore Glacier Area, Antarctica): Iridium enrichments

Dust bands on blue ice fields in Antarctica have been studied and have been identified to originate from two main sources: bedrock debris scraped up from the ground by the glacial movement (these bands are found predominantly at fractures and shear zones in the ice near moraines), and volcanic debris deposited on and incorporated in the ice by large-scale eruptions of Antarctic (or sub-Antractic) volcanoes. Ice core studies have revealed that most of the dust layers in the ice cores are volcanic (tephra) deposits which may be related to some specific volcanic eruptions. These eruptions have to be related to some specific volcanic eruptions. These eruptions have to be relatively recent (a few thousand years old) since ice cores usually incorporate younger ice. In contrast, dust bands on bare blue ice fields are much older, up to a few hundred thousand years, which may be inferred from the rather high terrestrial age of meteorites found on the ice and from dating the ice using the uranium series method. Also for the volcanic ash layers found on blue ice fields correlations between some specific volcanoes (late Cenozoic) and the volcanic debris have been inferred, mainly using chemical arguments. During a recent field expedition samples of several dust bands found on blue ice fields at the Lewis Cliff Ice Tongue were taken. These dust band samples were divided for age determination using the uranium series method, and chemical investigations to determine the source and origin of the dust bands. The investigations have shown that most of the dust bands found at the Ice Tongue are of volcanic origin and, for chemical and petrological reasons, may be correlated with Cenozoic volcanoes in the Melbourne volcanic province, Northern Victoria Land, which is at least 1500 km away. Major and trace element data have been obtained and have been used for identification and correlation purposes. Recently, some additional trace elements were determined in some of the dust band samples, including Ir. Iridium determinations were made using INAA, with synthetical and natural (meteorite) standards. These findings are discussed.

Koeberl, Christian↗
NASA NTRS1988

Evidence of volcanic ash at a K-T boundary section: Ocean drilling program hole 690 C, Maud Rise, Weddell Sea off East Antarctica

Rare vitric volcanogenic ash but more abundant clay minerals considered volcanogenic in origin are associated with an expanded and essentially complete K-T boundary sequence from Ocean Drilling Project (ODP) Hole 690 C on Maud Rise in the Weddell Sea off East Antarctica. Results at this writing are preliminary and are still based to some extent on shipboard descriptions. Further shore-based studies are in progress. It would appear, however, that the presence of volcanic ash and altered ash in the Danian section beginning at the biostratigraphically and paleomagnetically determined K-T boundary on Maud Rise can be cited as evidence of significant volcanic activity within the South Atlantic-Indian Ocean sector of the Southern Ocean coincident with the time of biotic crises at the end of the Maestrichtian. This is a postulated time of tectonic and volcanic activity within this Southern Hemisphere region, including possible initiation of the Reunion hot spot and a peak in explosive volcanism on Walvis Ridge (1) among other events. A causal relationship with the biotic crisis is possible and volcanism should be given serious consideration as a testable working hypothesis to explain these extinctions.

Wise, S. W.↗
NASA NTRS1989

Microbial trace fossils in Antarctica and the search for evidence of early life on Mars

It is possible to hypothesize that, if microbial life evolved on early Mars, fossil remnants of these organisms may be preserved on the surface. However, the cooling and drying of Mars probably resembled a cold desert and such an environment is not suitable for the process of fossilization. The frigid Ross Desert of Antarctica is probably the closest terrestrial analog to conditions that may have prevailed on the surface of the cooling and drying Mars. In this desert, cryptoendolithic microbial communities live in the airspaces of porous rocks, the last habitable niche in a hostile outside environment. The organisms produce characteristic chemical and physical changes in the rock substrate. Environmental changes (deterioration of conditions) may result in the death of the community. Although no cellular structures are fossilized, the conspicuous changes in the rock substrate are preserved as trace fossils. Likewise, microbial trace fossils (without cellular structures) may also be preserved on Mars: Discontinuities in structure or chemistry of the rock that are independent of physical or chemical gradients may be of biological origin. Ross Desert trace fossils can be used as a model for planning search strategies and for instrument design to find evidence of past Martian life.

Friedmann, E. Imre↗
NASA NTRS1988

Rapid growth of magnesium-carbonate weathering products in a stony meteorite from Antarctica

Nesquehonite, a hydrous magnesium carbonate, occurs as a weathering product on the surface of the Antarctic meteorite LEW 85320 (H5 chondrite). Isotopic measurements of delta(C-13) and delta(O-18) indicate that the nesquehonite formed at near freezing temperatures by reaction of meteoritic minerals with terrestrial water and carbon dioxide. Results from carbon-14 dating suggest that, although the meteorite has been in Antarctica for at least 32,000 to 33,000 years, the nesquehonite formed after AD 1950.

Jull, A. J. T.↗
NASA NTRS1988

Climatological observations and predicted sublimation rates at Lake Hoare, Antarctica

In December 1985, an automated meteorological station was established at Lake Hoare in the dry valley region of Antarctica. Here, the first year-round observations available for any site in Taylor Valley are reported. The mean annual solar flux at Lake Hoare was 92 W/sq m during 1986, the mean air temperature -17.3 C, and the mean 3-m wind speed 3.3 m/s. The local climate is controlled by the wind regime during the 4-month sunless winter and by seasonal and diurnal variations in the incident solar flux during the remainder of the year.

Clow, Gary D.↗
NASA NTRS1989

Iridium enrichment in volcanic dust from blue ice fields, Antarctica, and possible relevance to the K/T boundary event

The analysis of samples of volcanic ash dust layers from the Lewis Cliff/Beardmore Glacier in Antarctica shows that some of the samples contain Ir concentrations up to 7.5 ppb. It is shown that the Ir is positively correlated with Se, As, Sb, and other volcanogenic elements. The results show that Ir may be present in some volcanic ash deposits, suggesting that the Ir in the K/T boundary clays is not necessarily of cosmic origin, but may have originated from mantle reservoirs tapped during extensive volcanic eruptions possibly triggered by impact events.

Koeberl, Christian↗
NASA NTRS1989

Gamma-ray observations of SN 1987A from Antarctica

Gamma-ray lines from the dirction of supernova 1987A have been observed with a Ge detector flown on a high-altitude balloon platform over Antarctica in January 1988. Gamma rays at 844.1 + or - 1.0 and 1239.9 + or - 1.5 keV, with fluxes 0.0023 + or - 0.002 and 0.0021 + or - 0.001 photons/sq cm sec, respectively, are attributed to the radioactive decay of Co-56. Errors quoted do not include possible systematic effects.

Rester, A. C.↗
NASA NTRS1989

The planning and execution of ER-2 and DC-8 aircraft flights over Antarctica, August and September 1987

The significant ozone loss in the lower stratosphere over Antarctica during recent austral springs was studied by instrumented ER-2 and DC-8 aircraft. Data on the homogeneous gas composition, polar stratospheric clouds, and on tracers for dynamic motion are provided. The mission design is described, the aircraft and their payloads are documented, and the flight tracks are specified.

Tuck, A. F.↗
NASA NTRS1989

Balloon-borne measurements of aerosol, condensation nuclei, and cloud particles in the stratosphere at McMurdo Station, Antarctica, during the spring of 1987

Measurements of the vertical profile of particles with condensation nuclei counters and eight channel aerosol detectors at McMurdo Station, Antarctica, in 1987 verified observations made in 1986 concerning the absence of upwelling in the polar vortex and the presence of a condensation nuclei layer in conjunction with the ozone hole region. New observations of a bimodal aerosol size distribution, consisting of a large-particle mode mixed in with the small-particle sulfate mode, at temperatures below -79 C are consistent with the presence of nitric acid-water particles at low concentrations. Higher concentrations of large particles were observed in association with nacreous clouds. An unusual particle layer which contained enhanced concentrations of both the small-particle (sulfate) mode and the large-particle (nitric acid) mode was detected at temperatures below -85 C, suggesting simultaneous nucleation and growth phenomena. The vortex condensation nuclei layer was observed to form at the same time as the ozone hole, indicating that formation of the layer is triggered by photochemical processes and may be important in controlling ozone depletion above 22 km.

Hofmann, D. J.↗
NASA NTRS1989

Airborne measurements of stratospheric constituents over Antarctica in the austral spring 1987. I - Method and ozone observations

A Fourier transform spectrometer was flown aboard a DC-8 on 10 flights over Antarctica during August and September, 1987, as part of the Airborne Antarctic Ozone Experiment (AAOE). Observing the sun at infrared wavelengths, it was possible to determine the integrated column amount above the flight altitude for ozone and a number of other chemical species that are believed to be important in the perturbed chemistry of the 'ozone hole'. The paper describes the method, the observations, the data analysis procedure, and the ozone results. During the observation period, ozone developed a steep gradient near the edge of the polar vortex; deep within the vortex, the average ozone column decreased by about 1.6 percent per day during September.

Mankin, William G.↗
NASA NTRS1989

New observations of a large concentration of ClO in the springtime lower stratosphere over Antarctica and its implications for ozone-depleting chemistry

New measurements of stratospheric chlorine monoxide (ClO) were made at McMurdo Station, Antarctica, during the austral spring of 1987. Rotational emission line spectroscopy, employing a ground-based detector, was used to determine mixing ratio profiles over the range about 17-45 km. A spectral band pass double that was used for similar measurements in 1986 allowed an improvement to be made in the definition of the anomalous low-altitude stratospheric ClO layer associated with springtime ozone depletion. A peak mixing ratio of 1.6 + or - 0.4 parts per billion by volume (ppbv) (95 percent confidence level) was found at 19.5 + or - 1 km at midday during the period September 20-24, 1987. The observed peak mixing ratio and diurnal behavior are discussed in relation to chemical depletion theories. Calculations indicate that the large observed ClO concentration provides an efficient closure for a catalytic Cl cycle through the ClO dimer mechanism, yielding good agreement with various observed features of O3 depletion.

De Zafra, R. L.↗
NASA NTRS1989

Ground-based infrared measurements of tropospheric source gases over Antarctica during the 1986 austral spring

Simultaneous measurements of the atmospheric burdens of CH4, N2O, CO2, CF2Cl2, and CO above McMurdo Station, Antarctica, have been derived from solar absorption spectra obtained by the Jet Propulsion Laboratory high-resolution Fourier transform spectrometer. In all cases the burdens are smaller than midlatitude values. Furthermore, retrievals of N2O and CH4 indicate that the tropospheric mixing ratios were normal and that the depletion of the burdens can best be accounted for by a downward shift of the volume mixing ratio profiles by some 6-8 km. This rules out the possibility of large-scale upwelling of ozone-poor tropospheric air into the stratosphere being the cause of the Antarctic springtime ozone depletion.

Toon, G. C.↗
NASA NTRS1989

In situ observations of BrO over Antarctica - ER-2 aircraft results from 54 deg S to 72 deg S latitude

Bromine monoxide was observed in situ during nine flights of the NASA ER-2 aircraft from Punta Arenas, Chile (54 deg S latitude), to 72 deg S latitude over the Palmer Peninsula, Antarctica. The first flight for the BrO detection system was on August 28. The distribution of BrO inside the chemically perturbed region defined by greatly elevated ClO abundances was different from that found just outside. Inside, the BrO mixing ratio was 6.1 + or - 1.1 pptv above the 440 K potential temperature surface, 4.7 + or - 2.0 pptv between the 400 and 440 K surfaces, and less than 4 pptv below the 400 K surface. At high latitudes outside the chemically perturbed region, the BrO mixing ratio was 5.4 + or - 1.4 pptv near the 450 K surface, but decreased to 2.9 + or - 1.2 pptv at the 420 K surface. The abundance of BrO showed no discernible temporal trend during the course of the nine flights. Away from the south polar region, at latitudes between 47 deg S and 37 deg N and potential temperatures between 435 and 500 K (18.5- to 20.7-km altitude), the BrO mixing ratio was 0.5-3.0 pptv.

Brune, W. H.↗
NASA NTRS1990

Measurement of atmospheric opacity at 278 GHz at McMurdo Station, Antarctica in austral spring seasons, 1986 and 1987

A quasi-continuous record is presented of atmospheric opacity measured at 278 GHz (1.1 mm wavelength) from the McMurdo Station (Antarctica) during austral spring seasons of 1986 (August 30 - October 30) and 1987 (September 4 - October 13) with measurements taken every 20 minutes (except during storms or other periods of high opacity). All data are reduced to represent opacity in the zenith direction. It was found that, during much of September, the two successive years differed considerably in tropospheric opacity. In 1986, water vapor and attendant opacity were generally lower, due to low tropospheric temperatures. Measured opacities were found to be higher than would be expected from the empirical relationships representing opacity as a function of water vapor column density at mm-wavelengths, as proposed by Rice and Ade (1979), Zammit and Ade (1981), and Liebe (1985).

De Zafra, R. L.↗
NASA NTRS1991

Measurements in polar stratospheric clouds over Antarctica in September 1989

The results of six balloon flights at McMurdo Station, Antarctica, under varying temperature conditions, are used in a study of polar stratospheric clouds during Sept. 1989. A particle counter, with size resolution in the 0.5 micron radius region, indicates that cloud size distributions are always bimodal. Mode radii ranging from 0.05 to 0.10 microns were observed for the small particle mode, representing the sulfate layer or condensational growth enhancements of it. The data are not inconsistent with the expected increase in size with decreasing temperature of the small particle mode in the sulfate layer owing to deliquescence although this phenomenon is often masked by nitric acid trihydrate (NAT) condensation when temperatures are sufficiently low. Mode radii generally ranged from 1.5 to 3.5 micron for the large particle mode at concentrations 3 to 4 orders of magnitude lower than the small particle mode. The large particle mode, which normally comprises most of the mass, is presumably caused by NAT condensation on larger particles of the sulfate layer and indicates HNO3 mixing ratios of 1 to 5 ppbv for most of the cloud layers observed, suggesting substantial denitrification. On several occasions, distributions were observed with mode radii as high as 7 microns, and correspondingly large inferred mass, indicating water ice clouds in the 12 to 15 km region. On other occasions, absence of such clouds at very low temperatures indicated water vapor mixing ratios of less than 3 ppmv suggesting dehydration. Generally, the inferred HNO3 mixing ratios were higher in the lower stratosphere, suggesting redistribution through particle sedimentation.

Deshler, Terry↗