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At least 163 records · Page 9
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

FY24 Task 5: Leachate Disposition

Directly feeding sludge solids to the high-level waste (HLW) Waste Treatment Plant represents an alternative flowsheet seeking to initiate sludge processing as soon as possible. Key processing functions previously captured during baseline pretreatment operations include leaching and washing prior to solids concentration. These operations should be considered in the potential direct feed flowsheets to maximize waste feed loading, minimize HLW volume, and mitigate corrosion challenges associated with vitrification of high phosphate and fluoride concentrations. Additionally, single-shell tank (SST) retrievals and waste transfers to double-shell tanks (DSTs) in a direct feed flowsheet would likely also benefit from some level of leaching, washing, and solids concentration in order to reduce DST space and mission duration. These operations could occur in a new facility or potentially in available DSTs. If washing and leaching are utilized, an effective disposition pathway for the wash water and leachate solutions are needed. Three target species that benefit significantly from leaching and washing are phosphate, fluoride and aluminum. Phosphate (PO 4 3- ) and fluoride (F - ) can contribute substantially to the amount of carrier fluid needed for dissolution, and the resulting volume of liquid generated. Disposition of this retrieval solution should be evaluated in order to prevent crystallization of these anions throughout system processing. Since there is a high probability that any retrieval solutions will be at or near their PO 4 3- and F - solubility limits, evaporation or blending with a high Na supernate (>3.5 M) is not recommended for the wash water streams without a method to remove precipitants prior to solution disposal. Additionally, aluminum present in the southeast quadrant of the Hanford site represents roughly 60% of the waste solids in the initial processing tanks. These aluminum solids are in the form of gibbsite (Al(OH) 3 ) and can pose significant challenges for processing due to the fast-settling times and high solids loading associated with these materials. Easily remediated by caustic addition to the solids, these wash solutions could be processed through crystalline silicotitanate (CST) ion exchange columns to prepare the supernate solutions for disposition. The current target for feed conditions to the Low Activity Waste (LAW) melter are waste streams that contain nominally 5-6 M Na. Fractions within the tanks contain upwards of 0.2 M phosphate and fluoride in solution at 3.5 M Na. Concentrating these solutions above 5 M Na would result in an exceedance of the solubility limits, and potential for uncontrolled precipitation of the phosphate and fluoride crystal material. The resulting crystalline salt material is typically sodium fluoride phosphate, also referred to as natrophosphate (Na 7 FPO 4 ·19H 2 O). Salt phases are of importance in tank waste due to their chemical reactivity, which can result in precipitation, dissolution, or transformation, impacting any downstream processes (Bolling et al. 2020, Russell, Snow, and Peterson 2010). Salt generation and precipitation could pose challenges by causing system plugging and melter corrosion if left in the supernate stream, or limit sodium molarity of the supernate that would be accepted without incident in waste operations. To understand the impact of this salt generation, the crystallization of natrophosphate in multiple simulant feed matrices was studied to understand the implications of various tank waste supernate chemistries. Three matrices were examined: high PO 4 3- /low F - , low PO 4 3- /high F - , and an average matrix. Subsequent testing was performed with the average matrix with the inclusion of CsNO 3 , and a final run with the average matrix including CsNO 3 and a 137 Cs spike for tracer purposes.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2026

Cathodic Protection Modeling for Hanford Underground Double-Shell Tank Farms

Hanford stores millions of gallons of radioactive and chemically hazardous waste from the production of weapon materials in tank farms consisting of underground carbon-steel storage tanks surrounded by reinforced concrete. Six of these Hanford tank farms use double-shell storage tanks (DSTs). The DST farms were constructed from 1968 to 1986 with a planned 40–50 year design life, so some are already operating beyond their initial life expectancy. Ultrasonic testing (UT) has indicated significant thinning on the bottom of the secondary (outer) liner of these tanks, believed to arise from groundwater intrusion driving concrete side corrosion. There is no direct access to the steel/concrete interface between the tank and the concrete pad, making it difficult to apply a chemical-based mitigation strategy or to conduct repairs, but cathodic protection (CP) is a possible method to inhibit further concrete-side corrosion. Hanford already uses CP to protect below grade steel piping within the tank farms and connected to the tanks, but this system was not designed to protect the tank bottoms. CP design must account for the structures surrounding the DSTs, including the steel reinforcing bars (rebar) within the concrete pad and vault, various process lines, and the existing CP system. In this study, finite element analysis (FEA) modeling was carried out to simulate CP protection of 1) a single tank and CP anode to develop options for modeling the rebar and to compare to a simpler circuit model and 2) the entire Hanford AN tank farm as a representative example consisting of seven tanks, associated piping, and both existing and new CP anodes. Both circuit and FEA models predict that significant protective current could be delivered to the bottoms of the tanks with the addition of tank-protection anodes below the depth of the tanks. Simulations with only the existing pipe-protection anodes active confirmed that only a very small current to the tank bottoms is predicted under present conditions. Multiple simplified representations of the dome and wall rebar were tested to reduce the computational complexity of the tank-farm simulations, resulting in modeling the rebar as edge elements with a prescribed effective circumference that matches the real rebar surface area. The geometry of the rebar is also simplified into horizontal hoops around the tank walls and radial rebar over the dome with increased effective circumference to retain the target surface area. This simplification was found to greatly reduce the complexity and solution time of the models without large changes in current distributions, especially to the tank bottom. A range of values were tested for model parameters such as soil and concrete resistivities and polarization resistance to investigate their impact on the current and electric potential distributions. Depending on the parameters used, FEA simulations predict some risk of overprotection, particularly on the piping system; since overprotection can also lead to surface damage associated with hydrogen gas generation at the interface (e.g. hydrogen embrittlement or damage to coatings), this needs to be considered when refining the design of the new CP system. Comparison between the FEA models and the circuit model representation demonstrated that the circuit model could not match the predicted FEA current distribution, even when using the exact same surface areas. This discrepancy appeared to be at least partly attributable to the impact of the relative positions of the tank components and anodes to each other and to the ground surface. The FEA model accounts for the relative positions since it solves the governing equations in three dimensions, but the circuit model cannot account for the positioning. In particular, the circuit model underpredicts the current to the tank bottom and overpredicts the current to the dome compared to FEA for the baseline geometry. The FEA models omitted the electrically isolated rebar in the bottom concrete slab. However, a circuit based stray current model estimated that only 2.1% of the total current through the slab would stray into the rebar, corresponding to ~0.21 A for a target current density of 2 mA/ft2 to the tank bottom. The estimated corrosion driven by this amount of stray current is predicted to yield a lifetime of >400 years for the minimum rebar diameter, assuming an acceptable cross-section area loss of 10%.

d'Entremont, Anna [Savannah River National Laborat↗
DOE OSTI2025

Raw ERCOT 60-Day SCED Disclosure Reports

This dataset contains ERCOT plant-level wind power production data at a 15-minute time resolution. Data at ERCOT are called 60-Day SCED Disclosure Report; data product number NP3-965-ER. Raw data are in local time. DST is handled as "skip hour" (12a, 1a, 3a,...) in spring, "extra hour" (12a, 1a, 2a, 2a, 3a,...) in fall.

17 WIND ENERGY↗
NASA NTRS1972

Frequency dependence of ATS-1 observed micropulsations of some geophysical parameters

Low frequency oscillations in the earth's magnetic field at the synchronous orbit were observed with the magnetometer experiment on board the ATS 1 satellite since Dec. 1966. An analysis of oscillations in the range .002 f .02 H3 for the interval Dec. 1966 through Dec. 1968 is reported. It was found that the frequency of an event increases with the sum of Kp for 24 hours prior to the event midpoint. For events with duration greater than 6 hours, the product moment correlation coefficient for frequency f, and the sum Kp was R = 0.87. The best least squares linear fit to the data for these events was f = (0.32) sum Kp = 5.1. For the same events the correlation coefficient for frequency and Dst was R = -0.83.

Mason, F.↗
NASA NTRS1972

Ogo 5 observations of LHR noise, emissions, and whistlers near the plasmapause at several earth radii during a large magnetic storm.

On May 15, 1969, Ogo 5 crossed the plasmapause during a major storm that produced severe geomagnetic disturbances (Kp up to 8-), large and rapid variations in ring-current intensity (as measured by Dst), intense low-latitude aurora, and persistent SAR arcs. Near the highly structured plasmasphere boundary, the electric- and magnetic-field sensors on Ogo 5 detected lower-hybrid-resonance noise bursts, whistlers, ELF hiss, and other discrete signals or emissions. Some LHR noise bursts were associated with whistlers, and these high-altitude phenomena resembled the corresponding ionospheric ones. This report contains a description of the VLF observations. We also show that intense ULF magnetic signals were present near the plasmapause, and we attempt to relate these observations to the predictions of various theories of proton ring-current decay and SAR-arc formation.

Scarf, F. L.↗
NASA NTRS1972

Quiet-time magnetospheric field depression at 2.3 to 3.6 R sub E

Fluxgate magnetometer data obtained by OGO-5 near perigee were used to establish the existence of large field depressions in the magnetosphere under conditions of varying degree of disturbance at distances ranging from 2.3 to 3.6 R sub E at all local times. The results also provide the average delta B at these distances when Dst, as being derived at present, is zero.

Sugiura, M.↗
NASA NTRS1973

Geophysical disturbance environment during the NASA/MPE barium release at 5 earth radii on September 21, 1971.

The geophysical disturbance environment was quiet during the NASA/MPE barium release at 5 earth radii on September 21, 1971. At the time of the release, the magnetosphere was in the late recovery phase of a principal magnetic storm, the provisional Dst value was -13 gammas, and the local horizontal disturbance at Great Whale River was near zero. Riometer and other observations indicated low-level widespread precipitation of high-energy electrons at Great Whale River before, during, and after the release. Cloudy sky at this station prevented optical observation of aurora. No magnetic or ionospheric effects attributable to the barium release were detected at Great Whale River.

Davis, T. N.↗
NASA NTRS1974

Study of low frequency hydromagnetic waves using ATS-1 data

An analysis was made of ATS-1 data to determine at what point in the magnetic storm recovery phase are oscillations most likely to begin. The catalog of hourly values of equatorial Dst was used to determine the time of main phase decrease, and a catalog of oscillations from January to May 1968 to determine onset time as observed by ATS-1. For each oscillation event at ATS-1, the nearest prior main phase decrease with a magnitude of at least -35 gamma was determined, and the time difference between the onset of the event at ATS-1 and the time of main phase decrease was measured. The resulting data indicate that the most probable time to observe onset of transverse oscillations is within 24 hours after the main phase decrease.

Cummings, W. D.↗
NASA NTRS1974

Isolated cold plasma regions: Observations and their relation to possible production mechanisms

Regions of enhanced cold plasma, isolated from the main plasmasphere along the Explorer 45 orbit on the equatorial plane, are reported using the sheath induced potentials seen by the electric field experiment. The occurrence of these regions has a strong correlation with negative enhancements of Dst, and their locations are primarily in the noon-dusk quadrant. The data support the concept that changes in large scale convection play a dominant role in the formation of these regions. Plasmatails that are predicted from enhancements of large scale convection electric fields in general define where these regions may be found. More localized processes are necessary to account for the exact configuration and structure seen in these regions and may eventually result in detachment from the main plasmasphere.

Maynard, N. C.↗
NASA NTRS1973

Equatorward shift of the cleft during magnetospheric substorms as observed by Isis 1

Isis 1 satellite observations of the cleft position during magnetospheric substorms show that the cleft shifts equatorward as the interplanetary B sub z component turns southward and substorm activity increases and that it shifts back toward higher latitudes as substorm activity subsides and B sub z returns northward. Also, unusually low latitudes for the cleft (less than 70 deg invariant latitude) were found during geomagnetic storms with significant Dst values and large negative B sub z values. Significant shifts occur in the cleft location with no accompanying effect seen in the AE index; however, B sub z is observed to be southward during these periods.

Yasuhara, F.↗
NASA NTRS1974

On correlation analysis of the Explorer 12 substorm protons with some geophysical parameters

The intensity of Explorer-12 substorm protons with energies above 140 keV observed in the far outer belt are compared with several commonly used geomagnetic indices. The parameters considered in the correlation include Davis and Sugiura's (1966) AE index that provides a measure of the magnitude of substorm intensity, the asymmetric ring-current index R(DS) that is obtained from nine low-latitude stations, Sugiura and Hendricks' (1967) Dst index representing the symmetric component of the ring current, and the planetary magnetic index Kp.

Su, S.-Y.↗
NASA NTRS1975

A study of geomagnetic storms

Twenty-one geomagnetic storm events during 1966 and 1970 were studied by using simultaneous interplanetary magnetic field and plasma parameters. Explorer 33 and 35 field and plasma data were analyzed on large-scale (hourly) and small-scale (3 min.) during the time interval coincident with initial phase of the geomagnetic storms. The solar-ecliptic Bz component turns southward at the end of the initial phase, thus triggering the main phase decrease in Dst geomagnetic field. When the Bz is already negative, its value becomes further negative. The By component also shows large fluctuations along with Bz. When there are no clear changes in the Bz component, the By shows abrupt changes at the main phase onet. On the small-scale behavior of the magnetic field and electric field (E=-VxB) studied in details for the three events, it is found that the field fluctuations in By, Bz and Ey and Ez are present in the initial phase. These fluctuations become larger just before the main phase of the storm begins. In the largescale behavior field remains quiet because the small scale variations are averaged out.

Patel, V. L.↗
NASA NTRS1975

Interplanetary field and plasma during initial phase of geomagnetic storms

Twenty-three geomagnetic storm events during 1966 to 1970 were studied by using simultaneous interplanetary magnetic field and plasma parameters. Explorer 33 and 35 field and plasma data were analyzed on large-scale (hourly) and small-scale (3 min.) during the time interval coincident with the initial phase of the geomagnetic storms. The solar-ecliptic Bz component turns southward at the end of the initial phase, thus triggering the main phase decrease in Dst geomagnetic field. The By component also shows large fluctuations along with Bz. When there are no clear changes in the Bz component, the By shows abrupt changes at the main phase onset. On the small-scale, behavior of the magnetic field and electric field were studied in detail for the three events; it is found that the field fluctuations in By, Bz and Ey and Ez are present in the initial phase. In the large-scale, the behavior field remains quiet because the small-scale variations are averaged out. It appears that large as well as small time scale fluctuations in the interplanetary field and plasma help to alter the internal electromagnetic state of the magnetosphere so that a ring current could causing a geomagnetic storm decrease.

Patel, V. L.↗
NASA NTRS1974

Magnetic storm dynamics of the thermosphere

A theoretical study of the Dst component of magnetic storms is presented. The dynamic characteristics are found significantly different for Joule dissipation and electron precipitation, leading to the conclusion that the former is probably the predominant heat source for the upper thermosphere. Composition measurements on OGO-6, which reveal markedly different characteristics in N2, O and He, can be explained on the basis of energy advection and diffusive mass transport by thermospheric winds. Essential features in the F2-region response are explicable in terms of these dynamic processes. Electric field induced motions are estimated and it is concluded that resultant adiabatic heating could be significant.

Mayr, H. G.↗
NASA NTRS1974

Time response simulation of the 1975 Viking Orbiter digital tape recorder

The objective of the present study was to verify and understand in depth the performance of the speed control (frequency loop) servo of the 1975 Viking Orbiter (VO75) digital tape recorder (DTR). The time response method employed is written in the continuous system simulation language (CSSL) for the Univac 1108 computer system. In order to demonstrate the power and flexibility of the graphic interactive simulation program, four aspects of system dynamics are interactively adjusted to arrive at a number of stable system configurations that have significantly different tape transport and/or summing amplifier gain, larger static/dynamic Coulomb friction, and different system lag than envisioned in the nominal design by linear methods. Work is currently underway to derive a new higher-order DST transfer function and to simulate the servo using state-space variable techniques.

Mukhopadhyay, A. K.↗
NASA NTRS1974

Analysis of data from spacecraft relating to stratospheric warmings

A detailed study of six different stratospheric warmings is described which establishes that the magnetic indices AE, Ap, and Dst display a marked increase 1 to 3 days before warming phenomena and a marked decrease at 0 and -4 days. The definite correlation of the warming phenomena with the AE index indicates that the auroral electrojet joule heating near 100 km may be the original source of the heating that influences the atmosphere at 50 km and below. Whether this heating is the primary cause or trigger of stratospheric warmings remains to be determined.

Weiss, R.↗
NASA NTRS1975

Quiet time inflation of the inner magnetosphere in the afternoon and evening quadrants

The quiet-time depression of the magnetic field magnitude in the equatorial inner magnetosphere was studied for the interval Nov. 1971-June 1972. For periods when Kp was less than 2 and Dst was between +10 and -20 gamma, an inflated field region near the magnetic equator was found between noon and midnight. The inflation was greatest at the lowest altitude studied (L = 3) and appeared to be somewhat greater near midnight (-40 gamma) than near noon (-20 gamma). Protons of energy above 100 keV observed on the same satellite appeared to be sufficient to produce the quiet-time inflation.

Lee, Y. C.↗
NASA NTRS1975

Isolated cold plasma regions - Observations and their relation to possible production mechanisms

Regions of enhanced cold plasma, isolated from the main plasmasphere along the Explorer 45 (53-A) orbit in the equatorial plane, have been detected by using the sheath-induced potentials seen by the electric field experiment. The occurrence of these regions has a strong correlation with negative enhancements of Dst, and their locations are primarily in the noon-dusk quadrant. The data support the concept that changes in large-scale convection play a dominant role in the formation of these regions. Plasma tails that are predicted from enhancements of large-scale convection electric fields in general define where these regions may be found. More localized processes are necessary to account for the exact configuration and structure seen in these regions and may eventually result in detachment from the main plasmasphere.

Maynard, N. C.↗