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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9

Circumferentially-segmented collector usable with a TWT

A TWT collector has axially-positioned collector stages in which at least one of the stages includes a plurality of annularly-arranged stage segments. The collector enhances electron beam velocity sorting by facilitating a combination of (a) selecting axial electric field distributions with application of selected voltages to the axially-positioned collector stages and (b) selecting radial electric field distributions with application of selected voltages to the annularly-arranged stage segments.

Brown, II, Richard A.↗

Higher Magnification Imaging of the Polished Aluminum Collector Returned from the Genesis Mission

The polished aluminum collector (previously referred to as the polished aluminum kidney) was intended for noble gas analysis for the Gene-sis mission. The aluminum collector, fabricated from alloy 6061T, was polished for flight with alumina, then diamond paste. Final cleaning was performed by soak-ing and rinsing with hexane, then isopropanol, and last-ly megasonically energized ultrapure water prior to installation. It was mounted inside the collector canister on the thermal shield at JSC in 2000. The polished aluminum collector was not surveyed microscopically prior to flight.

Rodriquez, Melissa C.↗

Removing Contamination from Genesis Sapphire Collectors by Polishing

The Genesis Solar Wind Sample Re-turn Mission used a variety of materials as solar wind (SW) collectors. “Sapphire”, which is single crystal corundum, was ~6.7% of the collector material flown. But, a much higher percentage of Genesis sapphire collectors (SAP) survived the crash of the sample-return capsule as SAP is chemically inert, physically tough, and hard (MOHS 9, by definition). In fact, 39 sapphire fragments of bulk SW collector having areas ≥60 sq mm are available in JSC’s Genesis online catalog, whereas only 1 similarly sized silicon fragment is available (accessed 1/1/2020). In spite of the ease of accessing larger fragments, sapphire has not been popular among Genesis re-searchers because it is an electrical insulator (making SIMS more difficult) and its chemical inertness, high melting point and high hardness precludes the use of many mass-spectroscopic techniques. Recently, as alternative techniques for measuring Genesis samples are developed (e.g., synchrotron TXRF, INAA, laser ablation mass spectroscopy), more researchers are choosing to analyze sapphire. Thus, a number of researchers are actively studying how to best remove contamination from the Genesis sapphire surfaces. This report extends the task in Schmeling et al. that used polishing compounds to remove contamination from Genesis sapphire and focuses on contaminants (welded silicon, aluminum) that current chemical methods find recalcitrant.

M. Schmeling↗

Cold-Starting All-Solid-State Batteries from Room Temperature by Thermally Modulated Current Collector in Sub-Minute

All-solid-state batteries (ASSBs) show great potential as high-energy and high-power energy storage devices but their attainable energy/power density at room temperature is severely reduced because of the sluggish kinetics of lithium-ion transport. Here we first reported a thermally modulated current collector (TMCC), which can rapidly cold-start ASSBs from room temperature to operating temperatures (70–90 °C) in less than one minute, and simultaneously enhance the transient peak power density by 15-fold compared to one without heating. This TMCC is prepared by integrating a uniform, ultrathin (~200 nm) nickel layer as a thermal modulator within an ultralight polymer-based current collector. By isolating the thermal modulator from the ion/electron pathway of ASSBs, it can provide fast, stable heat control yet does not interfere with regular battery operation. Moreover, this ultrathin (13.2 μm) TMCC effectively shortens the heat transfer pathway, minimizes heat losses, and mitigates the formation of local hot spots. The simulated heating energy consumption can be as low as ~3.94% of total battery energy. This TMCC design with good tunability opens new frontiers towards smart energy storage devices in the future from the current collector perspective.

25 ENERGY STORAGE↗

twoaxistracking – a python package for simulating self-shading of two-axis tracking solar collectors

Self-shading in fields of two-axis tracking collectors typically ranges from 1% to 6% of the annual incident irradiation. It is thus essential to account for shading in order to obtain accurate yield estimates and financing for such solar projects. The present study presents the free and open-source Python package twoaxistracking for simulating self-shading in fields of two-axis tracking collectors. The package is freely available at: https://github.com/pvlib/twoaxistracking. The main steps of the method and mathematical formulation are described. Additionally, a demonstration of how to use the package is presented. The shading calculation method excels over previous methods found in the literature in that it can: handle arbitrary aperture geometries and distinguish between the total and active areas; account for sloped ground and collectors with different heights within the same field; reduce computation time by skipping calculations at high solar elevation angles.

14 SOLAR ENERGY↗

Influence of the concentration ratio on the thermal and economic performance of parabolic trough collectors

The thermal and economic performance of parabolic trough collectors (PTCs) and PTCs with double glass envelope (DGE-PTCs) are analyzed in this work. A model including thermal and optical effects is developed to evaluate the efficiency of vacuum and air-filled DGE-PTCs, while an economic model based on two commercial PTCs (SkyTrough and Ultimate Trough collectors) was developed to assess the economic performance. The efficiency and thermal output per unit cost of the proposed DGE-PTCs are analyzed as a function of the concentration ratio and are respectively compared with the thermal and economic performance of traditional and commercial PTCs. The optimum concentration ratio for maximum thermal performance varies from 11.0 to 23.3 for operation temperatures (T HTF ) between 100 degrees C and 400 degrees C, while the optimum concentration ratio for maximum economic performance ranges between 28.9 and 33.2 for the SkyTrough and between 40.0 and 43.8 for the Ultimate Trough collector designs. Finally, the DGE-PTCs present higher thermal and economic performance at high operating temperatures, which presents a valuable opportunity for implementation in new PTC designs pursuing higher operating temperatures to achieve superior thermal cycle efficiencies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A Brief History of the Curation of Genesis Sapphire Solar Wind Collectors

Commercial, high purity semiconductor sapphire (AKA corundum) wafers were used as one of the passive solar wind collector materials on the Genesis sample return mission because it exhibited lower diffusion rates for alkali elements than silicon and had sufficiently low alkali blanks. The 20 whole hexagons of sapphire flown on the Genesis spacecraft were distributed among the solar wind (SW) regimes as follows: 8 bulk solar wind (plus two half hexagons), 4 coronal mass ejection (CME), 4 coronal hole (CH), and 4 interstream (IS). Excellent overviews: a) collector material properties presented in [1] and b) solar wind environment experienced by collectors presented in [2].

Genesis sample return mission↗

Investigating the Ability of Plastic Current Collectors to Isolate Internal Shorts

Metallized plastic current collectors in Li-ion cells reduce mass and reduce the internal short circuit hazard compared to aluminum and copper foils. Shorts induced by nail and by our internal short circuit device were performed on control 18650 cells and on cells with the collectors replaced with metallized polyester and aramid films. Tests were performed inside our fractional thermal runaway calorimeter to quantify the heat transferred and its distributions and those runs done at a synchrotron yielded fascinating very high speedX-ray videography. These show tolerance to nail penetration and activation of defect internal shorts and when thermally forced into thermal runaway, the heat output is significantly reduced. Very high resolutionCT scans, cross sections, and cell tear downs give insights into the thermal and mechanism for these plastic collectors.

Plastic Current Collectors↗

Space Weathering of Genesis Mission Solar-wind Collectors with Inferences for Weathering on Airless Bodies

Samples from the Genesis Solar Wind Sample Return (NASA Discovery 5) are a unique opportunity to study the initial stages of space weathering, i.e., the physical and chemical effects of solar-wind irradiation. Arrays of collectors containing multiple materials were each exposed to a different solar-wind regime (fast, slow, bulk, or coronal mass ejection) at the L1 point for long durations (years). Materials exposed to the solar wind included metals, semiconductors, and insulators. Although the time of exposure was obviously short relative to samples having extraterrestrial origins, optical properties, surface chemical properties, and matrix structure have changed in many collectors due to exposure to solar wind. The thickness of amorphous zones, where present, appears to correspond with the depth of the peak of the solar-wind H distribution in each regime. Damage from high-energy particles was negligible because the collectors were 700 μm or less in thickness and shielded from the back by the spacecraft. Micrometeorite impacts and sputtering were also negligible because of the short exposure times. Our current results are preliminary: We hope future workers will extend this study both to support Genesis characterization efforts and to further understand space-weathering processes on a geologic timescale.

space weathering↗

In Situ Wind and Turbulence Measurements in a Field of Full-Size Parabolic Trough Solar Collectors

Concentrated Solar Power (CSP) is a promising method for using Solar power for electricity generation with thermal energy storage. One of the primary drivers of structural design costs of CSP collector structures is wind loading. To date, the design of these structures has relied on data from wind tunnels that do not adequately capture the dynamic effects observed at scale. NREL initiated a field measurement campaign at the operational Nevada Solar One (NSO) powerplant that uses parabolic troughs as solar collectors. The aim of the project is a detailed characterization of prevailing wind and turbulence conditions and resulting operational loads on parabolic troughs, providing insights on structural dynamic response, and generating a first-of-a-kind, comprehensive, high-resolution wind-loading dataset available for validating simulations of wind loading on collector structures. The measurements at NSO consist of Sonic anemometers on masts at different heights to characterize the incoming flow and conditions within and above the trough field, in combination with a Doppler Lidar scanning the horizontal plane above the troughs. The wind measurements at NSO have been continuously operating since October 2021 and provide a year-long dataset characterizing wind and turbulence conditions. The structural load measurements start in November 2022 and will complement the wind measurements. In this poster, we present first results of the wind measurement campaign by highlighting days with different atmospheric flow conditions. We identified three main factors altering the flow over the parabolic troughs: Wind speed, wind direction, and the angle of the parabolic troughs. The highest loads are expected when the wind blows perpendicular to the trough rows. In this case, the first rows experience the highest loads and block the subsequent rows, creating conditions with decreased wind speed and enhanced turbulence within the trough field. Also, turbulent length scales change. These affected conditions produce unique load cases on the structures that will be captured by the load measurements. If the wind blows along the trough rows, wind and turbulence conditions are less influenced by the troughs.

atmospheric turbulence↗

In Situ Wind and Turbulence Measurements in a Field of Full-Size Parabolic Trough Collectors

Concentrated Solar Power (CSP) is a promising method for using Solar power for electricity generation with thermal energy storage. One of the primary drivers of structural design costs of CSP collector structures is wind loading. To date, the design of these structures has relied on data from wind tunnels that do not adequately capture the dynamic effects observed at scale. NREL initiated a field measurement campaign at the operational Nevada Solar One (NSO) powerplant that uses parabolic troughs as solar collectors. The aim of the project is a detailed characterization of prevailing wind and turbulence conditions and resulting operational loads on parabolic troughs, providing insights on structural dynamic response, and generating a first-of-a-kind, comprehensive, high-resolution wind-loading dataset available for validating simulations of wind loading on collector structures. The measurements at NSO consist of Sonic anemometers on masts at different heights to characterize the incoming flow and conditions within and above the trough field, in combination with a Doppler Lidar scanning the horizontal plane above the troughs. The wind measurements at NSO have been continuously operating since October 2021 and provide a year-long dataset characterizing wind and turbulence conditions. The structural load measurements start in November 2022 and will complement the wind measurements. In this poster, we present first results of the wind measurement campaign by highlighting days with different atmospheric flow conditions. We identified three main factors altering the flow over the parabolic troughs: Wind speed, wind direction, and the angle of the parabolic troughs. The highest loads are expected when the wind blows perpendicular to the trough rows. In this case, the first rows experience the highest loads and block the subsequent rows, creating conditions with decreased wind speed and enhanced turbulence within the trough field. Also, turbulent length scales change. These affected conditions produce unique load cases on the structures that will be captured by the load measurements. If the wind blows along the trough rows, wind and turbulence conditions are less influenced by the troughs.

concentrated solar power↗

Combining 3D printing of copper current collectors and electrophoretic deposition of electrode materials for structural lithium-ion batteries

Serving as a proof of concept, additive manufacturing and electrophoretic deposition are leveraged in this work to enable structural lithium-ion batteries with load-bearing and energy storage dual functionality. The preparation steps of a complex 3D printed copper current collector, involving the formulation of a photocurable resin formulation, as well as the vat photopolymerization process followed by a precursors-based solution soaking step and thermal post-processing are presented. Compression and microhardness testing onto the resulting 3D printed copper current collector are shown to demonstrate adequate mechanical performance. Electrophoretic deposition of graphite as a negative electrode active material and other additives was then performed onto the 3D printed copper collector, with the intention to demonstrate energy storage functionality. Half-cell electrochemical cycling of the 3D multi-material current collector/negative electrode versus lithium metal finally demonstrates that structural battery components can be successfully obtained through this approach.

25 ENERGY STORAGE↗

Photoabsorption and Stability in Triple-Cation Perovskites Influenced by Interfacial Engineering of the Collector

Charge carrier dynamics in three-dimensional (3D) perovskites is critical to understand for enhancing device performance since the photoabsorption mechanism in perovskites influences key functional devices such as photodetectors and solar cells. Temperature-dependent optoelectronic transport measurements were conducted on our triple cation formulation for the first time from 4 K to 300 K to investigate the role of an interfacial Ti underlayer, beneath the conventional Au collector electrode. The photocurrent was 10X larger with the use of a Ti interfacial layer compared to only Au, where device measurements were made using a broadband white light source at room temperature. As temperature increased from 4 K, the photocurrent increased in both cases, consistent with the semiconducting nature of the triple-cation absorber. Besides computing the responsivity as a function of power and temperature, time-domain measurements with ON/OFF pulses of incident white light, showed the switching time constants to be in the tens to few hundred milliseconds range, and largely temperature-invariant for the two contacts examined. Finally, we constructed solar cells with the same triple cation absorber, in an n-i-p architecture with a Spiro-OMeTAD hole transport layer, but the collector was composed of both types of contacts. Exposing our devices to moisture-rich conditions of up to 70% relative humidity showed the Au/Ti contacted devices to be more robust. Here, our experimental results demonstrate that the addition of a Ti interlayer improves collector efficiency through the photoabsorption process while also potentially stabilizing the solar cells, compared to the bare Au, in moisture-rich environments

optoelectronics↗

Controllable Solar Flux Heating for Freeze Recovery in Molten Salt Parabolic Trough Collectors

In molten-salt parabolic trough plants, the melting process is particularly important for freeze recovery of salt that is solidified in a collector loop, should such an event occur. Currently impedance heating is expected for freeze recovery of the collector loops, but this method can be expensive. Here, a lower-cost alternative is proposed to use controllable concentrated solar flux directly from the parabolic mirrors to thaw salt that is frozen in the collector. A computational fluid dynamics model was developed to explore the solidification and melting processes of molten salt in a parabolic trough receiver and to assess the viability of this concept. Results indicate that concentrated solar heating has the potential to melt frozen salt in 5.6 h, compared to that in 8.8 h for a 300 W m –1 impedance heating system. At the same time, controllable solar flux heating introduces nonuniform solar fluxes on the receiver surface, which can induce significant thermal stress on the receiver tube. A preliminary stress analysis indicates that the temperature difference across the receiver tube should be maintained below about 70 °C for heating up to 300 °C at internal pressures ≤10 bar. At these conditions, freeze recovery using solar flux heating will not significantly affect receiver lifetime. These results suggest that controllable solar flux heating could effectively supplement or replace impedance heating in the freeze recovery system. Incorporating this methodology in future parabolic trough concentrating solar power plants is an opportunity for capital and operational cost-savings.

14 SOLAR ENERGY↗

Supercooled liquid sulfur maintained in three-dimensional current collector for high-performance Li-S batteries

In lithium-sulfur (Li-S) chemistry, the electrically/ionically insulating nature of sulfur and Li 2 S leads to sluggish electron/ion transfer kinetics for sulfur species conversion. Sulfur and Li 2 S are recognized as solid at room temperature, and solid-liquid phase transitions are the limiting steps in Li-S batteries. Here, we visualize the distinct sulfur growth behaviors on Al, carbon, Ni current collectors and demonstrate that (i) liquid sulfur generated on Ni provides higher reversible capacity, faster kinetics, and better cycling life compared to solid sulfur; and (ii) Ni facilitates the phase transition (e.g., Li 2 S decomposition). Accordingly, light-weight, 3D Ni-based current collector is designed to control the deposition and catalytic conversion of sulfur species toward high-performance Li-S batteries. This work provides insights on the critical role of the current collector in determining the physical state of sulfur and elucidates the correlation between sulfur state and battery performance, which will advance electrode designs in high-energy Li-S batteries.

25 ENERGY STORAGE↗

Wind Loading on CSP Collectors

The project significantly enhanced the community's understanding of the fundamental physics drivers underlying the wind-loading experienced by concentrating solar power (CSP) collector structures (i.e., parabolic troughs and heliostats) as well as their support structures. This project had two overarching objectives: (1) detailed measurements to characterize the prevailing wind conditions and resulting operational loads on collector structures, and (2) development and validation of a computationally efficient, high-fidelity modeling tool capable of predicting wind-loading in deep-array installations. Over three years, we conducted comprehensive at-scale field measurements of the atmospheric turbulent wind conditions, and the resulting wind loads on parabolic troughs and heliostats. Two at-scale measurement campaigns yielded first-of-its-kind, high-resolution, long-term datasets that are used to characterize the complex flow field and wind loading on parabolic-troughs and heliostats in operational power plants. The high-resolution measurements collected during these campaigns were used to validate the high-fidelity computational models developed at NREL. These open-source computationally efficient models were shown to be accurate in predicting wind-driven loads on collectors without the need for a large supercomputer.

14 SOLAR ENERGY↗

System efficiency of a microwave power tube with a multistage depressed collector

The efficiencies of a microwave power tube with a multistage depressed collector and of the power supply driving the tube are computed. An analytical expression for the collector efficiency, which includes the effect of secondary emission and the radial component of velocity, is derived for a hypothetical current probability distribution function. In addition, collector efficiency is calculated with the aid of a digital computer for a specific current distribution. The efficiency of the power supply required to operate the tube in a space environment is estimated by using a simple parallel inverter system.

Dayton, J. A., Jr.↗