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Compositional studies of primitive asteroids

The aqueous alteration history in the solar system are studied through acquiring additional CCD reflectance spectra in the blue-UV through near-IR spectral region and analyzing these spectra for information about iron oxides in phyllosilicates identified in the CM and CI carbonaceous chondrites. Emphasis is on the main-belt and Cybele primitive asteroids, as these asteroids show spectral diversity and are also spectral analogues for known meteorite samples. The porphyrin bands found in organics near 0.4 micron is also sought.

Vilas, Faith↗

Mineralogy and Textural Characteristics of Fine-grained Rims in the Yamato 791198 CM2 Carbonaceous Chondrite: Constraints on the Location of Aqueous Alteration

Carbonaceous chondrites provide important clues into the nature of physical and chemical processes in the early solar system. A question of key importance concerns the role of water in solar nebular and asteroidal processes. The effects of water on primary mineral assemblages have been widely recognized in chondritic meteorites, especially the CI and CM carbonaceous chondrites. These meteorites have undergone extensive aqueous alteration that occurred prior to their arrival on Earth. In the case of the CM chondrites, this alteration has resulted in the partial to complete replacement of the primary nebular phases with secondary alteration phases. Considerable controversy exists as to the exact location where the alteration of the CM chondrites occurred. Several textural lines of evidence have been cited in support of aqueous alteration prior to the accretion of the final parent asteroid. An important line of evidence to support this hypothesis is the dis-equilibrium nature of fine-grained rims and matrix materials. [2] also noted the juxtaposition of micron-sized Fe-Ni metal grains and apparently unaltered chondrule glass against hydrated rim silicates. Conversely, there is a large body of evidence in favor of parent body alteration such as the occurrence of undisturbed Fe-rich aureoles and the systematic redistribution of elemental components over millimeters, e.g., Mg(+2) into the matrix and Fe(+2) into chondrules etc.

Chizmadia, Lysa J.↗

Lunar and Planetary Science XXXV: Martian Meteorites: Petrology

The session "Martian Meteorites: Petrology: included the following reports:Volatile Behavior in Lunar and Terrestrial Basalts During Shock: Implications for Martian Magmas; Problems with a Low-Pressure Tholeiitic Magmatic History for the Chassigny Dunite; Fast Cooling History of the Chassigny Martian Meteorite; Rehomogenized Interstitial and Inclusion Melts in Lherzolitic Shergottite ALH 77005: Petrologic Significance; Compositional Controls on the Formation of Kaersutite Amphibole in Shergottite Meteorites; Chemical Characteristics of an Olivine-Phyric Shergottite, Yamato 980459; Pb-Hf-Sr-Nd Isotopic Systematics and Age of Nakhlite NWA 998; Noble Gases in Two Samples of EETA 79001 (Lith. A); Experimental Constraints on the Iron Content of the Martian Mantle; and Mars as the Parent Body for the CI Carbonaceous Chondrites: New Data.

Source record↗

Lunar and Planetary Science XXXVI, Part 7

Topics discussed include: Lunar Geologic Mapping: Preliminary Mapping of Copernicus Quad High-Resolution Topography of Layers in the Valles Marineris Via Thermoclinometry ; The Critical Importance of Data Reduction Calibrations in the Interpretability of S-type Asteroid Spectra; (sup 238)U-(sup 206)Pb Age and Uranium-Lead Isotope Systematics of Mare Basalt 10017; Morphological Investigations of Martian Spherules, Comparisons to Collected Terrestrial Counterparts; The Vapor Pressure of Palladium at Temperatures up to 1973K; Areas of Favorable Illumination at the Lunar Poles Calculated from Topography; An Indigenous Origin for the South Pole-Aitken Basin Thorium Anomaly; Ar-Ar Ages of Nakhlites Y000593, NWA998, and Nakhla and CRE Ages of NWA998; Experiments on the Acoustic Properties of Titan-like Atmospheres; Analysis of Downstream Transitions in Morphology and Structure of Lava Channels on Mars; Structure and Bonding of Carbon in Clays from CI Carbonaceous Chondrites; Comparison of Three Hydrogen Distributions at the Equator of Mars; An Impact Origin for the Foliation of Ordinary Chondrites; A New Micrometeorite Collection from Antarctica and Its Preliminary Characterization by Microobservation, Microanalysis and Magnetic Methods; Volcanic Plumes and Plume Deposits on Io; Results of the Alpha-Particle-X-Ray Spectrometer on Board of the Mars Exploration Rovers; Effects of Oceans on Atmospheric Loss During the Stage of Giant Impacts; and Identification of Predominant Ferric Signatures in Association to the Martian Sulfate Deposits

Source record↗

PAHs, Hydrocarbons, and Dimethylsulfides in Asteroid Ryugu Samples A0106 and C0107 and the Orgueil (CI1) Meteorite

Evaluating the molecular distribution of organic compounds in pristine extraterrestrial materials is cornerstone to understanding the abiotic synthesis of organics and allows us to better understand the molecular diversity available during the formation of our solar system and before the origins of life on Earth. In this work we identify multiple organic compounds in solvent extracts of asteroid Ryugu samples A0106 and C0107 and the Orgueil meteorite using two-dimensional gas chromatography and time-of-flight high resolution mass spectrometry (GC×GC-HRMS). Our analyses found similarities between the molecular distribution of organic compounds in Ryugu and the CI carbonaceous chondrite Orgueil. Specifically, several PAHs and organosulfides were found in Ryugu and Orgueil suggesting an interstellar and parent body origin for these compounds. We also evaluated the common relationship between Ryugu, Orgueil, and comets like Wild-2; however, until comprehensive compound-specific isotopic analyses for these organic species are undertaken, and until the effects of parent body processes and Earth’s weathering processes on meteoritic organics are better understood, their parent-daughter relationships will remain unanswered. Finally, the study of organic compounds in Ryugu samples and the curation practices for the future preservation of these unvaluable materials are also of special interest for future sample return missions, including NASA’s OSIRIS-REx asteroid sample return mission.

Hayabusa2↗

The Spatial Distribution of Soluble Organic Matter and Their Relationship to Minerals in the Asteroid (162173) Ryugu

We performed in-situ analysis on a ~1 mm-sized grain A0080 returned by the Hayabusa2 spacecraft from near-Earth asteroid (162173) Ryugu to investigate the relationship of soluble organic matter (SOM) to minerals. Desorption electrospray ionization-high resolution mass spectrometry (DESI-HRMS) imaging mapped more than 200 CHN, CHO, CHO–Na (sodium adducted), and CHNO soluble organic compounds. A heterogeneous spatial distribution was observed for different compound classes of SOM as well as among alkylated homologues on the sample surface. The A0080 sample showed mineralogy more like an Ivuna-type (CI) carbonaceous chondrite than other meteorites. It contained two different lithologies, which are either rich (lithology 1) or poor (lithology 2) in magnetite, pyrrhotite, and dolomite. CHN compounds were more concentrated in lithology 1 than in lithology 2; on the other hand, CHO, CHO–Na, and CHNO compounds were distributed in both lithologies. Such different spatial distribution of SOM is likely the result of interaction of the SOM with minerals, during precipitation of the SOM via fluid activity, or could be due to difference in transportation efficiencies of SOMs in aqueous fluid. Organic-related ions measured by time-of-flight secondary ion mass spectrometry (ToF–SIMS) did not coincide with the spatial distribution revealed by DESI-HRMS imaging. This result may be because the different ionization mechanism between DESI and SIMS, or indicate that the ToF–SIMS data would be mainly derived from methanol-insoluble organic matter in A0080. In the Orgueil meteorite, such relationship between altered minerals and SOM distributions was not observed by DESI-HRMS analysis and field-emission scanning electron microscopy, which would result from differences of SOM formation processes and sequent alteration process on the parent bodies or even on the Earth. Alkylated homologues of CHN compounds were identified in A0080 by DESI-HRMS imaging as observed in the Murchison meteorite, but not from the Orgueil meteorite. These compounds with a large C number were enriched in Murchison fragments with abundant carbonate grains. In contrast, such relationship was not observed in A0080, implying different formation or growth mechanisms for the alkylated CHN compounds by interaction with fluid and minerals on the Murchison parent body and asteroid Ryugu.

Ryugu↗

Preliminary Analyses of Asteroid Bennu Samples Returned by NASA’s OSIRIS-REx Mission

NASA’s OSIRIS-REx mission returned ~122 g of pristine carbonaceous regolith from Bennu on September 24, 2023. The science team is performing analyses of the mineralogy, chemical and isotopic compositions, and physical properties of the samples. The returned samples consist of particles ranging up to 3.5 cm in size with angular and hummocky morphologies predominating. Reflectance spectra over the visible and infrared wavelengths collected during the spacecraft encounter contained features indicating abundant hydrated phyllosilicates, carbonates, magnetite, organic matter, and rare anhydrous silicates. Laboratory analyses confirmed these detections and identified several other major and minor phases including abundant FeNi sulfides, minor hydrated Mg-rich phosphates as encrustations and in veins, and presolar grains. The Bennu samples show evidence for extensive aqueous alteration and resemble the rare and chemically primitive CI carbonaceous chondrites and samples returned from Ryugu by JAXA’s Hayabusa2 mission. Samples of Bennu’s uppermost surface, collected by contact pads, help us to understand how recent impacts and irradiation processes have changed the optical properties of Bennu surface materials measured by remote sensing. The analyses thus far highlight the value of sample return by illustrating the pristine nature of the samples compared to meteorites that have been compromised and altered by exposure to the terrestrial environment.

Lindsay P Keller↗

Evidence of an Extended Period of Aqueous Alteration on the Bennu Parent Body Revealed By I-Xe Analyses

NASA’s OSIRIS-REx mission delivered to Earth 121.6 g of regolith material from asteroid Bennu on 24th September 2023. We report multi-step laser pyrolysis xenon isotopic analysis to investigate the I-Xe system in individual particles separated from aggregate material (a mixture of small particles of undefined lithology). The high sensitivity of the RELAX mass spectrometer allows us to observe small excesses of individual isotopes and separate out different components, which may not be possible using a conventional noble gas mass spectrometer. The temperature resolution of RELAX is sufficient to seek an I-Xe isochron from step heating analysis of a sample mass <100 μg, which can contribute to our understanding of the nature and timing of aqueous alteration on Bennu’s parent body. We also aim to better estimate and understand the iodine concentration of CI chondrite-like material.

S A Crowther↗

The First Returned Samples From A C-Type Asteroid Show Kinship to the Chemically Most Primitive Meteorites

Bulk chemical and isotopic compositions, and mineralogy in the asteroid (162173) Ryugu samples show that Ryugu is mainly composed of materials related to the CI (Ivuna-like) carbonaceous chondrite group. The samples consist predominantly of minerals produced by aqueous alteration in a parent planetesimal from which Ryugu was derived. The 53Mn-53Cr systematics of dolomite suggest that this alteration occurred 5.2 (+0.7/–0.8) million years after formation of Ca-Al-rich inclusions, the first solids formed in the Solar System. The aqueous alteration temperature at the time dolomite and magnetite coprecipitated was 37±10°C. Unlike in CI chondrites, phyllosilicates in Ryugu have lost most of their interlayer water, but retained structural water. This indicates that following aqueous alteration the Ryugu samples avoided heating above ~90°C.

Tetsuya Yokoyama↗

Oxygen Isotope Ratios of Magnetite in CI-Like Clasts from a Polymict Ureilite

Polymict ureilites contain a variety of Less than or equal to mm to cm sized non-ureilitic clasts, many of which can be identifed as chondritic and achondritic meteorite types. Among them, dark clasts have been observed in polymict ureilites that are similar to CI chondrites in mineralogy, containing phyllosilicates, magnetite, sulfide and carbonates. Bulk oxygen isotope analyses of a dark clast in Nilpena plot along the CCAM line and above the terrestrial fractionation line, on the O-poor extension of the main group ureilite trend and clearly different from bulk CI chondrites. One possible origins of such dark clast is that they represent aqueously altered precursors of ureilite parent body (UPB) that were preserved on the cold surface of the UPB. Oxygen isotope analyses of dark clasts are key to better understanding their origins. Oxygen isotope ratios of magnetite are of special interest because they reflect the compositions of the fluids in asteroidal bodies. In primitive chondrites, Delta O (= Delta O - 0.52× Delta O) values of magnetites are always higher than those of the bulk meteorites and represent minimum Delta O values of the initial O-poor aqueous fluids in the parent body. Previous SIMS analyses on magnetite and fayalite in dark clasts from the DaG 319 polymict ureilite were analytically difficult due to small grain sizes, though data indicated positive Delta O values of 3-4 per mille, higher than that of the dark clast in Nilpena (1.49per mille).

Kita, N. T.↗

Mineralogy versus bulk composition of the carbonaceous chondrite clast Kaidun 2

Kaidun is an unusual chondritic meteorite. Its main mass is of CR-type (Kaidun I) and contains CI-like (Kaidun II), EL, and EH clasts. The classification of Kaidun II based on mineralogy and bulk chemical criteria does not allow an unambigious assignment to CI. Here we report on the bulk chemical composition and the mineralogy of the Kaidun II clasts. The results of our investigation show that Kaidun II has some characteristics of both CI and CM chondrites. A possible relationship to the texture and composition of micrometeorites is indicated. The Kaidun II clast shows some conflicting mineralogical and chemical characteristics that do not allow an unambigious assignment to the well established carbonaceous chondrite classes. The overall texture of the matrix-rich clast and morphology of opaques are typical for CI's. Bulk matrix and bulk sample compositions reveal similarities with CM's. In addition, the presence of low-Fe Mn-enriched olivines and the relatively high abundance of enstatite resembles some micrometeorites.

Brandstaetter, F.↗

Distribution of Aliphatic Amines in CO, CV, and CK Carbonaceous Chondrites and Relation to Mineralogy and Processing History

The analysis of water-soluble organic compounds in meteorites provides valuable insights into the prebiotic synthesis of organic matter and the processes that occurred during the formation of the solar system. We investigated the concentration of aliphatic monoamines present in hot acid water extracts of the unaltered Antarctic carbonaceous chondrites, Dominion Range (DOM) 08006 (CO3) and Miller Range (MIL) 05013 (CO3), and the thermally altered meteorites, Allende (CV3), LAP 02206 (CV3), GRA 06101 (CV3), Allan Hills (ALH) 85002 (CK4), and EET 92002 (CK5). We have also reviewed and assessed the petrologic characteristics of the meteorites studied here to evaluate the effects of asteroidal processing on the abundance and molecular distributions of monoamines. The CO3, CV3, CK4, and CK5 meteorites studied here contain total concentrations of amines ranging from 1.2 to 4.0 nmol/g of meteorite; these amounts are 1-3 orders of magnitude below those observed in carbonaceous chondrites from the CI, CM, and CR groups. The low-amine abundances for CV and CK chondrites may be related to their extensive degree of thermal metamorphism and/or to their low original amine content. Although the CO3 meteorites, DOM 08006 and MIL 05013, do not show signs of thermal and aqueous alteration, their monoamine contents are comparable to those observed in moderately/extensively thermally altered CV3, CK4, and CK5 carbonaceous chondrites. The low content of monoamines in pristine CO carbonaceous chondrites suggests that the initial amounts, and not asteroidal processes, play a dominant role in the content of monoamines in carbonaceous chondrites. The primary monoamines, methylamine, ethylamine, and n-propylamine constitute the most abundant amines in the CO3, CV3, CK4, and CK5 meteorites studied here. Contrary to the predominance of n-x-amino acid isomers in CO3 and thermally altered meteorites, there appears to be no preference for the larger n-amines.

mineralogy↗

Effects of Short-Term Thermal Alteration on Organic Matter in Experimentally-Heated Tagish Lake Observed by Raman Spectroscopy

Carbonaceous chondrites exhibit a wide range of aqueous and thermal alteration characteristics, while some are known to demonstrate mineralogical and petrologic evidence of having been thermally metamorphosed after aqueous alteration. This group of meteorites are commonly referred as thermally met-amorphosed carbonaceous chondrites (TMCCs), and their reflectance spectra show resemblances to that of C-type asteroids which typically have low albedos. This suggests that the surfaces of the C-type asteroids are also composed of both hydrous and dehydrated minerals, and thus TMCCs are among the best samples that can be studied in laboratory to reveal the true nature of the C-type asteroids. Although TMCCs are usually meteorites that were previously categorized as CI and CM chondrites, they are not strictly CI/CM because they exhibit isotopic and petrographic characteristics that significantly deviate from typical CI/CM. More appropriately, they are called CI-like and/or CM-like chondrites. Typical examples of TMCCs include the C2-ung/CM2TIV Belgica (B)-7904 and Yamato (Y) 86720. Thermal alteration is virtually complete in these meteorites and thus they are considered typical end-members of TMCCs exhibiting complete dehydration of matrix phyllosilicates. The estimated heating conditions are 10 to 103 days at 700 C to 1 to 100 hours at 890 C, i.e. short-term heating induced by impact and/or solar radiation. While the petrology and chemistry of TMCCs have only recently been extensively characterized, we have just begun to study in detail their organic contents. In order to understand how short-term heating affects the maturity of insoluble organic matter (IOM) in hydrous chondrites, we investigated experimentally-heated Tagish Lake meteorite using Raman spectroscopy, as the chemical and bulk oxygen isotopic compositions of the matrix of the carbonate (CO3)-poor lithology of the Tagish Lake (hereafter Tag) meteorite bears similarities to the TMCCs.

Chan, Q. H. S.↗

The Magnesium Isotope Composition of Samples Returned From Asteroid Ryugu

The nucleosynthetic isotope composition of planetary materials provides a record of the heterogeneous distribution of stardust within the early solar system. In 2020 December, the Japan Aerospace Exploration Agency Hayabusa2 spacecraft returned to Earth the first samples of a primitive asteroid, namely, the Cb-type asteroid Ryugu. This provides a unique opportunity to explore the kinship between primitive asteroids and carbonaceous chondrites. We report high-precision μ 26 Mg* and μ 25 Mg values of Ryugu samples together with those of CI, CM, CV, and ungrouped carbonaceous chondrites. The stable Mg isotope composition of Ryugu aliquots defines μ 25 Mg values ranging from –160 ± 20 ppm to –272 ± 30 ppm, which extends to lighter compositions relative to Ivuna-type (CI) and other carbonaceous chondrite groups. We interpret the μ 25 Mg variability as reflecting heterogeneous sampling of a carbonate phase hosting isotopically light Mg (μ 25 Mg ∼ –1400 ppm) formed by low temperature equilibrium processes. After correcting for this effect, Ryugu samples return homogeneous μ 26 Mg* values corresponding to a weighted mean of 7.1 ± 0.8 ppm. Thus, Ryugu defines a μ 26 Mg* excess relative to the CI and CR chondrite reservoirs corresponding to 3.8 ± 1.1 and 11.9 ± 0.8 ppm, respectively. These variations cannot be accounted for by in situ decay of 26 Al given their respective 27 Al/ 24 Mg ratios. Instead, it requires that Ryugu and the CI and CR parent bodies formed from material with a different initial 26 Al/ 27 Al ratio or that they are sourced from material with distinct Mg isotope compositions. Thus, our new Mg isotope data challenge the notion that Ryugu and CI chondrites share a common nucleosynthetic heritage.

Solar system evolution↗

Comparison of the Bright Boulders on the Surface of the C-Type Asteroid Bennu with White Clasts in the Murchison CM Chondrite Breccia

Spectroscopic observations of asteroid Bennu suggest that the materials on the surface of the asteroid are most similar to aqueously-altered CM- or possibly CI-type carbonaceous chondrites [1], although a relationship with heated CM [2] or CR chondrites [1] is also possible. Recently, [3] detected unusually bright boulders (Fig. 1A) on the surface of Bennu. The band ratio indicates the presence of an absorption feature beyond 0.85μm and is consistent with the presence of mafic minerals such as pyroxene or olivine. The hyperspectral data suggest that the exogenic boulders have the same distinctive pyroxene composition as the howardite-eucrite-diogenite (HED) meteorites. However, similar mineralogical features were also observed in indigenous, thermally metamorphosed white clasts reported in samples of the Murchison CM2 (Fig. 2B; [4-5]) and is an alternative interpretation for the bright boulders observed on Bennu. In addition to detailed petrographic characteristics, we report here further chemistry, O, Cr, and Ti isotopes of the clasts in order to confirm their classification, and discuss their possible relationship to Bennu.

I. Kerraouch↗

Magnetite as Possible Template for the Synthesis of Chiral Organics in Carbonaceous Chondrites

The main goal of the Japanese Aerospace Ex-ploration Agency (JAXA) Hayabusa-2 mission is to visit and return to Earth samples of a C-type asteroid (162173) 1999 JU3 in order to understand the origin and nature of organic materials in the Solar System. Life on Earth shows preference towards the set of organics with particular spatial arrangements, this 'selectivity' is a crucial criterion for life. With only rare exceptions, life 'determines' to use the left- (L-) form over the right- (D-) form of amino acids, resulting in a L-enantiomeric excess (ee). Recent studies have shown that L-ee is found within the alpha-methyl amino acids in meteorites [1, 2], which are amino acids with rare terrestrial occurrence, and thus point towards a plausible abiotic origin for ee. One of the proposed origins of chiral asymmetry of amino acids in meteorites is their formation with the presence of asymmetric catalysts [3]. The catalytic mineral grains acted as a surface at which nebular gases (CO, H2 and NH3) were allowed to condense and react through Fisher Tropsch type (FTT) syntheses to form the organics observed in meteorites [4]. Magnetite is shown to be an effective catalyst of the synthesis of amino acids that are commonly found in meteorites [5]. It has also taken the form as spiral magnetites (a.k.a. 'plaquettes'), which were found in various carbonaceous chondrites (CCs), including C2s Tagish Lake and Esseibi, CI Orgueil, and CR chondrites [e.g., 6, 7, 8]. In addition, L-ee for amino acids are common in the aqueously altered CCs, as opposed to the unaltered CCs [1]. It seems possible that the synthesis of amino acids with chiral preferences is correlated to the alteration process experienced by the asteroid parent body, and related to the configuration of spiral magnetite catalysts. Since C-type asteroids are considered to be enriched in organic matter, and the spectral data of 1999 JU3 indicates a certain de-gree of aqueous alteration [9], the Hayabusa-2 mission serves as a perfect chance to attest this argument. In order to understand the distribution of spiral magnetites among different meteorite classes, as well as to investigate their spiral configurations and correlation to molecular asymmetry, we observed polished thin sections of CCs using scanning electron microscope (SEM) imaging. Individual magnetite grains were picked, embedded in epoxy, thin-sectioned using an ultra-microtome, and studied with electron backscatter diffraction (EBSD) in order to reconstruct the crystal orientation along the stack of magnetite disks.

Chan, Q. H. S.↗

Phyllosilicates in the Mokoia CV carbonaceous chondrite - Evidence for aqueous alteration in an oxidizing environment

Most CV chondrites contain little if any phyllosilicate mineralization. A petrographic and transmission electron microscopy study of the Mokoia CV carbonaceous chondrite shows that the matrix, chondrules, aggregates, and inclusions all contain considerable amounts of phyllosilicates. The mineralogy and occurrence of phyllosilicates in Mokoia differ from those in the CI and CM chondrites. The differences suggests that aqueous alteration of the three meteorite groups probably occurred under a variety of conditions.

Tomeoka, Kazushige↗

The Search for Surviving Direct Samples of Early Solar System Water

We have become increasingly aware of the fundamental importance of water, and aqueous alteration, on primitive solar-system bodies. All classes of astromaterials studied show some degree of interaction with aqueous fluids. Nevertheless, we are still lacking fundamental information such as the location and timing of the aqueous alteration and the detailed nature of the aqueous fluids. Halite crystals in two meteorite regolith breccias were found to contain aqueous fluid inclusions (brines) trapped approx. 4.5 BYBP. Heating/freezing studies of the aqueous fluid inclusions in these halites demonstrated that they were trapped near 25 C. The initial results of our O and H isotopic measurements on these brine inclusions can be explained by a simple model mixing asteroidal and cometary water. We have been analyzing solids and organics trapped alongside the brines in the halites by FTIR, C-XANES, SXRD and Raman, as clues to the origin of the water. The organics show thermal effects that span the entire range witnessed by organics in all chondrite types. Since we identified water-soluble aromatics, including partially halogenated methanol, in some of the halite, we suspected amino acids were also present, but have thus far found that levels of amino acids were undetectable (which is very interesting). We have also been locating aqueous fluid inclusions in other astromaterials, principally carbonates in CI and CM chondrites. Although we have advanced slowly towards detailed analysis of these ancient brines, since they require techniques right at or just beyond current analytical capabilities, their eventual full characterization will completely open the window onto the origin and activity of early solar system water.

Zolensky, Michael↗