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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
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NASA NTRS1972

The origin and chemical composition of the earth's core

The process of core formation in the earth is subject to the constraints that it be nearly simultaneous with accretion and yet occur in a manner that the mantle retains radiogenic Xe-129 produced from the extinct radioactivity of I-129 with a half life of 17.6 million y. From these constraints, it appears that the only feasible mechanism is the segregation of an Fe-FeS melt. Trace element abundances in major classes of meteorites and the silicate fractions of the earth show that not only there is a high depletion of sulphur in the crust and the mantle, but that it is even more highly depleted than the rare gases, water and the halogens. From the nature of this depletion pattern and the fact that any model of accretion of the earth will necessarily produce an Fe-FeS melt, it is concluded that the light element in the core is largely sulphur with minor amounts of carbon. A consequence of this mode of core formation is found to be the availability of K-40 radioactive heat production in the liquid core, estimated at about 10 to the 19th power erg/s at the present time.

Murthy, V. R.↗
NASA NTRS1973

Chemical composition of Apollo 15, 16, and 17 samples

The authors analyzed 22 Apollo 15 samples, 21 Apollo 16 samples, 4 Luna 20 samples, and 6 Apollo 17 samples for 26 to 30 major, minor, and trace elements by instrumental neutron activation analysis (INAA). Major attention is given to Apollo 16 results and recent Apollo 17 data. The roster of elements via INAA has been extended to include Nd, Ni, Ir, and Au in the Apollo 16 and 17 samples. The latter three elements are highly abundant in these samples. Sample preparation, activation conditions, and the detailed INAA analytical procedure are essentially the same as reported by Laul and Schmitt (1973).

Laul, J. C.↗
NASA NTRS1974

The chemical composition of cosmic ray nuclei above 1.3 GeV per nucleus and 23 GeV per nucleus

Measurements made with a balloon-borne counter telescope are reported. The telescope was flown from Palestine, Tex., during the fall of 1971 for a total of 10 hours under an average residual atmospheric depth of 4.4 g per sq cm. The data analysis indicates that the integral flux ratios above 1.3 GeV per nucleus and 23 GeV per nucleus are consistent with energy independence.

Badhwar, G. D.↗
NASA NTRS1975

Emission-line strengths and the chemical compositions of quasi-stellar objects

Estimates of emission-line strengths in 160 QSOs are listed. They are used, together with those for 60 objects published earlier, to compile a table of rest-frame equivalent widths for a composite QSO containing 28 lines seen in objects with z from 0.06 to 3.53. Models are computed for matter partially filling a spherical volume, ionized by ultraviolet flux from a central object and optically thick with absorption from heavy elements taken into account. Constant temperature and density are taken for the He II region, where most of the important lines are emitted. Allowance is made for lower and higher temperatures in the H I and He III regions. Emergent emission-line equivalent widths are computed and compared with the observations. An abnormally low helium abundance is not needed to achieve a fit, since the only anomalously weak line is He II 4686 A whose upper level may be depopulated by stimulated emission of He II 1215 A caused by very strong L-alpha 1216 A flux.

Chan, Y.-W. T.↗
NASA NTRS1976

Laboratory reflection spectra for the determination of chemical composition of ice bodies

The visible (0.3 to 1.03 microns) spectral reflectances of N2O, NH3, H2S, and NH4HS frosts and mixtures of these frosts as well as their UV-irradiated products have been measured. These spectra are compared with the spectra of the Galilean satellites of Jupiter, Saturn's rings, and Saturn's satellites to place limits on their surface compositions.

Lebofsky, L. A.↗
NASA NTRS1977

The chemical composition of three planetary nebulae in the Magellanic Clouds

The paper studies the detailed spectral characteristics of the planetary nebulae N97 and N153 in the Large Magellanic Cloud (LMC), the planetary nebula N67 in the Small Magellanic Cloud (SMC), and the small H II regions N9, N61, and N81 in the SMC. Electron temperatures and densities for each nebula are derived from emission-line strengths determined by photographic spectrophotometry, and relative abundances are estimated for H, He, N, O, Ne, Ar, and S. The results show that: (1) N67 has a 60% overabundance in He/H while N97 and N153 have approximately normal He/H values; (2) all three planetaries have N/H values comparable to those of galactic planetaries but substantially higher than found in the H II regions of their respective Cloud; (3) the O/H values in the planetaries are similar to or lower than those in the H II regions of the respective Cloud; (4) the O/Ne, O/S, and O/Ar ratios in the two LMC planetaries are comparable to those in galactic planetaries; (5) the compositions of the small H II regions in the SMC are nearly identical to those of previously studied large H II regions in the same Cloud; and (6) the He/H ratio of the interstellar gas in the SMC is about 25% less than that in the Galaxy. It is concluded that most of the N abundance in both Clouds arose from nucleosynthesis sources other than planetary nebulae.

Dufour, R. J.↗
NASA NTRS1977

Chemical compositions of the moon, earth, and eucrite parent body

Model compositions of the moon and earth were calculated on the assumption that these planets had experienced chondrite-like nebular fractionation processes. The model correctly predicts the abundance ratios of certain volatile/refractory element pairs (e.g., Cd/Ba, Ga/La, Sn/Th, and Pb/U), the density of the moon, and the major rock types. The model is also used to reconstruct the composition of the parent eucrite body, which resembles the moon except for a lower content of refractory elements.

Anders, E.↗
NASA NTRS1977

Chemical compositions and possible immiscibility of two silicate melts in 12013

The lunar sample 12013, a complex mixture of gray breccia and black breccia, is described. The gray breccia consists of mostly basaltic and gabbroic lithic clasts as well as plagioclase and pyroxene mineral clasts set in a matrix of smaller clasts and a felsite of granitic composition, while the black breccia is comprised of mostly mineral clasts, some lithic clasts, and felsite blebs enclosed in an aphanitic groundmass of basaltic composition. Textural relationships indicate that the felsite and the black breccia groundmass crystallized from melts which coexisted prior to the final lithification of 12013 but failed to mix. Both the felsite and the black breccia groundmass have extreme enrichments of incompatible elements. The critical feature of their compositions is a 'splitting up' of incompatible element associations so that the highest REE and P concentrations are in the black breccia groundmass, and the highest K, Ba, and Rb concentrations are in the felsite.

Quick, J. E.↗
NASA NTRS1979

An Analysis of the Chemical Composition of the Atmosphere of Venus on an AMS of the Venera-12 Using a Gas Chromatograph

Eight analyses of the atmosphere of Venus were made beginning at an altitude of 42 km right down to the surface of the planet. The following were detected in the atmosphere of Venus: nitrogen in concentrations of 2.5 plus or minus 0.5 volumetric %, argon ir concentrations (4 plus or minus 2) x 10 to the minus 3 power volumetric %, CO--(2.8 plus or minus 1.4) x 10 to the minus 3 power volumetric % and SO2 in concentrations (1.3 plus or minus 0.6) x 10 to the minus 2 power volumetric %. The upper limits were estimated for the content of oxygen and water equal to 2 x 10 to the minus 3 power and 10 to the minus 2 power volumetric %, respectively.

Gelman, B. G.↗
NASA NTRS1980

Chemical composition of earth, Venus, and Mercury

Model compositions of the earth, Venus, and Mercury are calculated from the premise that planets and chondrites underwent four identical fractionation processes in the solar nebula. Because elements of similar properties stay together in these processes, five constraints suffice to define the composition of a planet: mass of the core, abundance of U, and the ratios K/U, TI/U, and FeO/(FeO + MgO). Complete abundance tables, and normative mineralogies, are given for all three planets. A review of available data shows only a few gross trends for the inner planets: FeO decreases with heliocentric distance, whereas volatiles are depleted and refractories are enriched in the smaller planets.

Morgan, J. W.↗
NASA NTRS1981

The chemical composition, gravity, and temperature of Sirius

Observational data available for Sirius are of poorer quality than those for Vega, with both the angular diameter and absolute fluxes at different wavelengths being less accurately known. While these data yield an effective temperature of 10,000 + or - 250 K, the 13-color photometry of Johnson and Mitchell (1975) suggests that Sirius is about 450 K hotter than Vega's effective temperature of 9650 + or - 200 K. The c(1) color of the uvby system, the 33-52 and 35-52 colors of the 13-color photometry, and the H-alpha, H-beta and H-gamma line profiles all give log g values of about 4.3, which is in agreement with the value deduced from the mass and the radius, the latter being deduced from the angular diameter and the parallax.

Bell, R. A.↗
NASA NTRS1982

The relationship of the lunar regolith less than 10-microns fraction and agglutinates. II - Chemical composition of agglutinate glass as a test of the 'fusion of the finest fraction' /F3/ model

Agglutinate glasses from nine Apollo soils have been studied using an automated electron microprobe technique in order to test the fusion of the finest fraction model proposed by Papike (1981). The nine average agglutinate glass compositions are compared with the calculated fused-soil-free compositions, the bulk compositions and the 90-20 micron fraction compositions of the soils in which they are found. It is found that the agglutinate glass data are consistent with the composition of most of the fractions finer than 10 microns, allowing for the volatile loss of K2O and Na2O; some inconsistencies that do arise may result from the degree of soil maturity and the amount of material finer than 10 microns. It is concluded that the fusion of the finest fraction model is a good first approximation of mechanisms affecting the formation of agglutinate glass.

Walker, R. J.↗
NASA NTRS1982

Chemical composition of cometary nuclei

Observational evidence pertaining to the origin and composition of cometary material is reviewed. Arguments favoring the undifferentiated character of the icy conglomerate are summarized. Theoretical descriptions of the sublimation of a cometary nucleus and the velocity field of the expanding gas are presented and compared with observations. The nature of cometary dust and the atomic abundances of H, C, N, O, and S in the volatile fraction are examined, and data on the dust and volatile fractions are combined to derive elemental abundances. It is shown that O, N, and S in cometary nuclei appear to have essentially cosmic abundances but that both H and C are drastically depleted with respect to the cosmic abundances. The apparent depletion of C by a factor of more than three is discussed. It is suggested that the missing carbon might be hidden in the dust fraction in the form of heavy organic molecules or might have remained in either the primeval solar nebula or interstellar space.

Delsemme, A. H.↗