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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Jaynesian Analysis of Environmental Chemistry: Systems Model Component Integration via the Arctic Aquatic Carbon Cycle

Focal Areas: All three are touched upon from the OBER call. We will consider formal logical inference and entropic information analysis for sparse but intensive chemical measurements, as optimal drivers for managing process complexity. As a centerpiece for the discussion we take soil-to-sea organic structural evolution within the Arctic hydro-geochemosphere, assessing detrital negentropy then algorithmic greed to generate ranked, reduced mechanisms for system integration.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Integration of proteomics and metabolomics into the Design, Build, Test, Learn cycle to improve 3-hydroxypropionic acid production in Aspergillus pseudoterreus

Biological engineering of microorganisms to produce value-added chemicals is a promising route to sustainable manufacturing. However, overproduction of metabolic intermediates at high titer, rate, and yield from inexpensive substrates is challenging in non-model systems where limited information is available regarding metabolic flux and its control in production conditions. Integrated multi-omic analyses of engineered strains offers an in-depth look at metabolites and proteins directly involved in growth and production of target and non-target bioproducts. Here we applied multi-omic analyses to overproduction of the polymer precursor 3-hydroxypropionic acid (3HP) in the filamentous fungus Aspergillus pseudoterreus. A synthetic pathway consisting of aspartate decarboxylase, beta-alanine pyruvate transaminase, and 3HP dehydrogenase was designed and built for A. pseudoterreus. Strains with single- and multi-copy integration events were isolated and multi-omics analysis consisting of intracellular and extracellular metabolomics and targeted and global proteomics was used to interrogate the strains in shake-flask and bioreactor conditions. Production of a variety of co-products (organic acids and glycerol) and oxidative degradation of 3HP were identified as metabolic pathways competing with 3HP production. Intracellular accumulation of nitrogen as 2,4-diaminobutanoate was identified as an off-target nitrogen sink that may also limit flux through the engineered 3HP pathway. Elimination of the high-expression oxidative 3HP degradation pathway by deletion of a putative malonate semialdehyde dehydrogenase improved the yield of 3HP by 3.4× after 10 days in shake-flask culture. This is the first report of 3HP production in a filamentous fungus amenable to industrial scale biomanufacturing of organic acids at high titer and low pH.

Pomraning, Kyle R.↗
DOE OSTI2021

The Effect of Spark-Plug Heat Dispersal Range and Exhaust Valve Opening Timing on Cold-Start Emissions and Cycle-to-Cycle Variability

The partnership for advancing combustion engines (PACE) is a US Department of Energy consortium involving multiple national laboratories and includes a goal of addressing key efficiency and emission barriers in light-duty engines fueled with a market-representative E10 gasoline. A major pillar of the initiative is the generation of detailed experimental data and modeling capabilities to understand and predict cold-start behavior. Cold-start, as defined by the time between first engine crank and three-way catalyst light-off, is responsible for a large percentage of NOx, unburned hydrocarbon and particulate matter emissions in light-duty engines. Minimizing emissions during cold-start is a trade-off between achieving faster light-off of the three-way catalyst and engine out emissions during that period. In this study, gaseous and soot emissions were measured at a distance representative of the three-way catalyst position downstream of the engine at a 2 bar net indicated mean effective pressure (NIMEP) steady-state operating condition representative of cold-start. The test matrix included sweeps of ignition timing 15 degrees-before to 10 degrees-after top dead center firing (TDCf) across three different spark-plug heat dispersal ranges (HR). Additionally, the effect of varying exhaust valve opening (EVO) timing on combustion stability and emissions was also studied. Results show that the spark plug HR affects the coefficient of variation (COV) of NIMEP under all cold-start conditions, while the impact on emissions was found to be minimal. At very retarded spark timings, colder spark plugs required higher air and fuel flow to maintain the desired 2bar NIMEP load, but the fraction of fuel energy going into the exhaust was found to be similar for all spark plugs. Finally, retarding exhaust valve timings showed a simultaneous reduction in emissions while increasing the fraction of fuel energy being fed into the exhaust. However, engine COV was also observed to increase with retarded exhaust timings.

42 ENGINEERING↗
NASA NTRS1981

Electrostatic bonding of thin (cycle sine 3 mil) 7070 cover glass to Ta2O5 AR-coated thin (cycle sine 2 mil) silicon wafers and solar cells

Electrostatic bonding of thin cover glass to thin solar cells was researched. Silicon solar cells, wafers, and Corning 7070 glass of from about 0.002" to about 0.003" in thickness were used in the investigation to establish optimum parameters for producing mechanically acceptable bonds while minimizing thermal stresses and resultant solar cell electrical parameter degradation.

Egelkrout, D. W.↗
NASA NTRS1985

Characterization of the relationship of the cure cycle chemistry to cure cycle processing properties

Dynamic dielectric analysis (DDA) is used to study curing polymer systems and thermoplastics. Measurements are made over a frequency range of six decades. This wide range of frequencies increases the amount of information which can be obtained. The data is analyzed in terms of the frequency dependence of the complex permittivity epsilon sup *, specific conductivity sigma (ohm/cm) and the relaxation time tau, parameters which are characteristic of the cure state of the material and independent of the size of the sample.

Kranbuehl, D. E.↗
NASA NTRS1985

Wilson study cycles: Research relative to ocean geodynamic cycles

The effects of conversion of Atlantic (rifted) margins to convergent plate boundaries; oceanic plateaus at subduction zones; continental collision and tectonic escape; southern Africa rifts; and global hot spot distribution on long term development of the continental lithosphere were studied.

Kidd, W. S. F.↗
NASA NTRS1990

A reverse KREBS cycle in photosynthesis: consensus at last

The Krebs cycle (citric acid or tricarboxylic acid cycle), the final common pathway in aerobic metabolism for the oxidation of carbohydrates, fatty acids and amino acids, is known to be irreversible. It liberates CO2 and generates NADH whose aerobic oxidation yields ATP but it does not operate in reverse as a biosynthetic pathway for CO2 assimilation. In 1966, our laboratory described a cyclic pathway for CO2 assimilation (Evans, Buchanan and Arnon 1966) that was unusual in two respects: (i) it provided the first instance of an obligate photoautotroph that assimilated CO2 by a pathway different from Calvin's reductive pentose phosphate cycle (Calvin 1962) and (ii) in its overall effect the new cycle was a reversal of the Krebs cycle. Named the 'reductive carboxylic acid cycle' (sometimes also called the reductive tricarboxylic acid cycle) the new cycle appeared to be the sole CO2 assimilation pathway in Chlorobium thiosulfatophilum (Evans et al. 1966) (now known as Chlorobium limicola forma thiosulfatophilum). Chlorobium is a photosynthetic green sulfur bacterium that grows anaerobically in an inorganic medium with sulfide and thiosulfate as electron donors and CO2 as an obligatory carbon source. In the ensuing years, the new cycle was viewed with skepticism. Not only was it in conflict with the prevailing doctrine that the 'one important property ... shared by all (our emphasis) autotrophic species is the assimilation of CO2 via the Calvin cycle' (McFadden 1973) but also some of its experimental underpinnings were challenged. It is only now that in the words of one of its early skeptics (Tabita 1988) 'a long and tortuous controversy' has ended with general acceptance of the reductive carboxylic acid cycle as a photosynthetic CO2 assimilation pathway distinct from the pentose cycle. (Henceforth, to minimize repetitiveness, the reductive pentose phosphate cycle will often be referred to as the pentose cycle and the reductive carboxylic acid cycle as the carboxylic acid cycle.) Aside from photosynthetic pathways which are the focus of this article, CO2 assimilation is also known to sustain autotrophic growth via the acetyl-CoA pathway (Wood et al. 1986). Our aim here is to discuss (i) the findings that led our group to the discovery of the reductive carboxylic acid cycle, (ii) the nature and resolution of the controversy that followed, and (iii) the possible evolutionary implications of the cycle as an ancient mechanism for photosynthetic CO2 assimilation that preceded the pentose cycle and served as a precursor of the Krebs cycle in aerobic metabolism.

Non-NASA Center↗
NASA NTRS2007

Anticipating Cycle 24 Minimum and Its Consequences

On the basis of the 12-mo moving average of monthly mean sunspot number (R) through November 2006, cycle 23 has persisted for 126 mo, having had a minimum of 8.0 in May 1996, a peak of 120.8 in April 2000, and an ascent duration of 47 mo. In November 2006, the 12-mo moving average of monthly mean sunspot number was 12.7, a value just outside the upper observed envelope of sunspot minimum values for the most recent cycles 16-23 (range 3.4-12.3), but within the 90-percent prediction interval (7.8 +/- 6.7). The first spotless day during the decline of cycle 23 occurred in January 2004, and the first occurrence of 10 or more and 20 or more spotless days was February 2006 and April 2007, respectively, inferring that sunspot minimum for cycle 24 is imminent. Through May 2007, 121 spotless days have accumulated. In terms of the weighted mean latitude (weighed by spot area) (LAT) and the highest observed latitude spot (HLS) in November 2006, 12-mo moving averages of these parameters measured 7.9 and 14.6 deg, respectively, these values being the lowest values yet observed during the decline of cycle 23 and being below corresponding mean values found for cycles 16-23. As yet, no high-latitude new-cycle spots have been seen nor has there been an upturn in LAT and HLS, these conditions having always preceded new cycle minimum by several months for past cycles. Together, these findings suggest that cycle 24 s minimum amplitude still lies well beyond November 2006. This implies that cycle 23 s period either will lie in the period "gap" (127-134 mo), a first for a sunspot cycle, or it will be longer than 134 mo, thus making cycle 23 a long-period cycle (like cycle 20) and indicating that cycle 24 s minimum will occur after July 2007. Should cycle 23 prove to be a cycle of longer period, a consequence might be that the maximum amplitude for cycle 24 may be smaller than previously predicted.

Wilson, Robert M.↗
NASA NTRS1984

A comparative look at sunspot cycles

On the basis of cycles 8 through 20, spanning about 143 years, observations of sunspot number, smoothed sunspot number, and their temporal properties were used to compute means, standard deviations, ranges, and frequency of occurrence histograms for a number of sunspot cycle parameters. The resultant schematic sunspot cycle was contrasted with the mean sunspot cycle, obtained by averaging smoothed sunspot number as a function of time, tying all cycles (8 through 20) to their minimum occurence date. A relatively good approximation of the time variation of smoothed sunspot number for a given cycle is possible if sunspot cycles are regarded in terms of being either HIGH- or LOW-R(MAX) cycles or LONG- or SHORT-PERIOD cycles, especially the latter. Linear regression analyses were performed comparing late cycle parameters with early cycle parameters and solar cycle number. The early occurring cycle parameters can be used to estimate later occurring cycle parameters with relatively good success, based on cycle 21 as an example. The sunspot cycle record clearly shows that the trend for both R(MIN) and R(MAX) was toward decreasing value between cycles 8 through 14 and toward increasing value between cycles 14 through 20. Linear regression equations were also obtained for several measures of solar activity.

Wilson, R. M.↗
NASA NTRS1997

Gauging the Nearness and Size of Cycle Minimum

By definition, the conventional onset for the start of a sunspot cycle is the time when smoothed sunspot number (i.e., the 12-month moving average) has decreased to its minimum value (called minimum amplitude) prior to the rise to its maximum value (called maximum amplitude) for the given sunspot cycle. On the basis (if the modern era sunspot cycles 10-22 and on the presumption that cycle 22 is a short-period cycle having a cycle length of 120 to 126 months (the observed range of short-period modern era cycles), conventional onset for cycle 23 should not occur until sometime between September 1996 and March 1997, certainly between June 1996 and June 1997, based on the 95-percent confidence level deduced from the mean and standard deviation of period for the sample of six short-pei-iod modern era cycles. Also, because the first occurrence of a new cycle, high-latitude (greater than or equal to 25 degrees) spot has always preceded conventional onset of the new cycle by at least 3 months (for the data-available interval of cycles 12-22), conventional onset for cycle 23 is not expected until about August 1996 or later, based on the first occurrence of a new cycle 23, high-latitude spot during the decline of old cycle 22 in May 1996. Although much excitement for an earlier-occurring minimum (about March 1996) for cycle 23 was voiced earlier this year, the present study shows that this exuberance is unfounded. The decline of cycle 22 continues to favor cycle 23 minimum sometime during the latter portion of 1996 to the early portion of 1997.

Wilson, Robert M.↗
NASA NTRS1997

Solar Cycle Predictions Near Sunspot Minimum

Observations of solar magnetic activity and the dynamics of the solar convection zone have produced severe constraints on models of the Sun's magnetic dynamo. These constraints are so severe that, at present, we do not have numerical models that can accept the current conditions and then march forward in time to predict future activity. Given this state of solar dynamo theory we are forced to examine previous behavior to discover patterns and trends that afford us some measure of predictability. Here we examine the behavior of several indicators of solar activity near solar minimum that are well correlated with the amplitude of the following solar maximum to predict the level of solar activity over cycle 23. Sunspot numbers, areas, and positions are useful for characterizing solar cycle behavior due to the extent of the data (12 cycles or more). These data exhibit several patterns that relate future activity to past behavior. With the Odd-Even effect the odd numbered cycles have been larger than their even numbered predecessors for each of the last six cycle pairs. With the Amplitude-Period effect short period cycles have been followed by large amplitude cycles and long period cycles have been followed by small amplitude cycles for 10 of the last 13 cycles. With the Maximum-Minimum effect the sunspot number at minimum is directly correlated with the sunspot number at maximum for a given cycle. The geomagnetic indices aa and Ap are also related to solar activity by the connections between disturbances in the solar wind and variations in the Earth's magnetic field. Like the Maximum-Minimum effect for sunspots, the size of the aa and Ap indices at minimum are directly related to the amplitude of the following maximum. The number of geomagnetically disturbed days (days with Ap >= 25) over the course of a cycle is another indicator for the size of the next cycle. The aa and Ap indices can each be separated into a component in phase with the current sunspot cycle and an "extended cycle" component that is directly related to the following cycle. Individually each of these indicators provides some measure of predictive ability for the amplitudes of previous cycles. Taken in combination we find that the predictions are much more accurate. Our multi-variate analysis indicates that a maximum sunspot number of 160 +/- 20 should occur near the end of 1999 for cycle 23.

Hathaway, David H.↗